• Resources Recycling
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• v.7 no.2
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• pp.16-22
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• 1998

Recently, the new technology for the recycling of waste plastics as an alternative he1 of blast furnace ha been developed. In this shldy, the test of plastics injection into a tuyere af the foundry blast furnace were carried out. The injection rate of plastics far this tcst facility war expressed as follows, ${W}_{s}=0.265\frac{{delta}PA}{U}_{g}$, where. Ws, AP, A and Ug are plastic conveying ratc (kgisec), pressure drop between feed hopper and blaqt pressure (alm), cross sectional area of conveying pipe (mi) and superficial velocity of transport air (mhzc) respcctiuely. From the results of semi-continuous test operation during 96 hours, the replacement raho mned out to be 1.38 according to the injection rate of 6. 4 kg-plasticsit-p. With increasing the rate of plaslics injcchon, the content of hydrogen in top gas became increased and the brick temperahlre at bzlly was also increased due to Lhe changes ot the combustion zone shape.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.15 no.5
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• pp.3351-3356
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• 2014

Recently, Importance of studying based on biomass materials have increased due to the concern about plastic waste problems. Cellulose acetate butyrate (CAB) is a potential alternative to petroleum-based plastics because of its biodegradable property. Poly(ethylene-co-isosorbide terephthalate) (PEIT) is bio-based plastic, produced by isosorbide monomer. In this study, CAB/PEIT blends were prepared by solution blending to improve thermal stability of CAB. CAB and PEIT were dissolved in chloroform, and then precipitated in ethanol. To evaluate the compatibility of CAB/PEIT blends, the morphology and glass transition behaviors were analyzed by FE-SEM and DMA, respectively. TGA results revealed the improved thermal stabilities of the PEIT-rich and 50:50 compositions. No new or changed crystal structures were observed in the XRD result. Finally, CAB/PEIT solution blends showed good compatibility in overall compositions.

• Journal of dental hygiene science
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• v.22 no.4
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• pp.241-248
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• 2022

Background: Plastic waste generates pollutants in the process of incineration or landfilling, and accumulates in water or marine organisms, causing adverse effects on the environment and the human body. Recently, various eco-friendly oral hygiene products (Eco-OHPs) such as bamboo toothbrushes and biodegradable plastic toothbrushes have been developed. Therefore, this study aimed to investigate the current level of awareness and purchasing status of eco-OHPs among adults who are interested in eco-friendly products. Methods: This study included adults aged >19 years who regularly visited eco-friendly shops and online sites; the online survey links were distributed during their visits to eco-friendly Internet cafés and companies. Of the 22 questions, seven assessed the participants' general characteristics, three assessed the general oral hygiene care products used, six assessed the level of awareness of Eco-OHPs, and six assessed the purchasing status of Eco-OHPs. Frequency analysis, chi-square test, and regression analysis were performed using SPSS software. Results: Among the respondents, 108 (51.4%) were aware of Eco-OHPs, and 79 (37.6%) had experience purchasing Eco-OHPs. The most common reason for not purchasing was the lack of information about related brands or products (74, 56.5%). The most common platform used in obtaining information was the Internet (general: 31.5%, eco-friendly: 46.3%), such as Social Network Service, Internet cafes, and blogs. The experience in purchasing Eco-OHPs was affected by whether the respondents recognized the possibility of contributing to environmental preservation, availability of vendors, product safety, and the number of eco-friendly products purchased. Conclusion: In order to expand the use of Eco-OHPs, various efforts such as promotion of eco-friendly characteristics, determination of related vendors, reliable analysis of product safety, and expansion of product experience opportunities are required.

• New & Renewable Energy
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• v.18 no.4
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• pp.12-21
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• 2022

The pyrolysis characteristics of high-density polyethylene (HDPE), low-density polyethylene (LDPE), and polypropylene (PP) were analyzed numerically using a 1D plug flow reactor (PFR) model. A lumped kinetic model was selected to simplify the pyrolysis products as wax, oil, and gas. The simulation was performed in the 400-600℃ range, and the plastic pyrolysis and product generation characteristics with respect to time were compared at various temperatures. It was found that plastic pyrolysis accelerates rapidly as the temperature rises. The amounts of the pyrolysis products wax and oil increase and then decrease with time, whereas the amount of gas produced increases continuously. In LDPE pyrolysis, the pyrolysis time was longer than that observed for other plastics at a specified temperature, and the amount of wax generated was the greatest. The maximum mass fraction of oil was obtained in the order of HDPE, PP, and LDPE at a specified temperature, and it decreased with temperature. Although the 1D model adopted in this study has a limitation in that it does not include material transport and heat transfer phenomena, the qualitative results presented herein could provide base data regarding various types of plastic pyrolysis to predict the product characteristics. These results can in turn be used when designing pyrolysis reactors.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.34 no.4
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• pp.1227-1240
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• 2014

Abandoned mines often cause environmental problems, such as alteration of landscape, metal contamination, and landslides due to a heavy rainfall. Geotechnical and rheological tests were performed on waste materials corrected from Imgi waste rock dump, located in Busan Metropolitan City. Debris flow mobility was examined with the help of 1-D BING model which was often simulated in both subaerial and subaqueous environments. To determine flow curve, we used a vane-penetrated rheometer. The shear stress (${\tau}$)-shear rate (${\dot{\gamma}}$) and viscosity(${\eta}$)-shear rate (${\dot{\gamma}}$) relationships were plotted using a shear stress control mode. Well-known rheological models, such as Bingham, bilinear, Herschel-Bulkley, Power-law, and Papanastasiou concepts, were compared to the rheological data. From the test results, we found that the tested waste materials exhibited a typical shear shinning behavior in ${\tau}$-${\dot{\gamma}}$ and and ${\eta}$-${\dot{\gamma}}$ plots, but the Bingham behavior is often observed when the water contents increased. The test results show that experimental data are in good agreement with rheological models in the post-failure stage during shearing. Based on the rheological properties (i.e., Bingham yield stress and viscosity as a function of the volumetric concentration of sediment) of waste materials, initial flowing shape (5 m, 10 m, and 15 m) and yield stress (100 Pa, 200 Pa, 300 Pa, and 500 Pa) were input to simulate the debris flow motion. As a result, the runout distance and front velocity of debris flow are in inverse propositional to yield stress. In particular, when the yield stress is less than 500 Pa, most of failed masses can flow into the stream, resulting in a water contamination.

• Journal of the Korean Recycled Construction Resources Institute
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• v.10 no.3
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• pp.276-284
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• 2022

In this study, performance evaluation and rheological characteristics were analyzed for recycling the fine powder of nuclear power plant dismantled waste concrete as a solidifying agent for radioactive waste disposal. The radioactive concrete fine powder was used to prepare a simulated sample, and the test specimen was prepared using Di-water, CoCl₂, and 1 mol CsCl aqueous solution as mixing water. Regardless of the aggregate mixing ratio and the type of mixing water, it satisfies the performance standard of 3.45 MPa for compressive strength at 28 days of age. All specimens satisfied the criteria for submersion strength, and the thermal cycle compressive strength satisfies the criteria for all specimens except Plain-50. As a result of evaluating the rheological properties of the solidifying agent, it was found that the increase in the aggregate mixing rate decreased the yield stress and plastic viscosity. The leaching index for cobalt and cesium of all specimens was 6 or higher, which satisfies the standard. In order to secure the stable performance of the solidifying agent, it is considered effective to use 40 % or less of the aggregate component in the solidifying agent.

• Journal of Energy Engineering
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• v.19 no.4
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• pp.221-227
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• 2010

In this study, we consider gas generation characteristics on pyrolysis of eco-fuel which were made by mixing of Pitch Pine and Lauan sawdust as biomass and polyethylene, polypropylene, polystyrene as municipal plastic wastes with catalyst in fixed bed reactor. From the result of higher heating value(HHV) measurement and of ultimate analysis, the heating value of plastic wastes and a hydrogen content in plastic sample are higher than biomass. An activation energy was reduced by a catalyst addition. However the catalyst content influence over 5 wt% was insignificant. The yield of hydrogen from gasification of biomass containing plastic wastes such as polyethylene, polypropylene and polystyrene were obtained higher than that of sole biomass. The high temperature and mixture ratio of catalyst conditions induced to high hydrogen yield in most of the samples. As the influence of catalyst, the hydrogen yield by catalytic reaction was higher than non-catalytic reaction. We confirmed that Ni-$ZrO_2$ catalyst is more active in increasing the hydrogen yield in comparison with that of carbonate catalyst. The maximum hydrogen yield was 65.9 vol.%(Pitch Pine / polypropylene / 20 wt.% Ni-$ZrO_2$(1:9) at $900^{\circ}C$).

• Journal of Powder Materials
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• v.25 no.3
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• pp.203-207
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• 2018

Plastic pollution is threatening human health and ecosystems, resulting in one of the biggest challenges that humanity has ever faced. Therefore, this study focuses on the preparation of macroporous carbon from biowaste (MC)-supported manganese oxide ($MnO_2$) as an efficient, reusable, and robust catalyst for the recycling of poly(ethylene terephthalate) (PET) waste. As-prepared $MnO_2/MC$ composites have a hierarchical pore network and a large surface area ($376.16m^2/g$) with a narrow size distribution. $MnO_2/MC$ shows a maximum yield (98%) of bis(2-hydroxyethyl)terephthalate (BHET) after glycolysis reaction for 120 min. Furthermore, $MnO_2/MC$ can be reused at least nine times with a negligible decrease in BHET yield. Based on this remarkable catalytic performance, we expect that $MnO_2$-based heterogeneous catalysts have the potential to be introduced into the PET recycling industry.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.22 no.5
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• pp.627-639
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• 1998

A combustion model for the incineration of municipal solid waste(MSW) in the stoker type incinerator was developed by considering the variation of physical composition of MSW. Theoretical analysis and numerical simulation for the combustion characteristics in incinerator were conducted by using the present model and the effects of compositional variation on the incineration characteristics of MSW was examined theoretically. It is found that large excess air enhances drying, but depresses volatilization. For the large value of moisture content, pyrolysis is fast but drying is slow. As the value of plastic content increases, devolatilization becomes slower. Larger amount of primary air supply to the rear side of stoker leads to increase the possibility of delaying the combustion.

• 한국신재생에너지학회:학술대회논문집
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• 2005.11a
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• pp.423-435
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• 2005

본 연구는 PVC를 포함한 혼합플라스틱을 연료화하는데 있어서 가장 큰 장애요인으로 되어있는 염소분을 효율적으로 제거하기 위한 목적으로 진행되었다. 염소성분을 원천적으로 제거하기 위해서는 PVC 내에 함유된 염소분을 제거하는 것이 관건이며 원천탈염을 통하여 제거하지 않으면 총괄 염소분의 변화가 없기 때문에 실제로 연료사용에는 한계가 있는 경우가 많다. 본 연구는 PVC중 56% 이상 함유되어 있는 염소성분을 연속식 스크루 반응기에 의하여 가열하여 제거하는 방식을 사용하였으며 각 공정의 변수별로 제거효율을 분석하여 최적조업조건에 대한 분석을 실시하였다. 일반적인 공정조업조건은 공급량, 혼합 플라스틱의 점도, 2차 반응기의 온도, 스크루 회전수 등이며 이 가운데 가장 결정적인 조건은 가열온도 변수이며 여타의 최적조업조건 하에서 $300^{\circ}C$ 이상인 경우에는 90% 이상의 탈염효율을 유지할 수 있음을 알 수 있었다.