• Journal of the Korean GEO-environmental Society
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• v.16 no.5
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• pp.27-33
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• 2015

Manganese in sludge precipitated during water treatment might be soluble again in effluent from sludge thickener. If that happens, the manganese concentration of effluent from water treatment plant will exceed the limit for clean reservation. In this study the influence of pH on Mn concentration of effluent from sludge thickener of water treatment plant was investigated. When the pHs of sludge solutions increased with alkaline materials such as NaOH, KOH, CaO, $Ca(OH)_2$, $CaCO_3$, the Mn concentrations of sludge solutions decreased under the limit. The Mn concentration of effluent from sludge thickener could be controlled with waste limestones from beneficiation process at limestone mine as an alkaline material.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2005.10a
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• pp.59-61
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• 2005

In Korea, hundreds of abandoned and closed coal and metallic mines are present in the steep mountain valleys due to the depression of the mining industry since the late 1980s. From these mines, enormous amounts of coal waste were dumped on the slopes, which causes sedimentation and acid mine drainage (AMD) to be discharged directly into streams causing detrimental effects on soil and water environments. A limestone slurry by-product (lime cake) is produced from the Solvay process in manufacturing soda ash. It has very fine particles, low hydraulic conductivities ($10^{-8}{\sim}10^{-9}cm/sec$), high pH, high EC due to the presence of CaO, MgO and $CaCl_2$ as major components, and traces of heavy metals. Due to these properties, it has potential to be used as a neutralizer for acid-producing materials. A field plot experiment was used to test the application of lime cake for reclaiming coal wastes. Each plot was 20 x 5 m (L x W) in size on a 56% slope. Treatments included a control (waste only), calcite ($CaCO_3$), and lime cake. The lime requirement (LR) for the coal waste to pH 7.0 was determined and treatments consisted of adding 100%, 50%, and 25% of the LR. The lime cake and calcite were also applied in either a layer between the coal waste and topsoil or mixed into the topsoil and coal waste. Each plot was hydroseeded with grasses and planted with trees. In each plot, surface runoff and subsurface water were collected. The lime cake treatments increased the pH of coal waste from 3.5 to 6, and neutralized the pH of the runoff and leachate of the coal waste from 4.3 to 6.7.

• Journal of the Korea Institute of Building Construction
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• v.14 no.3
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• pp.237-243
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• 2014

The environmental problem is serious due to global warming In a concrete industry, the effort to reduce the problem of the destruction of environment arising from the indiscriminate use of limestone that is the raw material of cement and aggregate and the exhaustion of resources are continually emphasized In this research, the waste porcelain and waste glass that are the natural aggregate substitute materials were mixed and were applied. In addition, the magnesia phosphate composite and fly ash are mixed with a cement substitute material and the properties of the artificial stone was examined. Density, water absorption, rate of aggregate on the surface, compressive strength, and flexural strength were performed. As a result of the test, it is that waste glass with 60% and waste porcelain with 70% are the most excellent mix to produce the artificial stone.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.28 no.6
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• pp.256-262
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• 2018

A great amount of fly ash, which is a waste from a thermal power plant, has not been appropriately recycled until now. Landfill of flay ash causes environmental pollution and enormous economic costs. In this study, manufacturing of architectural ceramic tile was investigated replacing fly ash with clay raw material. The properties of porcelain tile was analyzed after manufacturing porcelain tile with mineral based glaze and fast firing process. In particular, the effect of the fly ash addition on the properties of ceramic tile was investigated by increasing the amount of limestone addition. Porcelain tile with fly ash showed excellent bending strength, water absorption, warping and abrasion resistance. However, a significant decrease in durability was observed through the autoclave test. Addition of limestone increased the water absorption, twisting and hydration expansion of the ceramic tile, but it was confirmed that the durability of the ceramic tile with fly ash was greatly improved. In conclusion, recycled architectural ceramic tiles, which can meet domestic construction standards, could be manufactured with the addition of fly ash and limestone.

• Korean Journal of Soil Science and Fertilizer
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• v.47 no.6
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• pp.540-546
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• 2014

Acid mine drainage sludge (AMDS) has been classified as mine waste and generally deposited in land. For this reason, studies have been conducted to examine the possibility of recycling AMDS as an amendment for heavy metal stabilization in soil. The main objective of this study was to evaluate heavy metal stabilization efficiency of AMDS comparing with the widely used lime stone. Also, optimum mixing ratio was evaluated for enhancing heavy metal stabilization. AMDS and limestone were mixed at the ratio of 0:100, 25:75, 50:50, 75:25, and 100:0 with five different heavy metal solutions ($100mg\;L^{-1}$ of $NaAsO_2$, $CdCl_2$, $CuCl_2$, $Pb(NO_3)_2$, and $ZnSO_4{\cdot}7H_2O$). The amendments were added at a rate of 3% (w/v). In order to determine the stabilization kinetics, samples were collected at different reaction time of 0, 1, 2, 4, 8, 16, 32, 64, 128, 256, 512, 1024 minutes. The heavy metal stabilization by AMDS was faster and higher than those of limestone for all examined heavy metals. While limestone showed only 20% of arsenic (As) stabilization after 1,024 minutes, 96% of As was stabilized within 1 minute by AMDS. The highest effect on the stabilization of heavy metal (loid) was observed, when the two amendments were mixed at a ratio of 1:1. These results indicated that AMDS can be effectively used for heavy metal stabilization in soil, especially for As, and the optimum mixing ratio of AMDS and lime was 1:1 at a rate of 3% (w/v).

• Transactions of the Korean Society of Mechanical Engineers B
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• v.21 no.8
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• pp.1068-1076
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• 1997

Emission control of acid exhaust gases from coal-fired power plants and waste incinerators has become an increasing concern of both industries and regulators. Among those gaseous emissions, SO$_{2}$ has been eliminated by a Spray Drying Absorber (SDA) system, where the exhaust gas is mixed with atomized limestone-water slurry droplets and then the chemical reaction of SO$_{2}$ with alkaline components of the liquid feed forms sulfates. Liquid atomization is necessary because it maximizes the reaction efficiency by increasing the total surface area of the alkaline components. An experimental study was performed with a laboratory scale SDA to investigate whether the scrubbing efficiency for SO$_{2}$ reduction increased or not with the application of a DC electric field to the limestone-water slurry. For a selected experimental condition SO$_{2}$ concentrations exited from the reactor were measured with various applied voltages and liquid flow rates. The applied voltage varied from -10 to 10 kV by 1 kV, and the volume flow rate of slurry was set to 15, 25, 35 ml/min which were within the range of emission mode. Consequently, the SO$_{2}$ scrubbing efficiency increased with increasing the applied voltage but was independent of the polarity of the applied voltage. For the electrical and flow conditions considered a theoretical study of estimating average size and charge of the atomized droplets was carried out based on the measured current-voltage characteristics. The droplet charge to mass ratio increased and the droplet diameter decreased as the strength of the applied voltage increased.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2014.05a
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• pp.250-251
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• 2014

With the recent movement toward sustainable development, many efforts have been made to reduce environmental loads in various domains of industry. In particular, a great deal of research and technology development has been underway on approaches to reducing industrial waste and the emission of greenhouse gases. For this reason, a quantitative analysis of the reduction in CO₂ emission that could be achieved by replacing limestone material with cementitious waste powder was performed in this study. Through the analysis, it was found that CO₂ emissions were reduced by up to 50 percent compared with the scenario in which OPC was used, which suggests that it is possible to reduce global CO₂ emissions by approximately 5percent, or by 446.4 Tg of the 965 Tg of CO₂ emissions generated by the cement industry, in the total global CO₂ emissions of 19300Tg.

• International Journal of Highway Engineering
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• v.17 no.1
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• pp.25-33
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• 2015

PURPOSES : This paper, presents the results of a laboratory study aimed to verify the suitability of a particular type of Electric Arc Furnace (EAF) steel slag to be recycled in the lithic skeleton of both dense graded and porous asphalt mixtures for flexible pavements. METHODS : Cyclic creep and stiffness modulus tests were performed to evaluate the mechanical performance of three different asphalt mixtures (dense graded, porous asphalt, and stone mastic) prepared with two types of EAF steel slag. For comparison purposes, the same three mixtures were also designed with conventional aggregates (basalt and limestone). RESULTS : All the asphalt mixtures prepared with EAF steel slag satisfied the current requirements of the European standards, which support EAF steel slag as a suitable material for flexible pavement construction. CONCLUSIONS : Based on the experimental work, the use of waste material obtained from steel production (e.g. EAF steel slag) as an alternative in the lithic skeleton of asphalt mixtures can be a satisfactory and reasonable choice that fulfills the "Zero Waste" objective that many iron and steel industries have pursued in the past decades.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2013.11a
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• pp.160-161
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• 2013

Recently, the enviroment problem is serious due to the global warming phenomenon because of the greenhouse gas exhaustion. In addition, the effort to reduce the problem in the situation where the severity of the destruction of environment because of the indiscriminate picking of the that is the raw material of the cement, Accordingly, in the interior of a country, the industrial site using the artificial stone instead of the natural stone is increased. Thus the cement reduction amount of use and substitute material research is the urgent actual condition with the gas emission, which here it is generated in conducting compression molding in the building stone manufacturing process performance degradation phenomenon and fire resistance, and problem of the durability. limestone and aggregate and exhaustion of resource are emphasized is continued. In this research, the fly ash and waste porcelain is applied to the magnesia phosphate composite (MPC) and the characteristic of the artificial stone according to it tries to be looked into.

• Advances in concrete construction
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• v.9 no.2
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• pp.217-225
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• 2020

The recovery of waste proves a solution with two impacts: the environmental impact by the reduction of pollution and the gain of the occupied space by this waste, and the economic impact by the use of these lasts in the building and in the area of public works. The present research consists in recovering a waste marble (thrown powder exposed to the different meteorological phenomena) generated by the quarry marble of Fil-fila, located at the east side of Skikda in the north-east of Algeria, and add it, as sand in the composition of sand concrete. To carry out this research, we analyzed the evolution brought by the substitution of ordinary sand by marble waste sand, with 25%, 50%, 75% and 100% on the properties in the fresh state (density, workability and air content) and in the cured state (compressive strength, tensile strength, surface hardness and sound velocity). For durability we tested water absorption by immersion and chloride penetration. The results obtained are compared with control samples of 0% of substitution rate. In order to have a good filling of the voids in the granular skeleton; we added a quantity of limestone recycled fines from the quarries and for a good workability a super-plasticizing additive. The results showed that the partial substitution modified both the fresh and the hardened characteristics of the tested concretes, the durability parameters also improved.