• 한국신재생에너지학회:학술대회논문집
• /
• 2010.06a
• /
• pp.230.1-230.1
• /
• 2010

조촉매(Promotor)인 Na은 수성가스전이(Water Gas Shift, WGS) 반응 시 생성된 포름산염의 C-H결합을 쉽게 분해하는 역할을 한다. 본 연구에서는 $Pt/CeO_2$ 촉매의 성능 향상을 위해 Na의 담지량을 변화시켜 촉매적 활성을 비교하여 보았다. 제조된 담체는 침전법(Precipitation)을 사용하여 제조하였으며 $500^{\circ}C$에서 6시간 소성하였다. Pt 담지량은 1wt%로 고정하였고 Na 담지량은 1 wt%~5 wt%로 변화를 주어 동시(공)-함침법(Co-incipient wetness method)으로 담지 시켰다. 반응 실험은 공간속도(Gas Hourly Space Velocity, GHSV) $45,385h^{-1}$에서 수행하였다. WGS 반응 결과 3 wt%의 Na이 담지된 $Pt/CeO_2$ 촉매의 경우를 제외하고 나머지 Na이 담지된 촉매들은 비교적 높은 CO의 전환율을 나타내었다. 특히 2 wt%의 Na이 담지된 $Pt/CeO_2$ 촉매는 가장 높은 CO의 전환율을 나타내었다. 따라서 Na 담지량의 변화가 포름산염의 C-H결합 분해에 영향을 미친다는 것을 알 수 있다.

• 한국신재생에너지학회:학술대회논문집
• /
• 2006.11a
• /
• pp.451-454
• /
• 2006

WGS reaction over Mo2C and ceria based catalysts was investigated to develop an alternative commercial Cu-Zn/Al2O3 catalyst for fuel processor and hydrogen station. The Mo2C catalysts were prepared by a temperature programmed method and the various metal supported cerium oxide catalysts were prepared by an Impregnation method. The catalysts were characterized by the N2 physisorption, Co chemisorption, XRD, TEM and TPR. It was found that Mo2C and 0.2wt% Pt-40wt%, Ni/CeO2 catalysts had higher activity and stability than the Cu-Zn/Al203 above $260^{\circ}C$. Moreover, CO conversion of more than 85% was observed at $280{\sim}300^{\circ}C$. But all catalysts were deactivated during the thermal cycling runs. The results suggest that these catalysts are an attractive candidate for the alternative Cu-Zn/Al2O3 catalyst for fuel processor and hydrogen station applications.

• Journal of Electrical Engineering and Technology
• /
• v.12 no.4
• /
• pp.1357-1368
• /
• 2017

The lack of controllability over the wind causes fluctuations in the output power of the wind generators (WGs) located at the wind farms. Distribution Static Compensator (DSTATCOM) equipped with Battery Energy Storage System (BESS) can significantly smooth these fluctuations by injecting or absorbing appropriate amount of active power, thus, controlling the power flow of WGs. But because of the component aging and thermal drift, its harmonic filter parameters vary, resulting in performance degradation. In this paper, Quantitative Feedback Theory (QFT) is used as a robust control scheme in order to deactivate the effects of filter parameters variations on the wind power generation power smoothing performance. The proposed robust control strategy of the DSTATCOM is successfully applied to a microgrid, including WGs. The simulation results obviously show that the proposed control technique can effectively smooth the fluctuations in the wind turbines' (WT) output power caused by wind speed variations; taking into account the filter parameters variations (structural parameter uncertainties).

• Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
• /
• v.11 no.2
• /
• pp.27-34
• /
• 1993

The construction of the accurate, economic topographic information for a sorts of work and a base facilities of country is one of the very important subjects. In this paper, Global network which include south KOREA and Regional network which include Chung-Nam/Chung-Buk provinces were designed, obtained WGS84 coordinates of control points in networks by GPS. The coefficients of transformation between WGS84 coordinates and Bessel coordinates in consideration of geoid undulations was derived by 7-parameter method. Also, the efficiency of 7-parameter method was proved through successful application of T.M. and U.T.M projection for the precise mapping, and the effectiveness of the aquisition of three dimensional topographic information by GPS was suggested.

• Journal of the Korea Computer Industry Society
• /
• v.9 no.3
• /
• pp.121-128
• /
• 2008

This paper suggested a location-based traffic information service system using TPEG and GIS. Measurement technique, location server, applied service technique, and linkage technique with database were used to provide the location-based traffic information service. In particular, TPEG-RTM includes location information and load traffic message. The location information to be included in each message displayed a specific point, section or region limit of the load. Actually, because it was impossible to receive data using TPEG receiver, a proposed program included in this paper was used to produce an arbitrary database and read it, Also, TPEG event happened time was indicated on the map for matching test of a TPEG message and WGS84 coordinate, and finally it was verified with art example of a vehicle approaching to an event happened place.

• Membrane Journal
• /
• v.20 no.3
• /
• pp.228-234
• /
• 2010

In this study, dynamic simulation of membrane reactor was performed for water gas shift reaction and temperature, hydrogen concentration, etc. were investigated as a function of time and position. Simulation results indicated that differences of hydrogen concentration, hydrogen partial pressure, and temperature in the radial direction, were larger in the entrance than in the exit. In addition, the hydrogen flux was the largest in the entrance, where the hydrogen partial pressure difference was the largest, and the conversion of carbon monoxide in the exit was about 0.65.

• 한국신재생에너지학회:학술대회논문집
• /
• 2011.11a
• /
• pp.73.2-73.2
• /
• 2011

합성천연가스(SNG: Synthetic Natural Gas)를 얻기 위해, 석탄 가스화로부터 얻은 합성가스는 일반적으로 수소와 일산화탄소의 비가 3.0($H_2$/CO)이 되도록 수성가스전환(WGS)반응을 거친 후 메탄화반응기로 유입되며, 가능하면 낮은 온도에서 메탄 전환율이 높은 메탄화 반응의 특성상 강한 발열반응이 수반되므로 이를 낮추는 것이 중요하다. 또한, 최종생성물내의 메탄 농도를 높이기 위해 WGS 이후 탈황과 동시에 이산화탄소를 제거하기 위한 공정이 요구된다. 본 연구에서는 정제된 합성가스의 WGS와 이산화탄소 제거가 생략된 공정을 개발하기 위해, 상업용 촉매에 대하여 수소의 농도가 낮은 합성가스를 이용하여 스팀과 이산화탄소에 대한 메탄화반응 특성을 평가하였다. 또한, 이산화탄소의 존재여부에 따라 스팀으로 메탄화반응과 WGS가 동시에 일어날 수 있는 최적의 운전조건을 얻고자 하였다.

• Economic and Environmental Geology
• /
• v.48 no.6
• /
• pp.537-543
• /
• 2015

In Korea, the use of world geodetic system(WGS) has been mandated in year 2010. Accordingly, the national geographic information institute(NGIS) provides the digital maps according to the WGS. Nevertheless, most of the digital geological maps are still based on the Tokyo Datum(TD). Therefore, users should conduct 2D/3D geological spatial analysis after converting the coordinates of digital geological maps to WGS. The conversion process is often tedious and troublesome for certain users. Therefore, in this study, the method to transform coordinate from TD to WGS using ArcToolbox is introduced for users not familiar with the process. For a better appreciation, the Chungju and Hwanggang-ri digital sheets of 1:50,000 scale was chosen as an example. Here, Chungju and Hwanggang-ri sheets were defined based on the TD-central origin and TD-east origin, respectively. The two sheets were merged after the transformation of TD-east origin of Hwanggang-ri to the TD-central origin, and eventually transformed to WGS-central origin. The merged map was found to match exactly with the digital map(Daeso 367041). The problem of coordinate determination in previous digital geological maps was solved effectively. The proposed method is believed to be helpful to 2D/3D geological spatial analysis of various geological thematic maps.

• Korean Chemical Engineering Research
• /
• v.50 no.2
• /
• pp.358-364
• /
• 2012

The kinetics of the Fischer-Tropsch synthesis and water gas shift reactions over a precipitated iron catalyst were studied in a 5 channel fixed-bed reactor. Experimental conditions were changed as follows: synthesis gas $H_2$/CO feed ratios of 0.5~2, reactants flow rate of 60~80 ml/min, and reaction temperature of $255{\sim}275^{\circ}C$ at a constant pressure of 1.5 MPa. The reaction rate of Fischer-Tropsch synthesis was calculated from Eley-Rideal mechanism in which the rate-determining step was the formation of the monomer species (methylene) by hydrogenation of associatively adsorbed CO. Whereas water gas shift reaction rate was determined by the formation of a formate intermediate species as the rate-determining step. As a result, the reaction rates of Fischer-Tropsch synthesis for the hydrocarbon formation and water gas shift for the $CO_2$ production were in good agreement with the experimental values, respectively. Therefore, the reaction rates ($r_{FT}$, $r_{WGS}$, $-r_{CO}$) derived from the reaction mechanisms showed good agreement both with experimental values and with some kinetic models from literature.

• TTA Journal
• /
• s.102
• /
• pp.96-107
• /
• 2005