• 제목/요약/키워드: W-Ni

검색결과 865건 처리시간 0.026초

W-M(M=Cu, Sn, Ni)계 고밀도 복합재료 제조에 관한 기초연구(I) (A Basic Study on the Fabrication of W-M(M=Cu, Sn, Ni) System High Density Composite (I))

  • 장탁순;홍준희;이태행;구자명;송창빈
    • 한국분말재료학회지
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    • 제16권4호
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    • pp.268-274
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    • 2009
  • For the purpose of obtaining basic information on the development of lead-free materials, a high density composites (a) W-Cu, (b) W-Sn (c)W-Cu-Sn and (d) W-Cu-Ni were fabricated by the P/M method. The particle size of used metal powders were under 325 mesh, inner size of compaction mould was $\phi8$ mm, and compaction pressure was 400 MPa. A High density composite samples were sintered at a temperature between $140^{\circ}C$ and $1050^{\circ}C$ for 1 hour under Ar atmosphere. The microstructure, phase transformation and physical properties of the sintered samples were investigated. As the results, the highest relative density of 95.86% (10.87 g/$cm^3$) was obtained particularly in the sintered W-Cu-Sn ternary system sample sintered at 450 for 1hr. And, Rockwell hardness (HRB) of 70.0 was obtained in this system.

Design of Advanced Weathering Steel with High Corrosion Resistance for Structural Applications

  • Choi, B.K.;Jung, H.G.;Yoo, J.Y.;Kim, K.Y.
    • Corrosion Science and Technology
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    • 제4권4호
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    • pp.121-129
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    • 2005
  • Basic design concept of the future steel structure requires environmental compatibility and maintenance free capability to minimize economic burdens. Recent trends in alloy design for advanced weathering steel include addition of various alloying elements which can enhance formation of stable and protective rust layer even in polluted urban and/or high $Cl^{-}$ environment. The effects of Ca, Ni, W, and Mo addition on the corrosion property of Ca-modified weathering steel were evaluated through a series of electrochemical tests (pH measurement and electrochemical impedance spectroscopy: EIS) and structural analysis on rust layer formed on the steel surface. Ca-containing inclusions of Ca-Al-Mn-O-S compound are formed if the amount of Ca addition is over 25 ppm. Steels with higher Ca content results in higher pH value for condensed water film formed on the steel surface, however, addition of Ni, W, and Mo does not affect pH value of the thin water film. The steels containing a high amount of Ca, Ni, W and Mo showed a dense and compact rust layer with enhanced amount of ${\alpha}-FeOOH$. Addition of Ni, W and Mo in Ca-modified weathering steel shows anion-selectivity and contributes to lower the permeability of $Cl^{-}$ ions. Effect of each alloying element on the formation of protective rust layer will be discussed in detail with respect to corrosion resistance.

Investigating creep behavior of Ni-Cr-W alloy pressurized tube at 950 ℃ by using in-situ creep testing system

  • Zhong, Yang;Lan, Kuan-Che;Lee, Hoon;Zhou, Bomou;Wang, Yong;Tsang, D.K.L.;Stubbins, James F.
    • Nuclear Engineering and Technology
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    • 제52권7호
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    • pp.1481-1485
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    • 2020
  • The creep behavior of Ni-Cr-W alloy at 950 ℃ has been investigated by a novel creep testing system which is capable of in-situ measurement of strain. Tubular specimens were pressurized with argon gas for effective stresses up to 32 MPa. Experimental results show that the thermal fatigue reduces the creep life of the tubular specimens and with the introduction of thermal cycling fatigue the primary stage disappears and the creep rate higher than the pure thermal creep (without thermal fatigue). Also the creep behavior of Ni-Cr-W alloy doesn't consist in the secondary stage. A new creep equation has been derived and implemented into finite element method. The results from the finite element analyses are in good agreement with the creep experiment.

기계적 합금법을 이용한 Ni-W 합금제조

  • 신수철;김효영;장건인
    • 한국결정성장학회:학술대회논문집
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    • 한국결정성장학회 1997년도 Proceedings of the 13th KACG Technical Meeting `97 Industrial Crystallization Symposium(ICS)-Doosan Resort, Chunchon, October 30-31, 1997
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    • pp.69-74
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    • 1997
  • MCFC(Molten Carbonate Fuel Cell) Ni anode의 기계적 특성을 개선시키기 위해서 Ni-W복합재료를 기계적 합금법으로 제조하였다. 기계적 합금화한 분말을 XRD, SEM으로 관찰한 후 두께 1mm, 직경 8mm의 원반형으로 성형하였다. 소결은 120$0^{\circ}C$의 수소 분위기내에서 10시간 행하였다. 이렇게 제조한 시편의 절단된 면을 연마하여 SEM 및 EDX로 관찰하였으며 XRD로써 성분분석 하였다. 기계적 합금화 시간이 증가함에 따라 불충격에 의한 결정립 미세화가 이루어졌으며 80시간 기계적 합금시 재료의 규칙적인 결정이 파괴되어 비결정질화 되었다. 기계적합금으로 Ni 기지내에 균일하게 분포된 W은 분산강화효과를 통해 Ni anode의 기계적 특성을 개선시킬 것으로 기대된다.

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Ni-Cd전지용 충전 알고리즘을 이용한 고속전철용 ZVZCS형 충전장치개발 (The Development of ZVZCS type Battery Charger for High Speed Trail Car with Ni-Cd Battery Charging Algorithm)

  • 최욱돈;이종필;이재문;김연준
    • 전력전자학회논문지
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    • 제5권5호
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    • pp.493-500
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    • 2000
  • 고속전철용 충전기는 VVVF, CVCF, DC/DC 컨버터에 전원을 공급하고 안정성과 시스템의 신뢰성을 목적으로 하는 중요한 에너지원이다. 본 논문에서는 밧데리 충전 알고리즘과 고속전철용 ZVZCS형 밧데리 충전기의 전력회로를 포함한다. 또한 고속전철용 50kW 충전기의 최적 병렬운전과 Ni-Cd 밧데리의 충전 방법을 설명하고 실험을 통해 타당성을 입증한다.

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High Temperature Corrosion of Ni-17%W Coatings in Ar-0.2%SO2 Atmosphere

  • Lee, Dong-Bok;Kwon, Sik-Chol
    • 한국표면공학회지
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    • 제43권1호
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    • pp.31-35
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    • 2010
  • Coatings of Ni-17 at.%W were electroplated on a steel substrate, and their corrosion behavior was investigated between 600 and $800^{\circ}C$ in an Ar-0.2%$SO_2$ atmosphere. They delayed the corrosion of the steel substrate. They were corroded into an outer NiO-rich layer, and an inner ($WO_3+NiO+NiWO_4$)-mixed oxide layer. Below these oxide layers, a sulfide layer gradually formed.