• Bulletin of the Korean Chemical Society
• /
• v.18 no.2
• /
• pp.213-217
• /
• 1997

Magnesium reduction of Mo(N-C6H3-2,6-i-Pr2)2Cl2(DME) in the presence of trimethylphosphine led to a mixture of Mo(N-C6H3-2,6-i-Pr2)(PMe3)2Cl3, 1, and Mo2(PMe3)4Cl4, 2. In solution 1 is slowly air-oxidized to Mo(N-2,6-i-Pr2-C6H3)(OPMe3)(PMe3)Cl3, 3. 1 is chemically inert to carbon nucleophiles (ZnMe2, ZnEt2, AlMe3, AlEt3, LiCp, NaCp, TlCp, NaCp*, MeMgBr, EtMgBr), oxygen nucleophiles (LiOEt, LiO-i-Pr, LiOPh, LiOSPh), and hydrides (LiBEt3H, LiBEt3D). Crystal data for 1: orthorhombic space group P212121, a=11.312(3) Å, b=11.908(3) Å, c=19.381(6) Å, Z=4, R(wR2)=0.0463 (0.1067). Crystal data for 2: monoclinic space group Cc, a=18.384(3) Å, b=9.181(2) Å, c=19.118(3) Å, b=124.98(1)°, Z=4, R(wR2)=0.0228 (0.0568). Crystal data for 3: orthorhombic space group P212121, a=11.464(1) Å, b=14.081(2) Å, c=16.614(3) Å, Z=4, R(wR2)=0.0394 (0.0923).

• Proceedings of the Korean Vacuum Society Conference
• /
• 2012.02a
• /
• pp.315-316
• /
• 2012

반도체와 금속배선의 확산을 방지하기 위한 확산방지막의 필요성이 대두되고 있으며, 이에 대한 연구는 많은 연구 그룹에서 진행중에 있다. 하지만 이러한 연구의 대부분은 전기적, 결정학적 특성에 대하여 안전성 및 재료학적 연구에 국한되어 진행되어졌다. 본 연구그룹은 텅스텐(W)을 질화시킨 W-N 확산방지막에 대하여 연구를 진행하였고, 역시 결정학적 특성에 대한 열적인 안전성을 주로 연구하였으나, 본 연구에서는 W-N 박막의 나노영역에 대한 기계적 특성 평가에 주안점을 두어 W-N 박막의 stress를 nano-indenter 기법을 이용하여 측정하고자하였다. 특히 공정시간의 단축 효과 등의 이유로 박막의 두께를 감소시키는 현재 추세에 맞춰 더 얇은 W-N 확산방지막을 제작하였으며, 이에 대한 분석을 실시하였다. W-N 확산방지막은 Ar(Argonne), $N_2$ (nitrogen) 총유량을 40 sccm으로 고정하여, 질소 유입 조건을 0, 0.5, 1 sccm 으로 변화시켜 Si (silicon) (100) 기판 위에 rf (radio-frequency) magnetron sputter를 이용하여 증착하였다. 이때 W-N 박막의 두께를 30, 100 nm로 달리하여 증착하였으며, 증착된 박막은 질소 분위기 $600^{\circ}C$에서 30분간 열처리하였다. 증착된 시료는 nano-indent를 통하여 표면으로부터 10 nm 부근의 극 표면 물성을 측정하였다. 측정 결과, $N_2$ 가스의 유량을 0.5 sccm 흘려주면서 증착한 W-N 박막이 $N_2$가스를 흘려주지 않은 W 박막과 비교하여 압축응력을 덜 받아 비교적 열에 대하여 안정적임을 확인하였다. 또 30 nm 두께의 W-N 박막이 100 nm 두께의 W-N 박막보다 더 기계적으로 안정적인 상태임을 확인하였다.

• Korean Journal of Crystallography
• /
• v.12 no.3
• /
• pp.141-144
• /
• 2001

From the reaction of Na[Ga(N₃)₄] with PPh₃, an ionic compound [Ph₃P(OH)]/sup +/[N₃]/sup -/ (1) was isolated. Compound 1 was characterized by spectroscopy (¹H-NMR, /sup 13C{¹H}-NMR, and IR) and X-ray diffraction. Crystallographic data for 1 : orthorhombic space group P2₁2₁2₁, a = 10.491 (4) Å, b=11.603(5)Å, c=13.149(5)Å, Z=4, R(wR₂)=0.0547(0.0978).

• Journal of Astronomy and Space Sciences
• /
• v.17 no.1
• /
• pp.39-44
• /
• 2000

We reinvestigate UV line emissions of 44i Boo, W UMa, AW UMa and VW Cep, which are indicaters of chromospheric activity of these stars. C I, C II, C IV, Si IV lines show significant variation in orbital phase. Among those lines, the Line of C IV showed the strongest line flux. while other Si IV and N V lines showed relative low line intensities. 44i Boo emitted the strongest flux than other stars. UV light curves of target stars shoed UV maximum at phase around 0.2 an 0.8 Such UV emissions are generally believed to be observed at the active regions and contacting parts of the two stars due to the clear visibility at the phase 0.2 and 0.8. Total emissivity of four transitions lines lead to conclude that the activity of this region is 40 times larger than the quiet sun. It is obvious that the activity decrease according to increase period. We obtained also Mg II light curve of AW UMA and VW Cep. These stars showed more clearly phase-dependent light curves. We estimated effective temperature of two star, AW UMa and VW Cep, using by Mg II flux.

• Journal of the Korean Society of Environmental Restoration Technology
• /
• v.14 no.5
• /
• pp.53-67
• /
• 2011

The major objective of this study was to quantify the effects of substrate depth and substrate composition on the development of sedum etc., in a sloped rooftop (6 : 12 pitch) environment during a 4-year period. The experiment was conducted from 2006 October to 2010 December under several conditions without soil erosion control : two substrate depth (5cm, 10cm), four substrate composition (A5N3C2, A3N3C4, A6C4, G5L3C2: A: artificial lightweight soil, N : natural soil, G : granite decomposed soil, C : leave composite, L : loess), four sloped roof direction ($E40^{\circ}W$, $W40^{\circ}N$, $S40^{\circ}W$, $N40^{\circ}E$). In this experiment 4 sedum etc., were used: Sedum sarmentosum, Sedum kamtschaticum, Sedum rupestre, Sedum telephium, flowering herbs (mixed seed : Taraxacum platycarpum, Lotus corniculatus, Aster yomena, Aster koraiensis), western grasses (mixed seed : Tall fescue, Creeping redfescue, Bermuda grass, Perennial ryegrass). The establishment factor had two levels : succulent shoot establishment (sedum), seeding (flowering herbs, western grasses). 1. Enkamat, as it bring about top soil exfoliation, was unsuitable material for soil erosion control. 2. Sedum species exhibited greater growth at a substrate depth of 10cm relative to 5cm. All flowering herbs and western grasses established only at a substrate depth of 5cm were died. A substrate depth of 5cm was not suited in sloped rooftop greening without maintenance. If additional soil erosion control will be supplemented, a substrate depth of 10cm in sloped rooftop greening without maintenance was considered suitable. 3. For all substrate depth and composition, the most abundant species was Sedum kamtschaticum. The percentage of surviving Sedum kamtschaticum was 73.4% at a substrate depth of 10cm in autumn 2007 one year after the roof vegetation had been established. But the percentage of surviving other sedum were 33.3%~51.9%, therefor mulching for soil erosion control was essential after rooftop establishment in extensive sloped roof greening was proved. To raise the ratio of plant survival, complete establishment of plant root at substrate was considered essential before rooftop establishment. 4. There was a significant interaction between biomass and substrate moisture content. There were also a significant difference of substrate moisture and erosion among substrate composition. The moisture content of A6C4 was highest, the resistance to erosion of A5N3C2 was highest among substrate composition. The biomass of plants were not significantly higher in A5N3C2 and A6C4 relative to A3N3C4 and G5L3C2, For substrate moisture and erosion resistance, A5N3C2 and A6C4 were considered suitable in sloped rooftop greening without maintenance. 5. There were significant difference among roof slope direction on the substrate moisture. Especially, the substrate moisture content of $S40^{\circ}W$ was lower relative to that of $N40^{\circ}E$, that guessed by solar radiation and erosion.

• Korean Journal of Child Studies
• /
• v.36 no.5
• /
• pp.173-188
• /
• 2015

The main purpose of this study was to investigate the effects of a mother's big five personality factors and playfulness on maternal parenting behavior. The participants consisted of 270 mothers with young children, aged 3-6 years old. The subjects completed questionnaires on IPIP(International Personality Item Pool), PAS(Playfulness Scale for Adults) and Parenting Behavior. The results were as follows. First, regarding the relationships of the mother'personality and parenting behavior, higher levels of neuroticism(N) in the mothers resulted in lower levels of warmth acceptance(W A) in parenting behavior. Higher levels of extroversion(E), openness(O), agreeableness(A), and conscientiousness(C) resulted in higher levels of W A. In terms of the relationships of the mother's playfulness and parenting behavior, higher levels of playfulness resulted in higher levels of W A. and lower levels of permissiveness nonintervention(P N) and rejection restriction(R R). Second, N, E, C, and a maternal sense of humor had an effect in W A. C was found to have an effect in P N and N was observed to have an effect in R R.

• Kyungpook Mathematical Journal
• /
• v.59 no.4
• /
• pp.689-702
• /
• 2019

Let 𝓐 and 𝓑 be real (or complex) algebras. We investigate the stability of a sequence F = {f₀, f₁, ⋯, f_n, ⋯ } of mappings from 𝓐 into 𝓑 satisfying the higher functional equation: $$f_n(x+y+zw)=f_n(x)+f_n(y)+\;{\normalsize\sum\limits_{\tiny{i+j=n \atop i{\leq}j}}}\;[f_i(z)f_j(w)+c_{ij}f_i(w)f_j(z)]$$ for each n = 0, 1, ⋯ and all x, y, z, w ∈ 𝓐, where $$c_{ij}=\left\{1{\text{ if }}i{\neq}j,\\0{\text{ if }}i=j.\right.$$.

• Communications of the Korean Mathematical Society
• /
• v.10 no.2
• /
• pp.349-355
• /
• 1995

Let $D \subset C^n$ be a smoothly bounded pseudoconvex domain and let ${\bar{D}_r}_r$ be a family of smooth perturbations of $\bar{D}$ such that $\bar{D} \subset \bar{D}_r$. Let $K_D(z, w)$ be the Bergman kernel function on $D \times D$. Then $lim_{r \to 0} K_{D_r}(z, w) = K_D(z, w)$ locally uniformally on $D \times D$.

• Journal of the Korea Organic Resources Recycling Association
• /
• v.14 no.2
• /
• pp.63-70
• /
• 2006

The purpose of this study was to develop the stability index of landfill sites to assess it's degree of stability. In order to develop the stability index, field data including leachate qualities, Landfill gas (LFG) composition and element composition of wastes from 50 closed landfills were collected. Three parameters-BOD/CODcr among leachate quality parameters, $CH_4$ among landfill gases, and C/N ratio from wastes-were found to be the best parameters for measuring the stability of landfill sites. The trend line of these parameters were used to Also, $CH_4$ from landfill gases and C/N ratio from wastes were found to be the best parameters. The trend lines of these parameters were used to develop the stability index of landfill sites. The equation for the index was as following; $I_{LS}=S_L+S_G+S_W$ $S_L=-\{4.892+16.587{\cdot}ln[BOD/COD_{Cr]\}$ $S_G=53.872-12.782{\cdot}ln[CH_4]$ $S_W=79.382-20.013{\cdot}ln[C/N]$ (The maximum score for $S_L$, $S_G$, and $S_W$ was 33.3.) where, $I_{LS}$ : The stability index of the landfill $S_L$ : The stability score of the leachate $S_G$ : The stability score of the landfill gas $S_W$ : The stability score of the waste.

• Bulletin of the Korean Mathematical Society
• /
• v.53 no.2
• /
• pp.411-421
• /
• 2016

In this paper, we investigate the problem of transcendental entire functions that share two values with one of their derivative. Let f be a transcendental entire function, n and k be two positive integers. If $f^n-Q_1$ and $(f^n)^{(k)}-Q_2$ share 0 CM, and $n{\geq}k+1$, then $(f^n)^{(k)}{\equiv}{\frac{Q_2}{Q_1}}f^n$. Furthermore, if $Q_1=Q_2$, then $f=ce^{\frac{\lambda}{n}z}$, where $Q_1$, $Q_2$ are polynomials with $Q_1Q_2{\not\equiv}0$, and c, ${\lambda}$ are non-zero constants such that ${\lambda}^k=1$. This result shows that the Conjecture given by W. $L{\ddot{u}}$, Q. Li and C. Yang [On the transcendental entire solutions of a class of differential equations, Bull. Korean Math. Soc. 51 (2014), no. 5, 1281-1289.] is true. Also we exhibit some examples to show that the conditions of our result are the best possible.