• 제목/요약/키워드: W/C

검색결과 15,606건 처리시간 0.076초

미생물의 생체광물형성작용에 따른 모르타르 내구성 검토 (The Examination of Mortar Durability by Microbial Biomineralization)

  • 김성태;천우영;김화중
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2009년도 춘계 학술대회 제21권1호
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    • pp.525-526
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    • 2009
  • 본 논문에서는 Sporosarcina pasteurii라는 미생물의 생체광물형성작용을 이용하여 Calcite($CaCO_3$) 석출을 유도하고, 이를 Mortar에 적용하여 요구 성능 향상을 평가하였다. Sporosarcina pasteurii를 혼입(input)한 Mortar 시험체(C3S-S.p)와 일반 Mortar 시험체(C3S-W)의 중성화 반응을 실험을 통해 비교한 결과 C3S-S.p가 C3S-W에 비해 중성화가 지연되는 것을 육안으로 확인할 수 있었다. 또한 28日간 Urea-CaCl2 수용액(Medium)에서 양생한 C3S-S.p와 C3S-W의 내구성을 실험을 통해 비교한 결과 Sporosarcina pasteurii를 혼입한 Mortar 시험체(C3S-S.p)가 일반 Mortar 시험체(C3S-W) 비해 내구성이 향상된 것으로 나타났다.

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The high thermal stability induced by a synergistic effect of ZrC nanoparticles and Re solution in W matrix in hot rolled tungsten alloy

  • Zhang, T.;Du, W.Y.;Zhan, C.Y.;Wang, M.M.;Deng, H.W.;Xie, Z.M.;Li, H.
    • Nuclear Engineering and Technology
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    • 제54권8호
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    • pp.2801-2808
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    • 2022
  • The synergistic effect of ZrC nanoparticle pining and Re solution in W matrix on the thermal stability of tungsten was studied by investigating the evolution of the microstructure, hardness and tensile properties after annealing in a temperature range of 1000-1700 ℃. The results of metallography, electron backscatter diffraction pattern and Vickers micro-hardness indicate that the rolled W-1wt%Re-0.5 wt% ZrC alloy has a higher recrystallization temperature (1600 ℃-1700 ℃) than that of the rolled pure W (1200 ℃), W-0.5 wt%ZrC (1300 ℃), W-0.5 wt%HfC (1400-1500 ℃) and W-K-3wt%Re alloy fabricated by the same technology. The molecular dynamics simulation results indicated that solution Re atoms in W matrix can slow down the self-diffusion of W atoms and form dragging effect to delay the growth of W grain, moreover, the diffusion coefficient decrease with increasing Re content. In addition, the ZrC nanoparticles can pin the grain boundaries and dislocations effectively, preventing the recrystallization. Therefore, synergistic effect of solid solution Re element and dispersed ZrC nanoparticles significantly increase recrystallization temperature.

3%C-5%Mo-5%W-10%(Cr or V) 백주철의 응고거동에 관현 연구 (Solidification Behavior of 3%C-5%Mo-5%W-10%(Cr or V) White Cast Irons)

  • 류성곤
    • 한국재료학회지
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    • 제10권2호
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    • pp.144-147
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    • 2000
  • 10%C-5%Mo-5%W-10%Cr 및 10%C-5%Mo-5%W-10%V 백주철의 응고거동을 열분석을 통하여 연구하였다. 15Kg 용량의 고주파 유도옹해로에 선철, 고철, Fe-Mo, Fe-W, Fe-Cr, Fe-V 등을 장입시켜 용해시킨 후 슬래그를 제거시키고 $1550^{\circ}C$에서 Y블럭의 펩 주형에 주입하였다. 응고거동을 조사하기 위하여 50g을 Y블럭에서 채취한 뒤 알루미나 도가니에 넣어 재용해시킨 후 1$0^{\circ}C$/min의 냉각속도로 냉각시키면서 여섯 종류의 다른 온도에서 도중에 급냉시켜 응고조직을 광학현미경으로 관찰하였다. 10%C-5%Mo-5%W-10%Cr 백주철의 경우 초정 오스테나이트, 오스테나이트와 M(sub)7C(sob)3의 공정, 오스테나이트와 M(sub)6C의 공정으로, 10%C-5%Mo-5%W-10%V 백주철의 경우 초정 MC, 오스테나이트와 MC의 공정, 오스테나이트와 M(sub)2C의 공정으로 각각 순차적으로 정출하였다. 정출하였다.

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초고온 MEMS용 단결정 3C-SiC의 Ohmic Contact 형성 (Ohmic contact formation of single crystalline 3C-SiC for high temperature MEMS applications)

  • 정귀상;정수용
    • 센서학회지
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    • 제14권2호
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    • pp.131-135
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    • 2005
  • This paper describes the ohmic contact formation of single crystalline 3C-SiC thin films heteroepitaxially grown on Si(001) wafers. In this work, a TiW (Titanium-tungsten) film as a contact matieral was deposited by RF magnetron sputter and annealed with the vacuum and RTA (rapid thermal anneal) process respectively. Contact resistivities between the TiW film and the n-type 3C-SiC substrate were measured by the C-TLM (circular transmission line model) method. The contact phases and interface the TiW/3C-SiC were evaulated with XRD (X-ray diffraction), SEM (scanning electron microscope) and AES (Auger electron spectroscopy) depth-profiles, respectively. The TiW film annealed at $1000^{\circ}C$ for 45 sec with the RTA play am important role in formation of ohmic contact with the 3C-SiC substrate and the contact resistance is less than $4.62{\times}10^{-4}{\Omega}{\cdot}cm^{2}$. Moreover, the inter-diffusion at TiW/3C-SiC interface was not generated during before and after annealing, and kept stable state. Therefore, the ohmic contact formation technology of single crystalline 3C-SiC using the TiW film is very suitable for high temperature MEMS applications.

W-CU 복합재료의 전도도에 미치는 미세조직의 영향 (Effect of Microstructure on Conductivity of W-Cu Composite)

  • 이영중;박광현;이병훈;김덕수;김영도
    • 한국재료학회지
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    • 제15권2호
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    • pp.85-88
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    • 2005
  • [ $W-15wt.\%$ ] Cu nanocomposite powders are fabricated by ball-milling and subsequent hydrogen-reduction. The compacted parts of $W-15wt.\%Cu$ nanocomposite powders were sintered at $1200^{\circ}C$ for 1 h with various heating rates of 5 and $20^{\circ}C/min$. The homogeneity of the sintered microstructures was evaluated through homogeneity index by the standard deviation of Victor's hardness test. The W-W contiguities were calculated by using Voronoi diagrams. The sintered microstructure with the heating rate of $20^{\circ}C/min$ was more homogeneous and had lower W-W contiguity than that of $5^{\circ}C/min$. The microstructural homogeneity was directly related to the W-W contiguity. Thermal conductivity of the sintered parts with the heating rate of $20^{\circ}C/min$ was higher than that with heating rate of $5^{\circ}C/min$. This phenomenon indicates that the thermal conductivity is affected by the W-W contiguity resulting from the homogeneity of the sintered microstructure.

여수주변해역에서 분리한 유류분해세균 Pseudomonas sp. BCK-1의 특성 (Characterization of Oil Degrading Bacterium Pseudomonas sp. BCK-1 Isolated from the Coastal Water of Yosu, Korea)

  • 구헌서
    • 한국수산과학회지
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    • 제34권2호
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    • pp.145-150
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    • 2001
  • 한국 남해안 유류 오염지역인 전남 여수시 소리도 지역 해수로부터 유류 분해능이 우수한 균주를 선별하여 동정한 결과 Pseudomonas sp.로 동정되었으며, Pseudomonas sp. BCK-1으로 명명하였다. 균성장에 대한 최적배양온도, pH, NaCl 농도는 각각 $30^{\circ}C$, 7.0, $3\%$(w/v)였으며, $2\%$ (w/v) arabian light crude oil과 bunker C oil을 기질로 72시간 및 168시간 배양한 결과 arabian light crude oil는 $92\%$ (w/w), bunker, C oil은 $72\%$ (w/w)가 각각 생분해되었다.

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Cu 금속배선을 위한 카본-질소-텅스텐 확산방지막 특성 (Characteristics of W-C-N Thin Diffusion Barrier for Cu Interconnection)

  • 이창우
    • 마이크로전자및패키징학회지
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    • 제12권4호통권37호
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    • pp.345-349
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    • 2005
  • 300 mW-cm의 낮은 비저항을 갖는 카본-질소$\_$텅스텐 (W-C-N) 확산방지막을 원자층 증착법으로 제조하였으며, 반응기체로 $WF_6-N_2-CH_4$를 사용하였다. $N_2$$CH_4$ 반응기체를 주입 할 때는 고주파 펄스를 인가하여 플라즈마에 의한 반응물의 분리가 일어나도록 하였다. 다층금속배선에 사용하는 층간 절연층 (TEOS) 위에서 W-C-N 박막은 원자층 증착기구를 따르며, 10에서 100 사이클 동안 증착율이 0.2nm/cycles 로 일정한 값을 가진다. 또한 Cu 배선을 위한 확산방지막으로써 W-C-N 박막은 비정질 상을 가지며, $800^{\circ}C$에서 30분간 열처리해도 Cu의 확산을 충분히 방지할 수 있음을 확인하였다.

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Magnetic Properties of Nanocrystalline CoW Thin Film Alloys Electrodeposited from Citrate Baths

  • Park, Doek-Yong;Ko, Jang-Myoun
    • 전기화학회지
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    • 제6권4호
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    • pp.236-241
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    • 2003
  • Magnetic CoW thin film alloys were electrodeposited from citrate baths to investigate the resulting microstructure and magnetic properties. Deposit tungsten (W) content in the films electrodeposited at $70^{\circ}C$ were independent of current density, while coercivity decreased from hard $(H_{c,//}\~150\;Oe\;and\;H_{c.{\bot}}\;\~240\;Oe)$ to soft magnetic properties $(H_{c,//}\~20\;Oe\;and\;H_{c.{\bot}}\;\~30\;Oe)$ with increasing current densities from $10\;to\;100mA{\cdot}cm^2$, with deposit W content $(\~40\%)$ relatively unaffected by the applied current density. X-ray diffraction analysis indicated that hcp $Co_3W$ phases [(200), (201) and (220) planes] in the CoW films electrodeposited at $70^{\circ}C\;and\;10mA{\cdot}cm^{-2}$ were dominant, whereas amorphous CoW phases with small amount of hcp $Co_3W$ [(002) planes] were dominant with deposition at $70^{\circ}C\;and\;100mA{\cdot}cm^{-2}$. At intermediate current densities $(25\;and\;50mA{\cdot}cm^{-2}),\;hop\;Co_3W$ phases [(200), (002), (201) and (220)] were observed. The average grain size was measured to be 30 nm from Sheller formula. It is suggested that the change of the deposit coercivities in the CoW thin films electrodeposited at $70^{\circ}C$ is attributed to the change of microstructures with varying the current density. Nanostructured $Co_3W/amorphous-CoW$ multilayers were fabricated by alternating current density between 10 and $100 mA{\cdot}cm^{-2}$, varying the individual layer thickness. The magnetic properties of $Co_3W/amorphous-CoW$ multilayers were strongly dependent on the thickness of the alternating hard and soft magnetic thin films. The nanostructured $Co_3W/amorphous-CoW$ multilayers exhibited a shift from low to high coercivities suggesting a strong coupling effect.

프로그래밍 학업성취도에 관한 사례연구: 하드웨어 교과과정 중심으로 (A case study on programming academic achievement: Focused on the hardware curriculum)

  • 이승우
    • Journal of the Korean Data and Information Science Society
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    • 제25권4호
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    • pp.779-790
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    • 2014
  • 본 논문에서는 H/W 전공자들의 프로그래밍 수준을 S/W 전공자들과의 상대적 비교 분석을 통하여 파악하고자 첫째, H/W와 S/W 분야 졸업예정자들에게 C언어와 C++언어에 관한 프로그래밍 학업성취도를 비교 측정하였다. 둘째, H/W와 S/W의 교과과정 편성을 비교 분석하여 프로그래밍 학업성취도 향상에 관련된 정보를 교과과정을 통하여 도출하였다. 셋째, 수학적 학습능력이 프로그래밍 학업성취도에 어떠한 영향을 주는지 파악하기 위해서 수학 교과목과 프로그래밍 교과목간의 학업성취도에 관한 회귀분석을 실시하여 그 관련성을 분석했다. 이를 통하여 향후 H/W 교과과정에서 학과차원의 특수성과 실정을 반영한 효율적인 프로그래밍 학업성취도 증대 방안에 관하여 제안하였다.

진공 플라즈마 스프레이 공정을 이용한 W계 복합 코팅층의 제조 및 특성 연구 (Manufacturing and Properties of Low Vacuum Plasma Sprayed W-Carbide Hybrid Coating Layer)

  • 조진현;진영민;안지훈;이기안
    • 한국분말재료학회지
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    • 제18권3호
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    • pp.226-237
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    • 2011
  • W-ZrC and W-HfC composite powders were fabricated by the Plasma Alloying & Spheroidization (PAS) method and the powders were sprayed into hybrid coating layers by using Low Vacuum Plasma Spray (LVPS) process, respectively. Microstructure, mechanical properties, and ablation characteristics of the fabricated coating layers were investigated. The LVPS process led to successful production of W-Carbide hybrid coatings, approximately 400 ${\mu}M$ or above in thickness. As the substrate preheating temperature increased from $870^{\circ}C$ to $917^{\circ}C$, the hardness of the W-ZrC coating layer increased due to decreased porosity. Vickers hardness showed higher value (about 108.4 HV) in W-ZrC hybrid coating material compared to that of W-HfC while adhesive strength was found to be similar in both coating layers. The plasma torch test revealed good ablation resistance of the W-Carbide hybrid coating layers. The relatively high performance W-ZrC coating layer at the elevated temperature is thought to be attributed to both the strengthening effect of ZrC particle remained in the layer and the formation of ZrO2 phase with high temperature stability.