• Journal of the Mineralogical Society of Korea
• /
• v.15 no.3
• /
• pp.205-220
• /
• 2002

The gold-silver deposits in the Casado district were formed in the sheeted and stockwork quartz veins which fill the fault fractures in volcanic rocks. K-Ar dating of alteration sericite (about 70 Ma) indicates a Late Cretaceous age for ore mineralization. These veins are composed of quartz, adularia, carbonate, and minor of pyrite, sphalerite, chalcopyrite, galena, Ag-sulfosalts (argentite, pearceite, Ag-As-Sb-S system), and electrum. These veins are characterized by chalcedonic, comb, crustiform and feathery textures. Based on the hydrothermally altered mineral assemblages, regional alteration zoning associated with mineralization in the Gasado district is defined as four zones; advanced argillic (kaolin mineral-alunite-quartz), argillic (kaolin mineral-quartz), phyllic (quartz-sericite-pyrite) and propylitic (chlorite-carbonate-quartz-feldspar-pyroxene) zone. Phyllic and propylitic zones is distributed over the study area. However, advanced argillic zone is restricted to the shallow surface of the Lighthouse vein. Compositions of electrum ranges from 14.6 to 53.7 atomic % Au, and the depositional condition for mineralization are estimated in terms of both temperature and sulfur fugacity: T=245。$~285^{\circ}C$, logf $s_2$=$10^{-10}$ ~ $10^{-12}$ Fluid inclusion and stable isotope data show that the auriferous fluids were mixed with cool and dilute (158。~253$^{\circ}C$ and 0.9~3.4 equiv. wt. % NaCl) meteoric water ($\delta^{18}$ $O_{water}$=-10.1~8.0$\textperthousand$, $\delta$D=-68~64$\textperthousand$). These results harmonize with the hot-spring type of the low-sulfidation epithermal deposit model, and strongly suggest that Au-Ag mineralization in the Gasado district was formed in low-sulfidation alteration type environment at near paleo-surface.

• Analytical Science and Technology
• /
• v.12 no.6
• /
• pp.484-489
• /
• 1999

The extraction of trace amounts of Se in volcanic rock was investigated using the hydride generation method and atomic absorption spectrophotometry. The powdered rock, 1.0 g, was decomposed with the mixture of $HClO_4$, $HNO_3$ and HF in an acid digestion bomb at $140^{\circ}C$ for 2 hours. For the reduction of Se(VI) to Se(IV) in the solution, 10 mL of 6 M HCl and 0.2 mL of 1 M KBr were added to the solution and the mixture was heated for 30~45 minutes. $H_2Se$ was produced by adding 3% $NaBH_4$ as a strong reducing agent, extracted by nitrogen gas, and was absorbed twice into $KMnO_4$solution. The contents of Se in the solution were determined by generation/AAS. According to the proposed method, 1.0 ng or more of Se was quantitatively extracted and Se levels of 2.5 ng/g or more in rock samples could be determined. For example, Se in a rhyolite was determined with the precision of $19.5{\pm}1.3ng/g$(95% confidence, n=6).

• The Journal of the Petrological Society of Korea
• /
• v.22 no.1
• /
• pp.35-47
• /
• 2013

The Baegdusan Volcano which erupted violently at 1000 AD is still have possibility of eruption. Therefore, it is necessary to monitor regularly the possibility of eruption. However, it is very difficult to install regular monitoring system or to get regularly monitored data due to geopolitic problems. This is why we have to develop regular monitoring technique using satellite. The geoid in the Baegdusan Volcanic area calculated from gravity data obtained from GRACE satellite, decreased from 2002 to 2005. The period of decreasing is well matched with time when magma activities were recognized in the Baegdusan Volcanic area. The decrease in geoid is interpreted to be caused by the decrease of water storage. Considering that the amount of rainfall from 2002 and 2005 is almost constant, the decrease in geoid may be related to the magma activity under the Baegdusan Volcano. The geomagnetic total force in the Baegdusan Volcanic area measured by CHAMP satellite, decreased from 2000 to 2005 and increased after 2005. The period of decrease is well matched with the time with increased activity of magma chamber under the Baegdusan Volcano indicating that the decrease of geomagnetic total force is caused by demagnetization of surrounding rocks due to the increase of temperature of magma chamber. These data indicate the possbility of using change of geoid and geomagnetic total force observed by GRACE and CHAMP satellites for the monitoring of magma activity under the Baegdusan Volcano.

• Economic and Environmental Geology
• /
• v.35 no.6
• /
• pp.523-532
• /
• 2002

The rare earth elements (REE) and Nd, Sr and noble gas isotopic compositions eHer'He, 4$^{\circ}$Arp6Ar) for the Quaternary alkali basaltic rocks and mantle xenoliths in the basaltic rocks from the Baegryongdo were investigated to decipher the origin of alkali basaltic magma and xenolith beneath the Sino-Korean craton. Analytical results are summarized as follows; (1) The alkali volcanic rocks with voluminous xenoliths which are represented by the Mg-olivine and clinopyroxene dominant spinel-lherzolite in the Baegryongdo consist mainly of the basalt-mugearite and basaltic andesite. (2) The REE pattern of alkali basaltic rocks characterized by high HREE is similar to that of oceanic island basalt (OlB). Relatively concordant REE patterns of the basaltic rocks suggest that the alkali basaltic magma be formed by the identical source materials. (3) The Nd-Sr isotopic data of the alkali basaltic rocks suggest that the alkali basaltic magma be originated from the depleted mantle source with a little contamination of the continental crustal materials. (4) The $^3$He/ $^4$He ratios in olivines of xenoliths ranging from 5.0${\pm}$1.lRa to 6.7${\pm}$1.3Ra are lower than that of MORB (ca. 8.0Ra). It suggest that the xenolith be derived from the subcontinental lithospheric mantle. However, the high $^3$Her'He value of 16.8${\pm}$3.IRa at 1800$^{\circ}$C fraction (sample no OL-7) might be resulted from the post-eruptive cosmogenic $^3$He. The 4OAr/ 36 Ar ratios in olivines of mantle xenoliths are comparable to that of atmospheric argon, and are much lower than that of the MORB type mantle. These facts can lead to conclusion that the olivine of the xenolith in the Baegryongdo is affected by the post-eruptive atmospheric contamination during the slow degassing process.

• The Journal of the Petrological Society of Korea
• /
• v.28 no.3
• /
• pp.195-215
• /
• 2019

Geopark is a new system for development of the local economy through conservation, education, and tourism that is an area of scientific importance for the earth sciences and that has outstanding scenic values. The Hwaseong Geopark, the candidate for Korean National Geopark is composed of 10 geosites: Gojeongri dinosaur egg fossils, Ueumdo, Eoseom, Ddakseom, Goryeom, Jebudo, Baengmiri Coast, Gungpyeonhang, Ippado and Gukwado geosites. In this study, geosites, geoheritages, and geotrails of the Hwaseong Geopark were described in detail, and the value and significane as a geopark were also discussed. The geology of the Hwaseong Geopark area belonging to the Gyeonggi Massif consists of the Precambrian metamorphic and meta-sedimentary rocks, Paleozoic sedimentary and metamorphic rocks, Mesozoic igneous and sedimentary rocks, and Quaternary deposits, indicating high geodiversity. The Gojeongri Dinosaur Egg Fossils geosite, designated as a natural monument, has a geotrail including dinosaur egg nest fossils, burrows, tafoni, fault and drag fold, cross-bedding. Furthermore, a variety of infrastructures such as eco-trail deck, visitor center are well-established in the geosite. In the Ueumdo geosite, there are various metamorphic rocks (gneiss, schist, and phyllite) and geological structures (fold, fault, joint, dike, and vein), thus it has a high educational value. The Eoseom geosite has high academic value because of the orbicular texture found in metamorphic rocks. Also, various volcanic and sedimentary rocks belonging to the Cretaceous Tando Basin can be observed in the Ddakseom and Goryeom geosites. In the Jebudo, Baengmiri Coast, and Gungpyeonghang geosites, a variety of coastal landforms (tidal flat, seastacks, sand and gravel beach, and coastal dunes), metamorphic rocks and geological structures, such as clastic dikes and quartz veins can be observed, and they also provide various programs including mudflat experience to visitors. Ippado and Gukwado geosites have typical large-scale fold structures, and unique coastal erosional features and various Paleozoic schists can be observed. The Hwaseong Geopark consists of outstanding geosites with high geodiversity and academic values, and it also has geotrails that combine geology, geomorphology, landscape and ecology with infrastructures and various education and experience programs. Therefore, the Hwaseong Geopark is expected to serve as a great National Geopark representing the western Gyeonggi Province, Korea.

• Journal of the Korean earth science society
• /
• v.30 no.7
• /
• pp.801-809
• /
• 2009

The Salinas Grandes borate deposit located in Jujuy state, northern Argentina can be categorized into the playatype evaporite deposit. Major borate mineral is ulexite ($NaCaB_5O_9{\cdot}H_2O$), which boron could be originated from volcanic rocks nearby playa. The eastern part of the Jujuy state in northern Argentina belongs to the Altiplano-Puna platform which shows high altitude and semiarid climate. Lots of Mesozoic and Cenozoic volcanics that are source of boron as well as playas that are the basin for borate precipitation in the area are essential for boron evaporite deposit. Therefore, the extensive explorations for the playa-type evaporite deposit are need.

• Journal of the Korean Geographical Society
• /
• v.35 no.1
• /
• pp.17-38
• /
• 2000

The marine terraces often offer come important clues to understand the topographic development during the Quaternary and the present landforms in korea. We examined the mechanism of the marine terraces formation along the coast from Samjung-Ri(community), Guryongpo-Eup(county) to Haseo-Ri, Yangnam-Myun(county), Gyungju-Si(city). Among the various but unique factors of the given coastal environment, which should contribute to the marine terraces formation together, we focused on five possible factors for the present stydy. Geologic difference in bedrocks, protrusion degree of coastiline, topological relief of sea-bottom, fluvial characteristics on land, and pattern of the waves appeared to act cooperatibely on the terrace formation of Southeastem coast in korea, while the fluvial characteristics seemed play a significant but localized role in it. Wide distribution of middle surfaces on the coast of Samjungri-Janggilri could be due to the concentration of the high waves and the weakness of the Tertiary volcanic rocks. For the sporadic distribution of the terraces on the coast of Gupungri-Gyewonri, it seemed attributable to the erosion -susceptible weak bedrock, the coastline of inner bay, shallow sea-bottom with the gentle relief, and other fluvial characteristics with the low divides. Together with the geologic difference in bedrock, other factors including protrusion degree of coast, topological relief of sea-bottom, and the transportation loads by the stream Daejongchon are believed to act cooperatively on the mechanism of the marine terraces formation on the coast of Duwonri-Upchonri.

• Journal of the Korean earth science society
• /
• v.29 no.5
• /
• pp.386-395
• /
• 2008

The absolute age of lapilli tuff in sedimentary formation that contains dinosaur fossils in the Boseong area, Korea was determined radiometrically against volcanic rocks below and above the fossil-bearing horizons. The sanidine in the lapilli tuff below the fossil-bearing horizon (Seonso formation) has an $^{40}Ar-^{39}Ar$ age of $81.l{\pm}1.4Ma$. The Pilbong tuff above Seonso formation has an $^{40}Ar-^{39}Ar$ age of $81.0{\pm}2.4Ma$. An andesite dyke intruding all sedimentary units yields an $^{40}Ar-^{39}Ar$ age of $42.4{\pm}2.5Ma$. Thus 81 Ma age can be regarded as the best estimate for the age of the Seonso Formation and the associated the dinosaur eggs. This age correlates well with dinosaur fossil finds in the Haenam and Koseong regions of Korea. The occurrence of dinosaur eggs and clutches attests to the existence of dinosaurs in southern Korea at least inCampanian times.

• Economic and Environmental Geology
• /
• v.13 no.2
• /
• pp.104-116
• /
• 1980

The Ulsan mine is one of the largest contact metasomatic magnetite and scheelite deposits in the southeastern part of Korea. Mineralization at the Ulsan mine is localized along the contact between upper Cretaceous volcanic rocks and age unknown limestone which were intruded by 58 m.y. -old biotite-horndlende granite. General zonal sequence of skarn toward crystalline limestone from limestone-volcanics contact is grandite, grandite-salite and salite zones. On the otherhand volcanics origin skarns exhibits zonal sequences toward hornfels from boundary with limestone is garnet, garnet-epidote, and epidote zone. Compositions of garnets and clinopyro xenes are determined by the X-ray diffraction and reflective indecies. Local brecciation of these early skarns were followed by formation of the later skarn as zoned patches, breccia fillings and cross-cutting veins. Paragenetic sequence of late skarn minerals which is exhibited in the zoned patches and veins is an overlapping progression with time from andradite through hedenbergite or actinolite, quartz to calcite deposition. Magnetite metallization followed early formed skarns and pyrite pyrrhoite, sphalerite, galena, tennantite, scheelite and arsenopyrite deposition were simultaneously with hedenbergite, quartz and calcite of late skarn. Filling temperatures of fluid inclusions in calcites range from $160^{\circ}$ to $280^{\circ}C$.

• Economic and Environmental Geology
• /
• v.40 no.3 s.184
• /
• pp.319-330
• /
• 2007

The Muposan Tuff is a stratigraphic unit which is distinguished as a cooling unit in the volcanic rocks of the northeastern Kyeongsang Basin. The Muposan Tuff commonly belongs to tuff field according to the granulometric classification and to vitric tuffs according to the constituent classification. The tuffs are mostly densely to partially welded to include very flattened and sometimes stretched pumices and shards, and involve several flow indicator and lateral gradings in maximum diameter and content of their constituents. Movement pattern from flow lineation, lithic and pumice imbrications, asymmetric flow folds, and lateral gradings in maximum diameter and content of their constituents indicate that the Muposan Tuff had a source from the southeastern part.