• Title/Summary/Keyword: Visible and near-infrared

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Predicting Organic Matter content in Korean Soils Using Regression rules on Visible-Near Infrared Diffuse Reflectance Spectra

  • Chun, Hyen-Chung;Hong, Suk-Young;Song, Kwan-Cheol;Kim, Yi-Hyun;Hyun, Byung-Keun;Minasny, Budiman
    • Korean Journal of Soil Science and Fertilizer
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    • v.45 no.4
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    • pp.497-502
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    • 2012
  • This study investigates the prediction of soil OM on Korean soils using the Visible-Near Infrared (Vis-NIR) spectroscopy. The ASD Field Spec Pro was used to acquire the reflectance of soil samples to visible to near-infrared radiation (350 to 2500 nm). A total of 503 soil samples from 61 Korean soil series were scanned using the instrument and OM was measured using the Walkley and Black method. For data analysis, the spectra were resampled from 500-2450 nm with 4 nm spacing and converted to the $1^{st}$ derivative of absorbance (log (1/R)). Partial least squares regression (PLSR) and regression rules model (Cubist) were applied to predict soil OM. Regression rules model estimates the target value by building conditional rules, and each rule contains a linear expression predicting OM from selected absorbance values. The regression rules model was shown to give a better prediction compared to PLSR. Although the prediction for Andisols had a larger error, soil order was not found to be useful in stratifying the prediction model. The stratification used by Cubist was mainly based on absorbance at wavelengths of 850 and 2320 nm, which corresponds to the organic absorption bands. These results showed that there could be more information on soil properties useful to classify or group OM data from Korean soils. In conclusion, this study shows it is possible to develop good prediction model of OM from Korean soils and provide data to reexamine the existing prediction models for more accurate prediction.

Prediction of Soluble Solid and Firmness in Apple by Visible/Near-Infrared Spectroscopy (가시광선/근적외선 분광분석법을 이용한 사과의 당도 및 경도 측정)

  • 최창현;이강진;박보순
    • Journal of Biosystems Engineering
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    • v.22 no.2
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    • pp.256-265
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    • 1997
  • The objectives of this study were to examine the ability to predict soluble solid and firmness in intact apples based on the visible/near-infrared spectroscopic technique. Two cultivars of apples, Delicious and Gala, were handled, tested and analyzed separately. Reflectance spectra, Magness-Tayor (MT) firmness, and soluble solids in apples were measured sequentially. Maximum and minimum diameters, height, and weight of apples were recorded before the MT firmness tests. A spectrophotometer was used to collect reflectance spectra of intact apples over a wavelength range of 400 to 2, 498 nm. The W firmness tests were conducted using a standard 11.1mm (7/16 in.) MT probe mounted in an Instron universal testing machine. A digital refractormeter was used to measure soluble solid contents in the apples. Apple samples were divided into a calibration set and a prediction set. The calibration set was used during model development, and the prediction set was used to predict soluble solids and firmness from unknown spectra. The method of partial least square (PLS) analysis was used. An unique set of PLS loading vectors (factors) was developed for soluble solid content and firmness. The PLS model showed good correlations between predicted and measured soluble solids of intact apples in 860~1078 nm of the wavelengths. However, the PLS analysis was not good enough to predict the apple firmness.

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Optical and structural properties of metal-dielectric near-infrared cutoff filters for plasma display panel application

  • Lee, Jang-Hoon;Lee, Kwang-Su;Hwangbo, Chang-Kwon
    • Journal of the Korean Vacuum Society
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    • v.12 no.S1
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    • pp.88-91
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    • 2003
  • Electromagnetic interference shielding and near-infrared cutoff filters for plasma display panel application were designed and fabricated by radio frequency magnetron sputtering. Three types of the filters were prepared: the basic structure of type A consisted of [$TiO_2$ Ti Ag $TiO_2$]; type B, of [$TiO_2$ ITO Ag $TiO_2$]; type C, of [$TiO_2$ ITO Ag ITO $TiO_2$]. Ti and ITO layers deposited on Ag layers were employed as barriers to prevent the oxidation and the diffusion of Ag film into the adjacent oxide layers. Optical, electrical, chemical, and structural properties were investigated, and the result shows that the filters with the ITO barrier layers provided an enhancement in transmittance in the visible owing to a lower absorption of ITO layers than Ti layers. Type C filter showed better optical and electrical performances and smoother surface roughness than Type B and C filters: the average sheet resistance was as low as 1.51 $\Omega\Box$ (where $\square$ stands for a square film), the peak transmittance in the visible was as high as 78.2 %, and the average surface roughness was 1.48 nm.

Inorganic Nanoparticles for Near-infrared-II Fluorescence Imaging (근적외선-II 형광 이미징을 위한 무기 나노입자)

  • Park, Yong Il
    • Applied Chemistry for Engineering
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    • v.33 no.1
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    • pp.17-27
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    • 2022
  • Fluorescence imaging is widely used to image cells or small animals due to its high temporal and spatial resolution. Because conventional fluorescence imaging uses visible light, the penetration depth of light within the tissue is low, phototoxicity may occur due to visible light, and the detection sensitivity is lowered due to interference by background autofluorescence. In order to overcome this limitation, long-wavelength light should be used, and fluorescence imaging using near-infrared-I (NIR-I) in the region of 700~900 nm has been developed. To further improve imaging quality, researchers are interested in using a longer wavelength light, near-infrared-II (NIR-II) ranging from 1000 to 1700 nm. In the NIR-II region, light scattering is further minimized, and the penetration depth of light in the tissue is improved up to about 10 mm, and autofluorescence of the tissue is reduced, enabling high sensitivity and resolution fluorescence imaging. In this review, among various NIR-II fluorescence imaging probes, inorganic nanoparticle-based probes with excellent photostability and easily tunable emission wavelength were described, focusing on single-walled carbon nanotubes, quantum dots, and lanthanide nanoparticles.

Design and Calibration of Acousto-Optic Tunable Filter(AOTF) for Near Infrared Spectral Analysis (근적외선 분광 분석을 위한 음향광학변조필터의 설계 및 교정)

  • You, Jang-Woo;Kim, Dae-Suk;Kwak, Yoon-Keun;Kim, Soo-Hyun;Lee, Yun-Woo;Hwang, In-Duk
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.28 no.11
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    • pp.1697-1702
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    • 2004
  • In this paper, we proposed the design and calibration method for the near infrared Acousto-Optic Tunable Filter (AOTF). The theory and design principles of AOTF for the visible light are well known since I.C.Chang has developed the parallel tangent condition for the non-collinear AOTF. Deflection angle, frequency-wavelength relation, spectral resolution, etc. were calculated based on the theory of AOTF. From this result, important parameters - incident and acoustic angle - to fabricate AOTF were decided. We measured the spectral resolution and the relation between electrical driving frequency and the Optical wavelength of diffracted light to calibrate the near infrared AOTF. About 40 ∼ 80 MHz electrical frequency was required to get 1200 ∼ 2200 nm near infrared light. Spectral resolution was less than 10 nm in the near infrared region.

Determination of Rice Milling Ratio by Visible / Near-Infrared Spectroscopy (가시광선 / 근적외선 분광 분석법을 이용한 쌀의 정백수율 측정)

  • 김재민;민봉기;최창현
    • Journal of Biosystems Engineering
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    • v.22 no.3
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    • pp.333-342
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    • 1997
  • The objective of this research was to develop model equations for measuring rice milling ratio by using visible / HIR spectroscopy. Twelve kinds of brown rice(n = 149) were milled to obtain various milling ratio ranged from 86% to 94%. Visible/NIR spectra were collected with a spectrophotometer with sample transport module. The reflectance and transmission spectra were measured in the range of 400~2, 500nm and 600~1, 400nm, respectively, with 2 nm intervals. Multiple linear regression(MLR), Partial least square (PLS), and Artificial neural network(ANN) were used to develop models. Model developed with reflectance spectra showed better prediction results then those with transmission spectra. The MLR model with six-wavelength obtained from first derivative spectra gave to the best results for measuring the rice milling ratio(SEP = 0.535, , $r^2$ = 0.980). The PLS model(SEP = 0.604, $r^2$= 0.976) and ANN model(SEP = 0.566, $r^2$= 0.978) also can be used to determine the rice milling ratio effectively.

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Evaluating Spectral Preprocessing Methods for Visible and Near Infrared Reflectance Spectroscopy to Predict Soil Carbon and Nitrogen in Mountainous Areas (산지토양의 탄소와 질소 예측을 위한 가시 근적외선 분광반사특성 분석의 전처리 방법 비교)

  • Jeong, Gwanyong
    • Journal of the Korean Geographical Society
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    • v.51 no.4
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    • pp.509-523
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    • 2016
  • The soil prediction can provide quantitative soil information for sustainable mountainous ecosystem management. Visible near infrared spectroscopy, one of soil prediction methods, has been applied to predict several soil properties with effective costs, rapid and nondesctructive analysis, and satisfactory accuracy. Spectral preprocessing is a essential procedure to correct noisy spectra for visible near infrared spectroscopy. However, there are no attempts to evaluate various spectral preprocessing methods. We tested 5 different pretreatments, namely continuum removal, Savitzky-Golay filter, discrete wavelet transform, 1st derivative, and 2nd derivative to predict soil carbon(C) and nitrogen(N). Partial least squares regression was used for the prediction method. The total of 153 soil samples was split into 122 samples for calibration and 31 samples for validation. In the all range, absorption was increased with increasing C contents. Specifically, the visible region (650nm and 700nm) showed high values of the correlation coefficient with soil C and N contents. For spectral preprocessing methods, continuum removal had the highest prediction accuracy(Root Mean Square Error) for C(9.53mg/g) and N(0.79mg/g). Therefore, continuum removal was selected as the best preprocessing method. Additionally, there were no distinct differences between Savitzky-Golay filter and discrete wavelet transform for visual assessment and the methods showed similar validation results. According to the results, we also recommended Savitzky-Golay filter that is a simple pre-treatment with continuum removal.

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Measurement of Milling Ratio using the Visible and the Near-Infrared Rays Spectrum (가시광선 및 근적외선 스펙트럼을 이용한 도정비율 측정)

  • 이용국;이재현
    • Journal of Biosystems Engineering
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    • v.24 no.3
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    • pp.259-266
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    • 1999
  • This research was carried out to investigate the possibility of real time rice milling ratio measurement using the spectral reflection characteristics. In this study, various methods were compared such as \circled1 using the whiteness meter, \circled2 using the colorimeter, \circled3 using the Visible and the NIR reflection spectrum. The samples were milled in the domain of 84~96% by 0.5% interval classified by milling ratio. The NMG treatment method required about 20 minutes to determine the milled ratio and r2 was 0.0028 to 0.7959 that was very low. In case of whiteness meter, r2 was high but speed of measurement was 5 minutes that was very low. Measurement with the colorimeter required about 5 minutes and r2 was 0.60 to 0.85 that was low. The reflection spectrum were measured in the range of 400~2,500nm with 2nm interval and the MLR model with six-wavelength obtained from first derivative of spectra gave the best results(r2 = 0.967, SEP = 0.729%)

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A new method for mapping visible-near infrared light levels in Fruit

  • Fraser, Daniel G.;Jordan, Robert B.;Kunnemeyer, Rainer;Mcglone, V. Andrew
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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    • 2001.06a
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    • pp.1128-1128
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    • 2001
  • We have developed a probe for measuring the light levels inside illuminated fruit. The probe has minimal effect on the light levels being measured and enables the sampling of the light flux at any point within the fruit. We present experimental light extinction rates within apple, nashi, kiwifruit, and mandarin fruit. Moving from the illuminated side to the far side of the fruit, the extinction level follows an initial power law decay as the light diffuses into the fruit then reduces to an exponential decay through the rest of the fruit. Significant variations in the rates of light extinction are found in the core, skin and differing flesh regions. Monte Carlo simulations of the light distribution in fruit, which use scattering and absorption coefficients for the diffusely scattering tissue, and boundary conditions for the skin effects, produce results that follow the experimental results closely.

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