• Title/Summary/Keyword: Viscosity behavior

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Tuning the rheological properties of colloidal microgel controlled with degree of cross-links (가교도가 제어된 콜로이드 마이크로겔의 유변학적 물성 분석)

  • Han, Sa Ra;Shin, Sung Gyu;Oh, Seung Joo;Cho, Sung Woo;Jung, Naseul;Kang, Bu Kyeung;Jeong, Jae Hyun
    • Journal of the Korean Applied Science and Technology
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    • v.36 no.2
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    • pp.645-655
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    • 2019
  • In this study, colloidal microgel with viscoelasticity were prepared by using dispersion containing physical crosslinking agents and microgels with various strengths depending on the degree of cross-links.As the chemical crosslinking agent PEGDA400 content increased, hydrogels have various physical properties the swelling ratio decreased from $2.0{\times}10^4%$ to $6.0{\times}10^3%$ and increased viscosity by about 60%. The colloidal microgel was prepared with micro hydrogel grinded to $100{\mu}m$ size and the rheological behavior was confirmed with physical cross linking agent. A colloidal microgel having various viscosities was prepared by controlling starch and alginate based on micro-hydrogel containing 0.75% (w/v) of PEGDA400. In conclusion, these results would be highly useful for applying as a product that can give various physical properties to the colloidal suspensions, cosmetics, paint, and food industry.

Material Properties of Soil and Potteries Excavated From Ra-No.19 Site of Pung-nap Mudcastle (풍납토성 라-19호 출토 토양과 토기의 재료학적 특성)

  • Heo, Jun Su;Kim, Jo Yoon;Han, Ji Sun;Kim, Su Kyoung;Lee, Han Hyoung;Moon, Eun Jung;Yoo, Young Mi;Han, Min Su;Seo, Min Seok
    • Korean Journal of Heritage: History & Science
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    • v.45 no.3
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    • pp.194-211
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    • 2012
  • Pung-nap mudcastle has brought wide attention to archaeologists since scientific studies were carried out on the various types of building sites and excavated potteries related to A period of Baekje Kindom when it sat Hansung as the capital. It is identified that clay from Ra-No.19 site of Pung-Nap mudcastle has different from compositions that of residential soil. From archaeological point of view, it is believed that the the soil was a source material for potteries due to the appropriate viscosity and inclusions. Mineralogical and geochemical studies show that the compositions between the source material and randomly chosen two potteries from the same site are similar. Behavior pattern classification of major, trace and rare elements provides also very similar result. Artificial specimen has been made at different temperature in order to estimate firing temperature of the potteries by means of various kinds of instrumental application. As a result of the study, it is believed that the firing temperature of the red and brown pottery was $550{\sim}600^{\circ}C$ and $900{\sim}1,000^{\circ}C$ respectively.

Effect of Multi-Walled Carbon Nanotube on Rheological Behavior and Compressive Strength of Cement Paste (다중벽 탄소나노튜브가 시멘트 페이스트의 유변학적 물성 및 압축강도에 미치는 영향)

  • Kim, Ji-Hyun;Kim, Won-Woo;Moon, Jae-Heum;Chung, Chul-Woo
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.4
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    • pp.467-474
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    • 2020
  • Carbon nanotube has excellent mechanical strength and functionality, so it has been utilized in various applications. In recent years, utilization of carbon nanotube in construction material has started to get interests from researchers in the area of construction materials. However, there is limited amount of work with respect to the rheological properties of cement paste using carbon nanotube. In this work, solution made of multi-walled carbon nanotube with dispersing agent of polyvinyl pyrrolidone was used to prepare cement paste specimens, and rheological properties and 28 day compressive strengths of cement paste using multi-walled carbon nanotube were measured. According to the experimental results, as the amounnt of multi-walled carbon nanotube increased, plastic viscosity and yield stress of cement paste specimens also increased. It was also found that such effect was higher with lower w/c cement paste specimens. With respect to the compressive strength, it was maximized at carbon nanotube content of 0.1wt.% for w/c 0.30 cement paste, whereas the maximum strength of w/c 0.40 cement paste was observed with carbon nanotube content of 0.2wt%.

A Study on the Effect of Pigments used in Cosmetic Manufacturing on the Form of Water Dispersible Formulations (화장품 제조에 쓰이는 Pigments 가 수분산 제형에 미치는 영향에 대한 연구)

  • Kim, Hyun Jee;Oh, Ji Won;Kwak, Byeong Mun;Lee, Mi Gi;Bin, Bum Ho
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.47 no.1
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    • pp.41-48
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    • 2021
  • Formulations which are dispersed in water are often used in color cosmetics because they are characterized by no powder flying, not sticky, and high adherence while giving a light feeling of use. However, little research has been considered on the effect of the pigment on the above formulations used in color cosmetics. In this study, experiments were conducted to measure and analyze the effect of pigments on the formulation of pigments, organic pigments, and pearl polish, which are mainly used in the manufacture of color cosmetics, on appearance changes, pH changes, and photometric stability. Carmine or ferric ferrocyanide coated titanium dioxide mica-based pigments were not suitable for use due to poor photostability, with colors appearing on the surface from low viscosity formulations. Organic pigments had a good photostability of 1% of the formulation which are dispersed in water, but were not suitable for use because they came out of color on the water surface and did not spread well due to the clumping of powders. The titanium dioxide mica system pigments coated with pearl polish, inorganic pigments, and iron oxide were suitable for use due to their excellent appearance and optical stability in the formulation. Furthermore, the pH of all samples distributed by each pigment seems to be within the range of 3.0 to 9.0, which is suitable for cosmetic applications. This is expected to help manufacture color cosmetics with a stable water dispersible formulations by selecting and using stable pigments in anticipation of the behavior of pigments in the formulations.

Evaluation of Fluidity Over Time and Mechanical Properties of Cement-based Composite Materials for 3D Printing (3D 프린팅용 시멘트계 복합재료의 경시변화 및 역학적 특성평가)

  • Seo, Eun-A;Lee, Ho-Jae;Yang, Keun-Hyeok
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.26 no.4
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    • pp.73-80
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    • 2022
  • This study evaluated changes in fluidity and rheological properties over time for 3D printed composite materials, and evaluated compressive strength and splitting tensile strength properties for laminated and molded specimens. The composite material for 3D printing starts to change rapidly after 30 minutes of extrusion, and the viscosity of the material tends to be maintained up to 90 minutes, but it was confirmed that construction within 60 minutes after mixing is effective. The compressive strength of the laminated test specimen showed equivalent or better performance at all ages compared to the molded test specimen. In the stress-strain curve of the laminated specimen, the initial slope was similar to that of the molded specimen, but the descending slope was on average 1.9 times higher than that of the molded specimen, indicating relatively brittle behavior. The splitting tensile strength of the P-V laminated specimen was about 6% lower than that of the molded specimen. It is judged that this is because the interfacial adhesion force against the vertical load is affected by the pattern direction of the laminated test specimen.

An Analysis of the Settlement Behavior of Soft Clayey Ground Considering the Effect of Creep during the Primary Consolidation (1차압밀과정중의 크리프의 영향을 고려한 연약 점성토지반의 침하거동 해석)

  • Baek, Won-Jin;Matsuda, Hiroshi;Choi, Woo-Jung;Kim, Chan-Kee;Song, Byung-Gwan
    • Journal of the Korean Geotechnical Society
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    • v.24 no.5
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    • pp.107-115
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    • 2008
  • This paper is performed to examine the effect of creep during the primary consolidation and the applicability of the Yin's EVP (Elasto-Visco-Plastic) model. In ordinary consolidation theories using the elastic model, the primary consolidation process can be expressed but the secondary consolidation process cannot. It is due to the viscosity, which can express the secondary consolidation, and is sometimes related to the scale effect (difference of the thickness of clay layer between laboratory sample and field condition) such as hypotheses Type A and Type B shown by Ladd et al. (1977). Usually, the existence of the creep during the primary consolidation has been conformed and the Type B is well acceped. On the other hand, from the large-scaled consolidation tests the intermediate characteristic between Type A and Type B was proposed as Type C by Aboshi (1973). In this study, to clarify the effect of creep on the settlement-time relation during the primary consolidation in detail, Type B consolidation tests were performed using the separate-type consolidation test apparatus for a peat and clay. Then the test results were analyzed by using Yin's EVP Model (Yin and Graham, 1994). In conclusion, followings were obtained. At the end of primary consolidation, the compression for the subspecimens should not be the same because of the difference of the excess pore water pressure dissipation rate. And the average settlement measured by the separate-type consolidometer coincides with the analyzed one using the Yin's EVP model. As for the dissipation of the excess pore water pressure, however, the measured excess pore water pressure dissipates faster compared with the Yin's model.

Characteristics of Water Level and Velocity Changes due to the Propagation of Bore (단파의 전파에 따른 수위 및 유속변화의 특성에 관한 연구)

  • Lee, Kwang Ho;Kim, Do Sam;Yeh, Harry
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.28 no.5B
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    • pp.575-589
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    • 2008
  • In the present work, we investigate the hydrodynamic behavior of a turbulent bore, such as tsunami bore and tidal bore, generated by the removal of a gate with water impounded on one side. The bore generation system is similar to that used in a general dam-break problem. In order to the numerical simulation of the formation and propagation of a bore, we consider the incompressible flows of two immiscible fluids, liquid and gas, governed by the Navier-Stokes equations. The interface tracking between two fluids is achieved by the volume-of-fluid (VOF) technique and the M-type cubic interpolated propagation (MCIP) scheme is used to solve the Navier-Stokes equations. The MCIP method is a low diffusive and stable scheme and is generally extended the original one-dimensional CIP to higher dimensions, using a fractional step technique. Further, large eddy simulation (LES) closure scheme, a cost-effective approach to turbulence simulation, is used to predict the evolution of quantities associated with turbulence. In order to verify the applicability of the developed numerical model to the bore simulation, laboratory experiments are performed in a wave tank. Comparisons are made between the numerical results by the present model and the experimental data and good agreement is achieved.

The Effect of Heating Rate by Ohmic Heating on Rheological Property of Corn Starch Suspension (Ohmic Heating에 의한 가열속도 변화가 옥수수전분의 물성특성에 미치는 영향)

  • Lee, Seok-Hun;Jang, Jae-Kweon;Pyun, Yu-Ryang
    • Korean Journal of Food Science and Technology
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    • v.37 no.3
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    • pp.438-442
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    • 2005
  • Granule swelling is essential phenomenon of starch gelatinization in excess water, and characteristic of heated starch dispersion depends largely on size and distribution of swelled starch granule. Although swelling characteristic of starch granules depends on type of starch, heating rate, and moisture content, influence of heating rate on swelling phenomenon of starch granule has not been fully discussed, because constant heating rate of starch dispersion cannot be obtained by conventional heating method. Ohmic heating, electric-resistant heat generation method, applies alternative current to food materials, through which heating rate can be easily controlled precisely and conveniently at wide range of constant heating rates. Starch dispersion heated at low heating rates below $7.5^{\circ}C/min$ showed Newtonian fluid behavior, whereas showed pseudoplastic behavior at heating rates above $16.4^{\circ}C/min$. Apparent viscosity of starch dispersion increased linearly with increasing heating rate, and yield stress was dramatically increased at heating rates above $16.4^{\circ}C/min$. Average diameter of corn starch granules during ohmic heating was dramatically increased from $30.97\;to\;37.88\;{\mu}m$ by increasing heating rate from $0.6\;to\;16.4^{\circ}C/min$ (raw corn starch: $13.7\;{\mu}m$). Hardness of starch gel prepared with 15% corn starch dispersion after heating to $90^{\circ}C$ at different heating rates decreased gradually with increasing heating rate, then showed nearly constant value from $9.4\;to\;23.2^{\circ}C/min$. Hardness increased with increase of heating rate higher than $23.2^{\circ}C/min$.

Effect of Aqueous Phase Composition on the Stability of a Silica-stabilized Water-in-oil Emulsion (유화제로서 실리카를 이용한 유중수형 에멀젼의 안정성에 미치는 수상부 조성의 영향)

  • Kim Jin-Hwang;Kim Song-I;Kyong Kee-Yeol;Lee Eun-Joo;Yoon Moung-Seok
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.30 no.3 s.47
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    • pp.353-359
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    • 2004
  • The extent of silica flocculation can be modified by varying the silica concentration, aqueous phase pH, salt and polvmer concentration. High volume fraction W/O emulsion stabilized by hydrophobic silica was established with various aqueous phase conditions for cosmetic application. By increasing the silica concentration up to $1.0\;wt\%,$ the size of droplet decreased. A high silica concentration increased the viscosity of continuous oil phase by network formation, which resulted in target size of droplet. The stability of W/O emulsion is improved as increasing the aqueous phase pH. At low and intermediate pH, the emulsions became more stable by adding salt $(0.083\;mol\;dm^{-3}\;MgSO_4).$ At high PH, the presence of salt caused significant destabilization. The gelation behavior of the emulsion indicates that the effect of salt on silica-stabilized emulsion is derived from an electrostatic attraction. The addition of xanthan gum in aqueous phase increased the mono-dispersity of the W/O emulsion by making water more hydrophobic and hindering the recombination of droplets. In conclusion, these results indicate that very stable emulsifier-free, finely dispersed W/O emulsion can be achieved for cosmetic application by changing the aqueous phase composition.

Phase Behavior Study of Fatty Acid Potassium Cream Soaps (지방산 칼륨 Cream Soaps 의 상거동 연구)

  • Noh, Min Joo;Yeo, Hye Lim;Lee, Ji Hyun;Park, Myeong Sam;Lee, Jun Bae;Yoon, Moung Seok
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.48 no.1
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    • pp.55-64
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    • 2022
  • The potassium cream soap with fatty acid called cleaning foam has a crystal gel structure, and unlike an emulsion system, it is weak to shear stress and shows characteristics that are easily separated under high temperature storage conditions. The crystal gel structure of cleansing foams is significantly influenced by the nature and proportion of fatty acids, degree of neutralization, and the nature and proportion of polyols. In order to investigate the effect of these parameters on the crystal gel structure, a ternary system consisting of water/KOH/fatty acid was investigated in this study. The investigation of differential scanning calorimeter (DSC) revealed that the eutectic point was found at the ratio of myristic acid (MA) : stearic acid (SA) = 3 : 1 and ternary systems were the most stable at the eutectic point. However, the increase in fatty acid content had little effect on stability. On the basis of viscosity and polarized optical microscopy (POM) measurements, the optimum degree of neutralization was found to be about 75%. The system was stable when the melting point (Tm) of the ternary system was higher than the storage temperature and the crystal phase was transferred to lamellar gel phase, but the increase in fatty acid content had little effect on stability. The addition of polyols to the ternary system played an important role in changing the Tm and causing phase transition. The structure of the cleansing foams were confirmed through cryogenic scanning electron microscope (Cryo-SEM), small and wide angle X-ray scattering (SAXS and WAXS) analysis. Since butylene glycol (BG), propylene glycol (PG), and dipropylene glycol (DPG) lowered the Tm and hindered the lamellar gel formation, they were unsuitable for the formation of stable cleansing foam. In contrast, glycerin, PEG-400, and sorbitol increased the Tm, and facilitated the formation of lamellar gel phase, which led to a stable ternary system. Glycerin was found to be the most optimal agent to prepare a cleansing foam with enhanced stability.