• 한국음향학회지
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• 제16권1호
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• pp.16-23
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• 1997

강제진동에 의한 외팔보의 동적응답과 진동모드를 연구하였다. Bernoulli-Euler 이론과 유한요소법을 이용하여 외팔보의 고유진동수와 진동모드를 수치해석하고 실험으로 측정하여 비교하였다. 가진주파수를 1Hz에서 70Hz까지 변화시켜 외팔보의 1차, 2차 공진주파수를 구하고, 응답위치에 따른 진동 변위를 측정하여 진동모드를 살펴보았다. 실험결과에서 외팔보의 절점(node)이 1차모드에서는 0.2차모드에서는 0,0.786으로 측정되었다. 외팔보의 공진주파수와 진동모드에 대해 이론적으로 예상했던 결과와 실험으로 측정한 결과가 거의 일치하였다.

• Bulletin of the Korean Chemical Society
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• 제34권7호
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• pp.2051-2055
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• 2013

Existing theoretical calculations predict that infrared spectra of the two most fundamental reactive carbo-ions, methyl cation $CH{_3}^+$ with $D_{3h}$ symmetry and protonated methyl cation $CH{_5}^+$ with $C_s(I)$, $C_s(II)$, and $C_{2v}$ symmetries, appear together in the 7-${\mu}m$ region corresponding to the C-H bending modes. Vibrational band profiles of $CH{_3}^+$ and $CH{_5}^+$ have been compared by ab initio calculation methods that use the basis sets of MP2/aug-cc-pVTZ and CCSD(T)/cc-pVTZ. Our results indicate that the bands of rotation-vibration transitions of $CH{_3}^+$ and $CH{_5}^+$ should overlap not only in the 3-${\mu}m$ region corresponding to the C-H stretching modes but also in the 7-${\mu}m$ region corresponding to the C-H bending modes. Five band intensities of $CH{_5}^+$ among fifteen vibrational transitions between 6 and 8 ${\mu}m$ region are stronger than those of the ${\nu}_2$ and ${\nu}_4$ bands in $CH{_3}^+$. Ultimate near degeneracy of the two bending vibrations ${\nu}_2$ and ${\nu}_4$ of $CH{_3}^+$along with the stronger intensities of $CH{_5}^+$ in the three hydrogen scrambling structures may cause extreme complications in the analysis of the high-resolution carbo-ion spectra in the 7-${\mu}m$ region.

• Bulletin of the Korean Chemical Society
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• 제23권2호
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• pp.277-280
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• 2002

Mass-analyzed threshold ionization (MATI) spectra of 2-hydroxypyridines existing as lactims (2-pyridinol) in a molecular beam are obtained via (1+1') two-photon process to give accurate ionization energies of 8.9344${\pm}$0.0005 and 8.9284${\pm}$0.0005 eV for 2-pyridinol (2Py-OH) and its deuterated analogue (2Py-OD), respectively. Resonantly-enhanced two-photon ionization spectra of these compounds are also presented to give vibrational structures of their $S_1$ states. Vibrational frequencies of 2Py-OH and 2Py-OD in ionic ground states are accurately determined from MATI spectra taken via various $S_1$ intermediate states, and associated vibrational modes are assigned with the aid of ab initio calculations.

• 한국자동차공학회논문집
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• 제10권3호
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• pp.227-236
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• 2002

We have performed two kinds of experimental modal analyses fur a radial tire for passenger car under free-suspension. One is the modal analysis to obtain three-dimensional modes of tire using accelerometers and the other is the one to identify cavity resonance frequency using a pressure sensor. From the first analysis, we have obtained the three-dimensional natural modes, which makes it possible to grasp the features of the modes and to classify the vibrational modes into symmetric, non-symmetric, and antisymmetric modes in a simple way by using the experimental results. From the first and the second experimental analyses we have identified the cavity resonance frequency and its three-dimensional mode shape.

• Bulletin of the Korean Chemical Society
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• 제31권11호
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• pp.3385-3390
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• 2010

$Li^+$ ion complex of azacrown ether with restricted motion of freedom and pseudo-bilateral symmetry was studied by infrared spectroscopy, which has shown simplified and broadened vibrational features. The C=O and N-H stretching bands, in particular, shows anomalous broadening nearly ${\sim}50\;cm^{-1}$. The density functional calculation at the level of BP86/6-31+$G^{**}$ shows that $Li^+$ ion is trapped and rather free to move around inside the cavity, as much as about $0.70\;{\AA}$. Through the relocation of $Li^+$ ion inside the cavity, the conformational changes would occur rapidly in its symmetry $C_1\;{\rightleftarrows}\;C_2\;{\rightleftarrows}\;C_1$$. The potential barrier was obtained to be merely ~2.2 kJ/mol for $C_1\;{\rightarrow}\;C_2$. During this conformational alteration, the amide backbone twists concurrently its dihedral angle side to side about up to ${\pm}3$ degree. Selected vibrational modes were interpreted in terms of the force constant variations of local symmetry coordinates between conformations in the framework of $C_1\;{\rightleftarrows}\;C_2\;{\rightleftarrows}\;C_1$.

• 한국소음진동공학회:학술대회논문집
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• 한국소음진동공학회 2003년도 추계학술대회논문집
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• pp.486-491
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• 2003

The paper presents the relationship between the eigenvalue branches and the corresponding flutter modes of cantilevered pipes conveying fluid. The pipes are located on elastic foundations which can be regarded as a soil model. In this paper, elastic foundations are assumed as linear distributed translational springs. Governing equations of motion are derived by extended Hamilton's principle, and the numerical scheme using finite element method is applied to obtain the discretized equations. The critical How velocity and stability maps of the pipe are investigated according to the variation of elastic foundation parameters, mass ratios of the pipe and internal damping Parameter. Also, the vibrational modes associated with flutter are shown.

• 한국소음진동공학회:학술대회논문집
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• 한국소음진동공학회 1997년도 추계학술대회논문집; 한국과학기술회관; 6 Nov. 1997
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• pp.101-109
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• 1997

An analytical procedure on the base of the substructure synthesis and assumed modes method is developed to investigate the flexibility effect of bladed disk assembly on vibrational modes of flexible rotor system. In modeling the system, Coriolis forces, gyroscopic moments, and centrifugal stiffening effects are taken into account. The coupled vibrations between the shaft and bladed disk are then extensively investigated through the numerical simulation of simplified models, with varying the shaft rotational speed and the pretwist and stagger angles of the blade. It is found that the Coriolis and inertia forces and the inertia torque, which are induced by the one nodal diameter modes of the bladed disk and vary depending upon the stagger and pretwist angles, lead to the coupled motions of the shaft and the bladed disk.

• Journal of Photoscience
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• 제9권2호
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• pp.122-125
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• 2002

Coherent oscillations in is fluorescence dynamics of W.-t. PYP and its site-directed mutants have been observed. Two oscillatory modes coupled with the ultrafast fluorescence due to the twisting of the excited chromophore were identified, a high ftequency mode (∼135 cm$\^$-1/) with ∼550 is damping time and a low frequency overdamped mode (-45 cm$\^$-1/) with ∼250 is damping time, respectively. Both modes disappear in the fluorescence dynamics of denatured PYP emphasizing the important role of the protein nanospace as the environment for photoreaction. The qualitative picture of fluorescence dynamics in site-directed mutants was rather similar to that in W.-t. PYP, i.e., similar oscillatory modes (∼130-140 cm$\^$-1/ and ∼40-70 cm$\^$-1/) have been observed. This indicates that the vibrational modes and electron-vibration couplings do not change dramatically due to the mutation though the damping time of low frequency mode a little decreases as the protein nanospace structure becomes looser and more disordered by mutation. On the other hand, in the case of some PYP analogues, the qualitative picture of fluorescence dynamics changes, showing the familiar picture of solvation effect whereas the oscillations are almost damped. Comparative analyses of these observations are presented.

• 한국광학회지
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• 제4권4호
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• pp.496-501
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• 1993

레이저 반점 간섭계측법의 기본원리를 설명하고, 이를 응용하여 물체표면의 이동 및 변형측정 그리고 물체의 고유 진동 모우드를 분석하는 실험장치의 구성과 실험방법을 설명하였다.

• Bulletin of the Korean Chemical Society
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• 제31권8호
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• pp.2175-2179
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• 2010

Quantum mechanical properties of unsymmetrical and unfunctionalized trans-stilbene derivatives 1-3, which had been prepared by solid-phase parallel syntheses, were characterized using mPW1PW91/6-311G(d,p) (hybrid HF-DF) calculations. The total electronic energies, normal vibrational modes, Gibbs free energies, and HOMOs and LUMOs of sixteen different structures from three different groups were analyzed. The energy differences between the HOMOs and LUMOs of the various unsymmetrical trans-stilbenes are in accord with the maximum absorption peaks of the experimental UV spectra of 1-3. The calculated normal vibrational modes of 21 were comparable with its experimental IR spectrum. The $\pi$-conjugation in the para-connected biphenyl group of 2 is better than the one in the metaconnected biphenyl group on the shorter side of 3.