• Title/Summary/Keyword: Various Contamination

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Plasma Corrosion in Oxalic Acid Anodized Coatings Depending on Tartaric Acid Content

  • Shin, Jae-Soo;Song, Je-Boem;Choi, Sin-Ho;Kim, Jin-Tae;Oh, Seong-Geun;Yun, Ju-Young
    • Applied Science and Convergence Technology
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    • v.25 no.1
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    • pp.15-18
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    • 2016
  • Study investigated the optimal anodizing conditions for fabricating an oxide film that produces less contamination in a corrosive plasma environment, using oxalic acid and tartaric acid. Oxide films were produced using sulfuric acid, oxalic acid, and tartaric acid electrolyte mixtures with various mole ratios. The oxide film made by adding 0.05M tartaric acid to 0.3M oxalic acid showed higher breakdown voltage and lower leakage current. Additionally, contamination particles were reduced during plasma etching, thus demonstrates that this mixture presented optimal conditions. However, higher tartaric acid content (0.1 M, 0.15 M) led to lower breakdown voltages and higher leakage currents. Also, it resulted in more cracking during thermal shock tests as well as the generation of more contamination particles during plasma processing.

Effect of CO in Anode Fuel on the Performance of Polymer Electrolyte Membrane Fuel Cell (수소연료 중 일산화탄소의 고분자전해질 연료전지에 대한 영향)

  • Kwon, Jun-Taek;Kim, Jun-Bum
    • Transactions of the Korean hydrogen and new energy society
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    • v.19 no.4
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    • pp.291-298
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    • 2008
  • Carbon monoxide(CO) is one of the contamination source in reformed hydrogen fuel with an influence on performance of polymer electrolyte membrane fuel cell(PEMFC). The studies of CO injection presented here give information about poisoning and recovery processes. The aim of this research is to investigate cell performance decline due to carbon monoxide impurity in hydrogen. Performance of PEM fuel cell was investigated using current vs. potential experiment, long time(10 hours) test, cyclic feeding test and electrochemical impedance spectra. The concentrations of carbon monoxide were changed up to 10 ppm. Performance degradation due to carbon monoxide contamination in anode fuel was observed at high concentration of carbon monoxide. The CO gas showed influence on the charge transfer reaction. The performance recovery was confirmed in long time test when pure hydrogen was provided for 1 hour after carbon monoxide had been supplied. The result of this study could be used as a basis of various reformation process design and fuel quality determination.

A Study on the change of Ecological Environment in Cave cause by the Pollution of Cave Environment and Analysis of Environmental Pollutants in Cave (환경오염으로 인한 동굴생태환경의 변화와 환경오염물질 분석에 관한 연구)

  • 이경호
    • Journal of the Speleological Society of Korea
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    • no.61
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    • pp.5-16
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    • 2000
  • Recently many environmental researcher are concerned about the ecological environment and the issue of environmental pollution in cave. In this paper we discuss about air pollution, water pollution, state of water quality, ecological environment and situation of environmental public damage in cave The concerning of air pollution in cave is mainly to the type of secondary contamination, which much is developed in various fields recently. The natural water in the most of cave is no problems but ground water has slitting with natural water during much raining period. The state of water quality is gradually contaminated with artificial environmental pollution, that is, the contents of kinds of Aluminum, Nickel, Copper, Zinc and Calcium are higher than before. On the other hand it is very important things to keep the control of constant temperature, darkness and humidity in cave. The contamination by lamp flora and even black colored contamination are appeared nowadays. The ecological environment in cave destructed by growing of mi coorganism. In fact the internal of cave is shielded with the state of climate of cave external but the environment of internal cave is contaminated, because blowing from external climate state. In addition to environmental pollution caused by carbon dioxide and body temperature of tourists. By the way eco-examination of cave is black color public damage, green color one and white color one has been discovered, so we need to have the situation of demand of environmental reservation alternatives.

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Prediction of Surface Water Contamination with RDX Transported from Soil in a Neighboring Firing Range (포탄 사격장 토양의 RDX에 의한 인근 하천 오염 예측)

  • Park, Jungtae;Lee, Dong Soo
    • Journal of the Korea Institute of Military Science and Technology
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    • v.22 no.6
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    • pp.832-840
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    • 2019
  • Recently, pollution from gunpowder due to shell shootings at military drilling sites has raised various environmental concerns. The purpose of this study is to predict the contamination level of RDX in the soil area of the firing range zone near Anwol river watershed, the study site, and the intake area, Anwol river and Imjin river, as a function of time and space. In this study, a multimedia model was developed to predict the variation of RDX contamination by rainfall. The range of the medium was limited to soil, water, and sediment, and excluded the atmosphere, taking into account the physical and chemical properties of RDX with low vapor pressure and low Henry's constant. The pollutant levels of the waters of compartments, including the last section of the Imjin River affecting the water intake, was compared with the environmental standard for RDX.

Case for Detection and Prevention of Inflow Section for Contaminant through Annular Space in Borehole, Jeju Island (제주도 관정 공벽 내 오염물질 유입 구간 탐지 및 차단 사례)

  • Song, Sung-Ho;Hwangbo, Dongjun;Kim, Jin-Sung;Yang, Won-Seok
    • Journal of Soil and Groundwater Environment
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    • v.27 no.3
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    • pp.1-10
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    • 2022
  • Most wells developed in Jeju island before the enactment of the Groundwater Management Ordinance in 2002 are vulnerable to aquifer contamination due to inflow of upper groundwater having the high concentration of nitrate nitrogen, likely due to incomplete grouting in upper section of the wells. Although these wells require entire reinstallation, it is often necessary to rehabilitate the existing wells due to various constraints. Therefore, to identified the inflow section of contaminants, the thermal level sensor (TLS) technique was firstly applied for three wells, which enables to monitor temperature variations in every 50 cm depth. Then, the grouting material was injected to the upper section to prevent the inflow of upper contaminated groundwater into the entire aquifer. By applying TLS technique, it was found that the temperature deviations in the upper groundwater inflow section decreased sharply. Moreover, both the change in the concentration of nitrate nitrogen in the rainy/dry seasons and the average concentrations were found to decrease rapidly after grouting material injection. Consequently, the application of TLS proposed in the study turned out to be appropriate to prevent aquifer contamination.

In-situ Process Monitoring Data from 30-Paired Oxide-Nitride Dielectric Stack Deposition for 3D-NAND Memory Fabrication

  • Min Ho Kim;Hyun Ken Park;Sang Jeen Hong
    • Journal of the Semiconductor & Display Technology
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    • v.22 no.4
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    • pp.53-58
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    • 2023
  • The storage capacity of 3D-NAND flash memory has been enhanced by the multi-layer dielectrics. The deposition process has become more challenging due to the tight process margin and the demand for accurate process control. To reduce product costs and ensure successful processes, process diagnosis techniques incorporating artificial intelligence (AI) have been adopted in semiconductor manufacturing. Recently there is a growing interest in process diagnosis, and numerous studies have been conducted in this field. For higher model accuracy, various process and sensor data are required, such as optical emission spectroscopy (OES), quadrupole mass spectrometer (QMS), and equipment control state. Among them, OES is usually used for plasma diagnostic. However, OES data can be distorted by viewport contamination, leading to misunderstandings in plasma diagnosis. This issue is particularly emphasized in multi-dielectric deposition processes, such as oxide and nitride (ON) stack. Thus, it is crucial to understand the potential misunderstandings related to OES data distortion due to viewport contamination. This paper explores the potential for misunderstanding OES data due to data distortion in the ON stack process. It suggests the possibility of excessively evaluating process drift through comparisons with a QMS. This understanding can be utilized to develop diagnostic models and identify the effects of viewport contamination in ON stack processes.

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A Grey Wolf Optimized- Stacked Ensemble Approach for Nitrate Contamination Prediction in Cauvery Delta

  • Kalaivanan K;Vellingiri J
    • Economic and Environmental Geology
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    • v.57 no.3
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    • pp.329-342
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    • 2024
  • The exponential increase in nitrate pollution of river water poses an immediate threat to public health and the environment. This contamination is primarily due to various human activities, which include the overuse of nitrogenous fertilizers in agriculture and the discharge of nitrate-rich industrial effluents into rivers. As a result, the accurate prediction and identification of contaminated areas has become a crucial and challenging task for researchers. To solve these problems, this work leads to the prediction of nitrate contamination using machine learning approaches. This paper presents a novel approach known as Grey Wolf Optimizer (GWO) based on the Stacked Ensemble approach for predicting nitrate pollution in the Cauvery Delta region of Tamilnadu, India. The proposed method is evaluated using a Cauvery River dataset from the Tamilnadu Pollution Control Board. The proposed method shows excellent performance, achieving an accuracy of 93.31%, a precision of 93%, a sensitivity of 97.53%, a specificity of 94.28%, an F1-score of 95.23%, and an ROC score of 95%. These impressive results underline the demonstration of the proposed method in accurately predicting nitrate pollution in river water and ultimately help to make informed decisions to tackle these critical environmental problems.

Heavy Metal Contamination and Spatial Differences in Redox Condition of the Artificial Shihwa lake, Korea (시화호의 중금속 오염과 산화-환원 상태의 공간적 차이)

  • Hyeon, Sang-Min;Kim, Eun-Su;Paeng, U-Hyeon
    • Journal of Environmental Science International
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    • v.13 no.5
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    • pp.479-488
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    • 2004
  • Five sediment cores from the tidal flat of artificial Lake Shihwa are analyzed in terms of sedimentology and geochemistry to evaluate the heavy metal contamination and redox condition of surficial sediment following the Shihwa seawall construction. The variability of concentrations of various elements depends on the depositional environment, and reflects the various redox conditions and sediment provenances. The amounts of Ti and Al and their ratio of Ti/ Al with respect to Li clearly indicate that there is an anthropogenic contribution to the surficial sediment. The high concentrations of heavy metals suggest an anthropogenic contribution at ST. 34 and ST. 22. Concentrations of most elements (Cr, Cu, Zn and Pb) are higher near the Shihwa-Banwol industrial complex than in the central part of Lake Shihwa. Concentrations of heavy metal in surficial sediment near the Shihwa-Banwol industrial complex are two to eight times higher than in the center of Lake Shihwa. Enrichment factors (EF), which are normalized by the unpolluted shale, suggests a significant metallic contamination near the Shihwa-Banwol industrial complex (SBIC). The redox condition is divided into two anoxic and mixed oxi $c_oxic zones based on the carbon:sulfur (C/S) ratios of organic matter and elemental relationships. Correlations among geochemical elements Mn, U and Mo are significantly different from site to site, and may therefore be an indicator of the spatial redox condition. Controlling factors for switching anoxic/oxic conditions are thought to be water depth and the differences in industrial effluent supply. The variations of the Cu/Mn ratio in the sediments confirms above mentioned spatial differences of a redox condition in part, and therefore shows a location-dependence redox condition in sediments at four other sites. The redox condition of the surficial sediment characteristics of the Shihwa Lake are controlled by its geographic location and water depth.th.

The Microbial Contamination and Effective Control Method of Dental Unit Water System (치과용 유니트 수계의 미생물 오염 및 효과적인 관리 방법)

  • Yoon, Hye Young;Lee, Si Young
    • Journal of dental hygiene science
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    • v.15 no.4
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    • pp.383-392
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    • 2015
  • Dental chair unit (DCU) is the most essential equipment for the dental treatment in dentistry. DCU output water is used for various applications during dental treatment. DCU output water must be clean at the same level as drinking water since patients and dental staff are regularly exposed to water and aerosols generated from the DCU. Many studies demonstrated that DCU output water is frequently contaminated with microorganisms including opportunistic pathogen such as Legionella and Pseudomonas species. Thus, DCU output water may be a potential source of infection. In order to reduce microbial contamination levels in DCU output water, periodic management and continuous disinfection are necessary. Currently, there are a variety of disinfection methods for managing DCU output water and its efficacy is also diverse. We reviewed the level of microbial contamination, clinical implications of contaminated DCU output water and the various DCU disinfection methods.

A study on the effects of an artificial oil-spill on the ultrastructural changes in the digestive glands of Crassostrea gigas (태안반도 기름 유출사고 이후 인근해안에 서식하는 굴(Crassostrea gigas) 간췌장 (digestive gland) 의 미세구조 변화에 관한 연구)

  • Jun, Je-Cheon;Kang, Se-Won;Baek, Moon-Ki;Jeong, Ji-Eun;Shin, Yun-Kyung;Park, Young-Je;Han, Yeon-Soo;Lee, Yong-Seok
    • The Korean Journal of Malacology
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    • v.27 no.1
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    • pp.77-86
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    • 2011
  • The unwanted artificial oil-spill has severely contaminated the coastal environment in the world. Level of contamination has so far been monitered by various indicator species including mussel, oysters, flounder, and cockle. In this study, we decided to use the oyster as a model organism to observe the morphological changes being exposed to the artificial oil-spill in the coastal areas in Taean, Korea. The oysters were collected from four local sites (Sindu-ri, Uiwang-ri, Jonghyeon-dong, Ansan and Uihang-ri) exposed to various levels of pollution after an oil spill in Taean. Microscopic analysis of the hepatopancreatic microstructure in the digestive gland from the collected oysters show that the swelling, whorl, and destruction phenomenon of the nuclear membrane, a well-known microstructure induced by heavy metal exposure, was observed. Nuclear body (Nb), another typical characteristic of contamination or infection were also observed in some samples. Necrosis was observed in tissue samples collected from the area with a high degree of oil pollution. In addition, parasite-like particles (virus, perkinsus) were observed in most samples. Taken together, these results suggest that oil contamination in the oyster habitats influences the cytopathological changes in Crassostrea gigas.