• Journal of Ceramic Processing Research
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• v.19 no.5
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• pp.439-443
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• 2018

The outstanding characteristics of high quality GaN single crystal substrates make it possible to apply the manufacture of high brightness light emitting diodes and power devices. However, it is very difficult to obtain high quality GaN substrate because the process conditions are hard to control. In order to effectively control the formation of GaN polycrystals during the bulk GaN single crystal growth by the HVPE (hydride vapor phase epitaxy) method, a quartz ring was introduced in the edge of substrate. A variety of evaluating method such as high resolution X-ray diffraction, Raman spectroscopy and photoluminescence was used in order to measure the effectiveness of the quartz ring. A secondary ion mass spectroscopy was also used for evaluating the variations of impurity concentration in the resulting GaN single crystal. Through the detailed investigations, we could confirm that the introduction of a quartz ring during the GaN single crystal growth process using HVPE is a very effective strategy to obtain a high quality GaN single crystal.

• Journal of Ceramic Processing Research
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• v.13 no.spc2
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• pp.295-299
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• 2012

We investigated the crystal and the optical properties of GaN-based blue light emitting diodes (LEDs) which were simultaneously grown on c-plane (0001) and semipolar (11-22) GaN templates by using metal-organic chemical vapor deposition (MOCVD). The X-ray rocking curves (XRCs) full width at half maximums (FWHMs) of c-plane (0001) and semipolar (11-22) GaN templates were 275 and 889 arcsec, respectively. In addition, high-resolution X-ray ω-2θ scan showed that satellite peaks of semipolar (11-22) InGaN quantum-wells (QWs) was weaker and broader than that of c-plane (0001) InGaN QWs, indicating that the interface quality of c-plane (0001) QWs was superior to that of semipolar (11-22) QWs. Photoluminescence (PL) and electroluminescence (EL) results showed that the emission intensity and the FWHMs of polar c-plane (0001) LED were much higher and narrower than those of semipolar (11-22) LED, respectively. From these results, we believed that relative poor crystal quality of semipolar (11-22) GaN template might give rise to the poor interfacial quality of QWs, resulting in lower output power than conventional c-plane (0001) GaN-based LEDs.

• Atmosphere
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• v.22 no.1
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• pp.29-45
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• 2012

An unusual autumn storm developed rapidly in the western part of the East sea on the early morning of 23 October 2006. This storm produced a record-breaking heavy rain and strong wind in the northern and middle part of the Yeong-dong region; 24-h rainfall of 304 mm over Gangneung and wind speed exceeding 63.7 m $s^{-1}$ over Sokcho. In this study, MTSAT-1R (Multi-fuctional Transport Satellite) water vapor and infrared channel imagery are examined to find out some features which are dynamically associated with the development of the storm. These features may be the precursor signals of the rapidly developing storm and can be employed for very short range forecast and nowcasting of severe storm. The satellite features are summarized: 1) MTSAT-1R Water Vapor imagery exhibited that distinct dark region develops over the Yellow sea at about 12 hours before the occurrence of maximum rainfall about 1100 KST on 23 October 2006. After then, it changes gradually into dry intrusion. This dark region in the water vapor image is closely related with the positive anomaly in 500 hPa Potential Vorticity field. 2) In the Infrared imagery, low stratus (brightness temperature: $0{\sim}5^{\circ}C$) develops from near Bo-Hai bay and Shanfung peninsula and then dissipates partially on the western coast of Korean peninsula. These features are found at 10~12 hours before the maximum rainfall occurrence, which are associated with the cold and warm advection in the lower troposphere. 3) The IR imagery reveals that two convective cloud cells (brightness temperature below $-50^{\circ}C$) merge each other and after merging it grows up rapidly over the western part of East sea at about 5 hours before the maximum rainfall occurrence. These features remind that there must be the upward flow in the upper troposphere and the low-layer convergence over the same region of East sea. The time of maximum growth of the convective cloud agrees well with the time of the maximum rainfall.

• Journal of the Korean Vacuum Society
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• v.20 no.5
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• pp.361-366
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• 2011

An in-situ, real-time monitoring of GaN epilayers grown by low pressure metalorganic chemical vapor deposition system modified for spectral reflectance was performed. Reflectance spectrums from 190~861 nm were observed using p-polarized light with incident angle of $75^{\circ}$. All reflectance spectrums showed interference oscillation caused by multiple reflection within GaN epilayers, and the spectrum from GaN with low crystalline quality showed weak reflectance intensity and much low amplitude of the oscillation because many defects in GaN resulted in light scattering and absorption. Signal variation of reflected light which was selected around strong constructive wavelength range was also observed during $NH_3$ supplying and $NH_3$ cut-off. There was no significant change in signal intensity when $NH_3$ cut-off for 10 sec, but it showed higher intensity when $NH_3$ was cut off for over 30 sec and its intensity kept unchanged. This result indicates that GaN surface was N-terminated during $NH_3$ supplying but Ga-terminated during $NH_3$ cut-off because of high nitrogen equilibrium vapor pressure of GaN, and metallic Ga-terminated surface caused slightly higher reflectance intensity.

• Atmosphere
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• v.23 no.3
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• pp.307-320
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• 2013

We performed comprehensive quality control for eddy-covariance measurements from 3 farmland sites and 1 industrial site adjacent to Nakdong river. The quality control program is based on Foken and Wichura (1996) and Vicker and Mahrt (1997) and we added criteria for trend and standard deviation for scalar variables and modified criteria for non-stationarity condition of Foken and Wichura (1996) to consider random error of fluxes. The classification of data quality is designed for the raw data and the processed flux data, separately. Use of added criteria efficiently reduces the number of outlier for water vapor and $CO_2$ fluxes and use of modified criteria for non-stationarity reduces the number of outlier for scalar fluxes and increases the number of data with accepted quality for further work. Energy balance ratio is higher in farmlands than industrial site, which is due to neglect of heat storage term in industrial site. Among farmland sites, C4 site shows higher energy balance ratio than other sites. This is due to more homogeneous surface of C4 site than other farmland sites. However, energy balance ratio is very low or even negative at night. Mismatch between the flux footprint and the other energy component footprint over the heterogeneous surface is main cause for energy imbalance at night. Other possible causes are also discussed.

• Journal of Energy Engineering
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• v.24 no.4
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• pp.166-174
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• 2015

This study examined combustion characteristics by selecting the fuel which have a different physical properties compared to gasoline in order to examine the effects of vehicle performance and environment depending on the physical properties. The experiment examined the combustion characteristic in the optimum ignition timing according to the physical properties change and the lean burn by performing control about ignition timing and air-fuel ratio for each fuel, and it was also evaluated the exhaust gas according to the experiment. We used a single-cylinder engine for the experiment, and tested for gasoline properties change by selecting a fake fuel that beyond the fuel quality standards in 석대법. As a result, in the case of the selected fuel showed a difference in Octane and distillation characteristics, vapor pressure and it was also found to unstable combustion, and leads to a large amount of harmful exhaust gas.

• Proceedings of the Korean Vacuum Society Conference
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• 2011.02a
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• pp.48-48
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• 2011

We have developed a chemically-driven top-down approach using vapor phase HCl to form various GaN nanostructures and successfully demonstrated dislocation-free and strain-relaxed GaN nanostructures without etching damage formed by a selective dissociation method. Our approach overcomes many limitations encountered in previous approaches. There is no need to make a pattern, complicated process, and expensive equipment, but it produces a high-quality nanostructure over a large area at low cost. As far as we know, this is the first time that various types of high-quality GaN nanostructures, such as dot, cone, and rod, could be formed by a chemical method without the use of a mask or pattern, especially on the Ga-polar GaN. It is well known that the Ga-polar GaN is difficult to etch by the common chemical wet etching method because of the chemical stability of GaN. Our chemically driven GaN nanostructures show excellent structure and optical properties. The formed nanostructure had various facets depending on the etching conditions and showed a high crystal quality due to the removal of defects, such as dislocations. These structure properties derived excellent optical performance of the GaN nanostructure. The GaN nanostructure had increased internal and external quantum efficiency due to increased light extraction, reduced strain, and improved crystal quality. The chemically driven GaN nanostructure shows promise in applications such as efficient light-emitting diodes, field emitters, and sensors.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2005.11a
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• pp.17-20
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• 2005

This study investigates mock-up test of the concrete containing crushed sands with improved quality and following could be draws as conclusions. The slump satisfies the target value. The air content reaches the goal, however, it decreases by the occurrence of loss with elagse of age. In normal strength region, the setting time of CS24 member is shorter than that of SS24 member. In high strength region, the setting time of SS50 member is make only slower than that of CS5O because of the use of retarding AE agent. The compressive strength of the concrete using crushed sands is little higher than the concrete using washed sea sands, and the compressive strength of core sample increases at lower part. Drying shrinkage of the concrete using crushed sands is larger than that using washed sea sands. At water caring condition, both the concrete using crushed sands and using washed sands expand at first, exhibit to be swelled and with elagse of age, they remain relatirely constant. Also, the drying shrinkage occurred greatly when the width and thickness of a member are small because it is easy to evaporate the inner part vapor in the small width and thickness of a member. there can be little different according to the location of a contact gauge, however it is similar to the change of specimen's length change. The concrete using crushed sands, of which grading, grain shape and fine particle is improved, are comparable to the quality of the concrete using washed sea sand.

• Korean Chemical Engineering Research
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• v.51 no.2
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• pp.250-256
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• 2013

Gasoline generates organic acid and polymer (gum) by hydrocarbon oxidation depending on the storage environment such as temperature and exposure to sunlight, which can cause metal corrosion, rubber and resin degradation and vehicle malfunction caused by accumulation in fuel supply system. The gasoline which has not been used for a long time in bi-fuel (LPG-Gasoline) vehicle causes problems, and low octane number gasoline have evaporated into the field, but the exact cause has not been studied yet. In this study, we suggest a plan of quality management by investigating the gasoline oxidation behavior. In order to investigate the oxidation behavior of gasoline, changes of gasoline properties were analyzed at various storage conditions such as storage time, storage vessel type (vehicle fuel tank, PE vessel and Fe vessel) and storage circumstances (sunlight exposure and open system, etc.). Currently distributing gasoline and bioethanol blended fuel (blended 10%) were stored for 18 weeks in summer season. The sample stored in PE vessel was out of quality standard (octane number, vapor pressure, etc.) due to the evaporation of the high octane number and low boiling point components through the vessel cap and surface. Especially, the sunlight exposure sample stored in PE vessel showed rapid decrease of vapor pressure and increase of gum. Bioethanol blended fuel showed similar results as gasoline.

• Proceedings of the KSME Conference
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• 2007.05b
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• pp.2217-2221
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• 2007

Because of the ozone layer depletion and global warming, new alternative refrigerants are being developed. In this study, evaporation heat transfer characteristics of carbon dioxide flowing upward in a vertical tube have been investigated by experiment. Before the test section, a pre-heater is installed to adjust the inlet quality of the refrigerant to a desired value. A smooth tube with outer diameter of 5 mm and length of 1.44 m was selected as a test tube. The test was conducted at mass fluxes of 212 to 530 kg/$m^2s$, saturation temperature of -5 to 20$^{\circ}C$, and heat fluxes of 20 to 45 kW/$m^2$. As the vapor quality and mass fluxes increase, the heat transfer coefficients of carbon dioxide are decreased, and the heat transfer coefficients increase when the heat fluxes and saturation temperatures increase.