• Title/Summary/Keyword: Vapor pressure of water

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Development of Fuel Conditioning System for 30 kW-class LFG Gasturbine Power Generation (30kW급 LFG 가스터빈 발전용 연료화 정제시스템 개발)

  • Hur, Kwang-Beom;Park, Jung-Keuk;Rhim, Sang-Gyu;Lee, Jung-Bin
    • New & Renewable Energy
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    • v.6 no.1
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    • pp.29-37
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    • 2010
  • Biogas is a carbon neutral energy and consists of mostly methane and carbon dioxide, with smaller amounts of water vapor, and trace amounts of $H_2S$, Siloxane and other impurities. Hydrogen sulfide and Siloxane usually must be removed before the gas can be used for generation of electricity or heat. The goals of this project are to develope the Fuel conditioning system of Land Fill Gas for 30kW-Micro Gas Turbine co-generation system. The fuel conditioning system mainly consists of $H_2S$ removal system, Land Fill Gas compressor, Siloxane removal system and many filtering systems. The fuel requirement of 30kW MGT is at least 32% of $CH_4$, $H_2S$ (<30 ppm), Siloxane (<5ppb) and supply pressure (> 0.6 MPa) from LFG compressor. Main mechnical charateristics of Micro Gas Turbine system by using LFG have the specific performance; 1) high speed turbine speed (96,000 rpm) 2) very clean emmission NOx (<9 ppm) 3) high efficiency of energy conversion rate. This paper focuses on the development of design technology for LFG fuel conditioning system. The study also has the plan to replace the fuel of gas turbine and other distributed power systems. As the increase of Land Fill Gas (LFG), this system help to contribute to spread more New & Renewable Energy and the establishment of Renewable Portfolio Standards (RPS) for Korea.

Assessment of Reference Evapotranspiration Equations for Missing and Estimated Weather Data (기상자료의 결측과 산정에 따른 기준작물 증발산량 공식의 비교 평가)

  • Yoon, Pu Reun;Choi, Jin-Yong
    • Journal of The Korean Society of Agricultural Engineers
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    • v.60 no.3
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    • pp.15-25
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    • 2018
  • Estimating the reference evapotranspiration is an important factor to consider in irrigation system design and agricultural water use. However, there is a limitation in using the FAO Penman-Monteith (FAO P-M) equation, which requires various meteorological data. The purpose of this study is to compare three reference evapotranspiration (ETo) equations in the case of meteorological data missing for 11 study weather stations. Firstly, the FAO P-M equation is used for reference potential evapotranspiration estimation with the actual solar radiation data $R_n$ and the actual vapor pressure $e_a$. Then, in the case of $R_n$, and $e_a$ are missed, the reference evapotranspirations applying FAO P-M, Priestley-Taylor (P-T), Hargreaves (HG) equation were calculated using other meteorological factors. Secondly, MAE, RMSE, $R^2$ were calculated to compare ETo relationship from the ETo equations. From the results, ETo with Hargreaves equation in coastal areas and the Priestley-Taylor equation in the inland areas showed relatively high correlation with FAO P-M when $e_a$ data is missed. In the case of $R_n$ data is missed or two weather data, $e_a$, and $R_n$ data are all missed, $R^2$ value in Priestley-Taylor equation was highest in coastal areas, and $R^2$ values in Hargreaves equation were the high values for 7 inland areas. The results of sensitivity analysis showed that net radiation was the most sensitive for P-T and HG equation, and for FAO P-M, the most sensitive factor was net radiation and relative humidity, air temperature and wind speed were follows. Therefore, in considering of the accessibility to the coast, the types of the missing wether data, and the correlation and the magnitude of error, the reference evapotranspiration equations would be selected in sense of different conditions.

Pool Boiling Enhancement of R-123 Using Perforated Plates (다공판을 사용한 R-123 풀비등 열전달 촉진)

  • Kim, Nae-Hyun
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.40 no.5
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    • pp.275-281
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    • 2016
  • In this study, we investigate the pool boiling enhancement caused by perforated plates on top of a smooth surface. We conduct tests using R-123 at atmospheric pressure. It was shown that perforated plates significantly enhanced the pool boiling of the smooth surface. The reason may be attributed to the increased bubble contact area between the plates. The results showed that the enhancement ratio was dependent on the heat flux. At high heat flux, the enhancement ratio increased as the porosity increased. However, at low heat flux, the enhancement ratio decreased as the porosity increased. For the present investigation, the optimum configuration had a pore diameter of 2.0 mm, pore pitch of $2.5mm{\times}5.0mm$ or $5.0mm{\times}5.0mm$, and a gap width of 0.5 mm, which yielded heat-transfer coefficients that are close to those of GEWA-T. The optimum porosity for R-123 was significantly larger than that of water or ethanol. The reason for this may be the large liquid-to-vapor density ratio along with the small latent heat of vaporization of R-123. The perforated plates yielded smaller boiling hysteresis compared with that of the smooth surface.

Effect of ${Fe_2}{O_3}$ Addition on Mechanical and Optical Properties of t-$ZrO_2$/${Al_2}{O_3}$ Composites (${Fe_2}{O_3}$ 첨가에 따른 t-$ZrO_2$/${Al_2}{O_3}$ 복합체의 기계적 및 광학적 특성)

  • Lee, Deuk-Yong;Kim, Dae-Joon;Lee, Myung-Hyun;Park, Il-Seok;Choi, Hyun
    • Journal of the Korean Ceramic Society
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    • v.37 no.4
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    • pp.354-358
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    • 2000
  • Tetragonal (t)-ZrO2/Al2O3 composites doped with Y2O3, Nb2O5, and Fe2O3 ((Y, Nb, Fe)-TZP/Al2O3) were prepared over the range containing Fe2O3 from 0.1 to 0.5 mol% with 0.1 mol% intervals to evaluate the effect of Fe2O3 addition on chromaticity, hydrothermal stability, and mechanical property of the composites. After autoclaving for 20 h at 18$0^{\circ}C$ under 3.5 MPa water vapor pressure, no tlongrightarrowm phase transformation was observed probably due to the preferential solid solubility of Fe2O3 in Al2O3, the presence of the rigid Al2O3 particles, and the inherent phase stability of (Y, Nb)-TZP. The optimized strength and the fracture toughness of the composite were 700 MPa and 8.5 MPa.m1/2, respectively, when 0.1 mol% Fe2O3 was added. The composites have shown a gradual color change from a slightly white ivory to a pale yellowish brown with increasing the Fe2O3 concentration.

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Analysis of An Outflow Boundary Induced Heavy Rainfall That Occurred in the Seoul Metropolitan Area (수도권에서 유출류 경계(Outflow Boundary)를 따라 발생한 집중호우 분석)

  • Lee, Ji-Won;Min, Ki-Hong
    • Atmosphere
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    • v.27 no.4
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    • pp.455-466
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    • 2017
  • In Korea, property and human damages occur annually due to heavy precipitation during the summer. On August 8, 2015, heavy rainfall occurred in the Seoul metropolitan area due to an outflow boundary, and $77mmhr^{-1}$ rainfall was recorded in Gwangju, Gyeonggi Province. In this study, the simulation of the WRF numerical model is performed to understand the cause and characteristics of heavy rainfall using the Conditional Instability of the Second Kind (CISK), potential vorticity (PV), frontogenesis function, and convective available potential energy (CAPE) analyses, etc. Convective cells initiated over the Shandong Peninsula and located on the downwind side of an upper level trough. Large amounts of water vapor were supplied to the Shandong Peninsula along the southwestern edge of a high pressure system, and from the remnants of typhoon Soudelor. The mesoscale convective system (MCS) developed through CISK process and moved over to the Yellow Sea. The outflow boundary from the MCS progressed east and pushed cold pool eastward. The warm and humid air over the Korean Peninsula further enhanced convective development. As a result, a new MCS developed rapidly over land. Because of the latent heat release due to convection and precipitation, strong potential vorticity was generated in the lower atmosphere. The rapid development of MCS and the heavy rainfall occurred in an area where the CAPE value was greater than $1300Jkg^{-1}$ and the fronto-genesis function value of 1.5 or greater coincided. The analysis result shows that the MCS driven by an outflow boundary can be identified using CISK process.

Application of Ionic Liquids in Biotechnology (생물공학에서 이온성 액체의 응용)

  • Lee Sang-Mok;Chang Woo-Jin;Koo Yoon-Mo
    • KSBB Journal
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    • v.20 no.3
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    • pp.183-191
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    • 2005
  • Ionic liquids, composed of organic cations and either organic or inorganic anions remain liquid over a wide range of temperature. ionic liquids are a new group of solvents or extractants of great interest as a potential 'green solvent'. Ionic liquids are gaining wide recognition as novel solvents in many research fields, such as chemistry, chemical engineering, electrochemitry, etc. However, not much researches have been done related to biotechnology using ionic liquids, while a lot of researches have been performed in chemistry. The merits of ionic liquids in bioseparation technology are originated from some unique properties of ionic liquids, such as negligible vapor pressure, good thermal stability, controllable viscosity and miscibility with water and organic solvents. An appropriate selection of ionic liquid for bioprocesses requires basic knowledge on physicochemical properties of ionic liquids. This review gives a brief overview on the application of ionic liquids in biotechnology, including bioconversion and bioseparation.

Prediction of the Toxicity of Dimethylformamide, Methyl Ethyl Ketone, and Toluene Mixtures by QSAR Modeling

  • Kim, Ki-Woong;Won, Yong Lim;Hong, Mun Ki;Jo, Jihoon;Lee, Sung Kwang
    • Bulletin of the Korean Chemical Society
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    • v.35 no.12
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    • pp.3637-3641
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    • 2014
  • In this study, we analyzed the toxicity of mixtures of dimethylformamide (DMF) and methyl ethyl ketone (MEK) or DMF and toluene (TOL) and predicted their toxicity using quantitative structure-activity relationships (QSAR). A QSAR model for single substances and mixtures was analyzed using multiple linear regression (MLR) by taking into account the statistical parameters between the observed and predicted $EC_{50}$. After preprocessing, the best subsets of descriptors in the learning methods were determined using a 5-fold cross-validation method. Significant differences in physico-chemical properties such as boiling point (BP), specific gravity (SG), Reid vapor pressure (rVP), flash point (FP), low explosion limit (LEL), and octanol/water partition coefficient (Pow) were observed between the single substances and the mixtures. The $EC_{50}$ of the mixture of DMF and TOL was significantly lower than that of DMF. The mixture toxicity was directly related to the mixing ratio of TOL and MEK (MLR $EC_{50}$ equation = $1.76997-1.12249{\times}TOL+1.21045{\times}MEK$), as well as to SG, VP, and LEL (MLR equation $EC_{50}=15.44388-19.84549{\times}SG+0.05091{\times}VP+1.85846{\times}LEL$). These results show that QSAR-based models can be used to quantitatively predict the toxicity of mixtures used in manufacturing industries.

Hydrogen explosion effects at a containment building following a severe accident (중대사고시 수소폭발이 격납건물에 미치는 영향)

  • Ryu, Myeong-Rok;Park, Kweon-Ha
    • Journal of Advanced Marine Engineering and Technology
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    • v.40 no.3
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    • pp.165-173
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    • 2016
  • On March 11, 2011, a massive earthquake measuring 9.0 on the Richter scale and subsequent 10-.14 m waves struck the Fukushima Daiichi (FD) Nuclear Power Plant. The main and backup electric power was damaged preventing the cooling system from functioning. Fuel rods overheated and led to hydrogen explosions. If heat in the fuel rods is not dissipated, the nuclear fuel coating material (e.g., Zircaloy) reacts with water vapor to generate hydrogen at high temperatures. This hydrogen is released into the containment area. If the released hydrogen burns, the stability of the containment area is significantly impacted. In this study, researchers performed an explosion analysis in a high-risk explosion area, analyzing the hydrogen distribution in a containment building [1] and the effects of a hydrogen explosion on containment safety. Results indicated that a hydrogen explosion was possible throughout the containment building except the middle area. If an explosion occurs at the top of the containment building with more than 40% of the hydrogen collected or in the bottom right or left side of the of containment building, safety of the containment building could be threatened.

Investigating Statistical Characteristics of Aerosol-Cloud Interactions over East Asia retrieved from MODIS Satellite Data (MODIS 위성 자료를 이용한 동아시아 에어로졸-구름의 통계적 특성)

  • Jung, Woonseon;Sung, Hyun Min;Lee, Dong-In;Cha, Joo Wan;Chang, Ki-Ho;Lee, Chulkyu
    • Journal of Environmental Science International
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    • v.29 no.11
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    • pp.1065-1078
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    • 2020
  • The statistical characteristics of aerosol-cloud interactions over East Asia were investigated using Moderate Resolution Imaging Spectroradiometer satellite data. The long-term relationship between various aerosol and cloud parameters was estimated using correlation analysis, principle component analysis, and Aerosol Indirect Effect (AIE) estimation. In correlation analysis, Aerosol Optical Depth (AOD) was positively Correlated with Cloud Condensation Nuclei (CCN) and Cloud Fraction (CF), but negatively correlated with Cloud Top Temperature (CTT) and Cloud Top Pressure (CTP). Fine Mode Fraction (FMF) and CCN were positively correlated over the ocean because of sea spray. In principle component analysis, AOD and FMF were influenced by water vapor. In particular, AOD was positively influenced by CF, and negatively by CTT and CTP over the ocean. In AIE estimation, the AIE value in each cloud layer and type was mostly negative (Twomey effect) but sometimes positive (anti-Twomey effect). This is related to regional, environmental, seasonal, and meteorological effects. Rigorous and extensive studies on aerosol-cloud interactions over East Asia should be conducted via micro- and macro-scale investigations, to determine chemical characteristics using various meteorological instruments.

A Study on the Thermodynamic Analysis and the Computer Simulation for the $CO_2$ and $H_{2}S$ Capture Process Using Methanol as a Solvent (메탄올 용매를 이용한 이산화탄소와 황화수소 포집공정의 열역학적 해석 및 전산모사에 관한 연구)

  • Cho, Jung-Ho;Lee, Ji-Hwan
    • Clean Technology
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    • v.14 no.4
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    • pp.287-292
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    • 2008
  • In this study, computer simulation works have been performed for the capture process of the $CO_2$ and $H_{2}S$ gases contained in the effluent stream using methanol aqueous solution. In order to increase the solubilities of the $CO_2$ and $H_{2}S$ in the methanol aqueous stream, the operating pressure of the absorber was raised to 30 bar and the feeding temperature of the solvent was lowered to $-20^{\circ}C$ by using refrigeration cycle. NRTL liquid activity coefficient model was used to estimate the liquid phase nonidealities for methanol and water. Soave-Redlich-Kwong equation of state was used for the vapor phase nonidealities. Henry's law option was also used to calculate the solubilities of the supercritical noncondensible gases into the methanol aqueous solvent stream.

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