• KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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• v.12 no.2
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• pp.117-123
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• 2006

To mass-product useful biopolymer films, chitosan/gelatin blend films were prepared by solution casting method. Effect of mixing ratio, tensile strength(TS), elongation(${\Delta}E$) at break, total color difference(E), water vapor permeability(WVP) and oxygen permeability(OP) on chitosan/gelatin blend films properties were investigated. TS, ${\Delta}E$, E, WVP and OP values of chitosan/gelatin blend films were 43.43-38.30 MPa, 9.02-15.09%, 1.28-3.81, $0.8420-0.9673ng{\cdot}m/m^2{\cdot}s{\cdot}Pa$ and $1.5472{\times}10^{-7}-1.5424{\times}10^{-7}mL{\cdot}{\mu}m/m^2{\cdot}s{\cdot}Pa$, respectively. TS of the blend films decreased, while E and E of the blend films increased with increasing chitosan content. WVP and OP of the blend films did not show any significant relationship with mixing ratio and thickness of the blend films. OP of the blend films were lower than those of low density polyethylene and oriented polypropylene.

• Korean Journal of Food Science and Technology
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• v.26 no.2
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• pp.133-137
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• 1994

Functional properties of packaging films prepared with cellulose derivatives were measured. As a presolvation treatments of celluloses, 95% ethanol solution for methylcellulose (MC), hydroxypropyl-methylcellulose (HPMC) and ethylcellulose (EC) and water for hydroxypropyl cellulose (HPC) were used. For film sheeting, the ethanol concentration of final cellulose solution should exceed 50% for MC, HPMC and HPC and 80% for EC. Thickness and functionalities of the prepared films were varied by type, molecular weight and viscosity of the cellulose and kind of plasticizer used. Tensile strength of MC, HPMC and HPC films were $67.7{\sim}275.4\;MPa$, $124.6{\sim}260.0\;MPa$, and $14.8{\sim}29.4\;MPa$, respectively. The strength of MC and HPMC films was higher than that of low density polyethylene (LDPE) films $(13.1{\sim}27.6\;MPa)$. Solubility of the cellulose films varied widely by plasticizer used and the films containing polyethyleneglycol (PEG) as a plasticizer was more soluble than the films by glycerol. Maximum water vapor permeability and oxygen permeability of the cellulose films was more than 1,000 folds and less than one-twelfth of the LDPE film, respectively.

• Korean Journal of Food Science and Technology
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• v.37 no.1
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• pp.30-37
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• 2005

To mass-produce useful biopolymer films, chitosan/gelatin blend films were prepared by solution casting method. Effects of mixing ratio, tensile strength (TS), elongation (E) at break, total color difference (${\Dalta}E$), opacity, water vapor permeability (WVP), oxygen permeability (OP), and thermal properties on chitosan/gelatin blend films properties were investigated. TS, E, ${\Dalta}E$, opacity, WVP, and OP values were 58.24-22.01 MPa, 13.11-24.67%, 1.86-17.45, 0.3104-1.2161 nmO.D./${\mu}m$, $1.6875-1.7225ng{\cdot}m/m^{2}{\cdot}s{\cdot}Pa$, and $2.2380{\times}10^{-7}-2.2975{\times}10^{-7}\;mL{\cdot}{\mu}m/m^{2}{\cdot}s{\cdot}Pa$, respectively. TS of blend films decreased, while E, ${\Dalta}E$, and opacity increased with increasing chitosan content. WVP of blend films did not show any significant relationship with mixing ratio and thickness of blend films. Miscibility of films was examined over entire composition range by thermogravimetric analyzer (TGA) and dynamic mechanical analyzer (DMA). TGA results showed gelatin is more thermally stable than chitosan and some interactions among functional groups of two biopolymers. Glass transition temperature $(T_{2})$ of films as determined by DMA decreased with increasing content of chitosan in the blend. Results of thermal analysis indicate high miscibility among polymer components in the blend.

• Journal of the Korean GEO-environmental Society
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• v.9 no.2
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• pp.39-46
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• 2008

Due to the growth in industrialization, potential hazards in subsurface environments are becoming increasingly significant. The extraction of the contaminant from the soil and movement of the water are restricted due to the low permeability and adsorption characteristics of the reclaimed soils. There are a number of approaches to in-situ remediation that are used in contaminated sites for removing contaminants. These include soil flushing, dual phase extraction, and soil vapor extraction. Among these techniques, soil flushing was the focus of the investigation in this paper. Incorporated technique with PVDs has been used for dewatering from fine-grained soils for the purpose of ground improvement by means of prefabricated vertical drain systems. The laboratory model tests were performed by using the flushing tracer solutions for silty soils and recorded the tracer concentration changes with the elapsed time and flow rates. The modeling was intended to predict the effectiveness and time dependence of the remediation process. Modeling has been performed on the extraction, considering tracer concentration and laboratory model test characteristics. The computer model used herein are SEEP/W and CTRAN/W, this 2-D finite element program allows for modeling to determine hydraulic head and pore water pressure distribution, efficiency of remediation for the subsurface environment. It is concluded that the coefficient of permeability of contaminated soil is related with vertical velocity and extracted flow rate. The vertical velocity and extracted flow rate have an effect on dispersivity and finally are played an important role in-situ soil remediation.

• Korean Journal of Food Science and Technology
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• v.36 no.3
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• pp.432-439
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• 2004

Increase in water vapor barrier properties of sodium alginate films was studied by preparing composite films with fatty acids, i.e., lauric, palmitic, stearic, and oleic acids, and by treatment with 3% $CaCl_{2}$ solution for 3 min. Film thickness, surface color, microstructure, tensile strength (TS), elongation at break (E), water vapor permeability (WVP), water solubility (WS), and sorption isotherm of films were investigated. Microstructure of films observed with SEM was changed by fatty acid and $CaCl_{2}$ treatments. TS decreased 25-70% depending on fatty acid used, and increased 1.5- to 2-fold by $CaCl_{2}$ treatment. E decreased by both fatty acid and $CaCl_{2}$ treatments. Except oleic acid, WVP decreased significantly (p<0.05) by forming composite films with fatty acids, particularly with stearic acid, WVP decreased more than two-fold. WS also decreased by fatty acid and $CaCl_{2}$ treatments. In stearic acid, WS decreased about 30-fold by combined treatment of fatty acid and $CaCl_{2}$. Sorption isotherm showed typical biphasic pattern with deliquescent point of 0.75. Results of isotherms and BET monolayer moisture content indicated hydrophilicity of film decreased by $CaCl_{2}$ treatment.

• Applied Biological Chemistry
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• v.46 no.2
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• pp.113-116
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• 2003

Color value, total color difference $({\triangle}E)$, puncture strength (PS), tensile strength (TS), percent elongation(%E) at break values, and water vapor permeability (WVP) were determined for water-soluble chitosan films added with soy protein isolate (SPI) and $CaCl_2$. Mechanical and water vapor barrier properties of the chitosan films were affected by SPI and $CaCl_2$ concentrations. PS value $(174.5-448.8\;g_f)$ of the chitosan films increased with increasing concentration of $CaCl_2$ TS value of 0.05% $CaCl_2$-added chitosan films significantly increased to 1.58 MPa compared to 0.06 MPa of the control. %E values ranged from 12.25 to 44.80% and increased with increasing concentration of $CaCl_2$. WVP of $CaCl_2$-added films was lower than that of SPI-added films.

• Journal of the Korean Electrochemical Society
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• v.25 no.4
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• pp.134-153
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• 2022

Regardless of a trade-off relationship between energy density and safety, it is essential to improve both properties for future lithium secondary batteries. Especially, to improve the energy density of batteries further, not only thickness but also weight of separators including ceramic coating layers should be reduced continuously apart from the development of high-capacity electrode active materials. For this purpose, an attempt to replace conventional slurry coating methods with a deposition one has attracted much attention for securing comparable thermal stability while minimizing the thickness and weight of ceramic coating layer in the separator. This review introduces state-of-the-art technology on ceramic-coated separators (CCSs) manufactured by the deposition method. There are three representative processes to form a ceramic coating layer as follows: chemical vapor deposition (CVD), atomic layer deposition (ALD), and physical vapor deposition (PVD). Herein, we summarized the principle and advantages/disadvantages of each deposition method. Furthermore, each CCS was analyzed and compared in terms of its mechanical and thermal properties, air permeability, ionic conductivity, and electrochemical performance.

• Food Science and Preservation
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• v.31 no.1
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• pp.126-137
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• 2024

In this study, zinc oxide nanoparticles (ZnONPs) were synthesized using three distinct zinc salts: zinc acetate, zinc chloride, and zinc nitrate. These ZnONPs were subsequently utilized in the fabrication of carrageenan-ZnONPs (Car-ZnONPs) composite films. The study assessed influence of the various ZnONPs on the morphological, water vapor barrier, color, optical, and antimicrobial properties of the Car-ZnONPs composite films. The surface morphology and UV-blocking attributes of the composite films were affected by the type of ZnONPs used, but their surface color, transparency, and chemical structure remained unaltered. The composite film's thickness and elongation at break (EB) significantly increased, while the tensile strength significantly decreased. In contrast, film's elastic modulus (EM) and water vapor permeability coefficient (WVP) showed no significant difference. All the composite films with added ZnONPs demonstrated potent antibacterial activity against Escherichia coli O157:H7 and Listeria monocytogenes . Among the carrageenan-based composite films, Car-ZnONPs^ZC showed the highest antibacterial and UV-blocking properties, and its elongation at break was significantly higher than that of the pure carrageenan films. This suggests that ZnONPs composite films have the potential to be used as an active packaging film, preserve the safety of the packaged food and extend shelf life.

• Journal of the Korean Geosynthetics Society
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• v.6 no.3
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• pp.9-16
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• 2007

Soil vapor extraction (SVE) is an effective and cost efficient method of removing volatile organic compounds (VOCs) and petroleum hydrocarbons from unsaturated soils. Incorporating PVDs in an SVE system can extend the effectiveness of SVE to lower permeability soils by shortening the air flow-paths and ultimately expediting contaminant removal. With this approach, the real bounded system is replaced for the purposes of analysis by an imaginary system of infinite areal extent. The boundary conditions for the contaminant remediation model test include constant head and no flow condition. Due to these parallel boundaries conditions, image wells should be developed in order to maintain the condition of no flow across the impermeable boundary. It is also assumed that the flow is drawdown along the constant head boundary condition. The factors contributing to the difference between the theoretical and measured pressure heads were also analyzed. The flow factor increases as the flow rate is increased. The flow rate is the most important factor that affects the difference between the measured and theoretical pressure heads.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.26 no.9
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• pp.1260-1266
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• 2002

In this study, to make an excellent heat pipe, the manufacturing technology of a sintered wick was investigated. Making a sintered wick is known to be very difficult but it has many advantages. For example, the porosity and pore size can be controlled and the capillary force is great. The mixture of copper and pore former powder was used as a wick material and ceramic-coated stainless steel was used as a mandrel which is necessary for vapor flow. To analyze the feature of the manufactured wick, not only porosity and pore size were measured but also the sintered structure was observed. A heat pipe with sintered wick was manufactured and the performance test of the heat pipe was performed in order to review cooling performance. The performance test results for the 4mm diameter heat pipe with the sintered wick shows the stability since the temperature difference between a evaporator and a condenser of the heat pipe is less than 4.4$^{\circ}C$, and thermal resistance is less than 0.7$^{\circ}C$/W, In the meantime the composite wick that is composed with sintered and woven wire was also examined. The heat transfer limit of the heat pipe with composite wick was enhanced about 51%~60% compare to the one with sintered wick.