• Transactions of the Korean Society of Mechanical Engineers B
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• v.40 no.12
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• pp.777-784
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• 2016

All-vanadium redox flow batteries (VRFBs) are used as energy storage systems for multiple intermittent power sources. The performance of the VRFBs depends on the materials and operating conditions. Hence, performance characterization is of great importance in the development of the VRFBs. This paper proposes a method for determining the maximum current density based on stoichiometric ratios. A laboratory-scaled VRFB with a projected electrode area of $25cm^2$ is electrically charged when the state of the charge has begun from 0.6. The operating conditions, such as current density and volumetric flow rate are important in the test, and the maximum current density is influenced by the mass transfer coefficient. The results show that increasing the electrolyte flow rate from 5 mL/min to 60 mL/min enhances the maximum current density up to $520mA/cm^2$.

• Korean Chemical Engineering Research
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• v.57 no.3
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• pp.408-412
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• 2019

In this study, nitrogen doped carbon felt was prepared by pyrolysis of urea at high temperature and applied as an electrode for vanadium redox flow cell. Urea is easier to handle than ammonia and forms $NH_2$ radicals at higher temperatures, creating a nitrogen functional group on the carbon surface and acting as an active site in the vanadium redox reaction. Therefore, the discharge capacity of activated carbon felt electrodes using urea was 14.9 Ah/L at a current density of $150mA/cm^2$, which is 23% and 187% higher than OGF and GF, respectively. These results show the possibility that activated carbon felt electrode using urea can be used as electrode material for redox flow battery.

• Membrane Journal
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• v.30 no.5
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• pp.307-318
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• 2020

Conventional perfluorinated sulfonic acid membrane, Nafion is widely used for vanadium redox flow battery (VRFB). It is desired to prevent vanadium ion permeation through a membrane to retain the capacity, and to keep the cell efficiency of a VRFB. Highly proton conductive and chemically stable Nafion membranes, however, suffer from high vanadium permeation, which induce the reduction in charge and discharge capacity by side reactions of vanadium ions. In this study, to resolve the issue, silica nanoparticles, which are functionalized with 3-aminopropyl group (fS) are introduced to enhance the long-term performance of a VRFB by lowering vanadium permeation. It is expected that amine groups on silica nanoparticles are converted to positive ammonium ion, which could deteriorate positively charged vanadium ions' crossover by Gibbs-Donnan effect. There is reduction in proton conductivity may due to acid-base complexation between fS and Nafion side chains, but ion selectivity of proton to vanadium ion is enhanced by introducing fS to Nafion membranes. With the composite membranes of Nafion and fS, VRFBs maintain their discharge capacity up to 80% at a high current density of 150 mA/㎠ during 200 cycles.

• Bulletin of the Korean Chemical Society
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• v.34 no.6
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• pp.1651-1655
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• 2013

Anion exchange membranes for a vanadium redox flow battery (VRB) were prepared by pore-filling on a PE substrate with the copolymerization of vinylbenzyl chloride (VBC) and glycidyl methacrylate (GMA). The ion exchange capacity, water uptake and weight gain ratio were increased with a similar tendency up to 65% of GMA content, indicating that the monomer improved the pore-filling degree and membrane properties. The vanadium ion permeability and open-circuit voltage were also investigated. The permeability of the VG65 membrane was only $1.23{\times}10^{-7}\;cm^2\;min^{-1}$ compared to $17.9{\times}10^{-7}\;cm^2\;min^{-1}$ for Nafion 117 and $1.8{\times}10^{-7}\;cm^2\;min^{-1}$ for AMV. Consequently, a VRB single cell using the prepared membrane showed higher energy efficiency (over 80%) of up to 100 cycles compared to the commercial membranes, Nafion 117 (ca. 58%) and AMV (ca. 70%).

• Transactions of the Korean hydrogen and new energy society
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• v.27 no.2
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• pp.169-175
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• 2016

The electrolyte added the chlorosulfuric acid ($HSO_3Cl$) as an additive was tested for the electrolyte in all-vanadium redox flow battery (VRFB) to increase the thermal stability of electrolyte. The electrolyte property was measured by the CV (cyclic voltammetry) method. The maximum value of a voltage and current density in the electrolyte added $HSO_3Cl$ was higher than that in the electrolyte non-added $HSO_3Cl$. The thermal stability of the pentavalent vanadium ion solution, which was tested at $40^{\circ}C$, increased by adding $HSO_3Cl$. The performances of VRFB using the electrolyte added and non-added $HSO_3Cl$ were measured during 30 cycles of charge-discharge at the current density of $60mA/cm^2$. An average energy efficiency of the VRFB was 72.5%, 82.4%, and 81.6% for the electrolyte non-added $HSO_3Cl$, added 0.5 mol of $HSO_3Cl$, and added 1.0 mol of $HSO_3Cl$, respectively. VRFB using the electrolyte added $HSO_3Cl$ was showed the higher performance than that using the electrolyte non-added $HSO_3Cl$.

• Journal of the Korean Electrochemical Society
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• v.21 no.1
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• pp.1-5
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• 2018

In this study, boron - doped carbon was prepared by reducing carbon dioxide ($CO_2$) at high temperature by using sodium borohydride ($NaBH_4$). The boron - doped carbon was coated on carbon felt and applied as an electrode for a vanadium redox battery cell. As a result of electrochemical performance evaluation, reversibility of carbon felt coated with boron doped carbon compared to pure carbon felt was improved by about 20% and charge transfer resistance was reduced by 60%. In the charge / discharge results, energy density and energy efficiency were improved by 21% and 12.4%, respectively. These results show that carbon produced by reduction of $CO_2$ can be used as electrode material for redox flow battery.

• JOURNAL OF ELECTRICAL WORLD
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• s.450
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• pp.48-54
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• 2014

• Korean Chemical Engineering Research
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• v.52 no.2
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• pp.182-186
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• 2014

Two commercial carbon plates were evaluated as a current collector (bipolar plate) in the all vanadium redox-flow battery (V-RFB). The performance properties of V-RFB were test in the current density of $60mA/cm^2$. The electromotive forces (OCV at SOC 100%) of V-RFB using A and B current collector were 1.47 V and 1.54 V. The cell resistance of V-RFB using A current collector was $4.44{\sim}5.00{\Omega}{\cdot}cm^2$ and $3.28{\sim}3.75{\Omega}{\cdot}cm^2$ for charge and discharge, respectively. The cell resistance of V-RFB using B current collector was $4.19{\sim}4.42{\Omega}{\cdot}cm^2$ and $4.71{\sim}5.49{\Omega}{\cdot}cm^2$ for charge and discharge, respectively. The performance of V-RFB using each current collector was evaluated. The performance of V-RFB using A current collector was 93.1%, 76.8% and 71.4% for average current efficiency, average voltage efficiency and average energy efficiency, respectively. The performance of V-RFB using B current collector was 96.4%, 73.6% and 71.0% for average current efficiency, average voltage efficiency and average energy efficiency, respectively.

• Polymer(Korea)
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• v.35 no.6
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• pp.593-598
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• 2011

The IPA-co-HDO-co-(TPA/MA) copolymers for all-vanadium redox flow battery were synthesized by melt condensation polymerization using isophthalic acid(IPA), 1,6-hexandiol (HDO), terephthalic acid(TPA) and maleic anhydride(MA). The amination of chloromethylated IPA-co- HDO-co-(TPA/MA)(CIHTM) copolymer was carried out using trimethylamine, and the anion exchange membrane was also prepared by UV crosslinking reaction. The structure and thermal stability of IHTM copolymers were confirmed by FTIR, $^1H$ NMR, and TGA analysis. The anion membrane properties such as water uptake, ion exchange capacity, electric resistance and electrical conductivity, were measured by gravimetry, titration and LCR meter. The efficiency of the all-vanadium redox flow battery was analyzed. The ion exchange capacity, electric resistance and electrical conductivity were 1.10 meq/g, $1.98{\Omega}{\cdot}cm^2$, and 0.009 S/cm, respectively. The efficiency of charge-discharge, voltage, and energy for the allvanadium redox flow battery were 96.5, 74.6, 70.0%, respectively.

• Journal of the Korean Electrochemical Society
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• v.17 no.2
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• pp.94-102
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• 2014

Cation exchange membrane (Nafion) was modified to reduce the vanadium ion permeation through the membrane and to increase the vanadium redox flow battery (VRB) system performance by coating the graphene oxide (GO) which has nano-plate like morphology. Modified membrane properties were studied by measuring the ion exchange capacity (I.E.C), water uptake and proton conductivity. The thickness of the coated layer on the surface of the Nafion membrane was observed as $0.93{\mu}m$ by SEM. Proton conductivity and vanadium ion permeability of the modified membrane were decreased to 27% and 25% compared to that of the commercial Nafion membrane respectively. VRB single cell performance test was performed to compare the system performance of the VRB applied with commercial Nafion membrane and modified membrane. VRB system applied with modified membrane showed higher coulombic efficiency and energy efficiency than the VRB system applied with the commercial Nafion membrane due to the reduction of the vanadium ion permeation. From these result, we could suggest that the membrane modification by coating the GO on the surface of the Nafion membrane could be one of the promising strategies to reduce the vanadium ion permeation and to increase the VRB system performance effectively.