• Journal of the Mineralogical Society of Korea
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• v.31 no.2
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• pp.67-73
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• 2018

The objective of this study was to investigate the application of sulfate solvents for the economic and eco-friendly leaching of valuable metals from Au concentrate using an acid bake-water leaching system (AWS). AWS experiments were performed using an electric furnace with various baking temperatures ($100-500^{\circ}C$) and sulfate solvents ($H_2SO_4$, $K_2SO_4$, $(NH_4)_2SO_4$, $MgSO_4$, and $CaSO_4$). The efficiency of the valuable metal leaching increased as the baking temperature was increased to $400^{\circ}C$. Based on the AWS leaching time experiments, the maximum leaching rate occurred with the aqueous $(NH_4)_2SO_4$ solvent. This study demonstrates that aqueous $(NH_4)_2SO_4$ could be used as an effective solvent for valuable metal leaching using an AWS.

• Resources Recycling
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• v.3 no.1
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• pp.38-43
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• 1994

The separation of valuable metals from IC chip scrap generated by domestic electronic company was carried out using the mechanical beneficiation such as shredding, crushing, screening and magnetic separation. The distribution of metals in various sizes of crushed IC chip scrap was investigated and metals present in crushed products was separated with the magnetic separator. The particle size distribution of crushed IC chip scrap was 7.5% for +3mm, 17.0% for 3~1mm and 75.5% for -1mm. The weight loss of crushed IC chip scrap was 18% when roasted at $700^{\circ}C$. The content of metals was 96% for +3~1mm, 13% for 1~0.595mm, 3.7% for 0.95~0.5. Au of 99% was present in -1mm crushed IC chip scrap. Ni, Fe, Cu, Sn and Pb were separated from crushed IC chip scrap by the magnetic separator under 700 and 2, 500 Gauss.

• Proceedings of the Korean Institute of Resources Recycling Conference
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• 2003.10a
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• pp.44-48
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• 2003

• Resources Recycling
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• v.16 no.3 s.77
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• pp.27-33
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• 2007

It is very important in the view point of resource recycling to recover valuable metals such as copper and tin from waste electric and electronic scrap. The waste electric and electronic scrap contains significant amounts of copper, tin, and so on. In this study, a new process for extracting copper and tin contained in the waste electric and electronic scrap using waste copper slag which is generated from the melting furnace of copper smelter was presented. Advantage of the proposed process is to reuse waste copper slag instead of new fluxes as slag formatives. In each experiment, the waste electric and electronic scrap and waste copper slag were melted inputting suitable amount of CaO as an additional flux. Up to 95% of copper and 85% of tin in the raw material were extracted in a Cu-Fe-Sn alloy phase.

• Resources Recycling
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• v.24 no.1
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• pp.66-72
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• 2015

Various waste PCBs arose during disassembly of LCD TVs and monitors in which they originally functioned for transmission of imaging signal, power supply, and imaging control. In those functional PCBs, gold and copper are contained at far more acceptable level, exceeding mining grade ores. Those valuable metals and their contents widely vary with functionality and end use of PCBs. Therefore, compositional analysis of individual waste PCBs from disassembled LCD TVs and monitors were performed in the present study to classify them into three categories: high gold yield and low gold yield PCBs and those without gold contents. Besides, additional chemical analysis was made to reveal gold and copper contents in the waste PCBs arising from actual disassembly/separation of end-of-life LCD TVs and monitors.

• Resources Recycling
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• v.21 no.4
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• pp.76-85
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• 2012

Fluorescent lamps generally involve mercury within their lamp bulbs. Thus if the lamps are disposed as they are, it might cause environmental pollution. On the other hand, as the life of the lamps depends on the degradation of the discharge performance, the fluorescent substance composing the fluorescent substance coating can be recycled by reusing them as the recycled fluorescent substance. Also, the glass material composing the glass bulbs can be reused. The range of search was limited in the open patents of USA (US), European Union (EU), Japan (JP), Korea (KR) and SCI journals from 1977 to 2011. Patents and journals were collected using key-words searching and filtered by filtering criteria. The trends of the patents and journals was analyzed by the years, countries, companies, and technologies. Recovery method of metals from spent fluorescent lamps is mainly the focus on the recovery of precious metals using acid treatment and, detoxification technology is related with controlling process of mercury using a filter system.

• Resources Recycling
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• v.26 no.3
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• pp.3-16
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• 2017

Chemical catalyst products are applied to various fields such as petrochemical process, air pollution prevention facility and automobile exhaust gas purifier. The domestic and overseas chemical catalyst market is increasing every year, and the amount of waste catalyst generated thereby is also increasing. Most of the used chemical catalyst products, such as desulfurized waste catalysts and automobile waste catalysts containing valuable metals are important recyclable resources from a substitute resource point of view. The recycling processes for recovering valuable metals have been commercialized through some urban mining companies, and SCR denitration catalysts have been recycled through some remanufacturing companies. In this paper, the amount of domestic production and recycling of major catalyst products have thus been investigated and analyzed so as to be used as basic data for establishing industrial support policy for recycling of used chemical catalyst products. Also tasks for promoting the recycling of used chemical catalyst products are suggested.

• Resources Recycling
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• v.31 no.5
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• pp.59-66
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• 2022

To investigate the rate-determining step of nickel, cobalt and copper electrowinning, experiments were conducted by varying the electrolyte temperature and agitation speed using a rotating disc electrode. Analyzing the rate-determining step by calculating the activation energy in the electrowinning process, it was found that nickel electrowinning is controlled by a mixed mechanism (partly by chemical reaction and partly by mass transport), cobalt is controlled by chemical reaction, and copper is controlled by mass transfer. Electrowinning of nickel, cobalt and copper was performed by varying the electrolyte temperature and agitation speed, and the comparison of the current efficiencies was used the determine the rate-determining step.

• Resources Recycling
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• v.33 no.1
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• pp.15-21
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• 2024

The demand for electric vehicles powered by lithium-ion batteries is continuously increasing. Recovery of valuable metals from waste lithium-ion batteries will be necessary in the future. This research investigated the effect of reaction temperature on the lithium recovery ratio from hydrogen reduction followed by water leaching from lithium-ion battery NCM-based cathode materials. As the reaction temperature increased, the weight loss ratio observed after initiation increased rapidly owing to hydrogen reduction of NiO and CoO; at the same time, the H₂O amount generated increased. Above 602 ℃, the anode materials Ni and Co were reduced and existed in the metallic phases. As the hydrogen reduction temperature was increased, the Li recovery ratio also increased; at 704 ℃ and above, the Li recovery ratio reached a maximum of approximately 92%. Therefore, it is expected that Li can be selectively recovered by hydrogen reduction as a waste lithium-ion battery pretreatment, and the residue can be reprocessed to efficiently separate and recover valuable metals.

• Resources Recycling
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• v.25 no.2
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• pp.42-48
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• 2016

Although the generation of waste flat panel displays in Korea is expected to exceed one million sets in 2016, a comprehensive recycling technology has not yet been developed for effective recovery of valuable materials from the wastes, rendering to outshine the national prestige as a global leader in display industries. The overall aim of this study was to analyze the statistical data of various valuable materials and their ratio after dismantling 40-inch and 42-inch sized waste LCDs. The analysis results showed that plastic portion of the wastes was about 22% and the portion of PCB (Print Circuit Board) part was about 9% by weight whereas panel part was about 34% and leftovers including metals totalled about 35% by weight. Based on the analytical results, a higher value recycling process could be proposed with advanced material separation techniques.