• Title/Summary/Keyword: VOCs analysis

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Practical Usage of Low-Temperature Metal Catalyst for the Destruction of Volatile Organic Compounds (VOCs) (휘발성 유기화합물(VOCs) 제거를 위한 저온금속촉매 실용화에 관한 연구)

  • Jung, Sung-Chul;Lee, Seung-Hwan
    • Journal of Korean Society of Environmental Engineers
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    • v.34 no.6
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    • pp.397-405
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    • 2012
  • In this study, performance evaluation of newly developed technology for the economical and safe removal of volatile organic compounds (VOCs) coming out from electronic devices washing operation and offensive odor induction materials was made. Metal oxidization catalyst has shown 50% of removal efficiency at the temperature of $220^{\circ}C$. Composite metal oxidization catalyst applied in this study has shown that the actual catalysis has started at the temperature of $100^{\circ}C$. Comprehensive analysis on the catalyst property using Mn-Cu metal oxidization catalyst in the pilot-scale unit was made and the removal efficiency was variable with temperature and space velocity. Full-scale unit developed based on the pilot-scale unit operation has shown 95% of removal efficiency at the temperature of $160^{\circ}C$. Optimum elimination effective rates for the space velocity was found to be $6,000hr^{-1}$. The most appropriate processing treatment range for the inflow concentration of VOCs was between 200 ppm to 4,000 ppm. Catalyst control temperature showed high destruction efficiency at $150{\sim}200^{\circ}C$ degrees Celsius in 90~99%. External heat source was not necessary due to the self-heat reaction incase of VOCs inflow concentration is more than 1,000 ppm. Equipment and fuel costs compared to the conventional RTO/RCO method can be reduced by 50% and 75% respectively. And it was checked when there was poisoning for sulfide and acid gas.

Analysis of Higher Temporal Moments for Breakthrough Curves of Volatile Organic Compounds in Unsaturated Soil (불포화 토양에서 유동하는 가스상 Volatile Organic Compounds의 출현곡선에 대한 고차 Temporal Moment의 분석)

  • Kim, Heon-Ki
    • Journal of Soil and Groundwater Environment
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    • v.12 no.6
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    • pp.60-69
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    • 2007
  • Understanding the behavior of gas phase VOCs (volatile organic compounds) in unsaturated soils is of a great environmental importance for public health concerns. Moment analysis for the breakthrough curves (BTCs) during transport of chemicals in porous media was known to be a useful tool to evaluate the velocity, spreadness, and the skewness of the plume of the chemicals. In this study, the temporal moments of the BTCs of a group of VOCs were analyzed for the gaseous transport in an unsaturated soil. BTCs were measured using lab-scale column experiments for four different VOCs at the water saturation range of 0.04-0.46, and for eleven VOCs at a water saturation of 0.21. The central second and third moments of the VOCs were compared with the water saturation and the first moment. It was found that both central second and third moments increased with the first moment. The central third moment was, however, found to be more sensitive to the first moment.

Profiling Patterns of Volatile Organic Compounds in Intact, Senescent, and Litter Red Pine (Pinus densiflora Sieb. et Zucc.) Needles in Winter

  • CHOI, Won-Sil;YANG, Seung-Ok;LEE, Ji-Hyun;CHOI, Eun-Ji;KIM, Yun-Hee;YANG, Jiyoon;PARK, Mi-Jin
    • Journal of the Korean Wood Science and Technology
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    • v.48 no.5
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    • pp.591-607
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    • 2020
  • This study was aimed to investigate the changes of chemical composition of the volatile organic compounds (VOCs) emitted from red pine needles in the process of needle abscission or senescence. The VOCs in intact, senescent, and litter red pine needle samples were analyzed by headspace-solid phase microextraction gas chromatography-mass spectrometry (HS-SPME-GC/MS). And then, multivariate statistical interpretation of the processed data sets was conducted to investigate similarities and dissimilarities of the needle samples. Principal component analysis (PCA) and orthogonal partial least squares discriminant analysis (OPLS-DA) were used to investigate the dataset structure and discrimination between samples, respectively. From the data preview, the levels of major components of VOCs from needles were not significantly different between needle samples. By PCA investigation, the data reduction according to classification based on the chlorophyll a / chlorophyll b (Ca/Cb) ratio were found to be ideal for differentiating intact, senescent, and litter needles. The following OPLS-DA taking Ca/Cb ratio as y-variables showed that needle samples were well grouped on score plot and had the significant discriminant compounds, respectively. Several compounds had significantly correlated with Ca/Cb ratio in a bivariate correlation analysis. Notably, the litter needles had a higher content of oxidized compounds than the intact needles. In summary, we found that chemical compositions of VOCs between intact, senescent, and litter needles are different each other and several compounds reflect characteristic of needle.

Comparative Analysis of Indoor Mixture Gas Patterns and Reference Single Gas Patterns Obtained from E-Nose for Indoor Air Quality Monitoring

  • Choi, Jang Sik;Yu, Joon Boo;Jeon, Jin Young;Lee, Sang Hun;Kim, Jae Hong;Park, Jang Pyo;Jeong, Yong Won;Byun, Hyung Gi
    • Journal of Sensor Science and Technology
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    • v.27 no.4
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    • pp.227-231
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    • 2018
  • Indoor air pollution has become a serious issue, affecting the health and comfort of building occupants. Volatile organic compounds (VOCs) are among the most common indoor contaminants, and are released from numerous indoor emission sources. Among the VOCs, formaldehyde and toluene are toxic chemicals at low levels and are frequently detected indoors. Exposure to formaldehyde and toluene can irritate sensitive tissue and may increase the risk of cancer. Therefore, monitoring formaldehyde and toluene is critical for the health and comfort of residents. In addition, as human indoor activities can generate VOC gases, analysis of their influence on VOCs is needed. In this study, we compared electronic nose (E-Nose) data for formaldehyde and toluene with E-Nose data for indoor mixture gas with consideration for human indoor activities.

Health Effect Assessment on Cleanup Workers of an Oil Spill in Yeosu (여수 유류유출사고 방제작업자의 건강영향평가)

  • Kim, Geunbae;Kang, Tack Shin;Yoon, Mira;Jo, Hyejung;Joo, Youngkyung;Yu, Seung Do;Lee, Bo Eun
    • Journal of Environmental Health Sciences
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    • v.42 no.6
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    • pp.385-395
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    • 2016
  • Objectives: The aim of this study was to assess exposure to VOCs and PAHs and the health effects on volunteers who participated in an oil spill cleanup in Yeosu. Methods: Atmospheric VOCs were evaluated in the vicinity of the accident site and questionnaire surveys were conducted to identify personal characteristics and acute health symptoms of clean-up workers seven days after the accident. The levels of metabolites of VOCs (t,t-MA, HA, PGA, MA, MHA) and PAHs (2-NAP, 1-OHP, 2-HF, 1-HPH), oxidative stress markers (TABARS, 8-OHdG) in the urine of workers were analyzed. Their correlation was determined by multiple regression analysis with SAS ver. 9.4. Results: Although the concentration of atmospheric VOCs in the residential areas were low at the time of survey, the levels of VOCs and PAHs metabolites in clean-up workers were higher than those in the control group after clean-up activities. The levels of urinary VOC and PAH metabolites were significantly increased after clean-up compared to those measured before participation. The thiobarbituric acid reactive substance (TBARS) concentrations were also increased and showed significant correlations with those of metabolites of benzene. Conclusion: This study shows that oil spill clean-up activities affect exposure to VOCs and PAHs and the health of clean-up workers. The results suggest the need for check-ups of participants in oil spill cleaning work.

Evaluation of Concentration Polarization at Feed in the Permeation of VOCs/$N_2$ mixtures through PDMS membrane (VOCs/질소 혼합물 증기투과시 공급액부 경계층에서의 농도분극 분석을 위한 모델식 확립)

  • 염충균;이상학;최정환;이정민
    • Membrane Journal
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    • v.11 no.2
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    • pp.74-82
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    • 2001
  • By using a phenomenological approach, model equations incorporating the resistance-in¬series concept were established to evaluate quantitatively concentration polarization in the boundary layer in feed adjacent to the membrane surface in the vapor permeation and separation of volatile organic compounds (VOCS)/$N_2$ mixture through po]y(dimethylsiloxane) (PDMS) membrane. The vapor permeations of various VOCS/$N_2$ mixtures through PDMS membrane were carried out at various feed flow rates. Chlorinated hydrocarbons, such as, methylene chloride, chlorofonn, 1,2-clichloroethane and 1,1,2-trichloroethane were used as organic vapor. By fitting the model equations to the experimental penneation data. the model parameters were detennined. respectively. Both the mass transfer coefficient of VOC across tbe boundary layer and concentration polarization modulus as a measure of the extent of concentration polarization were eitimated Quantitatively by the mooe1 equations with the determined model parameters. From the analysis on the detennined model parameters, the boundary layer resistance due to the concentration polarization of VOCs component was found to be more significant when the condensability of voe was greater. This study seeks to emphasize the importance of the boundary resistance on the vapor penneation of the vapor/gas mixtures with high permeability and high selectivity towards the minor component VOC.

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