• Journal of the Korean Chemical Society
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• v.44 no.5
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• pp.415-421
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• 2000

Volatile organic compounds(VOCs) emitted from PC/Monitor set and chemical parts com-prising of PC/Monitor set were analyzed aran, and xylene of VOCs based on qualitative analysis. As a result of these analyses, when the Wedge Rub-ber of rubber product was heated from 60$^{\circ}C$ to 80$^{\circ}C$, the emission rate(%) of xylene was increased about 2.5 times. But it was evaluated that the left of chemical parts were not affected by temperature except Wedge Rub-ber. The results of qualitative analyses between RGA and GC-MS were a little different respectively. With quantitative analysis, concentration of xylene emitted from cabinet was measured to be maximum as 6029.3 ug/ m$^3$(1.3ppm). The concentrations of toluene, xylene, and benzofuran derived from PC/Monitor set were 10.25${\mu}g/m^3$, 690${\mu}g/m^3$, and 180 ${\mu}g/m^3$, and these concentrations were relatively high levels which can bring on the risk to human health.

• Journal of Korea Port Economic Association
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• v.35 no.2
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• pp.93-108
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• 2019

Recently, air pollution from the marine ports has become a serious issue all over the world. Because marine trade accounts for 99.7% of Korea's trade, efforts are required to recognize the level of port pollution and establish environmental policies. This study estimates air pollution emitted during the berthing process in the Gwangyang and Ulsan ports. Data on ship activity and characteristics are collected and reasonable methodologies and factors from EEA and EPA are adopted. The results show that 253.09 tons of CO, 1986.61 tons of NOx, 684.01 tons of SOx, 47.88 tons of $PM_{10}$, and 44.69 tons of $PM_{2.5}$ are emitted at the Gwangyang port. Further, the Ulsan port emitted 212.28 tons of CO, 1712.54 tons of NOx, 573.72 tons of SOx, 40.16 tons of $PM_{10}$, and 37.48 tons of $PM_{2.5}$. A stage-by-stage plan for installing AMP infrastructure is suggested as part of a green port policy. This research provides the current pollution status and contributes guidelines for the direction of future policy.

• Clean Technology
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• v.28 no.4
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• pp.285-292
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• 2022

Adsorption tower systems based on activated carbon adsorption towers have mainly been employed to reduce the emission of volatile organic compounds (VOCs), a major cause of air pollution. However, the activated carbon currently used in these systems has a short lifespan and thus requires frequent replacement. An approach to overcome this shortcoming could be to develop metal oxide photocatalysis-activated carbon composites capable of degrading VOCs by simultaneously utilizing photocatalytic activation and powerful adsorption by activated carbon. TiO₂ has primarily been used as a metal oxide photocatalyst, but it has low economic efficiency due to its high cost. In this study, ZnO particles were synthesized as a photocatalyst due to their relatively low cost. Silver nanoparticles (Ag NPs) were deposited on the ZnO surface to compensate for the photocatalytic deactivation that arises from the wide band gap of ZnO. A microfluidic process was used to synthesize ZnO particles and Ag NPs in separate reactors and the solutions were continuously supplied with a pack bed reactor loaded with activated carbon powder. This microfluidic-assisted pack bed reactor efficiently prepared a Ag-ZnO-activated carbon composite for VOC removal. Analysis confirmed that Ag-ZnO photocatalytic particles were successfully deposited on the surface of the activated carbon. Conducting a toluene gasbag test and adsorption breakpoint test demonstrated that the composite had a more efficient removal performance than pure activated carbon. The process proposed in this study efficiently produces photocatalysis-activated carbon composites and may offer the potential for scalable production of VOC removal composites.

• Journal of Korea Port Economic Association
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• v.39 no.3
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• pp.107-122
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• 2023

This study aims to analyze the effect of reducing air pollutant emissions of the ship fuel oil sulfur content regulation policy, which has been gradually introduced for three years. In addition, the emission reduction effect of VSR and AMP was also analyzed. The analysis was conducted on NOx, CO, VOC, SOx, TSP, PM10, and PM2.5, which are provided by EEA, and the spatial scope of the analysis was conducted on Incheon Port, which is located in the metropolitan area of Korea and has a large ripple effect on air pollution. Three scenarios were constructed for analysis. Scenario 1: If there is no policy, Scenario 2: If only fuel oil sulfur content regulation was implemented, Scenario 3: The analysis was conducted by reflecting fuel oil sulfur content regulation, VSR, and AMP. As a result of the analysis, in the case of scenario 1, 4,801 tons, 4,932 tons, and 5,144 tons of air pollutants were emitted during the three-year period. In Scenario 2, 4,219 tons, 4,152 tons, and 3,989 tons were discharged, and in Scenario 3, 4,198 tons, 4,138 tons, and 3,973 tons were discharged. The findings of this study are anticipated to be applied as fundamental research in port air environment management and Incheon Metropolitan City air management.

• Journal of Korean Society for Atmospheric Environment
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• v.22 no.E2
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• pp.49-56
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• 2006

This pilot study focuses on emissions characterization of air pollutants produced from incineration of some municipal solid wastes (MSWs). The MSWs incinerated by an electric furnace maintained up to $600^{\circ}C$ included food, paper, and plastic wastes. The pollutants analyzed in this study included concentrations of volatile organic compounds (VOCs), bottom ash contents, and heavy metals extracted from the bottom ash of each waste. The VOCs identified were classified based on their chemical structure. The total emissions of VOCs produced from incineration of the papers were identified as the highest followed by those from the plastics and the food wastes. Aliphatic alkenes were major VOC compounds produced from incineration of plastic or food wastes, while furans were major VOCs produced from incineration of papers. The second major VOCs produced from incineration of food, plastics, and papers were aromatics. In particular, hazardous air pollutants such as benzene were produced with considerable amount of emission concentration. The bottom ash contents of papers were usually much higher than those of food or plastic wastes. The bottom ash contents produced from incineration of food and plastics were much lower than those of other MSWs. In analysis of heavy metals extracted by an ultrasonic method from the bottom ashes of the papers, high concentrations of heavy metals were identified from incineration of newspapers and box (cardboard). In addition, it was identified that the general public might be exposed to considerable amounts of lead concentrations during incineration processes and uses of paper cup and from ashes.

• Proceedings of the Korean Vacuum Society Conference
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• 2015.08a
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• pp.86.2-86.2
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• 2015

Cu2ZnSn(S,Se)4 thin film solar cells have been fabricated using sputtered Cu/Sn/Zn metallic precursors on Mo coated sodalime glass substrate without using a toxic H2Se and H2S atmosphere. Cu/Sn/Zn metallic precursors with various thicknesses were prepared using DC magnetron sputtering process at room temperature. As-deposited metallic precursors were sulfo-selenized inside a graphite box containing S and Se pellets using rapid thermal processing furnace at various sulfur to selenium (S/Se) compositional ratio. Thin film solar cells were fabricated after sulfo-selenization process using a 65 nm CdS buffer, a 40 nm intrinsic ZnO, a 400 nm Al doped ZnO, and Al/Ni top metal contact. Effects of sulfur to selenium (S/Se) compositional ratio on the microstructure, crystallinity, electrical properties, and cell efficiencies have been studied using X-ray diffraction, Raman spectroscopy, field emission scanning electron microscope, I-V measurement system, solar simulator, quantum efficiency measurement system, and time resolved photoluminescence spectrometer. Our fabricated Cu2ZnSn(S,Se)4 thin film solar cell shows the best conversion efficiency of 9.24 % (Voc : 454.6 mV, Jsc : 32.14 mA/cm2, FF : 63.29 %, and active area : 0.433 cm2), which is the highest efficiency among Cu2ZnSn(S,Se)4 thin film solar cells prepared using sputter deposited metallic precursors and without using a toxic H2Se gas. Details about other experimental results will be discussed during the presentation.

• Journal of Environmental Science International
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• v.24 no.1
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• pp.31-46
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• 2015

In this study, the regional climate (WRF) and air quality (CMAQ) models were used to simulate the effects of future urban growth on surface ozone concentrations in the Seoul metropolitan region (SMR). These analyses were performed based on changes in ozone concentrations during ozone seasons (May-June) for the year 2050 (future) relative to 2012 (present) by urban growth. The results were compared with the impacts of RCP scenarios on ozone concentrations in the SMR. The fractions of urban in the SMR (25.8 %) for the 2050 were much higher than those (13.9 %) for the 2012 and the future emissions (e.g., CO, NO, $NO_2$, $SO_2$, VOC) were increased from 121 % (NO) to 161.3 % ($NO_2$) depending on emission material. The mean and daily maximum 1-h ozone in the SMR increased about 3 - 7 ppb by the effect the RCP scenarios. However, the effect of urban growth reduced the mean ozone by 3 ppb in the SMR and increased the daily maximum 1-h ozone by 2 - 5 ppb over the northeastern SMR and around the coastline. In particular, the ozone pollution days exceeding the 1-h regulatory standard (100 ppb) were far more affected by urban growth than mean values. As a result, the average number of days exceeding the 1-h regulatory standard increased up to 10 times.

• Journal of Korean Society for Atmospheric Environment
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• v.22 no.1
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• pp.85-97
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• 2006

The PAMS data collected at four sites in Seoul metropolitan area in 2004 were analyzed using the positive matrix factorization (PMF) technique, in order to identify the possible sources and estimate their contributions to ambient VOCs. Ten sources were then resolved at Jeongdong, Bulgwang, Yangpyeong, and Seokmo, including vehicle exhaust, LPG vehicle, petroleum evaporation, coating, solvent, asphalt, LNG, Industry & heating, open burning, and biogenic source. The PMF analysis results showed that vehicle exhaust commonly contributed the largest portion of the predicted total VOCs mass concentration, more than $30\%$ at four sites. The contribution of other resolved sources were significantly different according to the characteristics of site location. In the case of Jeongdong and bulgwang located in urban area, various anthropogenic sources such as coating, solvent, asphalt, residual LPG, and petroleum evaporation contributed about $40\%$ of total VOCs mass. On the other hand, at yangpyeong and Seokmo located in rural and remote area, the portion of these anthropogenic sources was reduced to less than $30\%$ and the contribution of natural sources including open burning and biogenic source clearly observed. These results were considerably corresponding to the emission inventory investigated in this region.

• Journal of Korean Society for Atmospheric Environment
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• v.29 no.6
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• pp.757-772
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• 2013

In this study, a combination of sorbent tube (ST)-thermal desorption (TD)-gas chromatography (GC)-mass spectrometry (MS) was used for quantitative analysis of liquid phase standards of 10 BVOC ((1) (+)-${\alpha}$-pinene, (2) (+)-${\beta}$-pinene, (3) ${\alpha}$-phellandrene, (4) (+)-3-carene, (5) ${\alpha}$-terpinene, (6) p-cymene, (7) (R)-(+)-limonene, (8) ${\gamma}$- terpinene, (9) myrcene, and (10) camphene). The results of BVOC calibration yielded comparatively stable pattern with response factor (RF) of 23,560~50,363 and coefficient of determination ($R^2$) of 0.9911~0.9973. The method detection limit (MDL) of BVOC was estimated at 0.03~0.06 ng with the reproducibility of 1.30~5.13% (in terms of relative standard error (RSE)). Emissions of BVOC were measured from four types of fruit samples ((1) tangerine (TO), (2) tangerine peel (TX), (3) strawberry (SO), and (4) sepals of strawberry (SX)). The sum of BVOC flux (${\sum}flux$ (BVOC) in ng/hr/g) for each sample was seen on the descending order of (1) TX=291,614, (2) TO=2,190, (3) SO=1,414, and (4) SX=2,093. If the results are compared between the individual components, the highest flux was seen from (R)-(+)-limonene (265,395 ng/hr/g) from TX sample.

• Journal of Korean Society for Atmospheric Environment
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• v.29 no.1
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• pp.38-55
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• 2013

This study has been performed to select several indicators of long-range transport process that can be applied to the Northeast Asia. We first classified high air pollution days into long-range transport (LRT) dominant cases and the local emission dominant (LED) cases based on the synoptic meteorological variables including vorticity and geostrophic wind speed/direction at a geopotential level of 850 hPa. LRT cases were further categorized into two types: LRT-I type with air mass pathways from northern China and/or Mongolia, and LRT-II type from central and southern China. In each categorized case, we examined the difference of both measured aerosol optical properties of AERONET at two sites in western Korea, and the simulated characteristics of LRT process by MM5-CMAQ model. We contrasted LRT case with LED case, and then generated the LRT indicators applicable to Northeast Asia. The results showed that fine and coarse modes of LRT-II were relatively smaller than LED and LRT-I cases, respectively. Aerosol size distribution showed significantly higher concentration of fine-mode particle (mainly smoke or urban aerosols) in LED case in comparison with that of LRT groups (LRT-I, II), suggesting the amplitudes fine modes of LRT relative to LED as a possible LRT indicator. From the results of MM5-CMAQ modeling, we concluded that the conversion ratios for sulfur ($F_s$) were the most effective indicators of LRT cases, and the ratio of VOC to NOx and NOx to CO were found to be the second most effective indicators of LED case.