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Electrochemical Properties of LiCoO2 Prepared by Mechanochemical Process (Mechanochemical Process로 제조된 LiCoO2의 전기화학적 특성)

  • Cho, Byung-Won;Lee, Joong Kee;Lee, Jae-Ryong;Kim, Su-Jin;Lee, Kwan-Young;Na, Byung-Ki
    • Korean Chemical Engineering Research
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    • v.46 no.1
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    • pp.69-75
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    • 2008
  • Discharge capacity of $LiCoO_2$ in preparation by mechanochemical process decreased remarkably over 4.3V. However, Zr coating of $LiCoO_2$ showed very stable electrochemical properties up to 4.5V. Zr coating of $LiCoO_2$ in this experiment showed the discharge capacity of 197 mAh/g at 3.0-4.5V, and it maintained 96% of the initial discharge capacity after 50 cycle of charge/discharge.

Porous and Porous Surfaced Ti-6Al-4V Implants Fabricated by Electro-Discharge-Sintering : (2) Hardness and Compressive Strength (전기방전소결에 의해 제조된 다공성 및 다공성 표면을 갖는 Ti-6Al-4V 임플란트 : (2) 경도 및 압축강도)

  • Hyun, C. Y.;Huh, J. K.;Lee, W. H.
    • Journal of Powder Materials
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    • v.12 no.5 s.52
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    • pp.332-335
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    • 2005
  • Porous and porous surfaced Ti-6Al-4V implant compacts were fabricated by electro-discharge-sintering (EDS) of atomized spherical Ti-6Al-4V powders with a diameter of $100-150\;{\mu}m$, The solid core formed in the center of the compact after discharge was composed of acicular ${\alpha}+{\beta}$ Widmanstatten grains, The hardness value at the solid core was much higher than that at the particle interface or particles in the porous layer, which can be attributed to both heat treatment and work hardening effects induced from EDS, The compressive yield strength was in a range of 19 to 436 MPa which significantly depends on both input energy and capacitance, Selected porous-surfaced Ti-6Al-4V implant compacts with a solid core have much higher compressive strengths compared to the human teeth and sintered Ti dental implants.

Measurement of Localized Corrosion Resistance in Additively Manufactured Ti-6Al-4V Alloys Using Electrochemical Critical Localized Corrosion Temperature (E-CLCT) versus Electrochemical Critical Localized Corrosion Potential (E-CLCP) (적층가공 (3D 프린팅) Ti-6Al-4V합금의 국부부식 저항성 평가를 위한 임계국부부식온도와 임계국부부식전위 측정방법의 비교)

  • Seo, Dong-Il;Lee, Jae-Bong
    • Corrosion Science and Technology
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    • v.20 no.1
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    • pp.37-43
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    • 2021
  • Additively manufactured (AM) Ti-6Al-4V alloys exhibit a dominant acicular martensite phase (α'), which is characterized by an unstable energy state and highly localized corrosion susceptibility. Electrochemical critical localized corrosion temperature (E-CLCT, ISO 22910: 2020) and electrochemical critical localized corrosion potential (E-CLCP, ISO AWI 4631: 2021) were measured to analyze the localized corrosion resistance of the AM Ti-6Al-4V alloy. Although E-CLCP was measured under mild corrosive conditions such as human body, the validity of evaluating localized corrosion resistance of AM titanium alloys was demonstrated by comparison with E-CLCT. However, the mechanisms of resistance to localized corrosion on the as-received and heat-treated AM Ti-6Al-4V alloys under E-CLCT and E-CLCP differ at various temperatures because of differences in properties under localized corrosion and repassivation. The E-CLCT is mainly measured for initiation of localized corrosion on the AM titanium alloys based on temperature, whereas the E-CLCP yields repassivation potential of re-generated passive films of AM titanium alloys after breaking down.

Lattice Deformation and Improvement Oxidation Resistance of Ti-6Al-4V Alloy Powders Prepared by Hydrogen Added Argon Heat Treatment (수소 첨가 열처리에 따른 Ti-6Al-4V 합금 분말의 격자 변형 및 내산화성 향상)

  • Cho, Gye-Hoon;Oh, Jung-Min;Lim, Jae-Won
    • Journal of Powder Materials
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    • v.26 no.2
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    • pp.126-131
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    • 2019
  • In the present work, a new hydrogen added argon heat treatment process that prevents the formation of hydrides and eliminates the dehydrogenation step, is developed. Dissolved hydrogen has a good effect on sintering properties such as oxidation resistance and density of greens. This process can also reduce costs and processing time. In the experiment, commercially available Ti-6Al-4V powders are used. The powders are annealed using tube furnace in an argon atmosphere at $700^{\circ}C$ and $900^{\circ}C$ for 120 min. Hydrogen was injected temporarily during argon annealing to dissolve hydrogen, and a dehydrogenation process was performed simultaneously under an argon-only atmosphere. Without hydride formation, hydrogen was dissolved in the Ti-6Al-4V powder by X-ray diffraction and gas analysis. Hydrogen is first solubilized on the beta phase and expanded the beta phases' cell volume. TGA analysis was carried out to evaluate the oxidation resistance, and it is confirmed that hydrogen-dissolved Ti-6Al-4V powders improves oxidation resistance more than raw materials.

Joint Properties of Inconel 718 Additive Manufactured on Ti-6Al-4V by FGM method (Ti-6Al-4V 합금 기지 위에 FGM 방식으로 적층제조 된 Inconel 718의 접합 특성 분석)

  • Park, Chan Woong;Park, Jin Woong;Jung, Ki Chae;Lee, Se-Hwan;Kim, Sung-Hoon;Kim, Jeoung Han
    • Journal of Powder Materials
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    • v.28 no.5
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    • pp.417-422
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    • 2021
  • In the present work, Inconel 718 alloy is additively manufactured on the Ti-6Al-4V alloy, and a functionally graded material is built between Inconel 718 and Ti-6Al-4V alloys. The vanadium interlayer is applied to prevent the formation of detrimental intermetallic compounds between Ti-6Al-4V and Inconel 718 by direct joining. The additive manufacturing of Inconel 718 alloy is performed by changing the laser power and scan speed. The microstructures of the joint interface are characterized by scanning electron microscopy, energy-dispersive X-ray spectroscopy, and micro X-ray diffraction. Additive manufacturing is successfully performed by changing the energy input. The micro Vickers hardness of the additive manufactured Inconel 718 dramatically increased owing to the presence of the Cr-oxide phase, which is formed by the difference in energy input.

Comparing Resistances to Pitting Corrosion of Additive Manufactured Ti-6Al-4V Alloys in NaCl and NaBr Aqueous Solutions (NaCl과 NaBr수용액에서 적층가공으로 제조된 Ti-6Al-4V 합금의 공식 저항성 비교)

  • Seo, Dong-Il;Lee, Jae-Bong
    • Corrosion Science and Technology
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    • v.18 no.3
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    • pp.110-116
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    • 2019
  • Resistances to pitting corrosion of additive manufactured (AM) Ti-6Al-4V alloys in 0.6 M NaBr and 0.6 M NaCl aqueous solutions were compared using micro-droplet cell techniques. With respect to the pitting corrosion resistance, this study focused on two different types of halide anions in aqueous solutions, i.e. $Br^-$ and $Cl^-$. The differences between $Br^-$ and $Cl^-$ halide anions for breakdown on passive films of AM Ti-6Al-4V alloy were explained using Langmuir adsorption model with their equilibrium adsorption coefficients. The results of the analysis showed that the lower resistance to pitting potential of AM Ti-6Al-4V alloy in $Br^-$ aqueous solution was attributed to the higher equilibrium adsorption coefficient of Br-. In addition, micro-electrochemical test results showed that the pitting corrosion resistance of dark grains in additive manufactured Ti-6Al-4V alloy was lower as compared to that of bright grains due to the larger volume of ${\alpha}^{\prime}$ phase that caused the susceptibility to pit initiation.

Quality Characteristics of Salt-Fermented Anchovy Sauce and Sandlance Sauce (멸치액젓 및 까나리액젓의 품질 특성)

  • OH Kwang-Soo
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.32 no.3
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    • pp.252-255
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    • 1999
  • The quality characteristics of the Korean traditional salt-fermented fish sauces, the traditional anchovy sauce (TAS) and the sandlance sauce(TKS) were evaluated comparing to the commercial anchovy sauce (CAS) and sandlance sauce (CKS). The acidity was higher in TKS than in TAS, whereas the contents of VBN, total-N and amino-N were higher levels in TAS. In color values, L and b values in TAS were generally higher than those in TKS, whereas a and ${\Delta}E$ values were higher in TKS. The contents of total free amino acids in TAS and TKS were $12.40\;g\%$ (w/v) and $9.549 g\%$ (w/v), respectively. The contents or six amino acids, alanine, glutamic acid, leucine, isoleucine, valine and Iysine were higher in TAS, whereas the contents of arginine, glutamic acid, leucine, alanine and valine were higher in TKS. Nucleotides such as IMP and hypoxanthine were principal components in both TAS and TKS. The nitrogen related compounds, TMAO, TMA and total creatinine were determined to be $108.8\;mg\%$ (w/v), $60.5\;mg\%$ (w/v), $62.4\;mg\%$ (w/v) in TAS, and those in TKS were $60.1\;mg\%$ (w/v), $24.1\;mg\%$ (w/v), $67.6\;mg\%$ (w/v), respectively.

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LINEAR MAPPINGS ON LINEAR 2-NORMED SPACES

  • White Jr. Albert;Cho, Yeol-Je
    • Bulletin of the Korean Mathematical Society
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    • v.21 no.1
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    • pp.1-5
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    • 1984
  • The notion of linear 2-normed spaces was introduced by S. Gahler ([8,9,10,11]), and these space have been extensively studied by C. Diminnie, R. Ehret, S. Gahler, K. Iseki, A. White, Jr, and others. For nonzero vectors x,y in X, let V(x,y) denote the subspace of X generated by x and y. A linear 2-normed space (X,v) is said to be strictly convex ([3]) if v(x+y,z)=v(x,z)+v(y+z) and z not.mem.V(x,y) imply that y=ax for some a>0. Some characterizations of strict convexity for linear 2-normed spaces are given in [1,3,4,5,12]. Also, a linear 2-normed space (X,v) is said to be strictly 2-convex ([6]) if v(x,y)=v(x,z)=v(y,z)=1/3v(x+z, y+z)=1 implies that z=x+y. These space have been studied in [2,4,6,13]. It is easy to see that every strictly convex linear 2-normed space is always strictly 2-convex but the converse is not necessarily true. Throughout this paper, let (X,v) denote a linear 2-normed space.

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Identification of Verticillium dahliae and V. albo-atrum Causing Wilt of Tomato in Korea

  • Kim, Jong-Tae;Park, In-Hee;Lee, Hyang-Burm;Hahm, Young-Il;Yu, Seung-Hum
    • The Plant Pathology Journal
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    • v.17 no.4
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    • pp.222-226
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    • 2001
  • In 1997, 103 isolates of Verticillium were obtained from roots and stems of tomato plants showing wilt symptoms in greenhouses in eight areas of Korea. Out of these isolates, 75 were edintified as V. dahliae while 28 were identified as V. albo-atrum based on their morpho-logical and cultural characteristics. Both Verticillium species produced colonies with conidiophores, which were more or less erect, hyaline, with verticillate branches, and with 3-4 phialides at each node. V. dahliae produced microsclerotia, while V. albo-atrum produced resting dark mycelium. Optimum temperatures for mycelial growth of V. dahliae and V. albo-atrum on PDA were 22 and $26^{\circ}$, respectively. Mycelial growth of V. albo-atrum was slower than that of V. dahliae. Pathoge-nicity tests revealed that tomato cvs. Zuikoh No. 102, Kyoryokubeiju No. 2, Zuiken, Kagimuza, and Momotaro were susceptible to V. albo-atrum, while cvs. Zuikoh No. 102 and Kyoryokubeiju No.2 were susceptible to V. dahliae.

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Effect of V2O5 Modification in V2O5/TiO2-ZrO2 Catalysts on Their Surface Properties and Catalytic Activities for Acid Catalysis

  • Sohn, Jong-Rack;Lee, Cheul-Kyu
    • Bulletin of the Korean Chemical Society
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    • v.28 no.12
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    • pp.2459-2465
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    • 2007
  • V2O5/TiO2-ZrO2 catalyst modified with V2O5 was prepared by adding Ti(OH)4-Zr(OH)4 powder into an aqueous solution of ammonium metavanadate followed by drying and calcining at high temperatures. The characterization of prepared catalysts was performed using XRD, DSC, solid-state 51V NMR, and FTIR. In the case of calcination temperature of 500 oC, for the catalysts containing low loading V2O5 below 25 wt % vanadium oxide was in a highly dispersed state, while for catalysts containing high loading V2O5 equal to or above 25 wt % vanadium oxide was well crystallized due to the V2O5 loading exceeding the formation of monolayer on the surface of TiO2-ZrO2. The strong acid sites were formed through the bonding between dispersed V2O5 and TiO2-ZrO2. The larger the dispersed V2O5 amount, the higher both the acidity and catalytic activities for acid catalysis.