• 제목/요약/키워드: V(IV)

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Metal Cupferrate Complex에 關한 硏究(第4報) Spectrophotometry에 의한 바나듐(IV) 및 바나듐(V)-Cupferrate 의 化學組成의 決定 (Study on Metal Cupferrate Complex (Part IV). Determination of Vanadium(IV) and Vanadium(V) Cupferrate Compositions)

  • 김시중
    • 대한화학회지
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    • 제8권4호
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    • pp.147-152
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    • 1964
  • 有機溶媒(benzene)에 의한 抽出法을 利用하고, 分光光度法에 의한 몰比法과 連續變化法을 써서, V(IV)-cupferrate와 V(V)-cupferrate의 化學沮成이 水溶液相에서 有機溶媒相으로 分配된 다음에도 雙하지 않을 것이라는 假定밑에서, 水溶液의 酸性度에 따르는 cupferrate 錯化合物의 化學組成을 決定하였다. V(IV)-cupferrate의 benzene 溶液에서의 最大吸光波長은 pH에 따라 445$m{\mu}$ 또는 450$m{\mu}$이고, V(V)-cupferrate의 그것은 pH 1.8以下에서는 pH에 無關하게 445$m{\mu}$이었다. V(V)-cupferrate의 化學組成은 沈澱이 形成되는 水溶液의 pH에 따라 다르며, pH 1.0 以下에서는 $VCupf_4$, pH 1.3∼1.7에서는 $HVOCupf_3$ 또는 $VCupf_4$$VOCupf_2$의 거의 같은 몰씩으로된 混合物이고, pH 1.8∼4.3에서는 $VOCupf_2$이었다. V(V)-cupferrate의 化學組成은 水溶液의 pH에 따라 變化가 없고, pH 1.8 以下에서는 $HVO_2Cupf_2$이었다.

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Simulation of the Solution EPR Spectra of Mixed-Valence Heteropolyanions Containing Vanadium(IV) and Vanadium(V)$^\dag$

  • So, Hyun-Soo;Lee, Chul-Wee;Lee, Duck-Hwan
    • Bulletin of the Korean Chemical Society
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    • 제8권5호
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    • pp.384-388
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    • 1987
  • Modified Bloch equations were used to simulate the solution EPR spectra of mixed-valence heteropolyanions containing vanadium(IV) and vanadium(V). Simulated are the 15-, 22-, 36- and 43-line spectra of $\alpha$-1,2-$[PV(IV)VW_{10})O_{40}]^{6-},\;[P_2V(IV)V_2W_{15}O_{62}]^{10-},\;[HP_2V(IV)V_2W_{15}O_{62}]^{9-}$ and $\alpha$-1,2,3-$[HSiV(IV)V_2W_9O_{40}]^{7-}$, respectively. The transition probabilities for the intramolecular electron transfer were determined from the simulations.

아쿠아옥소몰리브덴(IV) 삼합체 착물과 바나듐(V)과의 반응에 대한 속도와 메카니즘 (Rates and Mechanism of the Reactions of Aquaoxomolybdenum (IV) Trimer with Vanadium (V))

  • 김창수;이문평
    • 대한화학회지
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    • 제31권2호
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    • pp.178-183
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    • 1987
  • $VO_2^+$$[Mo_3O_4(H_2O)_9]^{4+}$의 산화반응에 대한 속도론을 $25^{\circ}C$에서 분광광도법으로 연구하였다. 과량의 $VO_2^+$에서 $[Mo_3O_4(H_2O)_9]^{4+}$의 산화반응은 $Mo^{IV}_3+6V^V{\rightleftarrows}3Mo^{IV}+6V^IV}$이다. 반응에 대한 관찰된 속도상수, $k_{obs}$는 수소이온과 $VO^{2+}$에 의존한다. $[Mo_3O_4(H_2O)_9]^{4+}$$VO_2^+$의 산화-환원반응에 대한 상세한 메카니즘이 제시되며 이에 대하여 논의된다.

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Epr Spectra of $\alpha$-1,2,3-$[H_{n}PV(IV)V_{2}W_{9}O_{40}]^{(7-n)-}$(n = 1, 2 or 3). The Effects of Protonation on the Electron Transfer Rate

  • Lee, Chul-Wee;So, Hyun-Soo;Lee, Kyu-Ryong
    • Bulletin of the Korean Chemical Society
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    • 제7권2호
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    • pp.108-110
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    • 1986
  • The solution epr spectra of ${\alpha}-1,2,3-[H_nPV(IV)V_2W_9O_{40}]^{(7-n)-}$were measured at various pH and three protonated species have been identified. The spectrum of $H_3PV(IV)Ⅴ_2$ consisting of 8 lines indicates that the V-OH-V bridge prevents effectively the electron transfer between the vanadium atoms. The spectrum of $H_2PV(IV)V_2$ consisting of 15 lines can be interpreted by assuming that the electron is hopping fast between the two vanadium atoms in the V-O-V sequence. The multi-line spectrum of $HPV(IV)V_2$ is interpreted as a poorly resolved 43-line spectrum which originates from the electron hopping among the three vanadium atoms with the forward and backward transition probabilities of 4:1 in the OH-V-O-V sequence.

Metagonimus yokogawai 세르카리아의 감각유두에 관한 연구 (Study on Sensory Papillae of Metagonimus yokogawai Cercaria)

  • 김재진;민득영소진탁
    • Parasites, Hosts and Diseases
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    • 제22권1호
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    • pp.11-20
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    • 1984
  • A number of studies on the papillae of cercariae of trematodes reported that the papillar patterns (or chaetotaxy) of cercariae might be an excellent method to attain better understanding of the digenetic trematodes (Richard, 1971 ; Short and Cartrett, 1973; Bayssade-Dufour, 1979) . The present study was aimed to determine the number, distribution pattern and structure of the sensory papillae of Metagonimus yokogawai cercariae, and to elucidate the chaetotaxy of this digenetic trematode. M. yokogawai cercariae were pipetted from a vial in which infected snails (Semisulcospira libertina) had been kept for 3 hours. The snails were collected from an endemic area of M. yokogawai, Boseong river in west-southern part of Korea. Observations of papillae were based on light microscopy of those stained with silver nitrate, and on scanning electron microscopy The results are summarized as follows: 1, All papillae observed were uniciliated. 2. Cilia in anterior tip were shorter than the others in other portions. 3. The body papillae were arranged in essentially symmetrical patterns, Total number of the papillae was 126(63 pairs) in average; anterior tip 40(20 pairs), ventral 20(10 pairs), lateral 42(21 pairs), and caudal 8(4 pairs). 4. The chaetotany of M. yokogawai cercaria was: Ci cycle ($3+3C_{I}V,{\;}2+2C_{I}L,{\;}2+3C_{I}D),{\;}C_{II}{\;}cycle(2C_{II}V,{\;}1C_{II}L,{\;}2C_{II}D),{\;}C_{lll}{\;}cycle{\;}(1+lC_{III}V,{\;}1C_{IlI}L),{\;}C_{IV}{\;}cycle{\;}(1C_{IV}V,{\;}IC_{lV}L){\;}in{\;}cephalic{\;}region:{\;}A_I(1A_{IV}V,{\;}1+2A_{I}L,{\;}1A_{I}D),{\;}A_{II}(1A_{II}V,{\;}1+3A_{II}L,{\;}1A_{II}D),{\;}A_{III}(1A_{III}V,{\;}1+1A_{III}L,{\;}1A_{III}D){\;}and{\;}A_{IV}(1A_{IV}V,{\;}2A_{IV}L)$ in antacetabular region: $1M_{I}V{\;}and{\;}2M_{I}L$ in median: $1+1P_{I}L,{\;}1P_{II}L,{\;}1P_{II}D,{\;}1P_{III}L,{\;}1P_{IV}L{\;}and{\;}1P_{IV}D$ in postacetabular region: 2-2-2-2 in caudal region.

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맥문동탕 흡연에 관한 효과 (The effect of Macmoondongtang in Rat Exposed to Cigarette Smoke)

  • 이선화;박동일
    • 생명과학회지
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    • 제7권1호
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    • pp.39-48
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    • 1997
  • Cigarette is the risk factor of Lung cancer, chronic obstructive pulmonary disease and ischemic heart disease. So I have studied the effect of Macmoondongtang in rat exposed to cigarette smoke. Thirty-six healthy rat subjects were divided into 6 groups-the control group(sample I), the groups of administration of Platycodi Radix(sampleII), Adenophorae Radix(sampleIII), Liriopsis Tuber(sampleIV), Maximowicziae Fructus(sample V) and Macmoondongtang(sample VI), and expose to cigarette per day for 12 days. 1. On level of leckocyte are significant all the group of sampleII, sampleIII, sample IV, sample V, sample VI on 6th day and singificant the groups of sampleIV, sample V on 12th day. 2. On level of hemoglobin are singificant the groups of sample IV, sample V, sample VI, on 6th day, and significant sample II, sample III, sample IV, sample V, sample VI on 12th day. 3. On platelet level are significant all the group of sampleII, sample III, sample IV, sample V, sample VI on 12th day. 4. On SOD activity are significant all the groups of sample IV, sample VI, on 6th day, and significant sampleII, sample III, sample VI on 12th day. According to the results, Macmoondogtang is effective to risk of cigarette smoke.

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16S rRNA 분석에 의한 Subsection IV cyanobacteria 균주들의 다계통성 기원의 증거 (Evidence for Polyphyletic Origin of the Members of the Subsection IV Cyanobacteria as Determined by 16S rRNA Analysis)

  • 신용국;서필수
    • 생명과학회지
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    • 제26권10호
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    • pp.1202-1206
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    • 2016
  • Subsection I과 II의 시아노박테리아 균주들은 단세포성이며, Subsection III의 시아노박테리아 균주들은 섬유상의 다계통성, 이형 사이토시스 형성성 균주들인 반면, Subsections IV와 V는 단일계통성으로 보고되어있다. 본 연구에서 13 균주의 시아노박테리아의 the small subunit rRNA (16S rRNA) 염기서열들이 - Subsection III의 Oscillatoria nigro-viridis PCC7112, Subsection IV에 속하는 Anabaena, Nostoc, Tolypothrix, Calothrix 및 Scytonema속을 포함한 6 균주, Subsection V에 속하는 Hapalosiphon, Fischerella and Chlorogloeopsis 속의 6 균주 - 결정되었다. 결정된 16S rRNA 염기서열을 이용하여 시아노박테리아의 분자계통분석을 수행하였다. 그러나, 16S rRNA의 염기서열 결정을 근거로 한 본 연구의 계통분석결과 Subsection IV는 단일 계통성이 아닌 다계통성이며, 반면 Subsection V는 이전에 보고되어진 것처럼 단일 계통성임을 나타내었다. 또한, 본 연구 결과는 Scytonema속이 이형 사이토시스 형성성 시아노박테리아인 Subsection IV 및 V의 공통 조상일 수 있음을 강력하게 나타낸다. 부가적으로, 본 연구의 분자계통 분석을 통해 Anabaena속은 다계통성으로 계통학적으로 다양한 종들로 구성되어 있음을 나타내고 있다. 본 연구 결과는 Anabaena속이 좀 더 세밀하게 재분류 되어져야 함을 나타낸다.

Maturity Grouping of Korean Soybean Cultivars and Character Relationships According to the Planting Date

  • Ha, Tae-Jeong;Lim, Sea-Gyu;Shin, Seong-Hyu;Choi, Kyung-Jin;Baek, In-Youl;Lee, Sang-Chul;Park, Keum-Yong;Shin, Sang-Ouk
    • 한국작물학회지
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    • 제54권1호
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    • pp.104-118
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    • 2009
  • This study was carried out to classify Korean soybean varieties base on maturity group (MG) and to find character relationships according to planting date for high quality soybean seed production adapted to early season cultivation environment of Miryang. Results of maturity grouping of Korean soybean varieties showed that Keunol (3 cultivars), belonged to Group 0; Seonnok and Danmi in Group II, Shinrok in Group III, Seonyu (17 cultivars), in Group IV, Taekwang (44 cultivars) in Group V, Daewon (25 cultivars) in Group VI, and Kwangdu and Keumdu in Group VII. Agronomic characteristics of 100 soybean varieties were compared based on MG, cultivation year and seeding date. Soybean varieties belonging to the MG $VI{\sim}VII$ showed longer days to flowering and growth period, high lodging density and higher yield. Seed quality analysis revealed that as maturity was delayed, seed weight becomes heavier while seed cracks become abundant. In addition, occurrence of purple seed and phomopsis were higher in MG $0{\sim}III$. Protein content was higher in MG $0{\sim}III$, and isoflavone content was higher as maturity was delayed. On the other hand, lipid content was generally similar across MGs. Correlation analysis of major agronomic characters showed positive relationships between days to flowering and growth days, seed weight and lodging in MG $IV{\sim}V$, seed crack and growth days in MG $0{\sim}III$, seed crack and days to flowering in MG $IV{\sim}V$ and MG $VI{\sim}VII$, seed crack and lodging in MG $IV{\sim}V$ and MG $VI{\sim}VII$, seed crack and seed weight in MG $IV{\sim}V$ and MG $VI{\sim}VII$, purple seed and growth days in MG $IV{\sim}V$, purple seed and seed weight in MG $VI{\sim}VII$, phomopsis and growth days in MG $IV{\sim}V$ and MG $VI{\sim}VII$, and phomopsis and purple seed in MG $IV{\sim}V$ and MG $VI{\sim}VII$. In contrast, a negative relationship was observed between seed weight and lodging in MG $0{\sim}III$. Correlating yield and major characters revealed negative relationships between days to flowering and growth days in MG $0{\sim}III$ and MG $IV{\sim}V$, whereas positive relationships were obtained on MG $VI{\sim}VII$ seeded on April 30. Lodging, seed weight and seed crack were all negatively correlated with yield in the MG $IV{\sim}V$ and MG $VI{\sim}VII$. Soybean cultivars identified as adaptable to early season planting for production of high quality soy curd and fermented soybean paste were Seonyu, Kwangdu, and Soho while those suited for the manufacture of soybean sprouts were Sobaeknanul, Kwangan, Sowon, and Bosuk. Geomjeong 2 chosen as best for mixing with rice.

Electrochemical Studies of Oxovanadium(IV) Complex of 2-Amino-1-cyclopentene-1-dithiocarboxylate

  • Young-Jin Kim;Duck-Soo Park;Yoon-Bo Shim;Sung-Nak Choi
    • Bulletin of the Korean Chemical Society
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    • 제11권2호
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    • pp.89-94
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    • 1990
  • The redox properties of 2-amino-1-cyclopentene-1-dithiocarboxylate anion (acdc) and its oxovanadium complex, $VO(acdc)_2$ have been investigated in dimethylformamide (DMF) with polarography and cyclic voltammetry. Bis(2-amino-1-cyclopentene-1-dithiocarboxylate) oxovanadium(IV) exhibits two polarographic oxidation waves and two reduction waves in the potential range from +0.50V to - 2.4V vs. the Ag/AgCl (DMF) reference electrode. The second oxidation wave appeared at - 0.08V is found to be reversible and is attributed to the formation of $VO(acdc)_2\;^+$. The first reduction process (at - 0.60V) is also reversible and this reduction process is caused by the electrode process of formation of $VO(acdc)_2$-species. The half wave potential for the reduction, V(IV)$\to$V(III) is more positive for oxovanadium complexes containing sulfur donor atoms than other VO(IV) complexes having oxygen or nitrogen donor atoms.

이온 교환수지에 의한 철 및 강의 분석에 관한 연구 (제2보). 음이온 성분의 분리 (The Study on the Separation of the Subsidiary Elements in Iron and Steel by Using Ion Exchangers (II). The Separation of Anions)

  • 이병조;박면용;박기채
    • 대한화학회지
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    • 제17권6호
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    • pp.428-433
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    • 1973
  • 음이온교환수지관(Dowex 1${\times}8,\;20cm{\times}3.14cm^2$)을 통하여 0.1M Si(IV), As(V), P(V), S(VI), W(VI), Cr(VI)의 용액을 각기 1ml씩 취하여 섞은 용액 6ml를 다음과 같은 용리액으로 용리시켜 정량적으로 분리하였다. 이때에 용리액은 Si(IV), As(V), P(V)에 대하여 0.07M 염산과 0.03M 염화나트륨을 섞은 용액(pH 1.3)을, S(VI), W(VI), Cr(VI)에 대하여 0.6M 염화나트륨과 0.3M 수산화나트륨을 섞은 용액을 사용하였다. 이때에 함께 용출된 P(V)와 As(V)의 혼합액은 아황산나트륨용액으로 처리하여 As(V)를 As(III)으로 환원시킨다음 0.1N 아황산나트륨용액(pH 3.48)으로 용리하여 분리하였다. 많은 양의 철(97% 이상)과 Si(IV), As(V), S(VI), P(V), W(VI)이 혼합된 용액은 양이온교환수지관(Dowex 50w${\times}12,\;30cm{\times}3.14cm^2$)을 통하여 디메틸술포옥시드와 질산나트륨의 혼합용리액으로 용리하여 철을 먼저 분리하고 다시 음이온들은 음이온교환수지관을 통하여 분리하였다. 철강중에 들어있는 음이온 성분들도 같은 방법으로 분리할 수 있었다.

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