• Title/Summary/Keyword: Unsaturated polyester

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Comparison of Geogrid Bonding Methods under Asphalt Overlay Layer for Reflection Cracking Retardation (아스팔트 덧씌우기 하부의 Geogrid 부착방법에 따른 반사균열 지연특성 비교)

  • Doh, Young-Soo;Kim, Bun-Chang;Ko, Tae-Young;Kim, Kwang-Woo
    • International Journal of Highway Engineering
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    • v.7 no.4 s.26
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    • pp.9-20
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    • 2005
  • This study was carried out to select most efficient bonding methods of geogrid at the interface of old concrete pavement before placing asphalt overlay layer for reflection cracking retardation. Three bonding methods, a RSC-4 emulsified asphalt, a compound and an unsaturated polyester resin (UPR) were compared in this study. Three types of asphalt mixture (AC 60-80, RLDPE 8%, PG 76-22) and a dense-graded aggregate were used for overlay asphalt pavement. A reinforcing material which consists of a woven fabric underneath a glass fiber grid was used. An expedite test method which is for simulating mixed mode (mode I and II) fracture test was performed using a wheel tracker in laboratory. Cracking development by load repetition was measured as fatigue life (number of load cycle) and expansion of specimen body were measured for each test specimen. The results showed that UPR was the best and RSC-4 the next. But considering field applicability, RSC-4 was considered as an appropriate choice for bonding reinforcing material.

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The Bisphenol A: A Modulator of Pregnancy in Rats

  • Kim, Pan-Gyi;Lee, Na-Rae;Hwang, Seong-Hee
    • Journal of Environmental Health Sciences
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    • v.29 no.4
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    • pp.27-34
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    • 2003
  • Bisphenol A is used in the manufacture of epoxy, polycarbonate, and corrosion-resistant unsaturated polyester-styrene resins required for food packaging materials in industrial processing. Some reports indicated the possibility of harmful effects on rats. In this study was used a method for the determination of bisphenol A in blood according to the OSHA High Performance Liquid Chromatography (HPLC) guideline. The method involved blood extraction using methylene chloride. And it was evaluated developmental and teratogenic effects in pregnant rats and second generation. The results obtained were as follows. There was a significant increase in the body weights and treated groups F1 female in liver, spleen, kidney, but according to dose-response. F1 female rat's relative body weight and absolute body weight are not different. There was a significant increase liver, spleen, kidney organ weight and reproductive organ weight epididymis, prostate gland in F1 male rats. There was a proestrous in pregnant rat, group 200 $\mu\textrm{g}$/kg, 2000 $\mu\textrm{g}$/kg, 20,000 $\mu\textrm{g}$/kg. The effect on rat treated with bisphenol A decrease organ weight and reproductive organ weight. Identification and quantitation were performed with using HPLC C18 column and using at retention time 5.5 min. The results of the detection of bisphenol A were at 20,000 $\mu\textrm{g}$/kg in average 1 $\mu\textrm{g}$/ml, 200 $\mu\textrm{g}$/kg average in 0.9 $\mu\textrm{g}$/ml blood samples. From those results, it could be concluded that the effects of pregnant rat and second generation(F1) by bisphenol A treatment during lactational period were estrogenic and bisphenol A was remained in serum at low level.

Hardening properties in MMA monomer using UP and EPS in addition hardener (경화제의 첨가에 따른 UP와 EPS 혼입 MMA 수지의 경화특성)

  • Lee, Jung-Hui;Song, Hun;Chu, Yong-Sik;Lee, Jong-Kyu
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.445-448
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    • 2008
  • The unsaturated polyester(UP) and epoxy resin have a superior material properties and a chemical resistance using sewerage pipes rehabilitation. However, UP and epoxy have not a low temperatures harding, the requirement $8{\sim}11$ hours long times harding and heating system used by reinforcement liner. This study is to evaluate the effects of low temperature harding properties methyl methacrylate(MMA) monomer using expanded polystyrene(EPS) and UP in addition of initiator and promoters. From the test result, viscosity tends to increase with increasing EPS and UP contents. However, harding time change of the MMA resins which it follows in addition of the initiator and promoter.

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Property improvement of natural fiber-reinforced green composites by water treatment

  • Cho, Dong-Hwan;Seo, Jeong-Min;Lee, Hyun-Seok;Cho, Chae-Wook;Han, Seong-Ok;Park, Won-Ho
    • Advanced Composite Materials
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    • v.16 no.4
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    • pp.299-314
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    • 2007
  • In the present study, natural fibers (jute, kenaf and henequen) reinforced thermoplastic (poly(lactic acid) and polypropylene) and thermosetting (unsaturated polyester) matrix composites were well fabricated by a compression molding technique using all chopped natural fibers of about 10 mm long, respectively. Prior to green composite fabrication, natural fiber bundles were surface-treated with tap water by static soaking and dynamic ultrasonication methods, respectively. The interfacial shear strength, flexural properties, and dynamic mechanical properties of each green composite system were investigated by means of single fiber microbonding test, 3-point flexural test, and dynamic mechanical analysis, respectively. The result indicated that the properties of the polymeric resins were significantly improved by incorporating the natural fibers into the resin matrix and also the properties of untreated green composites were further improved by the water treatment done to the natural fibers used. Also, the property improvement of natural fiber-reinforced green composites strongly depended on the treatment method. The interfacial and mechanical results agreed with each other.

A Study on the Preparation ana Mechanical Properties of Composites Reinforced FRP Waste and Rock-Crush Sludge (폐 FRP/석분슬러지 충전 복합재의 제조 및 기계적 물성에 관한 연구)

  • 황택성;박진원;이철호
    • Polymer(Korea)
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    • v.24 no.6
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    • pp.829-836
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    • 2000
  • In order to recyle the FRP waste from SMC bathtubs and rock-crush sludge obtained as a byproduct of stones, the composite consisting of the FRP and rock-crush sludge and the unsaturated polyester matrix resin were prepared. To enhance the interfacial bonding force between the reinforcements and the matrix resin, the rock-crush sludge was treated with silane coupling agent, ${\gamma}$-methacryloxypropyltrimethoxysilane (${\gamma}$-MPS) and their mechanical properties and interface phenomena were examined. The flexural modulus of the composite containing 10 wt% rock-crush powder treated with 3 wt% silane coupling agent showed the maximum value. And also the initial thermal degradation temperature of composites were in the range of 352~359$^{\circ}C$. From these results, we observed that the weight loss of composites was almost constant regardless of the concentration of silane coupling agent. It is confirmed that the interface of the composites containing filler treated with ${\gamma}$-MPS was improved in that there were no pull-out phenomena between the reinforcement and matrix resin.

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Strengths and Permeability Properties of Porous Polymer Concrete for Pavement with Different Fillers (충전재 종류에 따른 포장용 포러스 폴리머 콘크리트의 강도 및 투수 특성)

  • Kim, Young-Ik;Sung, Chan-Yong
    • Journal of The Korean Society of Agricultural Engineers
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    • v.49 no.4
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    • pp.51-59
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    • 2007
  • Recently, concrete has been made porous and used for sound absorption, water permeation, vegetation and water purification according to void characteristics. Many studies are carried out on the utilization of sewage sludge, fly ash and waste concrete to reduce the environmental load. This study was performed to evaluate the void, strength, relationship between void and strength, permeability and chemical resistance properties of porous polymer concrete for pavement with different fillers. An unsaturated polyester resin was used as a binder, crushed stone and natural sand were used as an aggregate and bottom ash, fly ash and blast furnace slag were used as fillers. The mix proportions were determined to satisfy the requirement for the permeability coefficient, $1{\times}10^{-2}$ cm/s for general permeable cement concrete pavement in Korea. The void ratios of porous polymer concrete with fillers were in the range of $18{\sim}23%$. The compressive strength and flexural load of porous polymer concrete with fillers were in the range of $19{\sim}22$ MPa and $18{\sim}24$ KN, respectively. The permeability coefficients of porous polymer concrete with fillers were in the range of $5.5{\times}10^{-1}{\sim}9.7{\times}10^{-2}$ cm/s. At the sulfuric acid resistance, the weight reduction ratios of porous polymer concrete immersed during 8-week in 5% $H_{2}SO_{4}$ were in the range of $1.08{\sim}3.56%$.

Compressive and Flexural Strength Development Characteristics of Polymer Concrete (폴리머 콘크리트의 압축 및 휨강도 발현 특성)

  • Jin, Nan Ji;Yeon, Kyu-Seok
    • Journal of The Korean Society of Agricultural Engineers
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    • v.60 no.1
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    • pp.101-110
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    • 2018
  • This study experimentally investigated the compressive and flexyral strength development characteristics of polymer concrete using four different type polymeric resins such as unsaturated polyester, vinyl ester, epoxy, and PMMA (polymethyl methacrylate) as binders. The test results show that the average compressive strength of those four different polymer concretes was 88.70 MPa, the average flexural strength was 20.30 MPa. Those test results show that compressive and flexural strengths of polymer concrete were much stronger than compressive and flexural strengths of ordinary Portland cement concrete. In addition, the relative gains of the compressive strength development at the age of 24 hrs compared to the age of 168 hrs were 68.6~88.3 %. Also, the relative gains of the flexural strength development at the age of 24 hrs compared to the age of 168 hrs were 73.8~93.4 %. These test results show that compressive and flexural strengths of each polymer concrete tested in this study were developed at the early age. Moreover, the prediction equations of compressive and flexural strength developments regarding the age were determined. The determined prediction equations could be applied to forecast the compressive and flexural strength developments of polymer concrete investigated in this study because those prediction equations have the high coefficients of correlation. Last, the relations between the compressive strength and the flexural strength of polymer concrete were determined and the flexural/compressive strength ratios were from 1/4 to 1/5. These results show that polymer concretes investigated in this study were appropriate as a flexural member of a concrete structure because the flexural/compressive strength ratios of polymer concrete were much higher than the flexural/compressive strength ratios of Portland cement concrete.

A Study on Characteristics of Flexural Behavior of High-strength Polymer Concrete Beams Using Recycled PET (PET 재활용 고강도 폴리머 콘크리트보의 휨거동에 관한 연구)

  • Cho Byung-Wan;Park Jong-Hwa;Park Seung-Kook;Bea Sung-Wan
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.05a
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    • pp.483-486
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    • 2005
  • The polymer concrete is drawing a strong interest as high-performance materials in the construction industry. Resins using recycled PET offer the possibility of a lower source cost of materials for making useful polymer concrete products. Also the recycling of PET in polymer concrete would help solve some of the solid waste problems posed by plastics and save energy. Polymer concrete beams using unsaturated polyester resins based on recycled polyethylene terephthalate (PET) plastic waste were used in our study for grasping its structural behavior of static and fatigue. As a result of static test, Compression stress distribution of Polymer concrete indicates linear behavior such as triangles. Although polymer concrete is high strength materials, its ductility capacity is excellent. From the fatigue test results, There was almost no difference on flexural characteristics between before and after fatigue loading. Therefore, recycled PET polymer concrete remains excellent structural ability after fatigue loading.

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A Study on Technology of Waterproofing of the Concrete Structure Which Used Soft FRP Resin and Square Groove Cutting Technique (연질 FRP 수지와 정방형 홈 컷팅 기술을 이용한 콘크리트 구조물의 방수기술에 관한 연구)

  • Lee, Hyung-Jun;Choi, Sung-Min;Kim, Sung-Sik;Ahn, Sang-Ku;Cho, Ah-Hyung;Oh, Sang-Keun
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.597-600
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    • 2008
  • In this study the reason which researches the feature of the exposure type waterproofing it uses the technique of the soft FRP it uses the soft unsaturated polyester and the square groove cutting technique with respects and solves the interface separate problem because of the rigid FRP it is used with the repairs and retrofit materials it is caused by in adhesion of concrete insufficiency. The feature of this technique was the dispersion and the reinforcement of the fatigue stress due to the integration behavior and the reinforcement due to the glass-fibre of the concrete due to the soft FRP resin and, it investigated the crack appearance confrontation of concrete and the cohesion stability of the concrete due to the square groove cutting technique with importance. The result of research when it applies the soft FRP with the exposure type waterproofing, is judged with the fact that it will be able to expect a bulge resistance confrontation and creak confrontation ability and cohesion stability improvement.

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Hardening properties of MMA Monomer Using EPS in addition of Initiator and Promoter (개시제 및 촉진제의 첨가에 따른 EPS 혼입 MMA 수지의 경화특성)

  • Lee, Jung-Hui;Song, Hun;Chu, Yong-Sik;Lee, Jong-Kyu
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.929-932
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    • 2008
  • The unsaturated polyester(UP) and epoxy resin have a superior material properties and a chemical resistance using sewerage pipes rehabilitation. However, UP and epoxy have not a low temperatures harding, the requirement $8{\sim}11$ hours long times harding and heating system used by reinforcement liner. This study is to evaluate the effects of low temperature harding properties methyl methacrylate(MMA) monomer using expanded polystyrene(EPS) in addition of initiator and promoters. From the test result, viscosity tends to increase with increasing EPS contents. However, harding time change of the MMA resins which it follows in addition of the initiator and promoter.

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