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Electrochemical Reduction of Perchlorate Using Mercury Film Electrode (수은 막전극을 이용한 수용액 중 과염소산이온의 전기화학적 환원)

  • Myung, Noseung;Kim, Eun Young;Jee, Hyung-Woo;Keum, Narae;Rhee, Insook;Paeng, Ki-Jung
    • Journal of the Korean Electrochemical Society
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    • v.19 no.3
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    • pp.95-100
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    • 2016
  • A method for electrochemical degradation of the perchlorate anion ($ClO_4{^-}$) using mercury film electrode has been studied. Electrochemical method has relatively simple pre-treatment. However, electrochemical method should avoid interference from hydrogen evolution at the applied potential to degradation of perchlorate ion, and thus applied electrode should have large hydrogen overvoltage which suppressed the hydrogen evolution at the working reduction potential to prevent hydrogen evolution. In this study, we used mercury film electrode as a working electrode which has a large overvoltage. Ag / AgCl (sat. NaCl) was used as a reference electrode, and platinum was used as a counter electrode. Mercury film electrode was made by cyclic voltammetry (CV) method. The deposition time was decided as 10 minute, and the stability of the mercury electrode in perchlorate solution was confirmed by CV. The reduction potential of perchlorate was checked by using CV method, and decomposition of perchlorate was performed by using chronoamperometric (CA) method. Also, ion chromatography (IC) was used to confirm the degradation rates of perchlorate.

Activation of Barley S-Adenosylmethionine Synthetase1 Gene Promoter in Response to Phytohormones and Abiotic Stresses

  • Kim, Jae-Yoon;Kim, Dae-Yeon;Jung, Je-Hyeong;Hong, Min-Jeong;Heo, Hwa-Young;Johnson, Jerry W.;Kim, Tae-Ho;Seo, Yong-Weon
    • Journal of Crop Science and Biotechnology
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    • v.10 no.1
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    • pp.50-56
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    • 2007
  • Barley S-adenosylmethionine synthetase1 gene, which was differentially expressed in seed development of extra early barley, was regulated by the phytohormones and abiotic stresses. In order to identify the regulation regions which were involved in transcriptional control of the phytohormones and abiotic stresses, we isolated 1459 bp fragment of HvSAMS1 gene promoter using genome walking strategy and deletion series were constructed. Deleted upstream fragments(-1459, -1223, -999, -766, -545, -301 bp) were fused to the GUS reporter gene and evaluated via Agrobacterium-mediated transient expression assay. Increased GUS activity of HvSMAS1 promoter -301/GUS construct under each of NaCl, $GA_3$, ABA and ethylene application was found. However, GUS activity was negligible in the leaves transformed with the HvSMAS1 promoter(-1459, -1223, -999, -766 and -545)/GUS constructs. No significant induction of GUS activity was observed for the ethionine and spermidine treatments. In order to locate promoter sequence of the HvSAMS1 gene that was critical for the activation of gene expression, deletion and addition promoter derivatives(+, includes 43 bp of 5' ORF) of the HvSAMS1 gene fused to the GUS reporter gene were applied. The tobacco leaves which harbored the additional HvSAMS1 promoter(-1459+, -1459 to -546, -545+ and -301+)/GUS construct did not significantly induce GUS activity as compared to the HvSAMS1 promoter(-1459, -545 and -301)/GUS constructs under each of NaCl, ABA and $GA_3$ treatment. However, the GUS activity was high in the tobacco leaves which harboring the -211 to -141 regions of the HvSAMS1 promoter. This result suggested that HvSAMS1 gene expression might be regulated by this region(from -211 to -141).

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Evaluations of Life Cycle Assessment on Indium-Tin-Oxide Electrochemical Recycling Process (디스플레이 투명전극용 인듐-주석-산화물의 전기화학적 재활용 공정에 관한 전과정 평가)

  • Kim, Raymund K.I.;Lee, Na-Ri;Lee, Soo-Sun;Lee, Young-Sang;Hong, Sung-Jei;Son, Young-Keun;Hong, Tae-Whan
    • Clean Technology
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    • v.19 no.4
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    • pp.388-392
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    • 2013
  • Iindium-tin-oxide (ITO) material was had to use in display application as transparent electrode. However it would be problems comes up, the depletion of indium, tin and energy consumption of production process. Therefore recently trend was demanded alternative ITO material and recycling/reused ITO. In this conditions, the environmental impact have to express correct value about recycling/reused ITO process. The life cycle assessment was valuable method in this process. Thus first step was carried out separating in/out put (material) sources and then, exactive data base (DB) was applied. The result of environment impact was calculated by affect categories and recycling rate was set to 34% (This value was measured in previous project). The rate (g) of ITO material was calculated by chemical equivalent. In result, environmental impact were revealed acidification potential and abiotic depletion and if do not recycle/reuse ITO, $ 476 per 1 ton waste in land.

Vertical Distribution of PAHs Concentrations in the Aerosol (대기 연직별 에어로졸 내 PAHs 농도분포 특성)

  • Hwang, Eun Jin;Ahn, Kang Ho;Eun, Hee Ram;Lee, Hong Ku;Lee, Yang Woo;Lee, Ji Yi
    • Particle and aerosol research
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    • v.10 no.4
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    • pp.169-176
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    • 2014
  • Air samples were collected at various altitudes (from 165 to 1153 m) to observe vertical distribution of particulate PAHs concentrations using a very compact and light particle sampling package developed by Eun et al.(2013). TD-GC-MS developed by Hwang et al.(2014) was applied to PAHs analysis for effective analysis of PAHs contained trace amounts in the samples. The ranges of total PAHs concentrations were from 6.95 to $96.0ng\;m^{-3}$ on the ground and from 3.75 to $21.74ng\;m^{-3}$ at high altitude, respectively. All of particulate PAHs concentrations measured on the ground were higher than those measured at high altitude, while, the profile of individual PAH compounds between the ground and high altitude samples were similar. It means the distribution of particulate PAHs concentrations at high altitude were affected by the emission of PAHs emitted from ground.

A Study on the Validity of the Infrastructure Construction Cost for the Commercialization of Online Electric Vehicles (온라인 전기자동차의 상용화를 위한 인프라 구축비용 타당성에 대한 연구)

  • Song, Yong Uk;Park, Sangun;Kim, Wooju;Hong, June S.;Jeon, DongKyu;Lee, Sangheon;Park, Jonghan
    • The Journal of Society for e-Business Studies
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    • v.18 no.1
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    • pp.71-95
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    • 2013
  • This study aims to validate the cost of building the infrastructure to commercialize online electric vehicles. For that purpose, we probe the cost to construct the necessary infrastructure for online electric vehicles regarding Seoul area public bus transit. OLEV and PEV are considered as alternative electric vehicle schemes, and each of them has their own cons and pros in terms of rechargeable battery cost and charger cost. An optimization model which minimizes the cost to install online electric bus feeding devices is proposed in order to compare the total costs of the two alternative schemes. We developed a Mixed Integer Programming model to locate the feeding devices of several different lengths at each bus stops. Furthermore, we implemented a computer simulator to obtain the parameters which will be used in the MIP model and a Web-based system which determines the optimal location of infrastructure for the whole city area from a result of the MIP model. The cost comparison result shows that the total cost of OLEV is cheaper than that of PEV considering the real data of Seoul area public transit, and, as a result, confirms the feasibility of the commercialization of OLEV.

Analysis of Energy Consumption Pattern and Greenhouse Gas Emission in the Academic Facility (대학에서의 에너지 소비패턴 및 온실가스 배출현황 분석)

  • Kim, Jin-Sik;Lee, Kyoung-Bin;Lee, Im-Hack;Kim, Shin-Do
    • Journal of Korean Society of Environmental Engineers
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    • v.34 no.9
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    • pp.604-612
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    • 2012
  • Self-management plan for GHG (Greenhouse Gas) reduction should be prepared in academic facilities, which occupy a large amount of energy consumption. In this study, a university was chosen as one of the major academic facilities and its energy consuming pattern and GHG emission were analyzed. The results have shown that annual $CO_2$ emission from university buildings was 10,452 ton-$CO_2$ (0.65 ton-$CO_2/m^2$), and dependent upon 78.0% electricity, 20.5% LNG and 1.5% oil, respectively as energy sources. According to more detail analysis by usage of energy consumption, appliances occupies 36.7% followed by gas heating (18.9%), lighting (18.6%), heating with electricity (12.5%), cooling with electricity (10.2%), transportation (1.5%), gas cooling (1.2%) and cooking (0.4%). Furthermore, annual $CO_2$ emissions per unit area and a student by electricity usage were evaluated to 51.30 kg-$CO_2/m^2$ and 981.86 kg-$CO_2$/capita, respectively and those by LNG usage were 14.61 kg-$CO_2/m^2$ and 241.01 kg-$CO_2$/capita.

Analysis of the Factors Affecting Nutrients Removal in Hybrid Constructed Wetland Treating Stormwater Runoff (강우 유출수 처리를 위한 하이브리드 인공습지의 영양물질 저감 인자 분석)

  • Gurung, Sher Bahadur;Geronimo, Franz Kevin F.;Choi, Hyeseon;Hong, Jungsun;Kim, Lee-Hyung
    • Journal of Wetlands Research
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    • v.20 no.1
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    • pp.54-62
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    • 2018
  • Nutrients generated from various land uses lead to eutrophication during the influx of water, and it is necessary to apply the LID techniques to reduce nutrients from nonpoint sources in order to mitigate the occurrence of the algal bloom. This study was carried out to derive the design factors of hybrid artificial wetland (HCW) to increase the removal efficiency of nutrients. HCW system was constructed in the year 2010 for the treatment of rainfall runoffs from parking lots and roads composed of 100% impervious floors in the Cheonan campus of Kongju University. The average nutrients removal efficiency of TN and TP was 74% and 72%, respectively. Both TN and TP removal efficiencies were higher than those of free surface wetlands and subsurface flow wetlands due to activated physical and ecological mechanisms. The critical design parameters for the efficient nutrients removal in the artificial wetlands were the ratio of the surface area to the catchment area (SA/CA), land use, the rainfall runoff, and the rainfall intensity. The optimal carbon to nitrogen (C/N) ratio was estimated at 5: 1 to 10.3: 1. The results of this study can be applied to the efficient design of hybrid artificial wetlands to treat nutrients in urban runoff with high efficiency.

Effect of Intercropping Ratio on the Cherry Tomato with Basil on the Growth, Physiological, and Productivity Parameters on the Rooftop in Urban Agriculture (옥상 도시농업에서 방울토마토(Lycopersicon esculentum)와 바질(Ocimum basilicum)간의 공영식재가 생육, 생리, 생산성에 미치는 영향)

  • Ju, Jin-Hee;Song, Hee-Yeon;Oh, Deuk-Kyun;Park, Sun-Yeong;Yoon, Yong-Han
    • Journal of Environmental Science International
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    • v.30 no.9
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    • pp.709-717
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    • 2021
  • This study evaluated the growth, physiological responses and productivity based on the intercropping ratio of cherry tomato (Lycopersicon esculentum L.) with basil (Ocimum basilicum L.). on the rooftops to determine out the efficient ratio in urban agriculture. From April to September 2019, an experiment was conducted on the rooftop of Konkuk University Glocal Campus. Cherry tomato and basil were selected as companion plants for eco-friendly urban agriculture on the rooftops. Each plot was created with a width of 100 cm, length of 100 cm, and height of 25 cm. After installing drainage and waterproof layers from bottom to top, substrate was laid out with a height of 20 cm. Intercropping ratio was consisted of a single tomato plant (TC), 2:1 tomato to basil (T2B1), 1:1 tomato to basil (T1B1), 1:2 tomato to basil 2 (T1B2), and a single basil plant (BC), were conducted using a randomized complete plot design with five treatments and three replication (a total 15 plots). Measurements were divided into growth, physiological responses, and productivity parameters, and detailed items were investigated and analyzed by classifying them into plant height, leaf length, leaf width, number of leaves, root length, root collar caliper, chlorophyll contents, fresh weight, dry weight, number of fruit, fruit caliper, fruit weight, and sugar content. Comparative analyses of cherry tomato with basil plants by intercropping ratio, growth, physiological, and productivity responses are determined to be efficient when the ratio of cherry tomato to basil ratio is 2:1 or 1:1.

Development of non-destructive freshness measurement system for eggs using PLC control and image processing (PLC제어와 영상처리를 이용한 계란의 비파괴 신선도 측정 시스템 개발)

  • Kim, Tae-Jung;Kim, Sun-Jung;Lee, Dong-Goo;Lee, Jeong-Ho;Lee, Young-Seok;Hwang, Heon;Choi, Sun
    • The Journal of Korea Institute of Information, Electronics, and Communication Technology
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    • v.12 no.2
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    • pp.162-169
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    • 2019
  • Non-destructive freshness measurement using spectroscopy has been carried out several times, but research on freshness and freshness has not been conducted. Therefore the purpose of this study is to develop a system for visually measuring and quantifying the air sack inside the egg by non - destructive method. The experimental environment which designed a small chamber was composed of 850nm band of two IR lasers, IR camera and two servo motors to acquire air sack Images. When the air sack volume ratio is 2.9% or less and the density is 0.9800 or more, the Haugh Unit value is 60 or more It was judged to be a fresh egg of a grade B or higher. These results mean, using the weight measurement, nondestructive decision system, and freshness evaluating algorithm. It can be expected to distinguish grade B or more marketable eggs without using destructive methods.

Study on Stable Gait Generation of Quadruped Walking Robot Using Minimum-Jerk Trajectory and Body X-axis Sway (최소저크궤적과 X축-스웨이를 이용한 4족 보행로봇의 안정적 걸음새 연구)

  • Lee, Dong-Goo;Shin, Wu-Hyeon;Kim, Tae-Jung;Lee, Jeong-Ho;Lee, Young-Seok;Hwang, Heon;Choi, Sun
    • The Journal of Korea Institute of Information, Electronics, and Communication Technology
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    • v.12 no.2
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    • pp.170-177
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    • 2019
  • In this paper, three theories for improving the stability of quadruped robot are presented. First, the Minimum-Jerk Trajectory is used to optimize the leg trajectory. Second, we compare the newly proposed sine wave and the conventional LSM in this paper based on the Jerk value. Third, we calculate the optimum stride of the sway through repetitive robot simulation using ADAMS-MATLAB cosimulation. Through the above process, the improvement of the robot walking is compared with the existing theory. First, the average gradient of the point where the leg trajectory changes rapidly was reduced from at least 1.2 to 2.9 by using the Minimum-Jerk targetory for the movement of the body and the end of the leg during the first walk, thereby increasing the walking stability. Second, the average Jerk was reduced by 0.019 on the Z-axis, 0.457 on the X-axis, and 0.02, 3D on the Y-axis by 0.479 using the Sin wave type sways presented in this paper, rather than the LSM(Longitude Stability Margin) method. Third, the length of the optimal stride for walking at least the Jerk value was derived from the above analysis, and the 20cm width length was the most stable.