• Title/Summary/Keyword: Unit-to-unit interaction

Search Result 435, Processing Time 0.033 seconds

Filler-Polymer Interactions in Filled Styrene-Butadiene Rubber Compounds

  • Park, Sung-Seen
    • Macromolecular Research
    • /
    • v.9 no.1
    • /
    • pp.45-50
    • /
    • 2001
  • Formation of bound rubber depends on the filler-polymer interactions including physical adsorption, chemisorption, and mechanical interaction. Bound rubbers consist of tightly and loosely bound ones. Styrene-butadiene rubber (SBR) is composed of styrene, 1,2-, cis-1,4-, and trans-1,4-units. Filler-polymer interactions of each components of SBR with fillers, carbon black and silica, were studied by analysis of microstructure of the bound rubber. Filler-polymer interaction of the 1,2-unit with the fillers was found to be stronger than those of the other components and this phenomenon was shown more clearly in the tightly bound rubber.

  • PDF

Influence of Intermolecular Interactions on the Structure of Copper Phthalocyanine Layers on Passivated Semiconductor Surfaces

  • Yim, Sang-Gyu;Jones, Tim S.
    • Bulletin of the Korean Chemical Society
    • /
    • v.31 no.8
    • /
    • pp.2247-2254
    • /
    • 2010
  • The surface structures of copper phthalocyanine (CuPc) thin films deposited on sulphur-passivated and plane perylene-3,4,9,10-tetracarboxylic dianhydride (PTCDA)-covered InAs(100) surfaces have been studied by low energy electron diffraction (LEED) and van der Waals (vdW) intermolecular interaction energy calculations. The annealing to $300^{\circ}C$ and $450^{\circ}C$ of $(NH_4)_2S_x$-treated InAs(100) substrates produces a ($1{\times}1$) and ($2{\times}1$) S-passivated surface respectively. The CuPc deposition onto the PTCDA-covered InAs(100) surface leads to a ring-like diffraction pattern, indicating that the 2D ordered overlayer exists and the structure is dominantly determined by the intermolecular interactions rather than substrate-molecule interactions. However, no ordered LEED patterns were observed for the CuPc on S-passivated InAs(100) surface. The intermolecular interaction energy calculations have been carried out to rationalise this structural difference. In the case of CuPc unit cells on PTCDA layer, the planar layered CuPc structure is more stable than the $\alpha$-herringbone structure, consistent with the experimental LEED results. For CuPc unit cells on a S-($1{\times}1$) layer, however, the $\alpha$-herringbone structure is more stable than the planar layered structure, consistent with the absence of diffraction pattern. The results show that the lattice structure during the initial stages of thin film growth is influenced strongly by the intermolecular interactions at the interface.

A Note on Environmental Policy Measures in a Green Market (Green market과 환경정책수단의 오염감축효과에 대한 소고(小考))

  • Rhee, Hosaeng
    • Environmental and Resource Economics Review
    • /
    • v.13 no.1
    • /
    • pp.119-131
    • /
    • 2004
  • A green market refers to a market that consists of environmentally aware consumers. A few researches have been carried out on the effects of environmental policy measures in a green market. These existing researches were based on a vertical differentiation model with firms' price-setting behavior, and derived that unit emission standard and environmental product taxes could not reduce the amount of pollution emission. This note considers a vertical differentiation model with firms' quantity-setting behavior, and shows that, contrary to the previous result, the amount of pollution emission is reduced by the introduction of unit emission standard. This implies the importance of the nature of firms' interaction in figuring out the pollution abatement effect of environmental policy measures in a green market.

  • PDF

DYNAMIC CHARACTERISTICS OF CYLINDRICAL SHELLS CONSIDERING FLUID-STRUCTURE INTERACTION

  • Jhung, Myung-Jo;Kim, Wal-Tae;Ryu, Yong-Ho
    • Nuclear Engineering and Technology
    • /
    • v.41 no.10
    • /
    • pp.1333-1346
    • /
    • 2009
  • To assure the reliability of cylinders or shells with fluid-filled annulus, it is necessary to investigate the modal characteristics considering fluid-structure interaction effect. In this study, theoretical background and several finite element models are developed for cylindrical shells with fluid-filled annulus considering fluid-structure interaction. The effect of the inclusion of the fluid-filled annulus on the natural frequencies is investigated, which frequencies are used for typical dynamic analyses such as responses spectrum, power spectral density and unit load excitation. Their response characteristics are addressed with respect to the various representations of the fluid-structure interaction effect.

Calculation of the Neutron Sensitivity in Rh Self-Powered Detector

  • Lee, Wanno;Gyuseong Cho;Kim, Ho kyung;Hur, Woo-Sung
    • Proceedings of the Korean Nuclear Society Conference
    • /
    • 1996.05d
    • /
    • pp.101-106
    • /
    • 1996
  • For the application of the neutron flux mapping, an accurate calculation of the sensitivity is required because the sensitivity is proportional to the neutron flux density. Sensitivity is defined as the current per unit length per unit neutron flux and it mainly depends on the depression factor(f), the escape probability from the emitter($\varepsilon$1) and the charge build-up factor of the insulator layer(c). A Monte Carlo simulation was accomplished to calculate the sensitivity of rhodium emitter material and alumina(Al$_2$O$_3$) insulator with a cylindrical geometry, based on the (n,${\beta}$) interaction and on other interaction including the secondary electron generation for the more accurate estimation of the sensitivity. From the simulation results, factors fur the sensitivity were accurately calculated and compared with other theoretical and experimental values. In addition, the sensitivity linearly increases and saturates as the emitter radius increases. The accomplished method is useful in the analysis for the change of SPND sensitivity as a function of burn-up and in the optimum design of SPND.

  • PDF

Primary Culture of Endothelial Cells from Murine Brain Microvessels

  • Lee Sun-Ryung
    • Biomedical Science Letters
    • /
    • v.12 no.2
    • /
    • pp.127-130
    • /
    • 2006
  • It is important to coordinated interaction among neurons, astrocytes and endothelial cells to maintain the function of brain. To study their regulatory mechanisms in vitro system, the co-culture system among the isolated cells from brain may be needed. However, the method for purifying brain microvascular endothelial cells (BMEC) far culture have not established yet. In this study, the proper culture methods of mice cells using two different strains, CD1 and C57BL6, to obtain the pure and plentiful endothelial cells were described. The flatted-round forms of CD1 endothelial cells grew on the collagen-IV coating plates, while the purified cells from C57 mice preferred type collagen-I dishes for their growth. Both cells displayed anti-PECAM-1 (CD31) and von Willebrand Factor immune-reactivity. These results indicated that different coating materials not only improve attachment of isolated cells but also promoting growth of cells, suggesting that this method of purifying murine Brain microvascular endothelial cells (BMEC) provides a suitable model to investigate blood-brain-barrier (BBB) properties within neurovascular unit in vitro.

  • PDF

Evaluation of spatial pressure distribution during ice-structure interaction using pressure indicating film

  • Kim, Hyunwook;Ulan-Kvitberg, Christopher;Daley, Claude
    • International Journal of Naval Architecture and Ocean Engineering
    • /
    • v.6 no.3
    • /
    • pp.578-597
    • /
    • 2014
  • Understanding of 'spatial' pressure distribution is required to determine design loads on local structures, such as plating and framing. However, obtaining a practical 'spatial' pressure distribution is a hard task due to the sensitivity of the data acquisition frequency and resolution. High-resolution Pessure-Idicating Flm (PIF) was applied to obtain pressure distribution and pressure magnitude using stepped crushing method. Different types of PIF were stacked at each test to creating a pressure distribution plot at specific time steps. Two different concepts of plotting 'spatial' pressure-area curve was introduced and evaluated. Diverse unit pixel size was chosen to investigate the effect of the resolution in data analysis. Activated area was not significantly affected by unit pixel size; however, total force was highly sensitive.

Response of a rocksalt crystal to electromagnetic wave modeled by a multiscale field theory

  • Lei, Yajie;Lee, James D.;Zeng, Xiaowei
    • Interaction and multiscale mechanics
    • /
    • v.1 no.4
    • /
    • pp.467-476
    • /
    • 2008
  • In this work, a nano-size rocksalt crystal (magnesium oxide) is considered as a continuous collection of unit cells, while each unit cell consists of discrete atoms; and modeled by a multiscale concurrent atomic/continuum field theory. The response of the crystal to an electromagnetic (EM) wave is studied. Finite element analysis is performed by solving the governing equations of the multiscale theory. Due to the applied EM field, the inhomogeneous motions of discrete atoms in the polarizable crystal give rise to the change of microstructure and the polarization wave. The relation between the natural frequency of this system and the driving frequency of the applied EM field is found and discussed.

Development of a Database System for Efficient Community Health Management - Focus on the Home Visiting Care of Family as a Unit by the Health Centers- (효율적인 지역사회 건강관리를 위한 데이터베이스 시스템 구현- 보건소의 가족단위 방문간호사업을 중심으로-)

  • Choi, In-Hee
    • Research in Community and Public Health Nursing
    • /
    • v.11 no.1
    • /
    • pp.67-79
    • /
    • 2000
  • In recent years, the recipients of the services of the health centers in Korea have been shifted from individual sick persons to families as a unit. As a result, the home visiting care records which are all filled out manually, will be increased. Since there is virtually no increase in the number of community health nurses, the CHNs are required to work more efficiently. One of the ways to make the CHNs' work more efficient is to reduce recording time by using a computer. However, a computer system that can manage the families as a unit has not yet been developed. In response to this need, we developed a database system that can be utilized in home visiting care service. The family assessment data is collected. diagnosed. and evaluated according to the family diagnosis classification. The system for family diagnosis consists of seven areas. Those areas are family structure. maintenance of the family system, interaction and interchange. support. coping and adaptation, health management. and housing environment. The areas of the family diagnosis consists of 99 items in all. We expect the following from this system. First. the CHNs will be able to identify family problems more easily. Second. the community's health level can be confirmed by the statistics the system produces. Thirdly, the CHNs' nursing services will be cost effective via reduced recording time. Finally, the family problems of the sick individuals which have been neglected under the health system oriented on individual persons can be effectively managed.

  • PDF

Mode of Action on EcoRI Restriction Endonuclease: EcoRI and EcoRI Variant N199H have Active Monomeric Forms

  • Kim, Jae-Jong;Koh, Suk-Hoon;Kim, Joong-Su;Lee, Dae-Sil
    • BMB Reports
    • /
    • v.31 no.2
    • /
    • pp.149-155
    • /
    • 1998
  • The N199H variant of the EcoRI endonuclease has about twice the catalytic activity of the wild-type. A comparison of their biochemical characteristics, using synthetic oligonucleotides 5'-dAAAACTTAAGAAAAAAAAAAA-3' (KA) and 5'-dTTTTTGAATTCTTTTTTTTTT-3' (KT), helps to define the cleavage reaction pathway of these enzymes. Both EcoRI and EcoRI variant N199H were found to cleave singlestranded KA or KT about three times faster than the double-stranded forms, although the KT oligonucleotide was more susceptible. Using the ssDNA substrate in kinetic analyses, lower $K_m$ values were obtained for the N199H variant than for the wild-type at low (50 mM), as well as high (200 mM), sodium chloride concentrations. This difference between the endonucleases is attributed to a grealter accessibility for tbe substrate by the variant, and also a higher affinity for the DNA backbone. It also appears that the relative activities of the two enzymes, particularly at high ionic strength, are proportional to their populations in the monomeric enzyme form. That is, according to gel filtration data, half of the N199H molecules exist as monomers in 200 mM NaCl, whereas those of the wild-type are mainly dimeric. Consequently, the Asp199 residue of the EcoRI endonuclease may be implicated in the protein-protein interaction leading to dimerization, as well as in coupling to DNA substrates. In summary, it is proposed that active monomeric endonuclease molecules, derived from the dimeric enzyme, recognize and form a complex with a single stranded form of the DNA substrate, which then undergoes nucleophilic substitution and cleavage.

  • PDF