• Title/Summary/Keyword: Unit Cell

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Multi-physics Unit Model of Fuel cell for Railway Vehicle Propulsion Systems

  • Abbas, Mazhar;Cho, Inho;Kim, Jonghoon
    • Proceedings of the KIPE Conference
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    • 2018.07a
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    • pp.356-357
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    • 2018
  • Fuel-cell powered Railway Vehicle Propulsion Systems (RVPSs) are highly desirable due to environment friendly characteristics, and high efficiency of fuel cell (FC). Among various types, the faster start-up and optimality to frequent starts and stops of Polymer electrolyte membrane fuel cell (PEMFC) makes it well suited for propulsion systems. A comprehensive model of PEMFC with reflection of multi-physics behavior required to identify and validate its performance in real RVPSs. Thus this paper will model and simulate the PEMFC unit cell model: a detailed reflection of governing laws and account of dynamic conditions.

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Preparation and Comparative Test of Polypyrrole Electrodes for Direct Methanol Fuel Cell

  • Park, Jae-Chan;Kim, Jeong-Soo;Jung, Doo-Hwan
    • Macromolecular Research
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    • v.10 no.4
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    • pp.181-186
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    • 2002
  • The displacement of carbon black to polypyrrole as a catalyst supporter in the fuel electrode of a direct methanol fuel cell was investigated. Polypyrrole was obtained as a black powder by the chemical polymerization of pyrrole with three different oxidants. The synthesized polypyrroles were pasted on carbon paper and transformed to the fuel electrodes with electrochemically deposited platinum. The prepared fuel electrode was assembled and mounted in a unit cell using a membrane and cathodic electrode film. In comparison with the carbon black fuel electrode, the performance of the unit cell was analyzed in relation to the state of the catalyst, the type of oxidant, and the morphology of the polypyrrole powder.

Characteristics and unit cell fabrication of molten carbonate fuel cell (용융탄산염형 연료전지의 단위전지 제작과 특성)

  • 엄승욱;김귀열
    • Electrical & Electronic Materials
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    • v.8 no.6
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    • pp.768-773
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    • 1995
  • We describe a manufacturing method and characteristics on components of molten carbonate fuel cell. Cr, Al, AI$_{2}$O$_{3}$, Co, MgO powder were mixed with Ni powder for anode components and NiO was used for cathode electrode. The electrolyte plate consisted of LiAIO$_{2}$ and carbonate (Li$_{2}$CO$_{3}$/K$_{2}$CO$_{3}$=62/38) and these three were manufactured by doctor-blade method. As a result, open circuit voltage was 1.05[VI at Ni-10Cr anode and porosity was above 60[%].

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Analytical Approach to Compression and Shear Characteristics of the Unit Cell of PCM Core with Pyramidal Configuration (피라미드 형상의 PCM 코어 단위 셀의 압축 및 전단특성에 관한 해석적 연구)

  • Kim, S.W.;Jung, H.C.;Lee, Y.S.;Kang, B.S.
    • Transactions of Materials Processing
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    • v.19 no.7
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    • pp.411-415
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    • 2010
  • A sandwich panel which is comprised of truss cores faced with solid face sheets is lightweight and multi-functional. So it is widely used to not only structural material but also heat transfer media in transportation field such as airplane, train and vessel. There are various core topologies such as pyramidal and tetrahedral truss, square honeycombs and kagome truss. The study focused on analytical approach to optimize compression and shear quality of the unit cell of PCM with pyramidal configuration. With various unit cell models which have the same core weight per unit area but different truss member angle, analytical solution for effective stress ($\bar{\sigma},\bar{\tau}$), peak stress ($\bar{\sigma}_{peak},\bar{\tau}_{peak}$) by yielding and buckling, relative density ($\bar{\rho}_c$) and effective stiffness ($\bar{E},\bar{G}$) have been computed and compared each other. With this approach, the most optimal core configuration was predicted. The result has become the efficient guidelines for the design of PCM core structure.

Permeability prediction of plain woven fabric by using control volume finite element method (검사체적 방법을 이용한 평직의 투과율 계수 예측)

  • Y. S. Song;J. R. Youn
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2002.05a
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    • pp.181-183
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    • 2002
  • The accurate permeability for preform is critical to model and design the impregnation of fluid resin in the composite manufacturing process. In this study, the in-plane and transverse permeability for a woven fabric are predicted numerically through the coupled flow model which combines microscopic with macroscopic flow. The microscopic and macroscopic flow which are flows within the micro-unit and macro-unit cell, respectively, are calculated by using 3-D CVFEM(control volume finite element method). To avoid checker-board pressure field and improve the efficiency on numerical computation, A new interpolation function for velocity is proposed on the basis of analytic solutions. The permeability of plain woven fabric is measured through unidirectional flow experiment and compared with the permeability calculated numerically. Based on the good agreement of the results, the relationships between the permeability and the structures of preform such as the fiber volume fraction and stacking effect can be understood. The reverse and the simple stacking are taken in account. Unlike past literatures, this study is based on more realistic unit cell and the improved prediction of permeability can be achieved. It is observed that in-plane flow is more dominant than transverse flow in the real flow through preform and the stacking effect of multi-layered preform is negligible. Consequently, the proposed coupled flow model can be applied to modeling of real composite materials processing.

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A Study on Poisoning of the Reforming Catalysts on the Position of Anode in the Direct Internal Reforming Molten Carbonate Fuel Cell (직접 내부개질형 용융탄산염 연료전지의 음극판 위치에 따른 개질 촉매 피독에 관한 연구)

  • Wee, Jung Ho;Chun, Hai Soo
    • Applied Chemistry for Engineering
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    • v.10 no.5
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    • pp.652-659
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    • 1999
  • The trend of poisoning of reforming catalyst along with the position of anodic catalyst bed was studied. Keeping the conditions that steam to carbon ratio was 2.5, operating voltage was 0.75 V, current density was $140mA/cm^2$, the unit cell was operated during 24 hrs at a steady state. And then the cell was stopped, the catalysts packed in the position of inlet, middle and outlet were sampled individually and then the amount of carbon, Li and K poisoned were analysed. After 100 hrs operated, the catalysts at the same positions were analysed at the same manner. The result of this experiment was as followings. After 24 hrs operated, the poisoning amounts of Li and K in the catalyst were 0.27 wt% at inlet, 0.23 wt% at middle and the highest value 1.59 wt% at outlet. After 100 hrs, the amount of poisoning is the highest in the catalyst packed at the inlet of unit cell. The performance simulation of unit cell explained these trends of poisoning catalysts. The simulation told that the catalyst in the region of the inlet of unit cell treated the 90% of initial methane flow rate and the highest electrochemical reaction happened in this region. So the catalysts of this region were the most poisoned with carbon, Li and K and also the rate of poisoning is faster than that of the catalyst at other regions. The temperature at the region of outlet of unit cell was $30^{\circ}C$ higher than that of other regions, so more Li, and K vaporized than at other regions and little reforming reaction at this region made the catalysts poisoning rate low.

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Developing Sealing Material of a Dye-Sensitized Solar Cell for Outdoor Power (실외 발전을 위한 염료감응형 태양전지의 봉지재 개발)

  • Ki, Hyun-Chul;Hong, Kyung-Jin
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.29 no.12
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    • pp.819-823
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    • 2016
  • DSSC (dye-sensitized solar cell) is expected to be one of the next-generation photovoltaics because of its environment-friendly and low-cost properties. However, commercialization of DSSC is difficult because of the electrolyte leakage. We propose thermal curable base on silicon resin and apply a unit cell and large area ($200{\times}200mm$) dye-sensitized solar cell. The resin aimed at sealing of DSSC and gives a promising resolution for sealing of practical DSSC. In result, the photoelectric conversion efficiency of the unit cell and the module was 6.63% and 5.49%, respectively. In the durability test result, the photoelectric conversion efficiency of the module during 500, 1,000, 1,500 and 2,000 hours was 0.73%, 0.73%, 1.82% and 2.36% respectively. It was confirmed that the photoelectric conversion efficiency characteristics are constant. We have developed encapsulation material of thermal curing method excellent in chemical resistance. A sealing material was applied to the dye-sensitized solar cell and it solved the problem of durability the dye-sensitized solar cell. Sealing material may be applied to verify the possibility of practical application of the dye-sensitized solar cell.

Selection of Constitutive Promoter for Exoinulinase Production in Fed-Batch Culture of Recombinant Yeast (재조합 효모의 유가배양에서 Exoinulinase생산을 위한 Promoter의 선별)

  • 김이경;고지현;김연희;김성구;남수완
    • Microbiology and Biotechnology Letters
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    • v.29 no.4
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    • pp.206-211
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    • 2001
  • In order to overexpress constitutively the Kluyveromyces marxianus exoinulinase gene (INUI) in Saccharomyces cerevisiae, four episomal expression systems employing GAPDH, ADHI, PGK and ENOI promoters were constructed as p YIGP aADHI -INU, pPGK-INU, and pENOI- INU plasmids respectively, When S cereviais transformants harboring each plasmid were batchwisely cultivated in the fermentor containing 5% glucose medium no significant differences in the cell growth are observed How- ever the experession level of exoinulinase and plasmid stability showed a strong dependency on the promoter employed. The expression levels of exoinulinase were about 1.70 unit/ml for GAPDH promoter 1.67 unit/ml for PGK promoter, 1.29 unit /ml for ADH1 promoter, and 0.80 unit/ml for ENOl promoter. The plasmid stabilites were maintaines above 80% in all experession systems. except the GAPDH promoter system of 55%, Based on the plas- mid stability and expression level of exoinulinase the ADHl and PGK promoter system were selected for the fed - batch culture to overproduce exoinulinase By the intermittent feeding of yeast extract and glucose, both promoter systems gave the cell concentration of about 30 g-dry cell weight/1 byt the maximal exoinulinase activity of 3.70 unit/ml and plasmid stability of 96% in the ADH1 promoter were higher than those (2.70 unit/ml, 80%) of PGK sys- tem Taking into account the plasmid stability and extended culture time the ADH1 promoter systems would be the most feasible expression systems for the constitutive overproduction of exoinulinase through high cell-density fed- batch cultures using non-selective rich medium.

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Implementation of Cell Voltage Monitoring System for Monitoring Multi-channel Battery (고속 다채널 배터리 모니터링을 위한 CVM 시스템의 구현)

  • Lee, Kyung-Ryang;Cho, Seung-Il;Yeon, In-Chol;Kim, Seong-Kweon
    • Journal of Satellite, Information and Communications
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    • v.8 no.3
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    • pp.15-19
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    • 2013
  • Lithium-ion batteries have been used for high density energy storage system due to the features such as low self-discharge rate. And the unit cell battery with the voltage less than 4V is recommended to use the series connections for a high voltage charger. When batteries are charged or discharged with series connection, there may be an explosion or degradation of unit cell battery owing to undistributed internal resistance of cell battery. therefore, the voltages of unit cell batteries should be monitored to prevent an overcharging and a deep discharging. This paper introduces the implementation of CVM (Cell Voltage Monitoring) system that can transmit the 12 channel's information including voltages and temperatures with the 12-bits resolutions and the transmission speed of 192 kbps.

An Effective Cell Scheduling Algorithm for Input Queueing ATM Switch (입력단 큐잉 방식의 ATM 스위치를 위한 효율적 셀 중재 방식에 관한 연구)

  • 김용웅;원상연;박영근
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.25 no.1A
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    • pp.122-131
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    • 2000
  • In this paper, we propose a cell scheduling algorithm for input queueing ATM switch. The input queueing architecture is attractive for building an ultra-high speed ATM (Asynchronous Transfer Mode) switch. We proposea WMUCS (Weighted Matrix Unit Cell Scheduler) based on the MUCS which resolves HOL blocking and outputport contention. The MUCS algorithm selects an optimal set of entries as winning cells from traffic matrix (weightmatrix). Our WMUCS differs from the MUCS in generating weight matrices. This change solves the starvationproblem and it reduces the cell loss variance. The performance of the proposed algorithm is evaluated by thesimulation program written in C++. The simulation results show that the maximum throughput, the average celldelay, and the cell loss rate are significantly improved. We can see that the performance of WMUCS is excellentand the cost-effective implementation of the ATM switch using proposed cell scheduling algorithm.

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