• 한국수소및신에너지학회논문집
• /
• 제28권6호
• /
• pp.663-668
• /
• 2017

SOFC anode fabricated core-shell using machano-fusion method using core with submicron size Ni, nano size YSZ for shell. Using prepared core-shell, depending on the thickness of the shell, we studied how the characteristics of sintering and SOFC cell change by sintering the anode. The Ni-YSZ core-shell has a Ni core of 0.5 to $1.2{\mu}m$ over 2 to 7 YSZ of 15 to 20 nm is, and as the high speed mixing time increases, the YSZ number increases and the shell thickness becomes uniform increased. When the fuel electrode is manufactured with core-shell, it has superior sintering property, has grain of uniform size compared with the one synthesized by general mixing, the falling path is short, the conductors (electrons and ions) connection is excellent, the electrical conductivity has become excellent. The thicker the shell, the lower the electrical conductivity. When the thickness of shell ranged from 46 to 139 nm and 61 to 81 nm, the performance was the highest and the ASR was the smallest.

• The Korean Journal of Ceramics
• /
• 제3권3호
• /
• pp.199-207
• /
• 1997

$Al_2O_3$/SiC particulate composites were fabircated by pressureless sintering. The dispersed phase was SiC of which the content was varied from 1.0 to 10 vol%. Three SiC powders having different median diameters from 0.28 $\mu\textrm{m}$ to 1.9 $\mu\textrm{m}$ were used. The microstructure became finer and more uniform as the SiC content increased except the 10 vol% specimens, which were sintered at a higher temperature. Under the same sintering condition, densification as well as grain growth was retarded more severly when the SiC content was higher or the SiC particle size was smaller. The highest flexural strength obtained at 5.0 vol% SiC regardless of the SiC particle size seemed to be owing to the finer and more uniform microstructures of the specimens. Annealing of the specimens at $1300^{\circ}C$ improved the strength in general and this annealing effect was good for the specimens containing as low as 1.0 vol% of SiC. Fracture toughness did not change appreciably with the SiC content but, for the composites containing 10 vol% SiC, a significantly higher toughness was obtained with the specimen containing 1.9$\mu\textrm{m}$ SiC particles.

• Bulletin of the Korean Chemical Society
• /
• 제29권5호
• /
• pp.1007-1012
• /
• 2008

Spray pyrolysis has been found as an excellent method for the preparation of mesoporous barium sulfate at higher temperature. Ethylene glycol, a reducing agent, and solvents had good inhibition effect for the preparation of $BaSO_4$ nano particles. The $BaSO_4$ solution was sprayed at 500 & 800 ${^{\circ}C}$ using different solvents such as methanol, ethanol, propanol and n-butyl alcohol. $N_2$ adsorption-desorption isotherm revealed that $BaSO_4$ is micropore free, possessing narrow mesopores size distribution and high BET surface areas of 72.52 $m^2\;g^{-1}$ at 800 ${^{\circ}C}$ using propanol as an additive. Scanning electron microscopy (SEM) indicates that the morphology of $BaSO_4$ nano material shows uniform shell like particles. Transmission electron microscopy (TEM) proved that the resulting BaSO4 nano particles were uniform in size and the average particle size was 4-8 nm. The surface functionality and ethylene glycol peaks were assessed by Fourier transform infrared resonance (FTIR) spectroscopy. Low intensity ethylene glycol specific absorption peak was observed in propanol which proved that propanol had good inhibition effect on the structural morphology of nano particles.

• 한국분말재료학회지
• /
• 제12권1호
• /
• pp.56-63
• /
• 2005

Ag powder was prepared from $AgNO_3$ by wet chemical reduction method using various reduction agent system involving $AgNO_3$, $AgNO_2$(AgCl) and Ag complex ion aqueous solution. The pure Ag powder could be prepared regardless of reaction system but the particle shape and distribution were affected very much according to the kind of reduction agents and reaction systems. The optimum reaction system for the preparation of the silver powder having the uniform particle shape and size distribution was Ag complex ion aqueous solution-reduction agent system and in particular, $H_2O_2$ and $C_6H_8O_6$as a reduction agent leaded the more uniform particle shape and size distribution.

• Journal of Biosystems Engineering
• /
• 제26권5호
• /
• pp.431-440
• /
• 2001

Generated agri-chemical droplets by orchard sprayers are evaporated regenerated and transported along wind streams. The droplets are deposited to targets after changing their sizes, affecting the retention of droplets. An orchard sprayer, designed for spraying grapevines was studied on the spatial distribution of droplet size. The experimental variables were spray direction (0, 22.5, 45, 67.5 and 90˚), distance(2.5, 3.0 and 3.5 m) and fan speed (2,075 and 3,031 rpm). Droplet sizes were converted and analyzed from spray stains, sampled using water sensitive papers. The number median diameter (NMD) increased with an increase of the distance due to disappeared fine droplets (<50 ㎛): however, the volume median diameter (VMD) decreased due to shrunken large droplets (>100 ㎛). Fast fan speed delivered large droplets to 3.5 m, but the spatial distributions of NMD and VMD were not uniform. Slower fan speed decreased the possibility of evaporation and drift; therefore, plenty of droplets were maintained up to 3.0 m. The upward blasting distance was limited within 3 m, but the limit to the ground level was extended to 3.5 m. Concentrated wind and droplets to the ground level should be redistributed to upper canopy direction, leading more uniform deposits. High speed wind and system pressure should be avoided because of generating fine droplets, which would be disappeared and drifted away.

• 한국전기전자재료학회논문지
• /
• 제37권1호
• /
• pp.26-35
• /
• 2024

Aluminum-induced crystallization (AIC) as a route to reduce the fabrication cost and to obtain polycrystalline Si (p-Si) thin-film of large grain size is a promising alternative of single-crystalline (s-Si) substrate or p-Si thin-film obtained by conventional methods such as solid phase crystallization (SPC) and laser-induced crystallization (LIC). As the AIC process occurs at the interface between a-Si and Al thin-films, there are various process and interface parameters. Also, it directly means that there is a certain parametric window to obtain p-Si of large grain size having uniform crystal orientation. In this article, we investigate the effect of the various process and interface parameters to obtain p-Si of large grain size and uniform crystal orientation from the literature review. We also suggest the potential use of the p-Si as a virtual substrate for the growth of various compound semiconductors in a form of low-dimension as well as thin-film as a way for their monolithic integration on Si.

• 한국의류학회지
• /
• 제40권4호
• /
• pp.669-684
• /
• 2016

This study investigates Korean fighter pilot's usage and satisfaction of a flight duty uniform (FDU). The survey was conducted from October 2014 to March 2015 using Focus Group Interview (FGI) and questionnaires. FGI collected qualitative data about duty and requirements; subsequently, surveys were performed to collect quantitative data about wearing conditions and satisfaction with FDU. The results of the FGI and the questionnaire were as follows. Type of pilot duty was divided into two parts, flight duty and ground duty. It is important to consider duties as well as factors related to survival when developing FDU. According to anthropometric data and wearing size, the basic size for apparel grading should be changed from actual size, 'M95XL' to 'M100L'. It is also necessary to improve the whole sizing system. Further studies about body form changes in pilot's movement are needed to improve mobility because the respondents perceived some restrictions at several body parts in movement with the coverall uniform. Summer FDU had a low satisfaction level in vent hole function and appearance. Furthermore, protection problems in the vent hole were also an issue. Making a seasonal classification of FDU fabric will be more effective than a vent hole to increase a pilot's thermal satisfaction. Respondents had a passive stance towards FDU reform (including pocket change); therefore, a new FDU design strategy should concentrate on improving current FDU functions like mobility (or comfort) rather than dramatic changes. Pilots complained about the quality stability of FDU; therefore, quality control by military administration as well as concrete and clear design instructions by the developer should be attained together. The results obtained in this study are expected to be used as an important basis for the further development of FDU.

• 한국입자에어로졸학회지
• /
• 제13권3호
• /
• pp.133-139
• /
• 2017

In this paper, we proposed an emulsification method without using an emulsifier and investigated the effects of particle size distribution in fluids on dispersion stability. Surfactant-free oil in water emulsion was prepared with 1 % (w/w) of olive oil by using high speed agitation, high pressure and ultrasonic dispersion methods. The particle size, microscopic observation, and dispersion stability of each sample were evaluated and dispersion stability according to various dispersion methods was compared. As a result, the emulsion dispersed by the ultrasonic dispersion method showed the smallest particle size and uniform distribution of $0.07{\sim} 0.3{\mu}m$ and was the most stable in a 7 days stability evaluation. In the above experiment, four olive oil emulsions having different particle sizes were prepared using ultrasonic dispersion technology that was capable of producing stable emulsions. The dispersion stability of each samples with oil droplet sizes of (A) 0.1 to $0.5{\mu}m$, (B) 0.3 to $4{\mu}m$, (C) 1 to $10.5{\mu}m$ and (D) 2 to $120{\mu}m$, was observed for 7 days, and the relationship between the stability and performance was studied. Emulsion (A) with particle size less than $0.5{\mu}m$ displayed the dispersion stability showing below 5 % change in a 7 days stability evaluation. In the case of (B), (C), and (D) that had larger particle than $0.5{\mu}m$, the changes of dispersion stability were 10 %, 13 % and 35 % respectively. From these results, it was proved that dispersion stability of emulsion with uniform particle size of $0.5{\mu}m$ or less was confirmed to be very stable.

• 한국멀티미디어학회논문지
• /
• 제15권4호
• /
• pp.439-448
• /
• 2012

TFT-LCD 패널을 저해상도로 획득한 영상은 불균일한 휘도 분포와 노이즈 신호, 그리고 결함 신호로 구성되어 있다. 불균일한 휘도 분포와 노이즈로 인해 결함 신호를 분할하기 어려우며 이를 위해 다양한 분할 방법이 개발되고 있다. 본 논문에서는 공간영역 상에서 Eikvil et al.'s에 의해 제안되어진 크기가 다른 두 개의 창을 두고 각 창의 평균을 계산하고 그 값의 차이를 이용하는 방법을 이용하여 TFT-LCD 패널 이미지 상에 존재하는 결함의 영역을 분할하는 방법을 제안한다. 하지만 이 방법은 창의 크기에 의해 검출 가능한 결함영역의 크기가 제한되어 큰 결함영역을 분할하기 위해서는 창을 키워야 하므로 효율적이지 못한 문제점을 가지고 있다. 이 문제를 해결하기위해 멀티스케일(Multi-scale)을 이용하고, 각 스케일에서 검출 가능한 결함 크기를 제한함으로써 다양한 크기의 결함 영역을 분할 할 수 있는 알고리즘을 제안한다. 알고리즘의 성능을 검증하기위해 다양한 크기의 결함 영역을 만들어 분할되어진 결과와 실제 결함이 존재하는 TFT-LCD 패널 이미지의 분할 결과들을 통해 실제 적용 가능한 알고리즘임을 보인다.

• 한국재료학회지
• /
• 제13권6호
• /
• pp.369-373
• /
• 2003

Magneto-optic Kerr Effect(MOKE), AFM and magnetoresistance measurements have been carried out on as-deposited and annealed Magnetic Tunnel Junctions(MTJs) with junction sizes 180, 250, 320 and 380 $\mu\textrm{m}$ in order to investigate the correlation among interlayer exchange coupling, surface roughness and junction size. Relatively irregular variations of coercivity $H_{c}$ (∼17.5 Oe) and interlayer exchange coupling $H_{E}$ (∼17.5 Oe) are observed over the junction in as-deposited sample prepared by DC magnetron sputtering. After annealing at $200^{\circ}C$, $H_{c}$ decreases to 15 Oe, while $H_{ E}$ increases to 20 Oe with smooth local variation. $H_{E}$ shows very good correlation with surface roughness across the junction in agreement with Neel's orange peel coupling. The increasing slope per $\mu\textrm{m}$ of normalized $H_{c}$ and $H_{E}$ are same near junction edge along free-layer direction irrespective of junction size, giving relatively uniform $H_{c}$ and $H_{ E}$ for wider junction size. Thickness profiles of the junctions measured with $\alpha$-step show increasingly flat top surface for larger junctions, indicating better uniformity for large. junctions in agreement with the normalized$ H_{c}$ and H$/_{E}$ curves. TMR ratios also increase with increasing junction size, indicating improvement for larger uniform junctions.