• Applied Chemistry for Engineering
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• v.30 no.3
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• pp.365-370
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• 2019

In this study, effects of the ultrasonic irradiation during the reaction process were investigated for the enantioselective kinetic resolution (EKR) reaction of racemic epoxides in the presence of chiral cobalt salen catalysts, as compared to that of using the conventional mechanical stirring. In order to compare catalytic activities, the chiral cobalt salen complexes having $AlCl_3-$, $BF_3-$ and nitrobenzenesulfonic acid (NBSA) were synthesized and used as catalysts, and then three kinds of the racemic epoxides such as ephichlorohydrine (ECH), epoxy phenoxypropane (EPP) and propylene oxide (PO) were used as reactants. In addition, EKR reactions have been performed using the water and methanol as nucleophiles, respectively. The unique contribution of ultrasonic irradiation as a powerful mixing medium was evaluated in this study to improve the kinetics in comparison to the conventional mechanical agitation during EKR reactions. The reaction time to obtain the highest 99 ee% became shorten more than that of above 60%, when the ultrasonic irradiation was used. This result may be interpreted by the cavitation effect of ultrasound in the solution, generating a powerful shear force for the very violent mixing.

• Journal of the Korean Society of Manufacturing Technology Engineers
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• v.26 no.1
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• pp.44-49
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• 2017

Titanium has been used in various fields due to its good corrosion and erosion resistance, and superior mechanical properties. The process for selective electro-deposition on a titanium surface using laser beam is proposed in this paper. The process consists of laser irradiation, electro-deposition, and ultrasonic cleaning. Laser irradiation can change the surface morphology of titanium. Through laser irradiation, the surface cleaning effect and a rough surface can be achieved. The surface roughness of titanium was measured according to the laser beam conditions. The characteristics of selective electro-deposition on titanium surface according to surface roughness are investigated by various analytical methods such as SEM, and EDS.

• Applied Chemistry for Engineering
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• v.22 no.2
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• pp.155-160
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• 2011

An animal fat is an attractive biodiesel energy source for its high stability against oxidation and low incomplete combustion ratio due to the high heating value and cetane value. However, it requires a refinery process because of the high content of saturated acid and impurity which increas the boiling point. In this study, the optimum biodiesel synthetic process of lard is suggested. Indeed, we demonstrate new biodiesel production processes to alter conventional process of heating and mixing by applying ultrasonic energy. While the optimum reaction temperature and mole ratio of methanol and lard, when using conventional mixing and heating process, were $55^{\circ}C$ and 12, respectively, the reaction time were reduced to 30 minutes by applying ultrasonic irradiation power of 500 W. The new process applying ultrasonic irradiation yielded synthetic biodiesel properties as followings: 3.34 cP of the viscosity, 37.0 MJ/kg of the caloric value and below 0.25 mgKOH/g of the acidic value, which satisfy biodiesel quality criteria.

• Macromolecular Research
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• v.15 no.1
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• pp.44-50
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• 2007

This study investigated the effect of ultrasound irradiation on the blend of poly(lactic acid) (PLA) and poly(butylene adipate-co-terephthalate) (PBAT). The blends of PLA/PBAT(50/50) (PBAT50) were prepared in a melt mixer with an ultrasonic device attached. Thermal, rheological, and mechanical properties, morphology, and biodegradability of the sonicated blends were analysed. The viscosity of the sonicated blends was increased by the ultrasound irradiation owing to the strong interaction. The morphology of the sonicated blends was significantly dependent on the duration o the ultrasound irradiation. For PBAT50, the phase size reduction was maximized when the blends were ultrasonically irradiated for 30 sec. At longer duration of ultrasound irradiation, the PBAT phase underwent flocculation. Measurement of the tensile properties showed an increased breakage tensile stress and an enhanced Young's modulus when the blends were properly irradiated. This improvement was ascribed to better adhesion between the PLA matrix and the PBAT domain and to better dispersion of the PBAT phase. However, the tensile properties were maximized after excessive energy irradiation, which was ascribed to an emulsifying effect leading to coalescence of the PBAT phase. Impact strength was increased to reach a peak with the ultrasound irradiation, and was higher than the untreated sample for all sonicated samples due to the difference of failure mechanism between the tensile test and the impact test.

• Proceedings of the KSME Conference
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• 2001.06d
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• pp.834-839
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• 2001

Calandria tube wrapping each pressure tube is one of the key structural components of CANDU reactor(Calandria) which is consisted of many pressure tubes containing nuclear fuel assemblies. As the Calandria tube(made of zirconium alloy) is sagging due to its thermal and irradiation creep during the plant operation, it possibly contacts with liquid injection nozzle crossing beneath the Calandria tube, which subsequently results in difficulties on the safe operation. It is therefore necessary to check the gap for the confirmation of no contacts between the two tubes, Calandria tube and liquid injection tube, with a proper measure during the life of plant. In this study, an ultrasonic measurement method was selected among several methods investigated. The ultrasonic device being developed for the measurement of the gap was introduced and its preliminary performance test results were presented here. The gap between LIN and CT at site was measured using by this ultrasonic device at site.

• Journal of Energy Engineering
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• v.18 no.3
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• pp.169-174
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• 2009

In the study, the effect of the ultrasonic energy in transportational diesel fuel on the engine performance and exhaust emission has been investigated for indirect injection diesel engine. It was tested to estimated change of engine performance and exhaust emission characteristics for the transportational diesel fuels and the reforming fuels which was irradiated by the ultrasonic energy. The results of the study may be concluded as follows; By the irradiation of ultrasonic energy on the diesel fuel, cylinder pressure, heat release rate and engine power were increased but bsfc, mass fraction burned, and smoke were reduced. Also, the combustion was more stabilized and became complete and NOx was increased.

• The Journal of the Acoustical Society of Korea
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• v.24 no.8
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• pp.431-440
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• 2005

The precise measurement of ultrasonic power is important to the qualify assurance and the safety of medical ultrasonic equipments In the Present work, a brier theory was introduced to determine the ultrasonic Power from the time valving balance-indication due to the radiation force acting on an absorbing target and/or other causes such as buoyancy during the repetition of on/off behavior of ultrasonic irradiation. The developed automated system measuring the ultrasonic power was described in detail with the precise mechanical alignment tool , the electric signal generation network, the control and measurement network and the appropriate procedure. The ultrasonic power measured by the developed system was compared to the reference data calibrated by the other national metrology institute at 1 MHz, 5 MHz, 10 MHz, and 15 MHz over the range 10 mW to 10 W. Their relative differences are within $5\%$.

• 전기의세계
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• v.25 no.6
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• pp.74-80
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• 1976

The temperature rise of the mortars while are being irradiated by ultrasonic waves and immersed in a liquid medium, are measured. The mixing ratios of sand to cement are varied for the different mortars. The results of the experiment are as follows, 1. The temperature rise of the mortar is decreased as themixing ration (S/C) is increased. 2. Thd temperature rise of the specimen is increased as its length is increased. 3. The surface conditions, either smooth or rough, may not have much influence on the temperature rise of the mortar. 4. The initial slope of temperature rise may not have much effect of the viscosity of liquid. The results, describes above, appear well coincide with the theory that the temperature rise is attributed mainly to the absorption heating. Since the absorption heating of the mortars varies with the mixing ratios of sand to cement, the strength of them would be estimated by means of irradiation of ultrasonic waves on the specimen.

• Journal of the Korean Society for Nondestructive Testing
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• v.26 no.3
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• pp.181-189
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• 2006

A 2D finite-element numerical simulation has been developed to investigate the generation of ultrasonic waves in a homogeneous isotropic elastic slab under a line-focused laser irradiation. Discussing the physical processes involved in the thermoelastic phenomena, we describe a model for the pulsed laser generation of ultrasound in a metal slab. Addressing an analytic method, on the basis of an integral transform technique, for obtaining the solutions of the elastodynamic equation, we outline a finite element method for a numerical simulation of an ultrasonic wave propagation. We present the numerical results for the displacements and the stresses generated by a line-focused laser pulse on the surface of a stainless steel slab.

• Proceedings of the Korean Society of Marine Engineers Conference
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• 2001.11a
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• pp.98-104
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• 2001

Recently, the researches on the prevention of marine oil pollution being strengthened. Sludge oils were unavoidably produced in ship's operations, therefore it is necessary to manage the sludge oils inside the ship itself with the view to prevent marine oil pollution from ship. The present study deals with the ultrasonic breaking systems that recycle the sludge oil from ships into usable oil to be burnt. At the first instanceexperimental studies were carried out to investigate the homogenizing effect of the marine oils and the erosion aspect of horn disc by repeated vibration of ultrasonic transducer. The erosion damages for horn disc SS41 steel with weight loss rate and the irradiation time to max. erosion rate were examined according to the variation of the transducer amplitude, the oil temperature and the immersing depth of horn disc. As the result of it, the erosion aspects of horn disk were varied with oil environments and testing time.