• Title/Summary/Keyword: Ultrafine particles

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Preparation of Ultrafine $SnO_2$ Powders by Spray-ICP Technique

  • Kim, Jung-Hwan;Kim, Young-Do;Shin, Kun-Chul;Park, Jong-Hyun
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1998.06a
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    • pp.65-70
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    • 1998
  • The Spray-ICP technique uses the ICP(Inductively Coupled Plasma) of ultra-high temperature which is produced by r.f power. The ICP is well-kwown as a clean heat source for the preparation of pure ceramic particles because the ICP is a electrodeless-thermal plasma without contamination. In this study,{{{{ { SnO}_{2 } }}}} particles were sythesized from metal salt solution by Spray-ICP technique. The effects of concentration of solution, collecting location of powders were investicated. The prepared {{{{ { SnO}_{2 } }}}} particles from each concentration of solution had same crystalline phase(tetragonal {{{{ { SnO}_{2 } }}}}) a nd the mean size decreased in proportion to the increase of solution concentration. Each {{{{ { SnO}_{2 } }}}} p owders collector in reactor and electrostatic collector had same crystalline phase and morphologies. The mean size of {{{{ { SnO}_{2 } }}}} p articles prepared by Spray-ICP technique was below 30nm.

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Charge/Discharge Characteristics of Lithium ion Secondary Battery Using Ag-deposited Graphite as Anode Active Material (은 담지한 흑연을 부극 활물질로 이용한 Lithium ion 2차전지의 충방전 특성)

  • 김상필;조정수;박정후;윤문수
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.11 no.9
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    • pp.727-732
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    • 1998
  • Ag-deposited graphite powder was prepared by a chemical reduction method of metal particles onto graphite powder. X-ray diffraction observation of Ag-deposited graphite powder revealed that silver existed in a metallic state, but not in an oxidized one. From SEM measurement, ultrafine silver particles were highly dispersed on the surface of graphite particles. Cylindrical lithium ion secondary battery was manufactured using Ag-deposited graphite anodes and $LiCoO_2$ cathodes. The cycleability of lithium ion secondary battery using Ag-deposited graphite anodes was superior to that of original graphite powder. The improved cycleability may be due to both the reduction of electric resistance between electrodes and the highly durable Ag-graphite anode.

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Experimental Study on the Size Distribution of Diesel Particulate Matter (DPM) (디젤 입자상물질의 크기분포 특성에 관한 실험적 연구)

  • 연익준;권순박;이규원
    • Journal of environmental and Sanitary engineering
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    • v.17 no.2
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    • pp.11-17
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    • 2002
  • Diesel particulate matter (DPM) is known to be one of the major harmful emissions produced by diesel engines. The majority of diesel particles are in the range of smaller than $I{\mu}\textrm{m}$. Because of their tiny volume, ultrafine diesel particles contribute very little to the total mass concentration which is currently regulated for automobile emissions. Diesel particles are known to have deleterious effects upon human health because they penetrate human respiratory tract and have negative effects on the health. The measurement of the number distribution of nanometer size particles (nanoparticles) in the diesel exhaust emission is important in order to evaluate their environmental and health impact, and to develop new types of diesel particulate filters. In this study, we directly sampled particulate matters emitted from a diesel truck mounted on the chassis dynamometer by a flow separator and dilution system, and measured the nanoparticles using two types of differential mobility analyzers combined with a Faraday cup electrometer (FCE) and a condensation particle counter (CPC). The particle size distributions were analyzed by changing engine operation condition, i.e. ratio of engine loading. The total number concentration of particles were increased with the engine loading ratio and the nanoparticles (less than 50nm) were affected by hydrocarbon (HC) concentration in the diesel exhaust.

Influence of Particles on the Electrical Properties of Electrospun PVDF Fiberwebs (전기방사된 PVDF 섬유웹의 전기적 특성에 있어 입자의 영향)

  • Lee, Young-Soo;Joo, Chang-Whan
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10b
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    • pp.271-272
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    • 2003
  • Electrospinning is a novel process for forming fibers with submicron scale diameters through the action of electrical force. In the previous study, we performed study on the ultrafine PVDF nanofiber production in the stable spinning condition. Recently it would be great interest to fabricate IP(inorganic particle) assemblies in nanofibe. since such IP/nanofiber hybrid materials might be used in a nonwoven form as nanowires, medical gauges for bums healing and cell growing, sensors, chemical and gas filteration. (omitted)

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Magnetic Properties of the Ultrafine Co Particle Systems

  • Perov, N.;Sudarikova, N.;Bagrets, A.
    • Journal of Magnetics
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    • v.8 no.1
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    • pp.7-12
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    • 2003
  • The method for evaluation of the particle size distribution of fine particles from hysteresis loop measurements is Presented. The method is illustrated on the SiO$_2$-based Co nanoparticle systems. The influence of technological conditions of sample preparation onto particle size distribution is investigated.

Sensing Characteristics of $SnO_2$ Gas Sensor Using Ultrafine Particles (TEX>$\Pi$) (가스 감지소자의 감지특성 ($\Pi$))

  • 최순돈;이상기;김규호
    • Electrical & Electronic Materials
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    • v.3 no.4
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    • pp.295-305
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    • 1990
  • 여러가스에 대한 저항변화를 측정하기 위해 초미립 분말을 사용하여 pellet형 SnO$_{2}$ 가스센서를 제조하였다. 초미립 분말은 화학기상반응법으로 만들어졌으며 평균입경은 0.08.mu.m이었다. 냉간 성형된 소자는 사용전 공기중에서 700~850.deg.C에서 10~60분간 소성되었다. 측정된 결과는 분말의 소결성 및 열린 기공도로 설명될 수 있었다.

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On-line Measurement of the Surface Area Concentration of Aerosols in Yokohama, Japan, using the Diffusion Charging Method

  • Hatoya, Kazuki;Okuda, Tomoaki;Funato, Koji;Inoue, Kozo
    • Asian Journal of Atmospheric Environment
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    • v.10 no.1
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    • pp.1-12
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    • 2016
  • Numerous researchers have proposed that surface area is a more appropriate indicator than mass for evaluating pulmonary inflammatory responses caused by exposure to fine and ultrafine particles. In this study, measurements of surface area concentrations of aerosols were conducted in Yokohama, Japan, using the diffusion charging method. $PM_{2.5}$ mass concentration and black carbon concentration in $PM_{2.5}$ were also measured. The 24-hour continuous measurement campaigns were conducted 39 times from March to November, 2014. The surface area concentration was more closely correlated with the black carbon concentration than with the $PM_{2.5}$ mass concentration. It is considered that the abundance of black carbon particles significantly affects the surface area concentration of $PM_{2.5}$. The strength of the correlation between the surface area and black carbon concentrations varied considerably among the measurement campaigns. A relatively weaker afternoon correlation was observed compared with the other time zones (morning, evening, and night). We consider that these phenomena are due to the transportation/formation of the particles other than black carbon that affects surface area concentration and/or the variation of the surface condition of the black carbon particles.

Formation and Hygroscopic Growth Properties of Ultrafine Particles in College Station, Texas, in 2003 (2003년 미국 텍사스 칼리지스테이션에서 관측된 초미세입자의 형성과 흡습 성장 특성)

  • Lee, Yong-Seob;Collins, Don R.
    • Journal of Environmental Science International
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    • v.16 no.7
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    • pp.793-798
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    • 2007
  • During May of 2003, smoke from fires in the Yucatan Peninsula was transported across the Gulf of Mexico and into Texas where it caused significant enhancement in measured aerosol concentrations and reduced visibility. During this event, the formation and growth of aerosol particles has been observed by a differential mobility analyzer (DMA) / tandem differential mobility analyzer (TDMA) system to characterize the size distribution and size-resolved hygroscopicity of the aerosol. The most number concentration is by the particles smaller than 100 nm, but the integrated number concentrations for over 100 nm increased due to the aerosol growth. Hygroscopic growth factor increase from 1.2 to 1.4 for 25, 50, and 100 nm particles during the nucleating period. This distribution and the aerosol properties derived from the TDMA data were used to calculate the growth rate. Particle growth rates were in the range 1-12 nm/hr.

Role of Different Oxide to Fuel Ratios in Solution Combustion Synthesis of SnO2 Nanoparticles

  • Chavan, Archana U.;Kim, Ji-Hye;Im, Ha-Ni;Song, Sun-Ju
    • Journal of the Korean Ceramic Society
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    • v.53 no.1
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    • pp.122-127
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    • 2016
  • Tin oxide ($SnO_2$) nanoparticles have been synthesized by solution combustion method using citric acid as a fuel. The oxide to fuel ratio has been varied to obtain ultrafine nanoparticles with better surface area; such particles will be useful in many applications. With this synthesis method, spherical particles are formed having a particle size in the range of 11-30 nm and BET surface area of ~ $24m^2/g$. The degree of agglomeration of $SnO_2$ nanoparticles has been calculated.

Characteristics of Formation and Growth of Aerosol Particles in an Indoor Smog Chamber (스모그 챔버 실험에 의한 에어로졸의 생성과 성장 현상의 관찰)

  • 김민철;배귀남;이승복;진현철;문길주;박주연;김용표
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2003.05b
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    • pp.43-44
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    • 2003
  • 스모그 챔버는 대기화학 반응을 물리적 변수를 제어할 수 있는 공간 내에서 재현하여 스모그 현상을 체계적으로 규명하기 위해 가장 많이 사용되는 방법이다(Dodge, 2000). 대기화학 반응을 통해 생성된 입자상 물질(secondary particles) 또는 초미세 입자(ultrafine particle, 〈0.1 $\mu\textrm{m}$)는 연속된 물리화학 반응을 통해 accumulation mode(0.1~l.0 $\mu\textrm{m}$) 입자로 성장한다. 특히, 대도시의 시정(visibility)은 accumulation mode 입자의 산란(scattering)과 흡수(adsorption)가 주요한 원인이기 때문에 이러한 물질의 생성에 영향을 주는 가스상 물질의 전화(gas-to-particle conversion) 반응과 초미세 입자의 성장 현상을 규명하는 것은 매우 중요하다. (중략)

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