• Title/Summary/Keyword: Ultra-high

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Thermal and Mechanical Properties of ZrB2-SiC Ceramics Fabricated by Hot Pressing with Change in Ratio of Submicron to Nano Size of SiC (서브마이크론/나노 크기의 SiC 비율변화에 따른 ZrB2-SiC 세라믹스의 열적, 기계적 특성)

  • Kim, Seongwon;Chae, Jung-Min;Lee, Sung-Min;Oh, Yoon-Suk;Kim, Hyung-Tae
    • Journal of the Korean Ceramic Society
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    • v.50 no.6
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    • pp.410-415
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    • 2013
  • $ZrB_2$-SiC ceramics are fabricated via hot pressing with different ratios of submicron or nano-sized SiC in a $ZrB_2$-20 vol%SiC system, in order to examine the effect of the SiC size ratio on the microstructures and physical properties, such as thermal conductivity, hardness, and flexural strength, of $ZrB_2$-SiC ceramics. Five different $ZrB_2$-SiC ceramics ($ZrB_2$-20 vol%[(1-x)SiC + xnanoSiC] where x = 0.0, 0.2, 0.5, 0.8, 1.0) are prepared in this study. The mean SiC particle sizes in the sintered bodies are highly dependent on the ratio of nano-sized SiC. The thermal conductivities of the $ZrB_2$-SiC ceramics increase with the ratio of nano-sized SiC, which is consistent with the percolation behavior. In addition, the $ZrB_2$-SiC ceramics with smaller mean SiC particle sizes exhibit enhanced mechanical properties, such as hardness and flexural strength, which can be explained using the Hall-Petch relation.

Chemical Vapor Deposition of Tantalum Carbide from TaCl5-C3H6-Ar-H2 System

  • Kim, Daejong;Jeong, Sang Min;Yoon, Soon Gil;Woo, Chang Hyun;Kim, Joung Il;Lee, Hyun-Geun;Park, Ji Yeon;Kim, Weon-Ju
    • Journal of the Korean Ceramic Society
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    • v.53 no.6
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    • pp.597-603
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    • 2016
  • Tantalum carbide, which is one of the ultra-high temperature ceramics, was deposited on graphite by low pressure chemical vapor deposition from a $TaCl_5-C_3H_6-Ar-H_2$ mixture. To maintain a constant $TaCl_5/C_3H_6$ ratio during the deposition process, $TaCl_5$ powders were continuously fed into the sublimation chamber using a screw-driven feeder. Sublimation behavior of $TaCl_5$ powder was measured by thermogravimetric analysis. TaC coatings have various phases such as $Ta+{\alpha}-Ta_2C$, ${\alpha}-Ta_2C+TaC_{1-x}$, and $TaC_{1-x}$ depending on the powder feeding methods, the $C_3H_6/TaCl_5$ ratio, and the deposition temperatures. Near-stoichiometric TaC was obtained by optimizing the deposition parameters. Phase compositions were analyzed by XRD, XPS, and Raman analysis.

The Degradation Analysis of Characteristic Parameters by NBTI stress in p-MOS Transistor for High Speed (고속용 p-MOS 트랜지스터에서 NBTI 스트레스에 의한 특성 인자의 열화 분석)

  • Lee, Yong-Jae;Lee, Jong-Hyung;Han, Dae-Hyun
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.35 no.1A
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    • pp.80-86
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    • 2010
  • This work has been measured and analyzed the device degradation of NBTI (Negative Bias Temperature Instability) stress induced the increase of gate-induced-drain-leakage(GIDL) current for p-MOS transistors of gate channel length 0.13 [${\mu}m$]. From the relation between the variation of threshold voltage and subthreshold slop by NBTI stress, it has been found that the dominant mechanism for device degradation is the interface state generation. From the GIDL measurement results, we confined that the EHP generation in interface state due to NBTI stress led to the increase of GIDL current. As a results, one should take care of the increased GIDL current after NBTI stress in the ultra-thin gate oxide device. Also, the simultaneous consideration of reliability characteristics and dc device performance is highly necessary in the stress parameters of nanoscale CMOS communication circuit design.

Bond Strength and Corrosion Resistance of Coated Reinforcing Bar Using Hybrid-Type Polymer Cement Slurry (Hybrid형 폴리머 시멘트 슬러리로 도장한 철근의 부착강도와 부식저항성)

  • Jo, Young-Kug
    • Journal of the Korea Institute of Building Construction
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    • v.8 no.3
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    • pp.93-99
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    • 2008
  • The purpose of this study is to evaluate the bond strength and corrosion resistance of coated reinforcing bar using hybrid-type polymer cement slurry(PCS). PCS coated steels, which is made from two types of polymer dispersions such as St/BA and EVA are prepared, and tested for bond strength and various corrosion resistances such as autoclaved cure, carbonation and H2SO4 solution. From the test results, the bond strength of PCS coated reinforcing bar using ordinary portland cement at 1-5, 2-1 and 4-5 of mixes is higher than that of uncoated regular steel. However, bond strength of almost PCS coated reinforcing bars using ultra rapid high strength cement is higher than that of epoxy coated bar, is also in ranges of 102% to 123% compared to that of uncoated regular steel. In autoclaved accelerating test, the ratio of corrosion of uncoated regular steel is increased with the increase in NaCl content, but the corrosion of PCS coated steel was very small. In the acceleration test for carbonation, increasing the amount of NaCl the corrosion of coated steel did not produce. The corrosion of uncoated regular steel is increased with the increase in the amount of NaCl. It can be seen that the NaCl following the acceleration test for carbonation can lower the corrosion resistance of concrete. As a result, the corrosion of steel largely is affected by the acceleration curing, chloride ion penetration and carbonation and shown more severe corrosion by applying complex factors. These corrosions of steel can be suppressed by the coating of PCS.

Structural Performance of a New Truss Deckplate System with UHPC Infilled Top Chords in Construction Stage (UHPC 충전형 상현재를 활용한 트러스 데크플레이트 시스템 시공단계 구조성능 평가)

  • Son, Hong-Jun;Kim, Young-Ho;Kim, Dae-Jin
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.33 no.2
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    • pp.137-144
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    • 2020
  • In this study, we propose a new truss deckplate system, which does not require temporary floor supports during construction, with ultra-high-performance concrete (UHPC) infilled top bars. The increased stiffness and strength of the proposed system were well retained as compared to those of the existing truss deckplate systems, thereby resulting in the reduction of maximum deflection at the span center. Four-point bending tests were performed on five specimens with a net span of 4.6 m to evaluate the structural performance of proposed system in the construction stage. In addition, the load-deflection curve was plotted for each specimen, and the effects of test parameters were analyzed. Further, a rigorous nonlinear three-dimensional finite element analysis was performed, and its results were compared with the test results. From the results, it was observed that the test specimens of the proposed system exhibited superior performance as compared to those of the existing one and also satisfied the serviceability requirement during construction provided by the Korea Building Code 2016.

Test and simulation of circular steel tube confined concrete (STCC) columns made of plain UHPC

  • Le, Phong T.;Le, An H.;Binglin, Lai
    • Structural Engineering and Mechanics
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    • v.75 no.6
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    • pp.643-657
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    • 2020
  • This study presents experimental and numerical investigations on circular steel tube confined ultra high performance concrete (UHPC) columns under axial compression. The plain UHPC without fibers was designed to achieve a compressive strength ranged between 150 MPa and 200 MPa. Test results revealed that loading on only the UHPC core can generate a significant confinement effect for the UHPC core, thus leading to an increase in both strength and ductility of columns, and restricting the inherent brittleness of unconfined UHPC. All tested columns failed by shear plane failure of the UHPC core, this causes a softening stage in the axial load versus axial strain curves. In addition, an increase in the steel tube thickness or the confinement index was found to increase the strength and ductility enhancement and to reduce the magnitude of the loss of load capacity. Besides, steel tube with higher yield strength can improve the post-peak behavior. Based on the test results, the load contribution of the steel tube and the concrete core to the total load was examined. It was found that no significant confinement effect can be developed before the peak load, while the ductility of post-peak stage is mainly affected by the degree of the confinement effect. A finite element model (FEM) was also constructed in ABAQUS software to validate the test results. The effect of bond strength between the steel tube and the UHPC core was also investigated through the change of friction coefficient in FEM. Furthermore, the mechanism of circular steel tube confined UHPC columns was examined using the established FEM. Based on the results of FEM, the confining pressures along the height of each modeled column were shown. Furthermore, the interaction between the steel tube and the UHPC core was displayed through the slip length and shear stresses between two surfaces of two materials.

Formation of Ultra fine Particle by the Polonium-218 Ions under Different Humidity Conditions (다른 습도조건하에서 Po-218 이온들의 극소입자형성에 관한 연구)

  • Yoon, Suk-Chul;Ha, Chung-Woo
    • Journal of Radiation Protection and Research
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    • v.17 no.1
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    • pp.1-10
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    • 1992
  • A number of investigators have reported the formation of the radiolytic ultrafine particles produced by the interaction of ionizing radiation with water vapor. Previous studies have suggested that a very high localized concentration of the OH radical produced by the radiolysis of water can react with trace gas like organic vapors and produce lower vapor pressure compounds that can then nucleate. In order to determine water vapor dependence of the active, positively charged, first radon daughter(Po-218), an experiment was conducted using a well-controlled radon chamber. The activity size distribution of the radon daughter in the range of 0.5-100nm was measured using the parallel graded wire screens system. Measurements were taken for different relative humidity. The resultant activity size distributions were analyzed. The addition of water vapor to the radon carrier gases resulted in the formation of ultrafine particles by OH radicals formed by radon radiolysis. It may be due to the neutralization of charged Po-218 ion with water vapor through the radio lysis.

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Ultra-High Frequency Characteristics of Double-Wall Carbon Nanotube Resonator with Different Length (서로 다른 길이를 갖는 이중벽 탄소 나노튜브 공진기의 초고주파 주파수 특성)

  • Kim, Jin-Tae;Lee, Jun-Ha;Lee, Kang-Ho;Choi, Jong-Ho
    • Journal of the Korea Society of Computer and Information
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    • v.15 no.12
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    • pp.175-180
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    • 2010
  • In this paper, we have investigated ultrahigh frequency nano-mechanical resonators, made of DWCNTs with various wall lengths, via classical molecular dynamics simulations. We have aimed our analysis on the frequency variations of these resonators with the DWCNT wall lengths. The results show that the variations can be well fitted by either the Pearson VII function when the resonant frequency of normalized by its maximum frequency is plotted as a function of the inner/outer wall length ratio L5/L10 for different values of the outer wall length L10, and the Gauss distribution function when the resonant frequency of normalized by its maximum frequency is plotted as a function of the outer/inner wall length ratio for different values of the inner wall length.

Air-tightness Evaluation of Tube Structures for Super-speed Tube Railway Systems: I. Analytical Modeling and Material Test (초고속 튜브철도 시스템을 위한 튜브 구조물의 기밀성 평가 : I. 해석모델 수립 및 재료 기밀성)

  • Park, Joo-Nam;Nam, Seong-Won;Kim, Lee-Hyeon;Yeo, In-Ho
    • Journal of the Korean Society for Railway
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    • v.14 no.2
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    • pp.143-150
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    • 2011
  • This paper presents a preliminary study for air-tightness evaluation of vacuum tube structures for super-speed tube railway systems. The formula for flow rate of the air caused by the pressure difference of the inside and outside of the tube structure is derived based on Darcy's law. A test is then performed to measure the air-permeability of concrete with various compressive strengths, the result of which is used for analytical simulation of the air intrusion for a tube structure with a preliminarily defined section. It has been shown that concrete with the compressive strength of at least more than 50MPa is recommended for effective operation and maintenance of the vacuum pump systems, as the air-permeability of concrete is inversely proportional to the exponent of its compressive strength.

Preparation of Pore-filled Ion-exchange Membranes using Poly(vinylbenzyl ammoninum salt) (Poly(vinylbenzyl ammonium salt)를 이용한 Pore-filled 이온교환막의 제조)

  • 변홍식
    • Membrane Journal
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    • v.11 no.3
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    • pp.109-115
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    • 2001
  • Pore-filled ion-exchange membranes in which polypropylene(PP) microporous membrane was used as a nascent membrane were prepared by an in-situ cross-linking technique. Poly(vinylbenzyl chloride)(PVBCI) reacted with piperazine(PIP) or 1,4-diaminobicyclo[2,2,2]octane(DABCO) in a di-methylforamide(DMF) solution was filled in the pores of the microporous base membrane. After gellation the remaining chloromethyl groups were, then reacted with an amine such as trimethylamine to form positively charged, ammonium site. This will produce the pore-filled anion-exchange membrane. It was shown that this simple 2 step procedure gave dimensionally stable, pore-filled membranes in which the MG of polymer gel and degree of cross-linking could be easily controlled by the concentration of PVBCI and cross-linker in the starting DMF solution. Specially, high water permeability (7.8 kg/$m^2$hr, host membrane: PP3, MG: 73%, degree of cross-linking: 10%, crosslinker: PIP) at ultra low pressure(100 kPa) indicates the produced pore-filled membranes is usable as a water softening membrane.

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