• Title/Summary/Keyword: Ultra-fine

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Crystallographic and Mossbauer Studies of Magnetic Garnet $Y_{3-x}Bi_xFe_5O_{12}$ by a Sol-Gel Method (Sol-gel 합성에 의한 자성 garnet $Y_{3-x}Bi_xFe_5O_{12}$의 결정학적 및 Mossbauer 분광학 연구)

  • 엄영란;김철성;이재광
    • Journal of the Korean Magnetics Society
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    • v.8 no.4
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    • pp.203-209
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    • 1998
  • Crystallographic and magnetic properties of single phase garnet $Y_{3-x}Bi_xFe_5O_{12}$ (x=0.0, 0.25, 0.5, 0.75, 1.0) were studied by using x-ray diffraction, Mossbauer spectroscopy and vibrating sample magnetometer (VSM). Ultra-fine polycrystalline cubic samples have been prepared by sol-gel method. The lattice constant increase linearly with increasing an amount of Bi. Annealing temperature was larger than 800 $^{\circ}C$ for the growth of a single-phase garnet powder. The second phase of garnet, $(BiFeO_3)$, was at 1000 $^{\circ}C$ for x=0.75, and 950 $^{\circ}C$ for x=1.00. From Mossbauer spectroscopy and VSM measurements, the magnetization and the coercivity were decreased and the Curie temperature $Y_{3-x}Bi_xFe_5O_{12}$(x=0.0, 0.25, 0.5, 0.75, 1.0) was slightly increased as increasing the Bi content.

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Formation of Ultra fine Particle by the Polonium-218 Ions under Different Humidity Conditions (다른 습도조건하에서 Po-218 이온들의 극소입자형성에 관한 연구)

  • Yoon, Suk-Chul;Ha, Chung-Woo
    • Journal of Radiation Protection and Research
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    • v.17 no.1
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    • pp.1-10
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    • 1992
  • A number of investigators have reported the formation of the radiolytic ultrafine particles produced by the interaction of ionizing radiation with water vapor. Previous studies have suggested that a very high localized concentration of the OH radical produced by the radiolysis of water can react with trace gas like organic vapors and produce lower vapor pressure compounds that can then nucleate. In order to determine water vapor dependence of the active, positively charged, first radon daughter(Po-218), an experiment was conducted using a well-controlled radon chamber. The activity size distribution of the radon daughter in the range of 0.5-100nm was measured using the parallel graded wire screens system. Measurements were taken for different relative humidity. The resultant activity size distributions were analyzed. The addition of water vapor to the radon carrier gases resulted in the formation of ultrafine particles by OH radicals formed by radon radiolysis. It may be due to the neutralization of charged Po-218 ion with water vapor through the radio lysis.

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Effect of Cobalt Oxide on Carbothermal Reduction of Spray Dried Titanium-Cobalt-Oxygen Based Oxide Powder (분무건조법에 의해 제조된 Ti-Co-O계 산화물 분말의 환원/침탄반응에 미치는 코발트 산화물의 영향)

  • Lee, Gil-Geun;Kim, Chan-Young
    • Journal of Powder Materials
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    • v.12 no.5 s.52
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    • pp.336-344
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    • 2005
  • In the present study, the focus is on the effect of cobalt oxide powder in the carbothermal reduction of the titanium-cobalt-oxygen based oxide powder by solid carbon for the optimizing synthesis process of ultra fine TiC/Co composite powder. The titanium-cobalt-oxygen based oxide powder was prepared by the combination of the spray drying and desalting processes using the titanium dioxide powder and cobalt nitrate as the raw materials. The titanium-cobalt-oxygen based oxide powder was mixed with carbon black, and then this mixture was carbothermally reduced under flowing argon atmosphere. Changes in the phase structure and thermal gravity of the mixture during carbothermal reduction were analysed using XRD and TGA. Titanium-cobalt-oxygen based oxide powder desalted at $600^{\circ}C$ had a mixture of $TiO_2\;and\;Co_{3}O_4$. And the one desalted at $800^{\circ}C$ had a mixture of $TiO_2\;and\;CoTiO_3$. In the case of the former powder, the reduction of cobalt oxide powder in the titanium-cobalt-oxygen based oxide powder occurred at lower temperature than the latter one. However, the carbothermal reduction of titanium dioxide powder in the titanium-cobalt-oxygen based oxide powder with a mixture of $TiO_2\;and\;Co_{3}O_4$ occurred at higher temperature than the one with a mixture of $TiO_2\;and\;CoTiO_3$. And also, the former powder showed a lower TiC formation ability than the latter one.

Quantitative Study on the Refinement Behaviors of TiC Powders Produced by Mechanical Milling Under Different Impact Energy (밀링 에너지 변화에 따른 TiC 분말의 미세화 거동에 관한 정량적 연구)

  • Hong, Sung-Mo;Park, Eun-Kwang;Kim, Kyeong-Yeol;Park, Jin-Ju;Lee, Min-Ku;Rhee, Chang-Kyu;Lee, Jin-Kyu;Kwon, Young-Soon
    • Journal of Powder Materials
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    • v.19 no.1
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    • pp.32-39
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    • 2012
  • This study investigated refinement behaviors of TiC powders produced under different impact energy conditions using a mechanical milling process. The initial coarse TiC powders with an average diameter of 9.3 ${\mu}m$ were milled for 5, 20, 60 and 120 mins through the conventional low energy mechanical milling (LEMM, 22G) and specially designed high energy mechanical milling (HEMM, 65G). TiC powders with angular shape became spherical one and their sizes decreased as the milling time increased, irrespective of milling energy. Based upon the FE-SEM and BET results of milled powders, it was found initial coarse TiC powders readily became much finer near 100 nm within 60 min under HEMM, while their sizes were over 200 nm under LEMM, despite the long milling time of up to 120 min. Particularly, ultra-fine TiC powders with an average diameter of 77 nm were fabricated within 60 min in the presence of toluene under HEMM.

Evaluation of Self-Compaction Property of Section Enlargement Strengthening Concrete (단면확대 보강 적용을 위한 콘크리트의 자기충전 성능 평가)

  • Hwang, Yong-Ha;Yang, Keun-Hyeok;Song, Keum-Il;Song, Jin-Kyu
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.3
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    • pp.235-242
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    • 2019
  • The objective of this study is to modify the mixture proportions of concrete that were developed for section enlargement strengthening elements using a specially designed binder composed of 5% ultra-rapid hardening cement, 10% polymer, and 85% ordinary portland cement in order to assign the self-compaction property to such concrete. The self-compaction abilities of concrete were estimated by the performance criteria specified in JSCE and EFNARC provions. Test results showed that the increase in the unit binder content at the consistent water-to-bider ratio led to increase in viscosity of fresh concrete but did not exhibit the decrease in the fluidity due to a greater viscosity. The mixture proportioning of self-compaction section enlargement concrete could be considered at the following conditions: unit binder contents of $430kg/m^3{\sim}470kg/m^3$ and fine aggregate-to-total aggregate ratios of 40%~46% at the water-to-binder ratio of 38%.

Synthesis and M$\ddot{o}$ssabuer Spectroscopy Studies of $Nd_{1-x}Bi_xY_2Fe_5O_{12}$ Nano-Particles

  • Uhm, Young Rang;Lee, Jae-Gwang;Kim, Chul Sung
    • Journal of Magnetics
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    • v.5 no.1
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    • pp.16-18
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    • 2000
  • The garnets $Nd_{1-x}Bi_xY_2Fe_5O_{12}$ ($\chi$=0.0, 0.25, 0.5, 0.75 and 1.0) have been studied by x-rays, electron microscopy, ferromagnetic resonance, vibrating sample magnetometer and Mossbauer spectroscopy, Ultra-fine polycrystalline cubic samples have been prepared by a melt-salt routed sol-gel method. The Mossbauer spectra consist of two sets of six-line patterns corresponding to $Fe^{3+}$ at the tetrahedral 24(d) and octahedral 16(a) sites. Magnetic hyperfine fields of $Nd_{0.5}Bi_{0.5}Y_2Fe_5O_{12}$ at 12 K are found to be 548 kOe (octahedral site) and 475 kOe (tetrahedral site), respectively, It is found that Debye temperatures for the tetrahedral and octahedral sites of $Nd_{0.75}Bi_{0.25}Y_2Fe_5O_{12}$ are $\theta_{tet}=436$ K and $\theta_{oct}=285$ K, respectively, The iron ions at both sites are highly covalent ferric. The Nel temperature decreases linearly with Bi concentration, from 630 K fur $\chi$=0.0 to 600 K for $\chi$=1.0, suggesting that the superexchange interaction for the Nd-O-Fe link is stronger than that for the Bi-O-Fe link. As a consequence, the coercivity of $Nd_{1-x}Bi_xY_2Fe_5O_{12}$ drastically decreases and the magnetization remains almost constant as x increases.

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A pin type current probe using Planar Hall Resistance magnetic sensor (PHR 자기센서를 적용한 탐침형 전류 프로브)

  • Lee, Dae-Sung;Lee, Nam-Young;Hong, Sung-Min;Kim, CheolGi
    • Journal of Sensor Science and Technology
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    • v.30 no.5
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    • pp.342-348
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    • 2021
  • For the characterization or failure analysis of electronic devices such as PCB (printed circuit boards), the most common method is the measurement of voltage waveforms with an oscilloscope. However, because there are many types of problems that cannot be detected by voltage waveform analysis, several other methods such as X-ray transmission, infrared imaging, or eddy current measurement have been applied for these analyses. However, these methods have also been limited to general analyses because they are partially useful in detecting physical defects, such as disconnections or short circuits. Fundamentally current waveform measurements during the operation of electronic devices need to be performed, however, commercially available current sensors have not yet been developed, particularly for applications in highly integrated PCB products with sub-millimeter fine pitch. In this study, we developed a highly sensitive PHR (planar hall resistance) magnetic sensor for application in highly integrated PCBs. The developed magnetic sensor exhibited sufficient features of an ultra-small size of less than 340 ㎛, magnetic field resolution of 10 nT, and current resolution of 1 mA, which can be applicable for PCB analyses. In this work, we introduce the development process of the magnetic sensing probe and its characteristic results in detail, and aim to extend this pin-type current probe to applications such as current distribution imaging of PCBs.

Contingent Valuation Survey on Changes in Citizens' Perception on Atmospheric Pollution in Seoul, Korea (조건부 가치 설문조사를 통한 대기 오염에 대한 서울 시민의 인식 변화 조사)

  • Hong, Je-Woo;Hong, Jinkyu;Kim, Junghwan
    • Atmosphere
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    • v.29 no.2
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    • pp.213-218
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    • 2019
  • A valuation of air pollution is critical for relevant policy-making for the public and research direction. This study conducted a willingness-to-pay (WTP) survey using contingent valuation method (CVM) in Seoul Korea. In detail, this study puts an emphasis on its temporal changes referred on two surveys conducted in 2014 and 2019. In reference to the previous studies in 2002, our survey indicated that the public awareness of air pollution and interests on its sources and solutions increased noticeably. Our survey showed that WTP increased significantly from 2588 to 4827 and 8240 Korean Won $month^{-1}$ in 2002, 2014, and 2019, respectively. Moreover, the percentage of respondents to pay the WTP also increased from 48% to 68% and 79% in 2002, 2014, and 2019, respectively. Our analysis based on the number of Google search on particulate matters (PMs) strongly suggests that such the noticeable increases of the public attention to air pollution is well accorded with the moment of the announcement of a standard for ultra-fine particles and the start of PM prediction in late 2013. But the Google search rate grew about 16.7 times in 2009 compared to 2014, which is much larger than the growth rate of interest and WTP between 2014 and 2019. Our results shed light on policy decision for the right person in the right place on the right time in the era of air pollution.

Strength Development Mechanism of Inorganic Injection Material (무기질계 주입재의 강도발현 메커니즘)

  • Han, yunsu;Lee, Jonghwi;Kang, Hyoungnam;Baeg, Seungin;Chun, Byungsik
    • Journal of the Korean GEO-environmental Society
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    • v.12 no.10
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    • pp.5-12
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    • 2011
  • Recently, NDS(Natural and Durable Stabilizer)method and other similar methods are composed of inorganic accelerating agent and the ultra-super fine cement have been studied as the ground improvement material in Korea. However, in the existing research, the chemical changing process of NDS in the strength development mechanism with the elapsed curing time and the principles of strength development did not give an explanation. For the popularization of the inorganic grout material, it determined that the mechanism verifying of the curing process had to be clearly preceded. Therefore, unconfined compression test, SEM and XRD analysis were performed by the elapsed curing time and were analyzed. In addition, the same trial for SGR method, that is the representative example of the water glass grout material, was selected as comparative target in order to distinguish properties of NDS more clearly. The result of experiment, the strength development mechanism of NDS could be investigated through the close correlation of the unconfined compression strength - SEM - XRD analysis, and excellence of a performance was confirmed.

Proposal to Supplement the Missing Values of Air Pollution Levels in Meteorological Dataset (기상 데이터에서 대기 오염도 요소의 결측치 보완 기법 제안)

  • Jo, Dong-Chol;Hahn, Hee-Il
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.21 no.1
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    • pp.181-187
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    • 2021
  • Recently, various air pollution factors have been measured and analyzed to reduce damages caused by it. In this process, many missing values occur due to various causes. To compensate for this, basically a vast amount of training data is required. This paper proposes a statistical techniques that effectively compensates for missing values generated in the process of measuring ozone, carbon dioxide, and ultra-fine dust using a small amount of learning data. The proposed algorithm first extracts a group of meteorological data that is expected to have positive effects on the correction of missing values through statistical information analysis such as the correlation between meteorological data and air pollution level factors, p-value, etc. It is a technique that efficiently and effectively compensates for missing values by analyzing them. In order to confirm the performance of the proposed algorithm, we analyze its characteristics through various experiments and compare the performance of the well-known representative algorithms with ours.