• Title/Summary/Keyword: UV-spectrum

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A Study of frequency tunable Ti:sapphire laser for UV lidar (UV 라이다용 주파수 가변 Ti:sapphire 레이저에 관한 연구)

  • Yi, Yong-Woo
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2002.11a
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    • pp.656-661
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    • 2002
  • Multipass Ti:sapphire amplifier for the light source of lidar was developed in an angular-multiplexing, and the characteristics of output energy and spectrum was investigated. In the two-stage multipass amplifier, we obtained the maximum output energy of 42 mJ, the amplification gain of 21 dB and the output efficiency of 26% on the wavelength of 790 nm. In the tuning range of 715~930nm the spectral linewidth is 0.05 $cm^{-1}$ /. The conversion efficiencies of 35% for SHG at 780 m and 13% for THG at 390 nm are obtained respectively. The continuous tunabilities of 240~306 m UV region and 360~460 nm in deep-blue region could be achieved.

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Effects of transition metal-doping on the properties of ZnO nanoparticles and the photocatalytic degradation of methylene blue (전이금속 도핑이 ZnO 나노분말의 특성 및 메틸렌블루 광촉매 분해 특성에 미치는 영향)

  • Chang, Han Kwon;Oh, Kyung Jun;Jang, Hee Dong;Cho, Kuk;Kim, Dong-Jin;Choi, Jin Hoon
    • Particle and aerosol research
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    • v.6 no.1
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    • pp.29-35
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    • 2010
  • Transition metals such as V, Fe, and Ni were used to synthesize doped zinc oxide nanoparticles from mixed liquid precursors by using the flame spray pyrolysis (FSP). The effects of dopants on the powder properties such as morphology, specific surface area, crystal structure, and light adsorption were analyzed by TEM, BET, XRD, and UV-Vis diffuse reflection spectrum (DRS), respectively. The results showed that hexagonal wurtzite structured ZnO:M (M = V, Fe, Ni) nanoparticles were successfully synthesized by the FSP. The transition metal-doping resulted in the decrease in its particle size and crystallite size. The UV-vis absorption spectra of ZnO:M nanoparticles were also red-shifted. ZnO:V showed the highest MB degradation of 99.4% under the UV irradiation after 3 hrs.

Dyeability and Functionality of Wool Fabrics Dyed with Chamaecyparis obtusa Leaf Extract (편백나무 잎 추출물로 염색한 모직물의 염색성 및 기능성)

  • Ko, Eunsook;Lee, Hyesun;Han, Chunghun
    • Journal of the Korean Society of Clothing and Textiles
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    • v.43 no.2
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    • pp.288-296
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    • 2019
  • This study examined the proper dyeing conditions, color fastness and functionality for wool fabrics dyed with Chamaecyparis obtusa leaf extract. FT-IR and UV-Vis spectrum analysis showed that tannin and flavonoids were contained in the extracted colorant. The dyeing of wool fabrics using Chamaecyparis obtusa leaf was good without pretreatment or mordant treatment. Optimal dyeing conditions for wool fabrics were a colorant concentration of 70%(v/v), dyeing temperature of $100^{\circ}C$, dyeing time of 100 minutes and dyebath pH of 5.8. Color fastness of dyed wool fabrics to washing, rubbing, perspiration was good, whereas light was grade 3. The UV protection rate and deodorization rate of wool fabrics dyed with Chamaecyparis obtusa leaf improved. Reduction rate of Staphylococcus aureus/Klebsiella pneumoniae were excellent at 99.9%. Therefore, it was confirmed that Chamaecyparis obtusa leaf can be used as environ-mentally friendly natural dye.

Toxicity and Characteristics of Antifungal Substances Produced by Bacillus amyloliquefaciens IUB158-03 (Bacillus amyloliquefaciens IUB158-03이 생산하는 항진균물질의 생화학적 특성 및 독성)

  • Kim, Hye-Young;Lee, Tae-Soo
    • Journal of Life Science
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    • v.19 no.11
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    • pp.1672-1678
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    • 2009
  • The purified antifungal substances produced by Bacillus amyloliquefaciens IUB158-03 was positive to ninhydrin but negative to aniline, suggesting that the antifungal substance could be a peptide. FAB-MS, UV adsorption spectrum, and amino acid composition analysis revealed that the molecular weight of the antifungal substance was 1042 and that maximal adsorption was at 220 nm and 277 nm. The antifungal substance was composed of $Asn_3$, $Gln_2$, $Ser_1$, $Gly_1$, and $Tyr_1$. The composition and structural characteristics of antifungal substance were analysed by $^1H$-NMR spectrum, $^1H$-COSY, HMQC, which revealed that the compound belongs to the iturin A family. Temperature and pH had little effect on the stability of the antifungal substance in the ranges of $-70{\sim}121^{\circ}C$ and pH 6.0~10.0, respectively. It showed strong antibiotic activity against fungi. An in vitro cytotoxicity test using NIH3T3 cell showed that the antifungal substance does not have cytotoxicity. The number of circulating leukocytes and the hematobiological analysis of the mice administered with the antifungal substances was similar to those of the control group, indicating no cytotoxicity in vivo. Therefore, the antifungal substances extracted from culture broth of Bacillus amyloliquefaciens IUB158-03 have future potential as biocontrol agents against plant diseases caused by fungi.

Hazards Caused by UV Rays of Xenon Light Based High Performance Solar Simulators

  • Dibowski, Gerd;Esser, Kai
    • Safety and Health at Work
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    • v.8 no.3
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    • pp.237-245
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    • 2017
  • Background: Solar furnaces are used worldwide to conduct experiments to demonstrate the feasibility of solar-chemical processes with the aid of concentrated sunlight, or to qualify high temperature-resistant components. In recent years, high-flux solar simulators (HFSSs) based on short-arc xenon lamps are more frequently used. The emitted spectrum is very similar to natural sunlight but with dangerous portions of ultraviolet light as well. Due to special benefits of solar simulators the increase of construction activity for HFSS can be observed worldwide. Hence, it is quite important to protect employees against serious injuries caused by ultraviolet radiation (UVR) in a range of 100 nm to 400 nm. Methods: The UV measurements were made at the German Aerospace Center (DLR), Cologne and Paul-Scherrer-Institute (PSI), Switzerland, during normal operations of the HFSS, with a high-precision UV-A/B radiometer using different experiment setups at different power levels. Thus, the measurement results represent UV emissions which are typical when operating a HFSS. Therefore, the biological effects on people exposed to UVR was investigated systematically to identify the existing hazard potential. Results: It should be noted that the permissible workplace exposure limits for UV emissions significantly exceeded after a few seconds. One critical value was strongly exceeded by a factor of 770. Conclusion: The prevention of emissions must first and foremost be carried out by structural measures. Furthermore, unambiguous protocols have to be defined and compliance must be monitored. For short-term activities in the hazard area, measures for the protection of eyes and skin must be taken.

Optical Properties of Diamond Like Carbon Films Deposited by Plasma Enhanced CVD (rf PECVD법으로 증착된 DLC film의 광학적 성질)

  • Kim, Moon-Hyup;Song, Jae-Jin;Kim, Seong-Jin
    • Korean Journal of Materials Research
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    • v.11 no.7
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    • pp.550-555
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    • 2001
  • A diamond-like carbon(DLC) films were deposited on the borosilicate glass substrate by radio frequency plasma enhanced chemical deposition(rf-PECVD). The $methane(CH_4)-hydrogen(H_2)$ gas mixture was used as precursor gas. The morphologies, the structure and the optical properties of the DLC films were investigated by SEM, Raman and UV spectrometer. The deposition rate was slightly increased with the hydrogen concentration in the gas mixture and it maintained constant at over 25 sccm of the gas flow rate. The optical band gap calculated by UV spectra decreased with increase of deposition time and DC self bias, but that were not effected by hydrogen content. Most effective parameter on the transmittance of film was bias voltage, especially in the range of ultra violet and visible light.

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The identification of amethyst origins by using FT-IR, UV-VIS spectrum analysis (ET-IR, UV-VIS 분광분석을 통한 자수정의 산지감별)

  • Yoon Si-Nae;Yon Seog-Joo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.16 no.1
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    • pp.25-31
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    • 2006
  • Many amethysts of different origins such as South America, Aftrica, and Asia were compared. According to ICP-AES analysis, the colorizing elements were Fe, Cr, Cu, and Co. Amethysts from South America showed higher concentrations of the elements. UV- VIS analysis showed that both natural and synthetic amethysts were characterized by the higher absorption at 350 nm and 550 nm wavelength. The natural amethysts had lower permeability than that of the synthetic amethysts. According to FT-IR analysis, the synthetic amethysts were distinguished from the natural amethysts in that they had a typical absorption band of $3543cm^{-1}$. The amethyst from South America showed strong absorption bands of $3584cm^{-1}\;and\;3435cm^{-1}$, and African amethyst had absorption bands of $3299cm^{-1}\;and\;3196cm^{-1}$. $3381cm^{-1}$ absorption band was shown strongly for Asian origins.

Isolation, Physico-chemical Properties and Biological Activity of Aurodox Group Antibiotics

  • Kim, Si-Kwan;Yeo, Woon-Hyung;Kim, Sang-Seock
    • Journal of Microbiology and Biotechnology
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    • v.6 no.4
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    • pp.265-269
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    • 1996
  • An isolate of Streptomyces rochei synonym was found to produce antibiotics with narrow anti-microbial spectrum against Streptococcus and Xanthomonas sp. Among the antibiotic complex produced by the strain, the main active compound was isolated, and its physico-chemical properties and biological activities were investigated. Molecular weight of the compound was determined to be ${[M+H]}^+$ 797 (FAB-MS). UV, $^1H \;and\;^{13}C$ NMR, and IR spectra suggested that the compound is a kirromycin-like aurodox group antibiotic. However, the anti-microbial spectrum of the main compound was slightly different from that of kirromycin. In addition, it was newly found that kirromycin showed a selective anti-microbial activity against Streptococcus pyogenes and phytopathogenic Xanthomonas sp.

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Bacillus sp. YJ-63이 생산하는 항곰팡이성 항생물질의 단리

  • Sin, Yeong-Jun;Jeong, Myeong-Ju;Jeong, Yeong-Gi
    • 한국생물공학회:학술대회논문집
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    • 2000.04a
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    • pp.509-511
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    • 2000
  • An antifungal antibiotic was produced from Bacillus sp. YJ-63, and antibiotic was purified to a homogeneity by butanol extraction, Silica-gel column chromatography, Sephadex LH-20 gel filtration column chromatography and HPLC. The purified antibiotic showed one spot on Thin Layer Chromatography, which was negative to ninhydrin and positive to iodine. This finding indicated that the antibiotic was a cyclopeptide structure. UV absorption spectrum of the antibiotic in methanol was maximal at 277 nm, which corresponded to the spectrum for all of the Iturin antibiotic. The antibiotic was stable up to $121^{cdot}C$ and in the range of pH $3.O{\sim}l2.0$ with a stable of ${\alpha}-amino$ acid and ${beta}-amino$ acid, and showed high activity for fungi and yeasts,

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Characterization and Structural Dtercination of an Antifungal Compound Produced by Pseudomonas aeruginosa KGM-100 (Pseudomonas aeruginosa KGM-100이 생산하는 항생물질의 특성 및 구조)

  • Kim, Kyung-Seok;Hong, Su-Hyung;Lee, Eun-Ju;Park, Yong-Bok;Park, Yong-Tae;Ha, Ji-Hong
    • Microbiology and Biotechnology Letters
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    • v.23 no.1
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    • pp.98-103
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    • 1995
  • During the screening of antifungal antibiotics from microbial metabolites, we selected Pseudomonas aeruginosa KGM-100 showing powerful antagonistic activity against various phytopathogenic fungi. Antibiotics KGM-100A and KGM-100B were purified from the culture broth of Pseudomonas aeruginosa KGM-100 by diaion HP-20 column chromatography, ethyl acetate extraction, silica gel column chromatography, preparative TLC and recrystallization. KGM-100A which was recrystallized in MeOH showed antimicrobial activities against a broad spectrum of fungi and bacteria. Physico-chemical properties of KGM-100A were determined and identified to be phenazine-l-carboxylic acid by UV, IR, $^{1}$H-NMR, $^{13}$C-NMR, mass spectrum, and elemental analyses.

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