• Title/Summary/Keyword: UV-Visible

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Spectrophotometric Determination of Cadmium and Copper with Ammonium Pyrrolodinedithiocarbamate in Nonionic Tween 80 Micellar Media

  • Lee, Seung Gwon;Choe, Hui Seon
    • Bulletin of the Korean Chemical Society
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    • v.22 no.5
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    • pp.463-466
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    • 2001
  • The determination of Cd2+ and Cu2+ with ammonium pyrrolidinedithiocarbamate (APDC) in Tween 80 micellar media has been studied. The UV-visible spectrum of Cd(PDC)2 complex in Tween 80 media had more sensitivity tha n in chloroform. Although the UV-visible spectrum of the Cu(PDC)2 complex in Tween 80 media had somewhat less sensitivity than that in chloroform, absorbance data of Cu2+ were more reproducible in Tween 80 media. The Cd(PDC)2 and Cu(PDC)2 complexes were very stable at pH 7.0 for up to 100 minutes and could be quantitatively chelated if APDC were added to the sample solution more than 30 times the moles of Cd2+ and Cu2+ . The optimum concentration of Tween 80 was 0.1%. The calibration curves of Cd(PDC)2 and Cu(PDC)2 complexes with good linearity were obtained in 0.1% Tween 80 media. The detection limits of Cd2+ and Cu2+ were 0.0493 ㎍mL-1 and 0.0393 ㎍mL-1 , respectively. Recovery yields of Cd2+ and Cu2+ ions in the spiked real samples were almost 100%. Based on experimental results, this proposed method could be applied to the rapid and simple determination of Cd2+ and Cu2+ in real samples.

Measurements of Transmittances and Calculations of Fundamental Radiative Properties (투과율의 측정 및 이를 이용한 복사물성치의 계산)

  • Hwang, Yong-Ha;Park, Seung-Ho;Lee, Young-Soo
    • Solar Energy
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    • v.14 no.2
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    • pp.29-37
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    • 1994
  • Radiative charaacteristics of glass windows and porous absorbing media which can be used for a solar air heater are determined through the measurements of spectral transmittances. Those in the visible range are measured by the UV-IR spectrometer. Refractive index of glass are obtained by the comparison of the measured transmittances and the correlations derived from the electromagnetic theory and are compared to the theoretical ones calculated from the classical dispersion theory. Absorption and back-scattering coefficients of 15-mesh stainless wire screens are calcuated by the comparison of the measured transmittances and the correlations derived from the two flux model.

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Properties of Photoisomerization of Organic-Ultrathin Films (아조벤젠기를 갖는 장쇄지방산LB막의 광이성화 특성)

  • Kim, Moo-Goon;Park, Tae-Gone;Park, Keun-Ho
    • Proceedings of the KIEE Conference
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    • 1995.07c
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    • pp.1184-1186
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    • 1995
  • The absorption spectra of synthesis of azobenzene containing long chain fatty acids were investigated by UV spectrophotometer in chloroform solution. Also, the pressure-area isotherms of the molecules on the water-air interface were obtained and the LB films were fabricated onto a quartz slides and quartz crystals by the conventional Langmuir-Blodggett(LB) method. The UV absorption spectra of Langmuir-Blodggett(LB) films on quartz slides have been measured. From these measurements, following conclusions were obtained. Azobenzene containing long chain fatty acids show a photoisomerization by irradiation of UV light and visible light alternatively. At the pressure-area isotherms, the value of surface pressure increment were decreased when the number of $C_n$ increased. Also the LB films show a photoisomerization characteristics. So the LB film of azobenzene containing long chain fatty acid has possibility to being applied to functional molecular device such as photomemory and light switching.

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Study of Homeotropic Liquid Crystal Characteristics Using Photo-polymer and Homeotropic Polyimide Blended Alignment Layer via UV Irradiation Method (UV 광배향법을 통한 광폴리머와 수직 폴리이미드 혼합 배향막의 수직 배향 특성 연구)

  • Lee, Jin-Woo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.25 no.12
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    • pp.996-999
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    • 2012
  • From UV irradiation, we achieved homeotropic liquid crystal alignment on blended photo-polymer layer which is composed of polyvinyl-cinnamate (PVCi) and homeotropic polyimide (PI). From vertical alignment (VA) mode, we measured threshold voltages by various PVCi doping concentration. Also, the rise time and fall time of VA cells were measured to verify the best doping concentration. Transmittance curves showed about 70% value between 380 nm and 780 nm wavelength which mean visible region.

A Study on the Characteristics of Fabrics Dyed with Astringent Unripe Persimmon juice (시협처리시의 특성에 관한 연구I)

  • 이혜선
    • Journal of the Korean Society of Costume
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    • v.28
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    • pp.205-212
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    • 1996
  • This paper is to study the characteristics of fabrics dyed with astringent unripe persimmon juice. The cotton silk rayon and nylon fabrics were dyed with astringet unripe persimmon juice. The structures of natural fabrics dyed fabrics and dyed fabrics followed by washing were examined by scanning electron mi-croscopy. Surface reflexibility of VIS trans-mittance of UV VIS and NIR were analyzed. The study conclues as follows: 1. Colour of cotton fabrics dyed with persim-mon juice became darkended as a function of exposing time to sunlight. That colour was chaged after washing. 2. Blocking effect of ultraciolet light and visible ray was increased in all dyed fabrics. Especially dyed cotton fabric blocked UV light perfectly and the blocking effect was still remained after 9 washings. 3. Persimmon juice dyeing produced coating effect to fabrics besides dyeing effect accord-ing to the scanning electron micrographs. In a word the cotton fabric dyed with per-simmon juice has blocking effect of UV light stiffness. Therefore I think persimmon juice dyeing is a very useful textile finishing and ex-pect a wide application of the technique in fu-ture.

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UV VISIBILITY OF MODERATE-REDSHIFT GIANT ELLIPTICAL GALAXIES

  • Rhee, Myung-Hyun;Lee, Young-Wook;Byun, Yong-Ik;Sohn, Young-Jong
    • Journal of Astronomy and Space Sciences
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    • v.15 no.1
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    • pp.49-52
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    • 1998
  • We show quantitatively whether giant elliptical galaxies would be visible at for UV wavelenghts if they were placed at moderate red shift of 0.4-0.5. On the basis of simple cosmological tests, we conclude that giant elliptical galaxies can be detectable up to the red shift of 0.4-0.5 in the proposed GALEX(Galaxy Evolution Explorer) Deep Imaging Survey. We also show that obtaining UV color index such as $m_{1550}$ - V from upcoming GALEX and SDSS (Sloan Digital Sky Survey) observations should be feasible.

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UV/IR flame detector using Microprocessor (마이크로프로세서를 사용한 UV/IR 불곶 감지기)

  • 박성진;임병현;임종연;김명원;윤길호
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.215-218
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    • 2001
  • A flame detector responds either to radiant energy visible to the human eye or outside the range of human vision. Such a detector is sensitive to glowing embers, coals, or flames which radiate energy of sufficient intensity and spectral quality to actuate the alarm. An infra-red detectors can respond to the total IR component of the flame alone or in combination with flame flicker in the frequency range of 5 to 30 Hz. A major problem in the use of infrared detectors receiving total IR radiation is the possible interference of solar radiation in the infrared region. When detectors are located in places shielded from the sun, such as vaults. filtering or shielding the unit from the sun's rays is unnecessary. In this study, we proposed method for redue a false alarm with using filtering & sensor technology for distinguish of causes of raise a false alarm and pure flame.

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The Characteristics of Photo-alignment with Photo-crosslinkable Polyimide (광 가교성 폴리이미드의 광배향 특성)

  • Shin, Dong-Muyng;Cho, Sun-Ju;Shon, Byoung-Choung;Choi, Jeong-Woo;Yi, Mi-Hie;Choi, Kil-Yeoung
    • Journal of the Korean Applied Science and Technology
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    • v.16 no.1
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    • pp.15-20
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    • 1999
  • Photo-crosslinkable polyimide(PI) which contains CF3 moiety was synthesized. Polarized UV light transformed ketone group of PI to hydroxyl group, which was confirmed by IR and UV-visible spectroscopy. We investigated the dichroic UV-absorption before and after photo-reaction with linearly polarized light. In particular we have attempted to clarify the relationship between the anisotropy of surface region and surface azimuthal anchoring energy and knew that the anchoring energy of photo-alignment PI is comparable with that of mechanical rubbing.

A study on the color analysis of the pigment by UV-Visible spectroscopy (분광분석기를 이용한 안료의 색상분석에 관한 연구)

  • Jung, Choong-Ho;Kang, Tae-Hee
    • Journal of the Korean Applied Science and Technology
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    • v.27 no.4
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    • pp.515-521
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    • 2010
  • In this research, we were prepared the glazed ceramic samples by the change of the pigment content and investigated to reveal the standardized color. The chemical composition of the pigment was analyzed using a ICP-OES. XRF mapping and UV-Vis spectroscopy were used to evaluate the color property and surface homogeneity. The color development was observed as a result of analyzing the pigment content and change of the color. The pigment content and the spectral reflection showed the relation of the inverse proportion and the standardized color which could be revealed through analysis data.

Iodine doping effect of $\sigma$ -conjugate poly(methyl-phenylsilene). ($\sigma$-공액 고분자 poly(methyl-phenylsilyene)의 요오드 도핑효과 연구)

  • ;;S. Nespurek
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.11a
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    • pp.145-148
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    • 2000
  • In contrast to the $\pi$ -conjugated polymers which typically absorb light only in the visible spectral region, the $\sigma$-conjugated polymers can be used as efficient material absorbing light in the UV region. In this work, the electronic and optical properties of I$_2$-doped $\sigma$ -conjugated poly (methyl-phenylsilylene) (PMPSi) polymer were investigated. DC conductivity up to 1.2$\times$10$^{-4}$ S/cm was obtained by I$_2$-doping. In UV/Vis absorbance spectrum, a new peak was observed near 370 nm, which was explained by polaron model. The photoluminescence (PL) intensity decreased with increasing degree of I$_2$-doping, and the Infrared (IR) spectrum analysis revealed that the dopants are not directly coupled to the polymer, but effect motions of the methyl and phenyl groups.

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