• 한국응용과학기술학회지
• /
• 제11권2호
• /
• pp.147-150
• /
• 1994

Ultra thin films of HDSM-CuPc(Tetra-3-hexadecylsulphamoylcopperphthalocya-nine) were formed on various substrates by Langmuir-Blodgett method, where HDSM-CuPc was synthesized by attaching long-chain alkylamine(hexa-decylamine) to CuPc. The reaction product was identified with FT- IR, UV-visible absorption spectroscopies, elemental analysis and thin layer chromatography. The formation of ultrathin films of HDSM-CuPc was confirmed by FT-IR and UV-visible spectroscpies.

• 한국진공학회:학술대회논문집
• /
• 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
• /
• pp.424.2-424.2
• /
• 2014

Ag-modified BiOX (X=Cl, Br and I) nanoplates were synthesized by an ion-exchange reaction. We examined the fundamental properties by scanning electron microscopy (SEM), electron transmission microscopy (TEM), X-ray diffraction, UV-visible absorption, Fourier-transform infrared and photoluminescence spectroscopy. The adsorption and photocatalytic performances of the catalysts were tested with dyes under UV and visible light. A chemical scavenger method was employed to test the roles of active species (${\cdot}OH$, ${\cdot}O2-$ and h+) and understand photodegradation mechanism. Photoluminescence spectroscopy was used to examine ${\cdot}OH$ radical formation using terephthalic acid during photoirradiation.

• 한국염색가공학회지
• /
• 제11권4호
• /
• pp.39-49
• /
• 1999

In order to study the properties of cochineal colors, uv-visible spectra of cochineal colors solution, dyeing properties on the wool in several dyeing conditions and thermodynamic parameters were investigated. UV-visible spectra of cochineal colors solution showed hypochromic effect with the lapse of irradiation time but bathochromic shift with decreasing acidity of solution and addition of metallic ions. The concentration of cochineal colors in wool fiber increased with the increase of dyeing temperature, time, and acidity of initial dyebath. The value of apparent diffusion coefficients and standard affinities of dyeing decreased with the increase of dyeing temperature. The standard heats of dyeing$(\Delta{H}^\circ)$ and variation of entropy$(\Delta{S}^\circ)$ increased with the increase of concentration of initial dyebath. The activation energy$(E_a)$ were calculated to be 1.399~2.595kcal/mol in condition of 6~1%(o.w.f) dyebath. Wool fabrics were dyed reddish blue by iron sulfate, copper sulfate, aluminum acetate and tannic acid, and red by tin chloride, respectively. Lightfastness of wool fabrics dyed by cochineal colors were increased by mordant treatment, especially copper sulfate and iron sulfate treatment.

• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 1996년도 추계학술대회 논문집
• /
• pp.195-198
• /
• 1996

In conducting systems based on LB films, TCNQ derivatives have been extensively studied as electron acceptor molecules. We have investigated the optical, electrical, and magnetic properties of Viologen-(TCNQ￣)$_2$LB films. In UV/visible absorption measurements, we have observed TCNQ￣ peak at 380 nm and dimer peak at 620 nm. The electron spin resonance measurements infer that Viologen-(TCNQ￣)$_2$LB film exhibits anisotropic properly. In other words, the LB film shows angular dependence. Iodine doping affects the degree of charge transfer and the conductivity of the films. The UV/visible absorption spectra of the LB film doped with I$_2$show peaks at near 400~430 nm and there is no dimer absorption peak. The in-plane electrical conductivity of the undoped film is approximately 4.2$\times$10$^{-6}$ S/cm.

• Environmental Engineering Research
• /
• 제11권6호
• /
• pp.318-324
• /
• 2006

The higher valence state of iron i.e., Fe(VI) was employed for the oxidation of one of an important toxic ion, cyanide in the aqueous medium. Cyanide was oxidized into cyanate, which is 1,000 times less toxic to cyanide and often accepted for its ultimate disposal. It was to be noted that Fe(VI) is a very powerful oxidizing agent and can oxidize most of the cyanide within few minutes i.e., ca 5 mins of contact. The data was obtained by the UV-Visible measurements for the Fe(VI) decomposition. The UV-Visible data was used to evaluate the overall rate constant for second order redox reaction between ferrate(VI) and cyanide. Also the pseudo first order rate constant was calculated as keeping the cyanide concentration in excess.

• 대한화학회지
• /
• 제53권5호
• /
• pp.560-564
• /
• 2009

용액침전법에 의해 ZnO 및 $Zn_{0.95}Mn_{0.05}O$를 제조하였다. Mn이 5% 치환된 ZnO 시료는 순수한 ZnO의 띠 간격인 3.37 eV (380 nm 흡광)로부터 1.50 eV (800 nm 흡광)까지 띠 간격이 줄어들게 되어 자외선 영역 뿐 아니라 가시광선 전체 영역에서도 흡광이 발생하였다. 가시광선에서의 광촉매 활성에서도 $Zn_{0.95}Mn_{0.05}O$ 시료는 P-25보다도 더 높은 활성도를 나타냈다.

• 한국조명전기설비학회지:조명전기설비
• /
• 제11권1호
• /
• pp.99-105
• /
• 1997

본 논문에서는 주상변압기 절연유의 가속열화반응을 수행하였다. 유중가스를 air bubbling 법으로 추출하여 가스크로마토크라프로 성분을 분석하였으며 가스농도는 각 가스의 추출율을 감안하여 보정하였다. 절연재료의 열화는 열분해반응과산화반응에의하여 진행되었으며 두 종류의 반응은 모두 0차반응의 특성을 보였고 탄화수소류, CO+{{{{ { CO}_{2 } }}}} 및 수소가스의 생성속도식을 얻었다. 유중가스 분석과 UV-Visible 분광광도법에 의하여 변압기내의 철심과 동코일이 열화과정에서 촉매역활을 함을 확인하였다.

• 한국조명전기설비학회지:조명전기설비
• /
• 제11권1호
• /
• pp.24-33
• /
• 1997

본 논문에서는 주상변압기 절연유의 가속열화반응을 수행하였다. 유중가스를 air bubbling법으로 추출하여 가스크로마토그라프로 성분을 분석하였으며 가스농도는 각 가스의 추출율을 감안하여 보정하였다. 절연재료의 열화는 열분해반응과 산화반응에 의하여 진행되었으며 두종류의 반응은 모두 0차반응의 특성을 보였고 탄화수소류, $CO+CO_2$ 및 수소가스의 생성속도식을 얻었다. 유중가스 분석과 UV-Visible 분광광도법에 의하여 변압기내의 철심과 동코일이 열화과정에서 촉매역활을 함에 확인하였다.

• 한국조명전기설비학회:학술대회논문집
• /
• 한국조명전기설비학회 1998년도 학술발표회논문집
• /
• pp.138-141
• /
• 1998

To evaluate the color change of the opaque resin materials, a measuring system including PAS(photodegradation acceleration system) was constructed. Xenon lamp is used as a light source in the PAS, and the radiant energy from the lamp is irradiated to the samples through serveral high-pass filters with cut-off wavelength in UV and visible region. The color difference of the samples were measured by using the measuring system with a spectrophotometer(CM-2002) and a computer. The result showed that the opaque resin materials changed severely in their color in the wavelength of UV region and changed a little in the wavelength of visible region.

• 한국결정학회지
• /
• 제1권2호
• /
• pp.61-65
• /
• 1990

수열육성법 (Hydrothermal growth technique)으로 연수정을 육성하고 원료, 용제, 발색제, 종자결정 및 irradiation등의 요소가 육성된 결정에 미치는 영향에 대하여 고찰하였다. UV-visible spectrum분석에 의해 육성된 결정과 천연 연수정의 광학적 특성 을 비교하였다. 본 연구결과로 결함이 적고 연색 (연색)이 선명한 길이 120mm. 폭 35mm, 두께 14m (135g)의 연수정 육성에 성공하였다.