• Title/Summary/Keyword: UV-Visible

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Hydrothermal Growth and Characteristics of ZnO Nanorods on R-plane Sapphire Substrates

  • Kim, Min-Su;Kim, So-A-Ram;Nam, Gi-Ung;Park, Hyeong-Gil;Yun, Hyeon-Sik;Im, Jae-Yeong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2012.05a
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    • pp.236-237
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    • 2012
  • ZnO nanorods were grown on R-plane sapphire substrates with the seed layers annealed at different temperature. The effects of annealing temperature for the seed layers on the properties of the ZnO nanorods were investigated by scanning electron microscopy, X-ray diffraction, UV-visible spectroscopy, and photoluminescence. For the as-prepared seed layers, the ZnO nanorods and the ZnO nanosheets were observed. Only the ZnO nanorods were grown as the annealing temperature was above $700^{\circ}C$. The optical transmittance in the UV region was almost zero while that in the visible region was gradually increased as the annealing temperature increased to $700^{\circ}C$. The optical band gap of the ZnO nanorods was increased as the annealing temperature increased to $700^{\circ}C$. In the visible region, the refractive index was decreased with increasing the wavelength, and the extinction coefficient was decreased as the annealing temperature increased to $700^{\circ}C$. The non-linear exciton radiative life time of the FX emission peak was established by cubic equation. The values of Varshni's empirical equation fitting parameters were ${\alpha}=4{\times}10^{-3}eV/K$, ${\beta}=1{\times}10^4K$, and $E_g(0)=3.335eV$ and the activation energy was found to be about 94.6 meV.

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Preparation of Visible-light Responsive TiO2:Zr, N Photocatalysts by Polymer Complex Solution Method and Photo-degradation of NO (복합고분자용액법에 의한 가시광에 반응하는 TiO2:Zr, N 광촉매의 제조 및 NO 광분해 특성)

  • Choi, Jae-Young;Kim, Ji-Young;Cho, Young-Hyuek;Jang, Hee-Dong;Chang, Han-Kwon;Kim, Byoung-Gon;Kim, Tae-Oh
    • Journal of Powder Materials
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    • v.15 no.1
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    • pp.13-17
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    • 2008
  • Visible-light responsive $TiO_2$:Zr, N powders were prepared by polymer complex solution method and the particle properties were characterized by using transmission electron microscope, BET method, X-ray diffractometer and UV-Vis spectrophotometer. The photocatalytic reactivity of the catalysts was also estimated by analyzing NO degradation. Polyhedral $TiO_2$ powder having about 20 um in the average particle diameter was successfully prepared, The XRD analysis revealed that the as-prepared powder consisted of anatase and rutile phases. The light absorption of the as-prepared $TiO_2$:Zr, N powder was shifted to the visible light. In addition, the as-prepared $TiO_2$:Zr, N nanoparticles showed the higher photocatalytic activity than the commercial $TiO_2$ under both UV and visible lights.

Evaluation of visible fluorescent elastomer tags implanted in marine medaka, Oryzias dancena

  • Im, Jae Hyun;Gil, Hyun Woo;Park, In-Seok;Choi, Cheol Young;Lee, Tae Ho;Yoo, Kwang Yeol;Kim, Chi Hong;Kim, Bong Seok
    • Fisheries and Aquatic Sciences
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    • v.20 no.9
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    • pp.21.1-21.10
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    • 2017
  • The aim of this study was to assess visible implant fluorescent elastomer (VIE) tagging and stress response in marine medaka, Oryzias dancena. The experimental fish were anesthetized individually and marked with red, yellow, or green elastomer at each of the following three body locations: (1) the abdomen, (2) the back, and (3) the caudal vasculature. During 12 months, the accumulated survival rates of fish in the experimental treatments were not different among red, yellow, and green elastomers. The experimental fish retained > 85% of the tags injected in the back, > 70% of the tags injected in the caudal vasculature, and > 60% of the tags injected in the abdomen (P < 0.05). An important observation was that the abdomen site was associated with poor tag retention. For all injected sites, the red and green tags were able to be detected more easily than the yellow tags when observed under both visible and UV lights. Tag readability was lower for the abdomen site than for the other sites (back and caudal vasculature). Thus, VIE tags were easy to apply to marine medaka (< 1 min per fish) and were readily visible when viewed under UV light.

Synergistic Effect of Reductase and Keratinase for Facile Synthesis of Protein-Coated Gold Nanoparticles

  • Gupta, Sonali;Singh, Surinder P.;Singh, Rajni
    • Journal of Microbiology and Biotechnology
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    • v.25 no.5
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    • pp.612-619
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    • 2015
  • We have synthesized gold nanoparticles (GNPs) using chicken feathers (poultry waste) and Bacillus subtilis RSE163. Disulfide reductase and keratinase produced by Bacillus subtilis during the degradation of chicken feather has been used to reduce Au3+ from HAuCl4 precursor to produce gold nanoparticles. The synthesized biogenic GNPs were characterized by UV-visible spectroscopy, transmission electron microscopy (TEM), and zeta potential measurements. Fourier transform infrared (FTIR) spectroscopy indicated the presence of protein capping on synthesized GNPs, imparting multifunctionality to the GNP surface. Furthermore, the nontoxic nature of biogenic GNPs was insured by interaction with Escherichia coli (ATCC11103), where TEM images and enhancement of growth rate of E. coli in log phase signified their nontoxic nature. The results indicate that the synthesis of biocompatible GNPs using poultry waste may find potential applications in drug delivery and sensing.

One-pot Synthesis of 5,7-Diaryl-3,4,6-trihydronaphthalen-2-ones (5,7-Diaryl-3,4,6-trihydronaphthalen-2-ones의 One-pot 합성)

  • Gopalakrishnan, M.;Manikandan, H.;Sureshkumar, P.;Thanusu, J.;Kanagarajan, V.
    • Journal of the Korean Chemical Society
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    • v.51 no.4
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    • pp.356-360
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    • 2007
  • 5,7-Diaryl-3,4,6-trihydronaphthalen-2-ones have been synthesized from 3,5-diaryl-cyclohex-2-en-1- ones and methyl vinyl ketone in the presence of sodium ethoxide. The products were characterized by IR, UV-Visible, 1H-NMR, 13C-NMR and mass spectral techniques. To confirm 1H and 13C signals, HSQC spectrum was recorded and analyzed.

Stability to the spreading solvent of(3-Alkyl benzimidazolium)-TCNQ(1:1) Complex for Langmuir-Blodgett Technigue (Langmuir-Blodgett법을 위한(3-Alkyl benzimidazolium)-TCNQ(1:1)착물의 분산용매 중에서의 안정성)

  • Sohn, Byoung-Chung;Hwang, Kyo-Hyun;Jeong, Soon-Wook
    • Journal of the Korean Applied Science and Technology
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    • v.11 no.1
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    • pp.39-44
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    • 1994
  • A Stability to the Spreading solvents, Which is acetonitrile, dichloromethane, benzene, chloroform and acetonitrile-benzene(1:1, v/v) of (3-Alkyl benzimidazolium)-TCNQ(1:1) Complex was investigated by UV-visible Spectrometer and was confirmed stabilized on acetonitrile, acetonitrilbenzene(1:1, v/v) for five hours. Using Ultra pure water as subphase for Langmuir-Blodgett (LB) Films, it was achived successively to fabricate the Y-type LB films of (3-Alkyl benzimidazolium)-TCNQ(1:1) Complex. For the identification of deposition of (3-Alkyl benzimidazolium)-TCNQ(1:1) Complex, UV-visible spectra was recorded on HP 8452A spectrometer.

Polyamic Acid Alkylamine Salts(PAAS) (Langmuir-Blodgett(LB) Films의 광학적 및 전기적 특성)

  • 이승엽;강도열;김태완
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.04a
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    • pp.277-280
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    • 1997
  • It is important to investigate the molecular arrangement and the orientational distribution in the study of LB films. Polarized UV/visible absorption spectra make it possible to reveal the molecular arrangement and the orientational distribution. It is clarified that the PAAS LB films have specific directions in the molecular arrangement and the orientational distribution, which art different in intensity corresponding to the surface pressure. Unpolarized UV/visible absorption spectra reveal that the surface pressure is proportional to the finn thickness and is related to the molecular orientation. Current-Voltage(I-V) measurements provide that the current decreases as the surface pressure increases and there are certain phenomena called switching phenomena. Switching effort indicates that the current flows in high conductivity during on-state and suddenly decreases into low conductivity during off-state.

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Limitations of time resolution and spatial overlap caused by group velocity mismatch in experiments using ultrashort UV and visible optical pulses. (자외선과 가시광선 극초단 펄스 실험의 군속도 차이에 의한 시간 분해능 및 공간 겹침의 제한)

  • 김성규
    • Korean Journal of Optics and Photonics
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    • v.5 no.2
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    • pp.252-259
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    • 1994
  • The method of calculating overlap dispersion caused by group velocity mismatch between uv and visible pulses in ultrafast pump-probe experiments is presented to discuss limitations of the time resolution and signal intensity. The calculations show arrangements using a single focusing lens shall result in undesirable time resolution and low signal intensity. Achromatic doublets result in unrealistic solutions. However, dramatic improvement in the time resolution and signal intensity is expected in the optical arrangements using separate lens for each pulse and in the arrangements using a cutoff secondary lens with a main lens. lens.

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Stability to the Spreading Solvent of (3-Alkyl Benzumidazolium)-TCNQ(l:2) Complex for Langmuir-Blodgett Technique (Langmuir-Blodgett법을 위한(3-Alkyl benzimidazolium)-TCNQ(1:2)착물의 분산용매 중에서의 안정성)

  • Jeoung, Soon-Wook;Hwang, Kyo-Hyun;Sohn, Byoung-Chung
    • Journal of the Korean Applied Science and Technology
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    • v.11 no.2
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    • pp.99-103
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    • 1994
  • A stability to the spreading solvent, which is acetonitrile, benzene, chloroform and acetonitrile-benzene(1:1, v/v) of (3-Alkyl benzimidazdium)-TCNQ(1:2) complex was investigated by UV-visible spectrometer and was confirmed stabilized on acetonitrile, acetonitrile-benzene (1:1, v/v) for five hours. Using Ultra pure water as subphase for Langmuir-Blodgett(LB) films, it was achived successively to fabricate the Y-type LB films of (3-Alkyl benzimidazolium)-TCNQ(1:2) complex. For the identification of (3-Alkyl benzimidazolium)-TCNQ(1:2) complex, UV-visible spectra was recorded on HP 8452A spectrometer.

Stability to the Spreading Solvent of (N-docosyl Quinolinium)-TCNQ(1:2) Complex by Langmuir-Blodgett Technique (Langmuir-Blodgett법을 위한(N-docosyl quinolinium)-TCNQ(1:2)착물의 분산용매 중에서의 안전성)

  • Jeoung, Soon-Wook;Lee, Yoong-Kook;Sohn, Byoung-Chung
    • Journal of the Korean Applied Science and Technology
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    • v.11 no.2
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    • pp.93-97
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    • 1994
  • A Stability to spreading solvent, which is acetonitrile, dichloromethane, benzene, chloroform, and acetonitrile-benzene (1:1, v/v) of (N-docosyl quinolinium)-TCNQ(1:2) complex was investigated by UV-visible spectrometer and was confirmed stabilized on acetonitrile, dichloromethane, and acetonitrile-benzene(1:1, v/v) for 7 hours. Using buffer solution($ph{\doteqdot}6.0$) as subphase for Langmuir-Blodgett(LB) film, it was achieved successively to fabricate the Y type LB films of (N-docosyl quinolinium)-TCNQ(1:2) complex. For the identification of deposition of (N-docosyl quinolinium)-TCNQ(1:2) complex, UV-visible spectra was recorded on HP 8452A spectrometer.