• Title/Summary/Keyword: UV-CURABLE

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Surface and Dielectric Properties of Oriental Lacquer Films Modified by UV-Curable Silicone Acrylate

  • Hong, Jin-Who;Kim, Hyun-Kyoung
    • Macromolecular Research
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    • v.14 no.6
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    • pp.617-623
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    • 2006
  • In order to achieve an oriental lacquer (OL) film with a thick consistency, UV-curable silicone acrylate (SA) was added to OL by a dual curing process. The addition of 5 wt% UV-curable SA to the OL fomulation enabled the preparation via a single drying step of a $77{\mu}m-thick$ film exhibiting excellent surface properties. FTIR-ATR was used to investigate the effect of UV-curable SA on the behavior of film formation during curing, and the relaxation behavior of the produced films was investigated by dielectric spectroscopy. Dielectric properties were measured in the frequency range $10^{-2}-10^5\;Hz$ at various temperatures between -100 and $200^{\circ}C$. The results demonstrated that OL modified by UV-curable SA has a higher glass transition temperature and stronger secondary relaxation at a lower temperature than the conventional OL system. The OL film modified with UV-curable SA was presumed to be harder at the surface and tougher than conventional OL film.

Review : The Advanced Inkjet Printing Technology - UV curable Jet Ink - (총설 : 최신 잉크제트 인쇄기술 - UV 경화형 제트잉크 -)

  • Jeong, Kyoung Mo;Won, Jong Myung;Lee, Yong Kyu;Koseki, Ken'ichi
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.46 no.2
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    • pp.46-56
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    • 2014
  • The aim of this reviews is to introduce the information concerning design of the UV-curable jet ink composition in order to provide a good adhesive property on non-porous surface. In order to clarify the viscosity dependence of flying speed for the UV curable jet ink, rheological analysis and observation of the flying state of the ink were carried out. The relationship between ink formulas and adhesive property on non-porous surface was investigated. It was examined the adhesive property of radical polymerization type UV curable jet ink included hydrogen abstraction type photo-initiator, it was expected that the strong adhesive strength can be obtained between the ink and non-porous surface in this study. UV curable jet ink with a slight amount of water was prepared. Optimum ratio of the cationic polymerization type UV curable jet ink shows an adequate adhesive strength towards two kinds of non-porous surface such as glass, poly(vinyl chloride) when tests were conducted on the ink jet-printing test machine.

The hybrid film characteristics of UV-curable organic-inorganic coating solutions (자외선 경화형 유/무기 코팅제의 복합 필름 특성)

  • Lee, Chang-Ho;Kim, Sung-Rae;Lee, Jong-Dae
    • Journal of the Korean Applied Science and Technology
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    • v.28 no.2
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    • pp.240-246
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    • 2011
  • UV-Curable hybrid coatings were synthesized to improve the surface properties of plastic film. Organic-inorganic coating solutions were prepared by the sol-gel method using urethane-acrylate oligomer, acrylate monomer, photo initiator and tetraethoxysilane (TEOS). Methacryloyloxypropyltrimethoxysilane(MPTMS) was used as a silane coupling agent to improve chemical interaction between inorganic phases and UV curable acrylate. In this study, the surface hardness and adhesive properties were improved with the use of inorganic component. The experimental results showed that UV-Curable hybrid films containing aliphatic urethane oligomer, hexanedioldiacrylate, trimethylolpropanetriacrylate, hydroxy dimethyl acetophenone exhibited good surface properties. Also, the optimum curing conditions were investigated.

Synthesis and Comparison of EB- and UV-curable Monomers for Anti-fogging Coatings (전자선 및 자외선 경화형 방무코팅용 모노머의 합성 및 물성비교)

  • Cho, Jung-Dae;Lee, Jae-Sung;Kim, Yang-Bae;Hong, Jin-who
    • Applied Chemistry for Engineering
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    • v.16 no.3
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    • pp.449-455
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    • 2005
  • Electron beam (EB) and ultraviolet (UV) curable monomers (AF-1 with mono functionality and AF-2 with tetra functionality) containing hydroxy and acrylate group for anti-fogging coating were synthesized and applied to EB and UV-curable coating systems. The synthesized reactive AF-1 and AF-2 monomers were first formulated into UV-curable system and the optimization of film properties for anti-fogging coating was investigated. The 5:17.5 ratio for AF-1 and AF-2 was found to be the best optimized formulation for anti-fogging coating without destroying the other essential properties such as hardness, solvent resistance, and adhesion. The optimized formulation was applied to the EB-curable system, and EB and UV-curable systems were compared. The results demonstrated that both EB and UV-cured films coated on PC sheet showed excellent anti-fogging properties; however, the EB-cured film exhibited better hardness, adhesion, and water repellent properties than the UV-cured film.

Mechanical Characteristics of CF Laminated Prepreg with UV-thermal Dual Curable Epoxy Resin (광·열경화형 수지를 이용한 탄소섬유 프리프레그의 물리적 특성)

  • Sim, Ji-hyun;Kim, Ji-hye;Park, Sung-min;Koo, Kwang-hoe;Jang, Key-wook;Bae, Jin-seok
    • Textile Coloration and Finishing
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    • v.29 no.1
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    • pp.37-44
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    • 2017
  • An issue of major concern in the utilization of laminated composites based epoxy resin is associated with the occurrence of delaminations or interlaminar cracks, which may be related to manufacturing defects or are induced in service by low-velocity impacts. A strong interfacial filament/brittle epoxy resin bonding can, however, be combined with the high fracture toughness of weak interfacial bonding, when the filaments are arranged to have alternate sections of shear stress. To improve this drawback of the epoxy resin, UV-thermal dual curable resin were developed. This paper presents UV-thermal dual curable resin which were prepared using epoxy acrylate oligomer, photoinitiators, a thermal-curing agent and thermoset epoxy resin. The UV curing behaviors and characteristics of UV-thermal dual curable epoxy resin were investigated using Photo-DSC, DMA and FTIR-ATR spectroscopy. The mechanical properties of UV-thermal dual curable epoxy resin impregnated CF prepreg by UV curable resin content were measured with Tensile, Flextural, ILSS and Sharpy impact test. The obtained results showed that UV curable resin content improves the epoxy toughness.

A Study on Micro-patterning used the UV-Curable Resin (UV경화성 수지를 이용한 미세패턴 형성에 관한 연구)

  • 남수용
    • Journal of the Korean Graphic Arts Communication Society
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    • v.19 no.2
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    • pp.68-78
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    • 2001
  • UV-curable resin has the properties of quick-drying, thigh productivity at low temperature, energy savint, space saving, solventless, non-polluting and low-stinking, and thus, UV-curing system has been widely used in the fields of printing inks, adhesives, paints and coating agents. This study has been executed to micro-patterning used UV-curable resin, The micro-patterning properties of this photoresist were investigated under irradiation of UV light low pressure mercury lamp. When the exposed photoresist film was developed by pure water developer, the resolution of this photoresist was about 50$\mu\textrm{m}$.

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A Novel Patterning Method for Silver Nanowire-based Transparent Electrode using UV-Curable Adhesive Tape (광경화 점착 테이프를 이용한 은 나노와이어 기반 투명전극 패터닝 공법)

  • Ju, Yun Hee;Shin, Yoo Bin;Kim, Jong-Woong
    • Journal of the Microelectronics and Packaging Society
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    • v.27 no.3
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    • pp.73-76
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    • 2020
  • Silver nanowires (AgNWs) intrinsically possess high conductivity, ductility, and network structure percolated in a low density, which have led to many advanced applications of transparent and flexible electronics. Most of these applications require patterning of AgNWs, for which photolithographic and printing-based techniques have been widely used. However, several drawbacks such as high cost and complexity of the process disturb its practical application with patterning AgNWs. Herein, we propose a novel method for the patterning of AgNWs by employing UV-curable adhesive tape with a structure of liner/adhesive layer/polyolefin (PO) film and UV irradiation to simplify the process. First, the UV-curable adhesive tape was attached to AgNWs/polyurethane (PU), and then selectively exposed to UV irradiation by using a photomask. Subsequently, the UV-curable adhesive tape was peeled off and consequently AgNWs were patterned on PU substrate. This facile method is expected to be applicable to the fabrication of a variety of low-cost, shape-deformable transparent and wearable devices.

Physical Properties of UV-Curable Powder Coatings with Different Photoinitiator Contents (광개시제의 함량에 따른 UV 경화형 분체도료의 물리적 특성)

  • Moon, Je-Ik;Choi, Jae-Hoon;Hwang, Hyun-Deuk;Kim, Hyun-Joong;Kim, Nam-Hong
    • Journal of Adhesion and Interface
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    • v.9 no.2
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    • pp.32-37
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    • 2008
  • A series of UV-curable powder coatings with different contents of photoinitiator (0.5 wt%, 1 wt%, 2 wt%) were formulated and measured gel content, tensile strength of cured film. Heat-sensitive substrates such as MDF, plywood and PVC were coated UV-curable powder and cured coatings were measured physical properties by pendulum hardness tester, glossmeter, pull-off adhesion tester. With increasing photoinitiator content, adhesion force between coating and substrate decreased because of crosslinking density increasing. The results of pendulum hardness was not significantly changed but gloss was changed according to different substrates. Adhesion of UV-curable coatings was enough to apply for heat-sensitive substrates. From these results, we concluded that contents of photoinitiator was a effective factor in UV-curable powder coatings. UV-curable coatings was a portential candidate for heat-sensitive substrates.

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The Physical Properties of UV-curable Resin for the Restoration of Glass Cultural Properties and Its Application in Conservation Treatment (유리제 문화재 복원용 광경화성 수지의 물성 연구 및 적용)

  • Lee, Hae Soon;Na, Ah Young
    • Conservation Science in Museum
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    • v.21
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    • pp.1-16
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    • 2019
  • This study investigated the material properties of UV-curable Resin in order to identify stable materials for use in the restoration of glass cultural properties. Tested samples were based on acrylic UV-curable Resin (SECURE CP-7321®), to which urethane UV-curable Resin (FLGPCL04 Clear®) was added in 10% increments to produce eleven samples. The results showed that all eleven samples had similar properties in terms of refractive index, density, adhesive strength, and anti-yellowing. But the surface hardness and compressive strength were optimal and effective for maintaining the shape of artifacts after restoration treatment when the proportion of urethane resin was in the range of 10-20%. Based on these findings, the mixing sample [acrylic UV-curable Resin(9) : urethane UV-curable Resin(1)] was applied in the conservation treatment of a glass cultural propertie (Hwangbuk 519) excavated from the North Mound of Hwangnamdaechong, Tomb in Gyeongju.

Investigating the Antibacterial Qualities of Copper Particle-Infused UV-Curable Paint for Wood Flooring Boards (구리입자 기반 UV경화도료 코팅 목질 마루판의 항균 특성)

  • Lee, Dong-Gun;Lim, Nam-Gi;Koh, Jae-Song
    • Journal of the Korea Institute of Building Construction
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    • v.23 no.4
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    • pp.393-404
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    • 2023
  • This research evaluates the antibacterial and transparency properties of UV-curable paint augmented with 20wt% copper particles. The transparency assessment indicated that the paint maintained a total luminous transmittance of 90% or above, thereby matching or surpassing the performance of standard UV-curing paints. To further test its antibacterial capabilities, wooden flooring boards were coated with the UV-curable paint laced with 20wt% copper particles, which had been surface-modified with a silane coupling agent. Following the fatigue tests of these treated boards, an impressive bacterial reduction rate of 99.9% was noted after a span of 6 hours, demonstrating the paint's exceptional antibacterial performance.