• Title/Summary/Keyword: UV index

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Generation of Graded Index Profile of Poly(methyl methacrylate) by a Photochemical Reaction

  • Yun, Hyun-Chu;Im, Sang-Hyuk;Suh, Duck-Jong;Park, O-Ok;Kwon, Moo-Hyun
    • Macromolecular Research
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    • v.11 no.4
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    • pp.236-240
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    • 2003
  • Fabrication of a graded index profile was possible via photochemical reaction of cinnamoyl groups with 350 nm wavelength UV light to form crosslinked structures. Such structural change may induce the change in the refractive index. In order to generate graded index profile in the PMMA polymer optical fiber (POF) with cinnamoyl groups by photochemistry, a methyl methacrylate monomer containing a cinnamoyl functional group in the side chain were prepared. This monomer was then copolymerized with methyl methacrylate with various compositions not only to utilize advantages of poly(methyl methacrylate) but also to overcome the drawbacks of the cinnamate homopolymer. Changes of refractive indices were investigated with various contents of cinnamoyl group and varying irradiation time. Large change in the refractive index (${\Delta}{\approx}0.01$) and its proper profile shape ($g{\approx}2.2$) can be obtained by changing irradiation time.

Evaluation of Organic Fouling Potential by Membrane Fouling Index (막오염 지수를 이용한 유기물에 의한 막오염 평가)

  • Kim, Hana;Park, Chanhyuk;Hong, Seungkwan
    • Journal of Korean Society on Water Environment
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    • v.22 no.1
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    • pp.140-144
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    • 2006
  • This study was performed to investigate the effect of organic characteristics and feed water solution chemistry on membrane fouling index such as Silt Density Index (SDI) and Modified Fouling Index (MFI). Specifically, Aldrich humic acids (AHA) and Suwannee river humic acids (SHA) were used in SDI/MFI experiments. Higher SDI values were observed with increasing organic concentration. AHA with larger molecular weight (MW) and SUVA (${\approx}UV_{254}/TOC$) resulted in higher SDI values, compared to SHA. The feed solution chemistry (i.e, pH, ionic strength, and hardness) also affects SDI values to some degree. In particular, SDI increased with increasing hardness ($Ca^{2+}$) concentration for AHA. Unlike SDI, the MFI developed on the basis of particle cake filtration theory, was not accurately assessed due to internal fouling by organics such as pore adsorption and subsequent pore blocking.

Luminescence Characteristics of Blue Phosphor and Fabrication of a UV-based White LED (UV 기반 백색 LED용 청색 형광체의 발광특성 및 백색 LED 제조)

  • Jung, Hyungsik;Park, Seongwoo;Kim, Taehoon;Kim, Jongsu
    • Korean Journal of Optics and Photonics
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    • v.25 no.4
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    • pp.216-220
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    • 2014
  • We have synthesized a $CaMgSi_2O_6:Eu^{2+}$ blue phosphor via a solid-state reaction method. The $CaMgSi_2O_6:Eu^{2+}$ phosphor has monoclinic structure with a space group of C2/c (15), and an emission band peaking at 450 nm (blue) due to the $4f^7-4f^65d$ transition of the $Eu^{2+}ion$. The emission intensity at $100^{\circ}C$ is 54% of the value at room temperature. A white LED was fabricated by integrating a UV LED (400 nm) with our blue phosphor plus two commercial green and red phosphors. The white LED shows a color temperature of 3500 K with a color rendering index of 87 (x = 0.3936, y = 0.3605), and a luminous efficiency of 18 lm/W. The white LED shows a luminance maintenance of 97% after operation at 350 mA for 400 hours at $85^{\circ}C$.

Analysis of Degradation Behaviors of Geomembrane by Accelerated Test under UV Exposure Conditions (자외선 노출조건 하에서 가속시험에 의한 지오멤브레인의 분해거동 해석)

  • Park, Yeong Mog;Khan, Belas Ahmed;Jeon, Han Yong
    • Polymer(Korea)
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    • v.37 no.1
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    • pp.5-14
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    • 2013
  • In this paper the effect of UV (ultraviolet) exposure on HDPE (high density polyethylene)-smooth and f-PP (flexible polypropylene) geomembranes is evaluated under UVB-313 (ultraviolet wavelength 290-315 nm) exposure. Tensile property, melt flow index (MFI), oxidation induction time (OIT), both standard-OIT and high pressure-OIT and Fourier transform infrared spectroscopy/attenuated total reflectance (FTIR/ATR) results are discussed. Although tensile properties of the exposed geomembrane samples remained unchanged, the depletion of antioxidants was found higher for f-PP than for HDPE geomembrane. Arrhenius model by extrapolation was used on the data to predict the antioxidant lifetime to a typical site temperature of $20^{\circ}C$. There was no significant difference between the MFI value of the virgin and UV exposed HDPE geomembrane samples but a decrease in MFI was found in f-PP geomembrane that signifies that crosslinking has occurred. From FTIR spectra, the small peak (near $1750\;cm^{-1}$) observed in the spectrum of UV exposed sample corresponds to a carbonyl (C=O) linkage, which suggests that oxidation has occurred in the polymer structure, and another new band for f-PP between 3100 and $3500\;cm^{-1}$ is attributed to a hydroxyl bond and/or hydroperoxide bond.

Application of Newly PAC Selection Method Based on Economic Efficiency (경제성을 고려한 새로운 PAC 선정방법의 적용)

  • Kim, Young-Il;Bae, Byung-Uk
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.11
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    • pp.1141-1147
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    • 2006
  • In order to applicate a newly method for powdered activated carbon(PAC) selection based on economic efficiency, PAC adsorption tests were performed for removal of MIB and dissolved organic carbon(DOC) in drinking water supplies. The removal rate of MIB increased when the PAC dose increased. The Coal-based PACs were superior for adsorption of MIB compared to wood-based PACs. PAC adsorption of DOC and $UV_{254}$ were a little different for different PACs and types of raw water, but both were lower than adsorption of MIB. Among the tested PACs, the one called P-1000 was most effective for removal of MIB, DOC and $UV_{254}$. Most of the organics in the tested samples were proven by excitation emission matrix(EEM) results to be fulvic-like materials. Especially, fulvic-like materials, humic-like materials, and soluble microbial byproduct(SMP)-like materials decreased after contact with PAC. P-1000 which had the lowest MIB cost index(MCI) was selected as the optimum PAC for the target water. PAC efficiency and treatability, particle size and distribution, and the cost associated with PAC dosing for MIB removal according to DOC concentration should all be considered before making the final selection of the best PAC for the target water.

Side Polished Fiber Optic UV Sensor Using Evanescent Coupling of Photo-Functional Polymer (광기능성 폴리머의 소산장 결합을 이용한 측면연마 광섬유형 자외선 센서)

  • Kim, Sang-Woo;Seo, Gyoo-Won;Yoon, Jong-Kuk;Jang, Su-Won;Yu, Yun-Sik;Lee, Seung-Ha;Kang, Shin-Won
    • Journal of Sensor Science and Technology
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    • v.11 no.6
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    • pp.335-341
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    • 2002
  • In this paper, we investigated a novel UV sensor using evanescent field coupling between the side polished fiber and photo-functional polymer waveguide. It was found that resonant wavelength shifts occur due to variation in the refractive index of polymer planar waveguide for its photo-functional properties on exposed UV. Spiroxazine (photochromic dye) was used as the planar waveguide. The resonant wavelength responses were exhibited at 1.44 nm/mW, 1.64 nm/mW, and 1.78 nm/mW when UV irradiations were exposed for 20 seconds, 30 seconds, and 40 seconds, respectively. The recovery time of sensor was independent of UV exposure power and 90% recovery time was 100 seconds.

Optical Properties of Column -II Nitride Semiconductors (III족 질화물반도체의 분광학적 성질)

  • 김선태;문동찬
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1995.05a
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    • pp.47-49
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    • 1995
  • We report the spectroscopic properties of column-III nitrifies of GaN, GaInN, and AlGaN. The column-III nitride semiconductors are promising materials to realize the current-injection-type blue-and ultraviolet (UV)-light-emitting devices with high performance. To acheive the lasing with low threshold, the devices are must constructed to double heterostructure by succesive epitaxial growth technique, and we must confine the carriers in the potential barrier and optical confinement in wave guide between barrier and active layers has different refractive index. The refractive index of column-III nitride semiconductors, however, are rarely reported. The measured refractive index was 2.9, and the observed characteristic peak near the enrgy gap was analysed using a dielectric function and may due to excitonic contribution.

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DETERMINATION OF STELLAR SURFACE TEMPERAURE USING ULTRAVIOLET SPECTRA (자외선 스펙트럼을 이용한 별의 표면온도 결정)

  • 강영운;지나현;한미려;최영준;한원용;이우백
    • Journal of Astronomy and Space Sciences
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    • v.15 no.1
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    • pp.91-100
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    • 1998
  • Color indexes and effective temperatures for 25 standard stars have been determined as a pilot project which show a relationship between color index and effective temperature in ultraviolet region. The effective temperature was determined by comparing energy distribution curves derived from the IUE low dispersion spectra with Kurucz atmosphere model. The UV color index was deduced by integrating fluxes in $300{\AA}$ interval of the IUE low disperion spectra. The relation between color index and effective temperature in ultraviolet is similar with that of optical region.

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EXTREMAL CHEMICAL TREES WITH RESPECT TO HYPER-ZAGREB INDEX

  • Ghalavand, Ali;Ashrafi, Ali Reza;Sharafdini, Reza;Ori, Ottorino
    • The Pure and Applied Mathematics
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    • v.26 no.3
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    • pp.177-188
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    • 2019
  • Suppose G is a molecular graph with edge set E(G). The hyper-Zagreb index of G is defined as $HM(G)={\sum}_{uv{\in}E(G)}[deg_G(u)+deg_G(v)]^2$, where $deg_G(u)$ is the degree of a vertex u in G. In this paper, all chemical trees of order $n{\geq}12$ with the first twenty smallest hyper-Zagreb index are characterized.

A Study on the Anti-Reflection Coating Effects of Polymer Eyeglasses Lens (폴리머 안경렌즈의 반사방지 코팅효과 연구)

  • Kim, Ki-Chul
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.1
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    • pp.216-221
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    • 2017
  • Reducing optical reflection in the visible light range, in order to increase the share of transmitted light and avoid the formation of ghost images in imaging, is important for polymer lens applications. In this study, polymer lenses with refractive indices of n=1.56, 1.60, and 1.67 were fabricated by the injection-molding method with a polymer lens monomer, dibutyltin dichloride as the catalyst and an alkyl phosphoric ester as the release agent. To investigate their anti-reflection (AR) effects, various AR coating structures, viz. a multi-layer AR coating structure, tri-layer AR coating structure with a discrete approximation Gaussian gradient-index profile, and tri-layer AR coating structure with a quarter-wavelength approximation, were designed and coated on the polymer lens by an E-beam evaporation system. The optical properties of the polymer lenses were characterized by UV-visible spectrometry. The material properties of the thin films, refractive index and surface roughness, were analyzed by ellipsometry and AFM, respectively. The most effective AR coating structure of the polymer lens with low refractive index, n=1.56, was the both side coating of multi-layer AR coating structure. However, both side coating of the tri-layered discrete approximation Gaussian gradient-index profile AR coating structure gave comparable results to the both side coating of the multi-layer AR coating structure for the polymer lens with a high refractive index of n=1.67.