• 보존과학회지
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• 제29권4호
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• pp.389-394
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• 2013

박제 표본이란 포유류, 조류, 파충류, 어류를 표본화한 것으로 국내 주요 자연사 박물관에서 전시 및 교육 목적으로 활용되고 있다. 그러나 현재 이러한 기관에서의 연구는 표본의 생태학적 연구에 집중되어 있어 박제 표본에 대한 보존과학적 연구는 거의 없으며, 박제 표본 제작에 사용되는 독성 화학약품과 이로 인해 발생되는 유해가스 분석은 전무한 실정이다. 따라서 본 연구는 박제의 손상에 따라 발생하는 유해가스에 대해 SPME법을 적용하여 분석하였다. 자외선 열화 실험 결과, 4종, 습도 및 포름알데히드 열화 실험 결과 7종의 주요 화학물질이 검출되었다. SPME 측정 결과, Naphthalene이 방부제로 사용되었음을 알 수 있으며, 열화 요인에 따라 Acetic acid와 같은 VOCs(휘발성유기화합물)이 검출되었다. 또한, 열화 및 고습의 환경에 노출될수록 Naphthalene의 농도가 감소하였다.

• 대한안전경영과학회지
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• 제25권3호
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• pp.31-36
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• 2023

The use of hanging scaffolding for exterior wall painting and cleaning in building construction and maintenance carries the inherent risk of fall accidents. While periodic rope replacement is crucial for preventing accidents resulting from rope breakage, current regulations lack specificity in determining appropriate disposal period for fiber ropes. This study analyzed the tensile strength of the most commonly used PP fiber ropes with different diameters (16 mm, 20 mm) in the domestic construction industry. Additionally, the effect of outdoor exposure was examined by measuring the tensile strength of new ropes and ropes exposing to outdoor conditions for 30 days and 90 days. The results showed that the new ropes and those exposed to outdoor for 30 days met the KS (Korean Standards) criteria for tensile strength. However, a significant decrease in tensile strength was observed in ropes exposed to outdoor for 90 days compared to both the new ropes and those exposed for 30 days. Furthermore, the ropes exposed for 90 days did not meet the KS criteria. These findings indicate the degradation of PP fiber ropes due to UV (Ultra Violet) radiation, highlighting the importance of considering this factor when determining the replacement period for fiber ropes used in scaffolding work.

• 한국산학기술학회논문지
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• 제19권9호
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• pp.279-287
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• 2018

실란트는 현대 건축물의 중요한 요소로 사용되고 있으며, 습기, 공기, 기타 물질의 침입에 대한 방벽을 제공함으로서 내후성에 대한 건물 보호의 역할을 한다. 다양한 환경에 노출되어 물리적, 화학적, 기계적 특성이 변화되어 수명이 단축되는 경우가 많으며, UV, 습기, 온도 신축 등은 내구성과 직결되는 중요한 이슈이다. 본 연구에서는 구조용 실링마감재의 내구성능을 실내에서 검증하기 위한 장비로서 외기의 환경을 모사할 수 있는 복합열화시험 챔버를 제작하였다. 황사, 산성비, 미생물에 의한 오염 등 특이 기상 상황의 재현은 어려우며 외기 환경을 100 % 모사하는 것은 불가능한 것으로 판단되며, 구조용 실링재의 옥외폭로시험방법과 복합열화시험장치에 대한 내후성 시험 결과 간의 상관관계를 통해 재현성을 확보하고자 연구하였다. 옥외폭로시험의 변위량 시험 결과 실링재의 응집력이 분해되어 연질화가 진행되는 것으로 판단되었고, 옥외폭로 1년 후 변위는 초기 물성치보다 3600 Pa에서 3배 정도 차이가 나는것을 볼 수 있었고, 비교제품의 경우 최대 7배까지 변위가 차이나는 것으로 확인되었다. 복합열화시험장치에서 변위시험결과 열화되어 탄성 및 인장특성이 감소하는 경향을 나타내었다. 변성실리콘 실링재의 경우는 현재 400 Cycle을 완료하여 옥외폭로 12개월의 물성저하를 확인하였다. 시험체의 변형은 육안으로는 확인할 수 없어 상대적으로 실리콘 실링재 제품보다 상태 안정성이 양호한 것으로 판단된다. 옥외폭로시험 결과, 복합열화시험장치가 체계화되어 관련 지침 또는 규격 등에 제안된다면, 실제 사용환경에서 12개월의 예상수명을 실내에서 3개월 미만에서 검증할 수 있는 방법으로 향후, 경제적 손실저감, 공기단축, 설계에 예상 가능한 재료의 선정 등에 활용될 것으로 기대된다.

• Journal of the Korean Wood Science and Technology
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• 제46권5호
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• pp.449-470
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• 2018

본 총설에서는 외부에 사용되는 목재를 풍화인자로부터 보호하기 위해 실행되고 있는 최근의 연구동향에 대해 조사 분석하였다. 주요 기상열화 인자로부터 목재의 표면 보호를 위한 연구 동향에 대하여 조사한 결과 다음과 같은 결론을 얻었다. 목재보존제로 사용된 크롬, 구리 등의 무기화합물이 목재를 기상열화로부터 보호할 수 있는 것으로 보고되었다. 또한 ACQ처리 목재의 표면에 wax나 oil같은 소수성물질과 UV 흡수제, HALS(Hindered Amine Light Stabilizers) 등을 방부목재 표면에 precoating하면 기상열화 저항성을 강화할 수 있다고 보고되었다. 또한 방부목재 표면에 불투명 도막형성의 페인트/스테인 및 반투명스테인등이 기상열화방지에 대한 시너지 효과가 높힐수 있다는 보고들이 다수 있었다. 또한 방부목재의 표면보호를 위한 재도장 처리의 필요성이 시사되었다. 투명성의 도막에 UV방지를 위한 첨가물로서 미세입자의 ZnO 또는 $TiO_2$, Co, Cr, Fe, Mn, Ni과 Ti 등의 금속이온, Tris-resorcinol triazine derivatives, triazine 및 Benzotriazole과 같은 UV흡수제 등이 소개되었다. Methylation, acetylation 또는 alkylation 등과 같이 화학적으로 개질된 경우에는 이로 인한 중량증가가 높은 경우 기상열화 방지효과가 상승된다는 연구들이 소개되었다, 열처리목재의 기상열화 저항성에 대해서는 여러 가지 상반되는 연구보고 들이 있었고, UV저항성을 지닌 도장의 필요성이 강조된 보고가 있어 보다 심도 있는 연구의 필요성이 시사되었다.

• 복식
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• 제34권
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• pp.109-120
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• 1997

The conservation of collections in muse-ums is an important aspect for our her-itage. The control of museum environment is a vital factor in the preservation of cool-lections. Inappropriate or fluctuating envi-ronmental conditions can cause irreparable damage to works of arts. In this research we investigated the ac-tual conditions of museum environment for old testiles using questionnaire and mea-sured dye fasing of old textiles on exhibi-tion for 2 months in a university museum the major results are as follows: 1. The control of temperature and rela-tive humidity is a vital factors I the preservation of old textiles in museum generally acceptable temperature and rel-ative humidity standards for old textiles are 18-23$^{\circ}C$ and 50-65% R. H and light level for textiles on exhibition should be limited to 30-50 lux. 2, In university museums the limate control system in exhibition and storage area is in an early stage. Therefore to minimize the deterioration of old textiles the best method of controlling the envi-ronment is to have centralized climate control system in sorage area as well as in display area. 3. Conservator is needed to maintain collections scientifically. Only professional conservator by combining scientific tech-nical and artistic training has the exper-tise needed to maintain the physical in-tegrity of old textiles. In order to solve the inferior environment of museums the staff should recognize the importance of the condition of exhibition and storage. 4. Old textiles are susceptible to damage by light and associated heat. Dyed textiles which have been exhibited under the light without any UV filter were faded notice-ably within two months of exhibition. Light levels for textiles on exhibition should be limited to 30-50 lux. It is de-sirable to use special light source that can absorb UV. and UV filter is also recom-mended to reduce photodegradation of old textiles.

• 한국염색가공학회지
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• 제29권2호
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• pp.97-103
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• 2017

Polyketone fiber, a newly developed high strength fiber, has a tenacity and modulus similar to the p-aramid fiber, and can be used for reinforcing mechanical rubber goods(MRG), such as tires, hoses, and technical textiles. It will be expected for replacement of super fiber such as aramids and increasing the technical textile market share. This paper surveys the mechanical properties of polyketone fiber for technical textiles. For this purpose, dyed polyketone fabric is prepared, mechanical properties of coated and uncoated polyketone fabrics such as tensile strength, elongation and tear strength were examined before and after weather resistance test(temperature $63{\pm}3^{\circ}C$, humidity 60%, amount of power $0.35w/m^2$). The differences of mechanical properties between uncoated and coated fabrics for high functional technical textiles and composite materials are estimated through this study. The UV-stability of polyketone fabric showed obvious improvement after coating. After 168h(7day) of UV exposure, the coated fabric showed less deterioration in mechanical properties with the retained tensile strength and elongation at break greater than 22 and 17% of the uncoated polyketone fabrics values, respectively.

• 한국세라믹학회지
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• 제56권1호
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• pp.98-103
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• 2019

Optical filters to control light wavelength of displays or cameras are fabricated by multi-layer stacking process of low and high index thin films. The process of multi-layer stacking of thin films has received much attention as an optimal process for effective manufacturing in the optical filter industry. However, multi-layer processing has disadvantages of complicated thin film process, and difficulty of precise control of film morphology and material selection, all of which are critical for transmittance and coloring effect on filters. In this study, the composite $TiO_2$, which can be used to control of UV absorption, coated on nano hollow silica sol, was synthesized as a coating material for optical filters. Furthermore, systematic analysis of the process parameters during the chemical reaction, and of the structural properties of the coating solutions was performed using SEM, TEM, XRD and photo spectrometry. From the structural analysis, we found that the 85 nm nano hollow silica with 2.5 nm $TiO_2$ shell formation was successfully synthesized at proper pH control and titanium butoxide content. Photo luminescence characteristics, excited by UV irradiation, show that stable absorption of 350 nm-light, correlated with a 3.54 eV band gap, existed for the $TiO_2$ shell-nano hollow silica reacted with 8.8 mole titanium butoxide solution. Transmittance observed on substrate of the $TiO_2$ shell-nano hollow silica showed effective absorption of 200-300 nm UV light without deterioration of visible light transparency.

• 한국신뢰성학회지:신뢰성응용연구
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• 제7권4호
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• pp.173-181
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• 2007

Out door exposure to daylight and weather climate conditions can cause adverse effect on the properties of automotive plastic materials. The effects of sunlight exposure, especially ultra violet (UV) radiation, can break down the chemical bonds in a polymeric material. This degradation process is called photo-degradation and ultimately leads to color changes, cracking, chalking, the loss of physical properties and deterioration of other properties. To explore the effect of sunlight exposure on the automotive materials, this study investigated photo-oxidation degree and surface property change of molding parts by analytical methods. For the further study, accelerated weathering test methods are proposed, which can correlate with out door weathering, to predict long term performance of automotive plastic materials.

• 한국환경보건학회지
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• 제30권4호
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• pp.308-313
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• 2004

Native and acetylated soybean protein with acetylation percentage of $25\%$ were incubated with glucose to induce Maillard reaction. Acetylation of ${\varepsilon}$-amino group of lysine residues changed the conformation of soybean protein. The direct uv spectrum of native and acetylated soybean protein showed conformational changes with accessibility of tyrosine and tryptophan residues increased. Acetylation suppressed Maillard reaction between soybean protein and glucose. Acetylated soybean protein showed improved water sorption, fat binding, foam formation, and emulsion activity of the protein, but depressed brown pigment development and trypsin digestion. Thus aceylation prevented deterioration of certain functional characteristics that occurred during storage, besides causing functional characteristics to be improved on its own.

• 한국응용과학기술학회지
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• 제4권2호
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• pp.19-23
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• 1987

The addition of dipeptides and 1,2-bis (aminoacyl) hydrazine derivatives a level of 250 ppm to corn oil resulted in the retardation of the oxidaitive deterioration of the oil when it was stored in the oven at $70^{\circ}C$ during 5 days. Their antioxidant activities were investigated by UV absorbance of the corn oil at the wavelength of 234nm. 1,2-bis (aminoacyl) hydrazine derivatives showed higher antioxidant activity than normal dipeptides. Dipeptides containing phenyl ring with which is conjugable a-carbon radical showed antioxidant activity.