• 제목/요약/키워드: UV absorbance

검색결과 414건 처리시간 0.025초

Depigmentation activity of plant extracts (Okyong-san)

  • Han, Sung-Chul;Lee, Young-Jin;Lee, Ki-Young;Kim, Yeon-Zu;Jin, Sang-Hyeop
    • 한국생물공학회:학술대회논문집
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    • 한국생물공학회 2003년도 생물공학의 동향(XIII)
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    • pp.794-798
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    • 2003
  • 천연추출물로서 미백 재료로 널리 쓰이고 있는 옥용산에 대해서 in vitro 미백활성을 UV 흡수능, tyrosinase 저해활성 그리고 free radical 소거활성을 측정함으로서 검정해 보았다. 옥용산 UV-B와 C 영역에 걸쳐서 높은 자외선 흡수능을 보이는 것으로 관찰이 되었으며 0.8 % 이상의 농도에서 80% 이상의 tyrosinase 저해활성을 가지는 것을 관찰하였다. 또한 조협, 승마, 감송, 정향, 찹쌀분과 옥용산의 추출물은 높은 free radical 소거능을 가지는 것으로 확인되었다.

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Comparison of Phenol Removal between Electrochemical Reaction and Plasma Reaction

  • Kim, Dong-Seog;Park, Young-Seek
    • 한국환경과학회지
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    • 제25권7호
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    • pp.905-916
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    • 2016
  • The characteristics of phenol removal and $UV_{254}$ matters variance were investigated and compared by the variation of operating factors (NaCl concentration, air flow rate, initial phenol concentration) in electrochemical reaction (ER) and dielectric barrier discharge plasma reaction (DBDPR), respectively. The phenol removal rate was shown as $1^{st}$ order both in ER and DBDPR. Also, the absorbance of $UV_{254}$ matters which means aromatic intermediates was analyzed to investigate the complete phenol degradation process. In ER, the phenol degradation and aromatic intermediates production rates increased by the increase of NaCl concentration. However, in DBDPR, the variation of NaCl concentration had no effect on the degradation of phenol and $UV_{254}$ matters. Air flow rate had a little effect on the removal of phenol and the variation of $UV_{254}$ matters in ER. The phenol removal rate in ER was a little higher than that in DBDPR. The produced $H_2O_2$ and $O_3$ amounts in ER were 2 times and 10 times higher than those in DBDPR. The chlorine intermediates ($ClO_2$ and free chlorine) were produced in ER, however, they were not produced in DBDPR.

SnS 기반의 고성능 투명 UV 광검출기 (SnS-embedded High Performing and Transparent UV Photodetector)

  • 박왕희;반동균;김현기;김홍식;;유정희;김준동
    • 한국전기전자재료학회논문지
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    • 제29권7호
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    • pp.445-448
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    • 2016
  • Transparent UV photodetector was achieved by using wide bandgap metal oxide materials. In order to realize transparent heterojunction UV photodetector, n-type ZnO and p-type NiO metal oxide materials were employed. High light-absorbing SnS layer was inserted into the n-ZnO and p-NiO layers. High-performing UV photodetector was realized by ZnO/SnS/NiO/ITO structures to provide extremely fast response times (Fall time: $7{\mu}s$ and rise time: $13{\mu}s$) and high rectifying ratio. The use of functional SnS-embedded photodetector would provide a route for high functional photoelectric devices.

요오드를 전자수용체로 한 항히스타민제의 분광학적 분석 (Spectrophotometric Determination of Antihistaminics by using Iodine as Electron Acceptor)

  • 문홍섭;백채선
    • 약학회지
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    • 제33권3호
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    • pp.141-148
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    • 1989
  • The weak UV absorbing antihistaminics such as chlorpheniramine, triprolidine, tripelennamine and diphenhydramine were analyzed by charge-transfer spectrophotometric method. The results obtained are summarized as folows. It was possible to determine a weak UV absorbing antihistaminics using the intense charge-transfer UV bands in chloroform. Charge transfer complexes were formed in a 1:1 ratio between antihistaminics and iodine in chloroform. Linear relationship was found between absorbance and concentration in the range of $1.0\;{\times}\;10^{-5}M-5.0\;{\times}\;10^{-5}M$ for chlorpheniramine( ${\varepsilon}\;=\;2.082\;{\times}\;10^4$) and tripelennamine ( ${\varepsilon}\;=\;1.578\;{\times}\;10^4$), $1.0\;{\times}\;10^{-5}M-8.0\;{\times}\;10^{-5}M$ for triprolidine ( ${\varepsilon}\;=\;1.120\;{\times}\;10^4$) and $1.0\;{\times}\;10^{-5}M-1.0\;{\times}\;10^{-4}M$ for diphenhydramine ( ${\varepsilon}\;=\;9.900\;{\times}\;10^3$). Charge transfer complexes of chlorpheniramine, triprolidine and tripelennamine have absorption maxima at 293 nm and complex form of diphenhydramine has absorption maximum at 270 nm. By UV, IR spectra, it could be inferred that CT-complexes were formed by interaction between the basic nitrogen of antihistaminics as electron donor (non bonding electron) and iodine as electron acceptor (${\sigma}$ bonding electron).

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순환식 유전체 장벽 플라즈마 반응기를 이용한 수중 페놀 처리 (Degradation of Phenol in Water Using Circulation Dielectric Barrier Plasma Reactors)

  • 김동석;박영식
    • 한국환경보건학회지
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    • 제38권3호
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    • pp.251-260
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    • 2012
  • Objectives: The purpose of this study was evaluating the applicability of the circulation dielectric barrier plasma process (DBD) for efficiently treating non-biodegradable wastewater, such as phenol. Methods: The DBD plasma reactor system in this study consisted of a plasma reactor (discharge, ground electrode and quartz dielectric tube, external tube), high voltage source, air supply and reservoir. Effects of the operating parameters on the degradation of phenol and $UV_{254}$ absorbance such as first voltage (60-180 V), oxygen supply rate (0.5-3 l/min), liquid circulation rate (1.5-7 l/min), pH (3.02-11.06) and initial phenol concentration (12.5-100 mg/l) were investigated. Results: Experimental results showed that optimum first voltage, oxygen supply rate, and liquid circulation rate on phenol degradation were 160 V, 1 l/min, and 4.5 l/min, respectively. The removal efficiency of phenol increased with the increase in the initial pH of the phenol solution. To obtain a removal efficiency of phenol and COD of phenol of over 97% (initial phenol concentration, 50.0 mg/l), 15 min and 180 minutes was needed, respectively. Conclusions: It was considered that the absorbance of $UV_{254}$ for phenol degradation can be used as an indirect indicator of change in non-biodegradable organic compounds. Mineralization of the phenol solution may take a relatively longer time than that required for phenol degradation.

자색 옥수수 잎과 줄기를 이용한 직물의 천연염색 (Natural Dyeing Fabrics with Leaf and Stem of Purple Corn)

  • 김정태;손범영;이진석;백성범;김선림;김미정;정건호;권영업
    • 한국작물학회지
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    • 제58권2호
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    • pp.113-118
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    • 2013
  • 본 연구는 자색 옥수수 부산물인 옥수수 줄기와 잎을 이용하여 염액을 추출하여 여러 가지 염색 조건에서 염색정도를 관찰하고 자색옥수수 부산물의 염료로서의 가능성을 타진하여 이용성 증진을 위한 기초자료를 제공하고자 실시하였다. 1. 자색 옥수수 추출시 pH에 따른 흡광도의 변화가 없으므로 자색 옥수수 색소 함량을 측정하기 위하여 UV 흡광도를 측정할 때 520~560 nm를 이용하는 것이 효율적일 것으로 생각된다. 2. 자색 옥수수 잎 추출물로 염색한 silk와 cotton은 pH가 높아질수록 직물의 밝기와 적색도가 낮아졌다. 줄기 추출물의 경우에는 뚜렷한 경향을 나타내지는 않았지만 pH 값이 높아질수록 밝기와 적색도가 높아지는 경향을 나타내었다. 3. 농도에 따른 직물의 염색 정도는 silk와 cotton 모두 농도가 높아질수록 밝기는 낮아지고 적색도는 증가하는 경향을 나타내었다. 4. Silk와 cotton은 일반적으로 염색시간이 길어질수록 명도가 증가하고, 적색도는 감소하는 경향을 나타내었다.

Pilot 플라즈마 반응기를 이용한 하수 중 미생물의 불활성화 (Inactivation of Microorganisms in Sewage Using a Pilot Plasma Reactor)

  • 김동석;박영식
    • 한국환경보건학회지
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    • 제39권3호
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    • pp.289-299
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    • 2013
  • Objectives: For the field application of the dielectric barrier discharge plasma reactor, scale-up of the plasma reactor is needed. This study investigated the possibility of inactivation of microorganisms in sewage using pilot multi-plasma reactor. We also considered the possibility of degradation of total organic carbon (TOC) and nonbiodegradable matter ($UV_{254}$) in sewage. Methods: The pilot plasma reactor consists of plasma reactor with three plasma modules (discharge electrode and quartz dielectric tube), liquid-gas mixer, high voltage transformers, gas supply equipment and a liquid circulation system. In order to determine the operating conditions of the pilot plasma reactor, we performed experiments on the operation parameters such as gas and liquid flow rate and electric discharge voltage. Results: The experimental results showed that optimum operation conditions for the pilot plasma reactor in batch experiments were 1 L/min air flow rate), 4 L/min liquid circulation rate, and 13 kV electric discharge voltage, respectively. The main operation factor of the pilot plasma process was the high voltage. In continuous operation of the air plasma process, residual microorganisms, $UV_{254}$ absorbance and TOC removal rate at optimal condition of 13 kV were $10^{2.24}$ CFU/mL, 56.5% and 8.6%, respectively, while in oxygen plasma process at 10 kV, residual microorganisms, $UV_{254}$ absorbance and TOC removal rate at optimal conditions were $10^{1.0}$ CFU/mL, 73.3% and 24.4%, respectively. Electric power was increased exponentially with the increase in high voltage ($R^2$ = 0.9964). Electric power = $0.0492{\times}\exp^{(0.6027{\times}lectric\;discharge\;voltage)}$ Conclusions: Inactivation of microorganisms in sewage effluent using the pilot plasma process was done. The performance of oxygen plasma process was superior to air plasma process. The power consumption of oxygen plasma process was less than that of air plasma process. However, it was considered that the final evaluation of air and oxygen plasma must be evaluated by considering low power consumption, high process performance, operating costs and facility expenses of an oxygen generator.

Novel polyvinyl alcohol film dosimeter containing 3-(4,5-Dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide dye for high dose application

  • Khalid A. Rabaeh;Ahmed A. Basfar;Issra' M.E. Hammoudeh
    • Nuclear Engineering and Technology
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    • 제55권9호
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    • pp.3383-3387
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    • 2023
  • A new dyed polyvinyl alcohol (PVA) film dosimeter based on 3-(4,5-Dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide (MMT) tetrazolium dye is proposed in this study for measuring high gamma radiation dose. Gamma cell irradiator that contains Co-60 gamma-ray source was used to expose the novel MMT-PVA films to different doses up to 25 kGy. The changed in optical property of irradiated and unirradiated films were characterized by UV-Vis spectrophotometer. The results show that the dose sensitive and the linear range of irradiated films were increased considerably with increase of MMT concentration from 1 to 5 mM. The dose response of dyed PVA film changed substantially with changing relative humidity (12-74%) as well as irradiation temperature (10-40 ℃). The absorbance of the unirradiated films does not change up to 10 days in dark while a significant increase in their absorbance was reported for similar films under fluorescent light. The irradiated dosimeters that kept in dark showed a perfect stability for 54 days. It was found that no obvious impact of dose rate on the irradiated MMT-PVA film dosimeters.

음용수로부터 동화성 유기물질의 제거를 위한 생물학적 공정개발 (Development of biological processes for the removal of assimilable organic carbon from potable water)

  • 이민규;감상규
    • 생명과학회지
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    • 제10권1호
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    • pp.14-21
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    • 2000
  • 음요수 중의 유기탄소의 제거수단으로써 biofiltration법의 타당성을 검토하였다.NOM에서의 생분해 가능한 분율을 알아보기위하여 행하여 졌다. UV 조사량을 3가지로 달리하였을 경우에 회분식에서의 생분해능과 비교하였다. 생물여과 반응기 실험의 경우에 생분해 특성을 검토한 결과 EBCT, 순환비 및 유입농도등과 같은 운전피라미터들이 생물여과 반응기의 생분해능에 영향을 미침을 알 수있었다. 생물여과 반응기의 유출수에서의 UV/DOC의 비는 반응기에 공급되는 원료중의 UV/DOC비에 비해 증가하였으며, 이로부터 생분해에 의해 저거된 DOC는 UV에 의해 그다지 흡수되지 않는 물질임을 알 수있었다. 본 여눅를 통해 생분해 가능한 DOC의 부분을 제거하는데 있어서 생물여과공법이 효과적인 방법이라는 것을 알수있었으며 UV처리와 bilfiltration을 연계한 공정은 수처리 시설에서 유출수의 DOC농도는 낮추는데 효과적인 한가지 방안으로 사료되었다.

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납-티오황산 착물생성과 구리치환에 의한 미량 납(II)의 비색분석에 관한 연구 (Spectrophotometric Determination of Trace Lead(II) After Extraction of Lead-Thiosulfate Complex into Aliquat336-CHCl$_3$ and Replacement by Cu)

  • Lee, Seok-Ki;Joung, Chang-Ung
    • 한국환경보건학회지
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    • 제24권3호
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    • pp.1-5
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    • 1998
  • A spectrophotometric method was developed for the acidic solution stripped after an extraction of 0.5 to 2.5 ppm of Lead(II) from 50 mL of $Na_2S_2O_3$ solution into chloroform as the ion-pairs formed between their thiosulfate complexes and alkylamine, Aliquat336. Pb(II) in the stripped solution forms an complex with DDTC in pH 7.3 buffer solution, and was developed in yellow by copper replacement. The ydlow-colored solution have the maximum absorbance at 435 nm in the measurement of absorbance by UV-Visible spectrophotometer. The interference ions such as Fe(III), Hg (II), Al(III), Co, Cu, Ni, Zn, Ca, Sn, have great effects on the extraction, but they were overcomed by the usage of adequate masking agents before an extraction. At last, a good result was obtained in applying this method to synthetic water.

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