• 천문학회지
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• 제37권4호
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• pp.193-197
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• 2004

Anomalies in the far-infrared [C II] 158 ${\mu}m$ line emission observed in the central one-kiloparsec regions of spiral galaxies are reviewed. Low far-infrared intensity ratios of the [C II] line to the continuum were observed in the center of the Milky Way, because the heating ratio of the gas to the dust is reduced by the soft interstellar radiation field due to late-type stars in the Galactic bulge. In contrast, such low line-to-continuum ratios were not obtained in the center of the nearby spiral M31, in spite of its bright bulge. A comparison with numerical simulations showed that a typical column density of the neutral interstellar medium between illuminating sources at $hv {\~} 1 eV $ is $N_H {\le}10^{21}\;cm^{-2}$ in the region; the medium is translucent for photons sufficiently energetic to heat the grains but not sufficiently energetic to heat the gas. This interpretation is consistent with the combination of the extremely high [C Il]/CO J = 1-0 line intensity ratios and the low recent star-forming activity in the region; the neutral interstellar medium is not sufficiently opaque to protect the species even against the moderately intense incident UV radiation. The above results were unexpected from classical views of the [C II] emission, which was generally considered to trace intense interstellar UV radiation enhanced by active star formation.

• 한국세라믹학회지
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• 제45권6호
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• pp.345-349
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• 2008

$TiO_2$ coating ceramic tile for self-cleaning purpose was prepared by the precipitant dropping method using $TiCl_4$ as a precursor. $TiO_2$ film was formed on the ceramic tile by spray-coating technique and heat-treated at $500^{\circ}C$ for 1 h. The size and crystalline structure of $TiO_2$ particles were 15.3 nm and anatase phase. The outdoor exposure tests were conducted and the effects of outdoor exposure test conditions, such as exhaust concentration of contamination materials (test places), the UV light intensity (irradiation direction) and coating amounts of $TiO_2$ on the self-cleaning properties were investigated by the brightness measurements. As a results, self-cleaning property of $TiO_2$ coating tile was affected by the coating amount of $TiO_2$ however, not affected by the UV light intensity included in sun's ray (irradiation direction). $TiO_2$ coating ceramic tile can be utilized for exterior finishing materials because of self-cleaning property of $TiO_2$ coating tile.

• 한국환경과학회지
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• 제14권8호
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• pp.785-792
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• 2005

In order to reduce roadside and indoor air pollution for volatile organic compounds VOC), it may be necessary to apply photocatalyst-coated construction materials. This study evaluated the technical feasibility of the application of $TiO_2$ photocatalysis for the removal of VOC present in roadside or indoor air. The photocatalytic removal of five target VOC was investigated: benzene, toluene, ethyl benzene and o,m,p-xylenes. Variables tested for the current study included ultraviolet(UV) light intensity coating materials, relative humidity (RH), and input concentrations. Prior to performing the parameter tests, adsorption of VOC onto the current experiment was surveyed, and no adsorption was observed. Stronger UV intensity provided higher photocatalytic destruction(PCD) efficiency of the target compounds. For higher humidity, higher PCD efficiency was observed. The PCD efficiency depended on coating material. Contrary to certain previous findings, lower PCD efficiencies were observed for the experimental condition of higher input concentrations. The current findings suggested that the four parameters tested in the present study should be considered for the application of photocatalyst-coated construction materials in cleaning VOC of roadside or indoor air.

• 한국세라믹학회지
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• 제45권1호
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• pp.43-47
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• 2008

The photocatalyst of $TiO_2$ coated on a fly ash composites (TCF) was prepared from precipitant dropping method to remove the acetaldehyde by photocatalytic reaction. The TCF were characterized by crystal aize, crystal structure and specific surface area. The photodegradation of acetaldehyde has been investigated using a UV-illuminated fixed photocatalytic reactor with TCF catalyst and P-25 catalyst in gas phase. The effect of photodegradation reaction conditions, such as initial concentration of acetaldehyde, concentration of oxidant in mixed gas and the light intensity on the photodegradation of acetaldehyde were investigated. P-25 catalyst showed the highest photodegradation of acetaldehyde and anatase $TiO_2$ coated TCF showed higher decomposition rate than rutile coated TCF. The photodegradation rate of acetaldehyde increased with the decrease of flow rate, initial concentration of acetaldehyde ($C_i$) and water vapor, however, it was increased with the increas of UV light intensity. The optimum conditions were weight of TCF=10 g, flow rate=50 ml/min $C_i$=100 ppm, concentration of oxygen=20%, concentration of water vapor=100 ppm.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1994년도 추계학술대회 논문집 학회본부
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• pp.225-227
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• 1994

The second-order nonlinear optical effect, especially the second harmonic generation, in Langmuir-Blodgett(LB) films have get much attention over the past few years. For second harmonic generation(SHG) of the ultrathin organic films, the multilayer structure of the film should have the noncentrosymmetric arrangements of molecules. The Langmuir-Blodgett technique can result in the production of thin films of precisely controlled dimensions and structure. In this paper, n-octadecyl 4-(4'-nitrophenylazo)-1-naphthyl ether, ONNE(azohenzene derivative), was synthesized and the optical properties of ONNE was studied. Nonccntrosymmctric Z-type LB films of ONNE were prepared and SHG intensity of the film were measured. The structural characteristics of floating monolayer(L film) and LB film of ONNE were discussed with $\pi$-A isotherm. UV-visible absorption spectroscopy and spectroscopic ellipsometry. The polarized UV-visible absorption spectroscopy and SHO intensity suggest the molecular orientation in LB film.

• 한국의류학회지
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• 제46권3호
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• pp.390-406
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• 2022

This study aims to establish the optimal environmental conditions for storing textile products. Four textile products (cotton, wool, nylon, cotton/polyurethane) were used to produce experimental fabrics according to artificial contamination and washing conditions. Each fabric was subjected to three environmental conditions (A: 20-25℃/20% RH, B: 20-25℃/50% RH, C: 30-35℃/65% RH) for 4-12 weeks. Changes in textile characteristics include tensile strength, wrinkle recovery rate, and odor intensity. Results show that the change in tensile strength for the four test fabrics slightly decreased with a storage time of 4 to 12 weeks. The wrinkle recovery rate of the fabrics was the lowest under the C condition. UV exposure causes a substantial decrease in the tensile strength of the textiles. The change in odor characteristics was the highest for the odor intensity in the C condition. For storing textile products for sustainable management, it is desirable to maintain a temperature of 20 to 25℃ with a relative humidity of 50% RH or less and to provide ventilation in an enclosed storage space that can also block UV rays.

• 한국환경보건학회지
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• 제26권4호
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• pp.29-37
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• 2000

Fenton’s oxidation process is one of the most commonly applied processes to the wastewater which cannot be treated by conventional biological treatment processes. However, it is necessary to minimize the cost of Fenton’s oxidation treatment by modifying the treatment processes or other means of chemical treatment. So, as a method for the chemical oxidation of biorefractory or nonbiodegradable organic pollutants, the Photo-Fenton-Reaction which utilizes iron(11)salt. $H_2O$$_2$ and UV-light simultaneously has been proprosed. Therfore, the purpose of this study is to test a removal efficiency of dye-wastewater and treatment cost with Fenton’s and Photo-Fenton’s oxidation process. The Fe(11)/$H_2O$$_2$ reagent is referred to as the fenton’s reagent. which produces hydroxy radicals by the interaction of Fe(11) with $H_2O$$_2$. In this exoeriment, the main results are as followed; 1. The Fenton oxidation was most efficient in the pH range of 3-5. The optimal condition for initial reaction pH was 3.5 for the high CO $D_{Cr}$ & TOC-removal efficiency. 2. The removal efficiency of TOC and CO $D_{Cr}$ increased up to the molar ration between ferrate and hydrogen peroxide 0.2:1, but above that ratio removal efficiency hardly increased. 3. The highest removal efficiency of TOC and CO $D_{Cr}$ were showed when the mole ration of ferrate to hydrogen peroxide was 0.2:3.4. 4. Without pretreatment process, photo-fenton oxidation which was not absorbed UV light was not different to fenton oxidation. 5. And Fenton oxidtion with pretreatment process was similar to Fenton oxidation in the absence of coagulation, the proper dosage of F $e^{2+}$: $H_2O$$_2$ was 0.2:1 for the optimal removal efficiency of TOC or CO $D_{Cr}$ .6. Also, TOC & CO $D_{Cr}$ removal efficiency in the photo-fenton oxidation with pretreatment was increased when UV light intensity enhanced.7. Optimum light intensity in the range from 0 to 1200 W/$m^2$ showed that UV-intensity with 1200W/$m^2$ was the optimum condition, when F $e_{2+}$:$H_2O$$_2$ ratio for the highest decomposition was 0.2:2.5.EX>$_2$ ratio for the highest decomposition was 0.2:2.5.

• 한국진공학회지
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• 제20권3호
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• pp.211-216
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• 2011

본 연구에서는 수열합성법으로 성장시킨 정렬된 산화아연 나노로드의 성장온도에 따른 구조적, 광학적 특성이 조사되었다. Zinc nitrate ($Zn(NO_3)_2$)와 hexamethylenetetramine가 전구체로 사용되었으며 40 nm 두께의 산화아연 버퍼막이 증착된 실리콘 (100) 기판이 사용되었다. 산화아연 나노로드는 $55^{\circ}C$에서 $115^{\circ}C$까지의 성장 온도에서 40 nm 산화아연 버퍼레이어 위에 성장되었다. 결과 분석을 위하여 FE-SEM, XRD, PL 방법 등이 사용되었다. 분석 결과, 잘 정렬된 산화아연 나노로드가 모든 샘플에서 관찰되었다. $95^{\circ}C$ 이하의 증착 온도에서 성장된 산화아연 나노로드의 끝부분은 평평하였으며, $115^{\circ}C$의 증착 온도에서 성장된 산화아연 나노로드의 끝부분은 날카로운 바늘모양의 형태를 나타내었다. 또한 $115^{\circ}C$의 증착 온도에서 비평형 성장때문에 엉킨 나노 구조물이 부분적으로 생성되었다. 성장 온도는 산화아연의 구조적, 광학적 특성에 영향을 미칠 수 있다. 구조적 특성의 경우 성장 온도가 $75^{\circ}C$까지 증가함에 따라 XRD (002) 피크 세기가 증가했고, 성장온도가 $115^{\circ}C$까지 계속적으로 증가함에 따라 피크의 크기는 다시 감소하였다. 광학적 특성에서는, 성장 온도가 증가함에 따라 가시광선 영역 피크 세기에 대한 UV 피크 세기 비율이 증가하였고, $95^{\circ}C$의 성장온도에서는 가장 큰 UV 피크의 세기를 얻을 수 있었다.

• International Union of Geodesy and Geophysics Korean Journal of Geophysical Research
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• 제21권1호
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• pp.31-46
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• 1993

대기 가열율과 복사속의 연직 분포를 계산하기 위하여 two-stream/delta-Eddington 근사법을 이용한 복사전달모형이 개발되었다. 이 모형의 결과를 ICRCCM의 결과와 비교하므로써 모형의 완성도를 평가하였다. 이 모형은 정확성 뿐 아니라 경제적인 면에서도 태양복사를 계산하는데 적합한 것으로 증명되었다. 대기 꼭대기에서의 복사속과 지표에서의 복사속 간의 관계를 비교하므로써 자외선 B 영역(UV-B; 280-320nm)의 특징들이 검토되었다. 이 영역에서는 강한 오존 흡수가 있어 UV-B의 관계가 2차 함수로 나타난다. 또한, 성층권 오존 감소와 화산 폭발로 기인한 성층권 에어로졸 안개가 UV-B 복사에 미치는 영향을 다양한 태양의 천정각에서 조사했다. 태양의 천정각이 증가함에 따라 지표 UV-B도 증가하였다. 성층권 에어로졸은 후방 산란을 통해 행성 반사도를 증가시켰다. 행성 반사도는 에어로졸 효과로 인해 태양의 천정각이 증가함에 따라 증가한다. 그러나, 행성 반사도의 변화가 태양의 천정각 변화에 따라 민감하게 나타나지는 않는다. 이것은 태양의 천정각이 클 때 에어로졸의 산란 효과가 상대적으로 긴 복사 경로에서 포화되었기 때문일 것이다. 끝으로, 화산 폭발에서 비롯된 성층권 에어로졸이 지표 UV-B 복사 강도에 미치는 지역적 영향이 추정되었다. 고위도에서는 에어로졸의 광자 포획(photon trap)이나 일몰 효과로 복사 강도가 증가하는 반면 저위도에서는 감소한다. 고위도에서 에어로졸의 산란과 오존 흡수는 지표 UV-B 복사의 최대 증가는 봄 기간 중에 양 반구 모두 중위도에서 나타난다.

• Macromolecular Research
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• 제17권6호
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• pp.403-410
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• 2009

Cytotoxicity is a severe problem of cadmium sulfide nanoparticles(CSNPs) for use in biological systems. In the present study, mercaptoacetic acid-coated CSNPs were conjugated with bovine serum albumin (BSA) to improve biocompatibility. The surface properties of the CSNPs and albumin-conjugated CSNPs (ACSNPs) were characterized by XRD, UV, FTIR, EA, TEM and DLS. Human breast cancer cells (KB cells) were then cultured in the presence of the nanoparticles to evaluate the cytotoxicity of CSNPs and ACSNPs. Finally, the fluorescence intensity of the nanoparticles' aqueous solution was examined using a fluorescence spectrometer. The results showed that the cell compatibility and fluorescence intensity of ACSNPs were higher than those of CSNPs. The strongly luminescent features of the biocompatible ACSNPs are promising for use in biological fields such as cellular labeling, intracellular tracking and molecular imaging.