• Title/Summary/Keyword: UV Efficiency

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Electrochemical Properties of Dye-sensitized Solar Cells with Improving the Surface Structure (표면형상 변화에 따른 염료감응 태양전지의 전기화학적 특성)

  • Zhao, Xing Guan;Jin, En Mei;Gu, Hal-Bon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.25 no.2
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    • pp.153-158
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    • 2012
  • We use UV(ultraviolet)-$O_3$ treatment to increase the surface area and porosity of $TiO_2$ films in dye-sensitized solar cells (DSSCs). After the UV-$O_3$ treatment, surface area and porosity of the $TiO_2$ films were increased, the increased porosity lead to amount of dye loading and solar conversion efficiency was improved. Field emission scanning electron microscopy images clearly showed that the nanocrystalline porosity of films were increased by UV-$O_3$ treatment. The Brunauer, Emmett, and Teller surface area of the $TiO_2$ films were increased from $0.71cm^2/g$ to $1.31cm^2/g$ by using UV-$O_3$ treatment for 20 min. Also, UV-$O_3$ treatment of $TiO_2$ films significantly enhanced their solar conversion efficiency. The efficiency of the films without treatment was 4.9%, and was increased to 5.6% by UV-$O_3$ treatment for 20 min. Therefore the process enhanced the solar conversion efficiency of DSSCs, and can be used to develop high sensitivity DSSCs.

A Study on the Dye Wastewater Treatment Using TiO2 Photocatalyst/Ozonation (광촉매/오존을 이용한 염색폐수처리에 관한 연구)

  • Kim, Chang-Kyun;Chung, Ho-Jin;Kim, Jong-Suk
    • Journal of Korean Society of Water and Wastewater
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    • v.21 no.6
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    • pp.663-670
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    • 2007
  • This study was performed to provide basic information for evaluating the efficiency and applicable extent of photocatalysis and ozonation for the treatment of dye wastewater. The treatability of dye wastewater by $UV/TiO_2$ and $UV/TiO_2/O_3$ advanced oxidation process (AOP) was investigated under various conditions. The experiments were conducted in a batch reactor of 50 liters equipped with twelve UV Lamps of 16W. In $UV/TiO_2$ AOP, the removal efficiency of TCODMn and Color increased to 58% and 67% respectively with increasing UV intensity. Also, The removal efficiency of TCODMn and Color increased to 97% and 99% respectively with increasing $H_2O_2$. Acid area was more efficient than neutral and alkalic areas in wastewater treatment, and pH 5 was the most effective and the treatment efficiency continually increased as the amount of photocatalyst was increased. When the photocatalyst was increased, TCODMn was removed faster than Color.

UV emission characteristics of Ne+$N_2$ gas-mixture discharges in AC Plasma Display Panel

  • Baek, Byung-Jong;Hong, Sang-Min;Choi, Kyung-Cheol
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.586-589
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    • 2002
  • The Ultra Violet(UV) emission characteristics of Neon + Nitrogen gas-mixture discharge was investigated in AC plasma display panel. The firing voltage of Ne+$N_2$ gas-mixture discharge increased with increasing nitrogen concentration. The UV intensity emitted from the gas discharge also increased with increasing nitrogen concentration. The UV efficiency increase with increasing $N_2$ partial pressure at low $N_2$ concentration, and then UV efficiency is saturated at high $N_2$ concentration.

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Removal of taste and odor causing compounds in drinking water using Pulse UV System (Pulse UV 장치를 이용한 먹는 물의 이취미 유발물질 제거효과에 관한 연구)

  • Sohn, Jin-Sik;Park, Soon-Ho;Jung, Eui-Taek
    • Journal of Korean Society of Water and Wastewater
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    • v.26 no.2
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    • pp.219-228
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    • 2012
  • Problems due to the taste and odor in drinking water are common in treatment facilities around the world. Taste and odor are perceived by the public as the primary indicators of the safely and acceptability of drinking water, and are mainly caused by the presence of two semi-volatile compounds-2-methylisoborneol(2-MIB) and geosmin. Conventional treatment processes in water treatment plants, such as coagulation, sedimentation and chlorination have been found to be ineffective for the removal of 2-MIB and geosmin. Pulse UV system is a new UV irradiation system that is a non-mercury lamp-based alternative to currently used continuous wave systems for water disinfection. This study shows pulse UV system to be effective in treatment of these two compounds. Geosmin removal efficiency of UV process alone achieved approximately 70% at 10sec contact time. 2-MIB removal efficiency of UV only process achieved approximately 60% at 10sec contact time. The addition of $H_{2}O_{2}$ 7mg/L increased geosmin and 2-MIB removal efficiency upto approximately 94% and 91%, respectively.

Removal of PCBs in Aqueous Phase in Ultraviolet (UV), Ultrasonic (US), and UV/US Processes (자외선 및 초음파 공정에 의한 수용액 상의 PCBs 분해)

  • Lee, Dukyoung;Son, Younggyu
    • Journal of Soil and Groundwater Environment
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    • v.26 no.4
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    • pp.1-7
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    • 2021
  • The removal of PCBs (Polychlorinated biphenyls) in aqueous phase was investigated in the ultraviolet (UV) process, ultrasonics (US) process and ultraviolet/ultrasonic (UV/US) process using PCB No.7 and Aroclor 1260. For PCB No.7 relatively high removal efficiency over 90% was obtained during 20 min in the UV process and UV/US process. On the other hand, lower removal efficiency of 50 - 70% was achieved for it consisted of individual congeners of PCBs containing 3~8 of chlorine atom. It was found that the dechlorination reaction (the photolytic cleavage of C-Cl bond) was considered as a main removal mechanism in the UV process while PCBs were removed by cavitation-induced radical reaction in the US process. No significant dechlorination occurred in the US process. Consequently, it was suggested that the UV process or UV/US process was applicable for the removal of PCBs in aqueous phase in terms of the removal efficiency and operation time. In addition, the application of saturating gas such as Ar and Air could be considered to control redox condition and enhance the severity of acoustic cavitation for the removal of PCBs.

Study on Characteristic by ITO Surface Treatment and Cathode Change of Organic Light Emitting Diodes (ITO 표면 처리와 음전극 변화에 따른 OLEDs의 특성 연구)

  • Kim, Doo-Seok;Jang, Yoon-Ki;Kwon, Young-Soo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.18 no.12
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    • pp.1143-1147
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    • 2005
  • In this study, we report an improved efficiency of Organic light emitting diodes(OLEDs), using $UV/O_3$ treated anode and different cathode. We investigated the efficiency of OLEDs by $UV/O_3$ treatment of ITO surface. We Performed $UV/O_3$ treatment and found that $UV/O_3$ treatment enhanced the performance of OLEDs. The fundamental structure of the OLEDs was ITO $anode/{\alpha}-NPD/Alq_3/Al$ or Li:Al cathode. The Li:Al can improve the OLEDs efficiency dramatically in cathode because it has lower work function than Al. Current-voltage, Luminance-voltage characteristics and luminance efficiency were measured at room temperature.

A Study on the degradation of Lindane in water by a Photo-Fenton process and a UV/$H_2O_2$ process (Photo-Fenton 공정과 UV/$H_2O_2$ 공정을 이용한 Lindane의 분해특성 비교 연구)

  • Lee, Ju-Hyun;Choi, Hye-Min;Kim, Il-Kyu
    • Journal of Korean Society of Water and Wastewater
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    • v.24 no.1
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    • pp.109-117
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    • 2010
  • In the present study, the degradation characteristics of Lindane by Advanced Oxidation Processes(UV/$H_2O_2$, Photo-Fenton process) were studied. The degradation efficiency of Lindane in aqueous solution was investigated at various initial pH values, Fenton's reagent concentrations and initial concentrations of Lindane. GC-ECD was used to analyze lindane. Lindane has not been degraded without application of AOPs over two hours. But, approximately 5% of lindane was degraded with UV or $H_2O_2$ alone. Lindane with UV/$H_2O_2$ process showed approximately 7% higher removal efficiency than $H_2O_2$ process. In the UV/$H_2O_2$ process, the pH values did not affect the removal efficiency. The optimal mole ratio of $H_2O_2/Fe^{2+}$ for lindane degradation is about 1.0 in Photo-Fenton process. Also, the experimental results showed that lindane removal efficiency increased with the decrease of initial concentration of lindane. Under the same conditions, the order lindane of removal efficiency is as following : Photo-Fenton process > UV/$H_2O_2$ process > $H_2O_2$ process. In addition, intermediate products were identified by GC-MS techniques. Than PCCH(Pentachlorocyclohexene) was identified as a reaction intermediate of the Photo-Fenton process.

Treatment of an Authentic Textile-dyeing Wastewater Utilizing a Fluidized Biofilter and Hybrid Recirculating System Composed of the Fluidized Biofilter and a UV/photocatalytic Reactor (실제 혼합염색폐수의 유동상 시스템을 활용한 미생물처리와 하이브리드 재순환시스템처리)

  • Lee, Eun Ju;Lim, Kwang-Hee
    • Korean Chemical Engineering Research
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    • v.53 no.1
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    • pp.71-77
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    • 2015
  • A fluidized biofilter was filled with Pseudomonas sp. and Bacillus cereus/thuringiensis-fixed waste-tire crumb media and was run to treat authentic textile-dyeing wastewater mixed with alkaline polyester-weight-reducing wastewater. As a result, its removal efficiency of $COD_{Cr}$ and color were 75~80% and 67%, respectively. In addition, upon constructing hybrid-recirculating system composed of the fluidized biofilter and a 450 W-UV/photocatalytic reactor, only fluidized biofilter was run bypassing UV/photocatalytic reactor at stage I. Subsequently, the hybrid system was continuously run at stage II-i, ii and iii. At stage II-i, the total removal efficiency of $COD_{Cr}$ was enhanced to be 80~85%, compared to 75% at stage I, owing to 20~30% removal efficiency of the UV/photocatalytic reactor. However, at stage II-i, the total removal efficiency of color was enhanced to be 65~70%, compared to 45~65% at stage I, even though the removal efficiency of the UV/photocatalytic reactor was tantamount to merely 0~5%. As far as the removal efficiency of fluidized biofilter of the hybrid-recirculating system is concerned, its removal efficiency of color was enhanced by the synergy effect of the hybrid-recirculating system unlike $COD_{Cr}$. Besides, despite of the increase of hybrid-recirculating system-recycle ratio, the deactivation of photo-catalytic activity was scarcely observed to eliminate the color while its irreversible deactivation was observed to eliminate $COD_{Cr}$.

A Study on the Swine Wastewater Treatment Using UV/TiO2/H2O2 (UV/TiO2/H2O2를 이용한 축산폐수처리에 대한 연구)

  • Kim, Chang-Kyun;Chung, Ho-Jin
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.26 no.3B
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    • pp.321-327
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    • 2006
  • This study was performed to provide basic information for evaluating the efficiency and applicable extent of photocatalysis for the treatment of swine wastewater. Acid area was more efficient than neutral and alkalic areas in wastewater treatment, and level of pH3 was the most effective and the treatment efficiency continually increased as the amount of photocatalyst was increased. When the photocatalyst was increased, $TCOD_{Mn}$ was removed faster than chromaticity. Pollutants were more effectively eliminated with both UV light illumination and $TiO_2$ than with either UV or $TiO_2$ alone. The removal efficiency was increased with the addition of $H_2O_2$ as an oxidant, but the removal efficiency was decreased with over an dosage of $H_2O_2$. The optimal dosage of $H_2O_2$ was 200 mg/L. Continuous injection of $H_2O_2$ was required for effective oxidation.

Evaluation of inactivation kinetics on pathogenic microorganisms by free chlorine/UV hybrid disinfection system (전해 염소수/자외선 결합 시스템을 이용한 병원성 미생물의 불활성화 키네틱스 평가)

  • Seo, Young-Seok;Kim, Aerin;Cho, Min
    • Journal of Korean Society of Water and Wastewater
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    • v.33 no.5
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    • pp.379-388
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    • 2019
  • Chlorination and UV illumination are being widely applied to inactivate a number of pathogenic microbials in the environment. Here, we evaluated the inactivation efficiency of individual and combined treatments of chlorination and UV under various aqueous conditions. UV dosage was required higher in waste water than in phosphate buffer to achieve the similar disinfecting efficiency. Free chlorine generated by electrolysis of waste water was abundant enough to inactivate microbials. Based on these, hybrid system composed of sequential treatment of electrolysis-mediated chlorination and UV treatment was developed under waste water conditions. Compared to individual treatments, hybrid system inactivated bacteria (i.e., E. coli and S. typhimurium) and viruses (i.e., MS-2 bacteriophage, rotavirus, and norovirus) more efficiently. The hybrid system also mitigated the photo re-pair of UV-driven DNA damages of target bacteria. The combined results suggested the hybrid system would achieve high inactivation efficiency and safety on various pathogenic microbials in wastewater.