• Title/Summary/Keyword: UV$^{254}$

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Effect of Advanced Treatment Process for Residual Chlorine Decay and THM Formation in Water Distribution System (고도처리공정이 관로 내 잔류염소 감소 및 THM 생성에 미치는 영향)

  • Lee, Doo-Jin;Kim, Young-Il;Kim, Sung-Su;Lee, Kyung-Hyuk;Park, Hyun-A
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.4
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    • pp.419-424
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    • 2007
  • According to increase of consumer's desire for clean tap water, advanced treatment processes include with membrane, ozone, and granular activated carbon(GAC) were introduced. In order to evaluate the effect of advanced treatment processes for residual chlorine decay and trihalomethane(THM) formation in water distribution system, dissolved organic matter(DOC) removal of each advanced treatment process was investigated. The residual chlorine decay and THM formation using bottle tests were also evaluated. $UV_{254}$ removal in all advanced treatment was better than DOC removal. Especially, DOC by ozone treated was removed as 4% in contrast with sand filtered water, but $UV_{254}$ was removed about 17%. This result might be due to convert from hydrophobic DOC to hydrophilic DOC by ozonation. Ozone/GAC process was most effective process for DOC removal. The residual chlorine decay constants in treated water by sand filtration, ozonation, GAC adsorption, and ozone/GAC processes were 0.0230, 0.0307, 0.0117 and 0.0098 $hr^{-1}$, respectively. The sand filtered water was produced 81.8 ${\mu}g/L$ of THM after 190 hours of reaction time, as the treated water by ozone, GAC, and Ozone/GAC was less produced 6.0, 26.2, 30.3% in contrast with sand filtered water, respectively. Consequently, the durability of residual chlorine and reduction of THM formation were improved by advanced treatment processes.

Effect of Water Treatment for Nakdong River Raw Water by Continuous Ozone Process (연속식 오존처리공정을 이용한 낙동강 상수원수의 정수처리 효과)

  • Lim, Young-Sung;Kang, Gwan-Ho;Lee, Hong-Jae;Seo, Dong-Cheol;Park, Moon-Su;Heo, Jong-Soo;Cho, Ju-Sik
    • Korean Journal of Environmental Agriculture
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    • v.21 no.3
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    • pp.189-196
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    • 2002
  • This study was carried out to evaluate the pollutant removal efficiencies of the advanced drinking water treatment using ozonation process. For raw water, Nakdong River was used. By conducting continuous ozonation experiments, the following results were obtained. Efficiency of water treatment was enhanced with increase in ozone dosage. When ozone dosage of 3 mg/L was used, preozonation ot raw water reduced TDOC, ADOC, A &BDOC and NRDOC as much as 0.6 mg/L, 0.2 mg/L, 0.1 mg/L and 1.0 mg/L, respectively. On the other hand, content of BDOC increased at the level of 0.8 mg/L. Ratio of UV254 absorbance to DOC content by the preozonation with 1, 3 and 5 mg/L dosage were 0.048, 0.044 and 0.037, respectively. In case of postozonation, it were 0.018, 0.015 and 0.012, respectively. When the ratios of consumpted ozone content to 1 mg of initial DOC were 1.5 and 2.3 in preozonation and postozonation treatment, respectively, the highest DOC removal rates of 25% and 32% were obtained by the continuous ozonation.

Effect of GAC Packing Mass in Hybrid Water Treatment Process of PVdF Nanofibers Spiral Wound Microfiltration and Granular Activated Carbon (PVdF 나노섬유 나권형 정밀여과와 입상 활성탄의 혼성 수처리에서 활성탄 충진량의 영향)

  • Kyung, Kyu Myung;Park, Jin Yong
    • Membrane Journal
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    • v.27 no.1
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    • pp.68-76
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    • 2017
  • Flat membrane with $0.4{\mu}m$ pore size was prepared with PVdF (polyvinylidene fluoride) nanofiber, which has the advantages such as excellent strength, chemical resistance, non-toxicity, and incombustibility. The spiral wound module was manufactured with the flat membrane and a woven paper. Hybrid water treatment process was composed of the PVdF nanofibers spiral wound microfiltration and granular activated carbon (GAC) adsorption column. Effect of GAC packing mass was investigated by comparing the case of recycling or discharging the treated water using the synthetic solution of kaolin and humic acid. After each filtration experiment, water back-washing was performed, and recovery rate and filtration resistances were calculated. Also, effect of GAC adsorption was compared by measuring turbidity and $UV_{254}$ absorbance. As a result, there was no effect of GAC packing mass on turbidity treatment rate; however, the treatment rate of $UV_{254}$ absorbance was 0.7~3.6% for recycling the treated water, and increased to 3.2-5.7% for discharging the treated water. In the case of recycling the treated water, reversible filtration resistance ($R_r$) and irreversible filtration resistance ($R_{ir}$) trended to decrease as increasing GAC packing mass; however, total fitration resistance ($R_t$) was almost constant, and recovery rate of water back-washing trended to increase a little.

A study on the removal characteristics of bisphenol in water by coagulation (응집에 의한 Bisphenol A의 제거특성)

  • Park, Jihyun;Shin, Daeyewn;Park, Sunku
    • Analytical Science and Technology
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    • v.19 no.2
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    • pp.181-187
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    • 2006
  • This study was carried to survey the removal characteristics of BPA using coagulation process by PAC and PAHCS. BPA removal for PAC and PAHCS was 20.4 with 8.7 Al mg/L and 6.8 Al mg/L, respectively. Removal of BPA was lower than $UV_{254}$ and DOC but removal characteristics were similar. BPA removal for PAC and PAHCS was most high in pH 6.5 and 7.0 respectively. The time for removal by mixing time was 40 min in PAC and 30 min in PAHCS. When powdered activated carbon 50 mg/L was added in coagulation process, a high remove of BPA (61%) was noticed. Specially BPA was highly increase powdered activated carbon 5 mg/L alone. These results will be appliable in the conventional water treatment plants for improvement of water treatment system.

Synthesis of New Bicyclic Aziridines Containing Chalcone Analogs and Investigation of Their Photochromic Properties

  • Besharati-Seidani, Tayebeh;Mahmoodi, Nosrat O.
    • Bulletin of the Korean Chemical Society
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    • v.34 no.3
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    • pp.875-883
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    • 2013
  • Ten new derivatives of 1,3-diazabicyclo[3.1.0]hex-3-enes linked via ether linkage to chalcones were synthesized and characterized by UV, FT-IR, $^1H$ NMR and $^{13}C$ NMR spectral techniques. The spectra of all synthesized compounds, confirmed structure-photochromic behavior relationships (SPBR) both in solution or in solid state by irradiation under UV light at 254 nm. In other efforts for first time photochromic behavior of ketoaziridines has been investigated.

$TiO_2$ 광촉매를 이용한 LAS의 제거에 관한 연구

  • 김효정;오윤근;류성필
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2001.11a
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    • pp.82-83
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    • 2001
  • LAS(Linear Alkylbenzene sulfonate)를 $TiO_2$ 광촉매를 사용하여 분해시켰을 때 실험조건에 변화를 주어 반응시간에 따른 제거효율을 비교하는 실험을 수행하였다. pH 변화에 의해서는 산성과 중성 영역이 알카리성 영역에 비해 제거효율이 우수하였으며, 파장영역은 254nm > 312nm > 365nm의 순서로 나타났다. UV/$TiO_2$ 공정과 UV/$TiO_2$$H_2O_2$공정을 비교해보면 $H_2O_2$의 첨가에 의한 제거효율이 다소 우수함을 알 수 있었다.

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Effects of Radioprotective Ginseng on Protein UV induced Sister Chromatid Exchanges

  • Kim, Choon-Mi;Choi, Jeong-Eun
    • Archives of Pharmacal Research
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    • v.11 no.2
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    • pp.93-98
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    • 1988
  • To elucidate the reaction mechanism of ginseng protein on its antiradiation activity, its effects were studied on sister chromatid exchanges (SCE) induced by UV irradiation in CHO-KI cells. When cells were irradiated with 254 nm UV light at the dose of 0 to 8erg$\textrm{mm}^2$, the frequencies of CSE were increased more than two fold. However, when radio protective ginseng protein was added to the cells before the after UV irradiation, SCE frequencies were decreased significantly at all UV doses in both cases with no significant differences. As the amount of ginseng protein was varied from 100 to 500 .mu.g/ml, with UV irradiation at 60 erg$\textrm{mm}^2$, SCE frequencies dropped sharply at the first two concentrations and then reached a sort of plateau in both cases of pre-and post-treatment. When the ginseng protein was treated alone without UV irradiation, there were no changes in SCE frequencies no matter when the protein was added. There results suggest that the ginseng protein could reduced DNA damages, which may play an important role in the reaction mechanism of radioprotective activity of the protein.

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Decolorization of Rhodamine B Using UV/$TiO_2$ System (UV/$TiO_2$ 시스템을 이용한 Rhodamine B의 색도 제거)

  • 박영식;나영수;안갑환
    • Journal of Environmental Health Sciences
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    • v.28 no.5
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    • pp.59-64
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    • 2002
  • The photocatalytic decolorization of the Rhodamine B (RhB) was studied using a UV/TiO$_2$ reactor. Yakuri titanium dioxide(anatase) was used as the suspended photocatalyst and proved to be effective for decolorization irradiated with UV light (254 mm). The photocatalyzed dioxide concentrations, light intensity and air flow rates. In 0.01 mM RhB, color could be completely photodegraded after 3 hours. Absorption spectrum of an aqueous solution containing RhB showed a continued diminution of the RhB concentration in the solution bulk : concomitantly, no new absorption peaks appeared. This confirmed the decolorization of RhB, i.e., the break up of the chromopore. The optimum loaded titanium dioxide for the decolorization was 0.75 g/(equation omitted). The light intensity showed exponential decay with distance. The decay of light intensity of RhB solution showed different tendency from TiO$_2$. These results suggested that the photocatalytic decolorization of dyes may be available method for decolorizing in wastewater.

Development of a Wastewater Detection System using UV Fluorescence Reaction (자외선 형광반응을 이용한 오폐수 검출장치 개발)

  • Kim, ByoungChang
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.19 no.12
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    • pp.28-33
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    • 2020
  • Oil-related products have provided many benefits to humanity, but are significant contributors to environmental pollution. As per the International Maritime Organization (IMO) requirements, in the future, all ships must be equipped with filtering equipment and 5ppm bilge alarms that can help remove or reduce oil products during wastewater treatment. In this study, a UV fluorescence measurement system that can detect the oil components in wastewater containing both water and oil was developed. When an excitation wavelength of 254nm was used to irradiate the wastewater, the amount of UV at a divergent wavelength of 360nm was measured to measure the contamination. Based on the measurement, it was concluded that this system is suitable for use as the 5ppm bilge alarm proposed by IMO.

Degradation of Formaldehyde in Indoor Air Quality by $TiO_2$ Sol Coated Wall Paper ($TiO_2$ 광촉매 졸(Sol)의 벽지코팅에 의한 실내공기질에서의 포름알데히드 분해)

  • An, Sang-Woo;Cho, Il-Hyoung;Park, Jae-Hong;Chang, Soon-Woong;Kim, Young-Gyu
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.8
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    • pp.872-877
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    • 2006
  • It has been concerned about the indoor air contaminants because of the hours spend in indoor space. These contaminants are emitted from various indoor facilities. Therefore, even though there concentrations are very low, adverse effects can't be ignored. However, treatment technologies are insufficient to deal with these contaminants. For this reason, the objective of this study was to investigate the feasibility of artificial ultraviolet(UV) detoxification using $TiO_2$ system for degrading formaldehyde contaminated indoor air. The experiment was also performed to investigate the formaldehyde removal effect of fluorescence lamp as an alternative UV light source because it is used in indoor as a light source. The results presented demonstrated that as the $TiO_2$ dosage is more and the reaction area is wider, the photocatalytic degradation rate does more enhanced. Degradation of TCE was more rapid used in $UV_{254}$ lamp than in fluorescence lamp. However, if it is operated during enough time, it will be able to remove the considerable quantity of TCE in case of using fluorescence lamp.