• 제목/요약/키워드: UF4

검색결과 212건 처리시간 0.024초

Ultra- and Nano-Filtration Process Optimization of Isoflavones and Oligosaccharides from Sunmul

  • Kim, Woo-Jung;Kim, Hak-Hyun;Yoo, Sang-Ho
    • Food Science and Biotechnology
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    • 제14권3호
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    • pp.380-386
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    • 2005
  • Optimal conditions of ultrafiltration (UF) and nanofiltration (NF) were investigated for separation and concentration of isoflavones and oligosaccharides from Sunmul. Levels of COD, BOD, and suspended solids (SS) in UF and NF permeates were also determined to evaluate effectiveness of these processes for reducing water pollution. Optimal UF operation conditions to achieve minimal fouling and maximal flux were $33-34^{\circ}C$ operating temperature and 2.3-2.4 bar trans-membrane pressure. Recovery yields of isoflavones and oligosaccharides in UF retentate were 11.49-28.16% and 12.77-27.57%, respectively. Increase in volumetric concentration factor (VCF) resulted in more functional compounds of isoflavones and oligosaccharides passing through UF membrane. Total isoflavone and oligosaccharide yields decreased by 3% as VCF increased from 6.0 to 8.0 and from 8.0 to 10.0, while decreased significantly by 10% as VCF decreased from 4.0 to 6.0. Optimal NF operating conditions were 192-195 psig operating pressure at $30-33^{\circ}C$. Total yields of isoflavones and oligosaccharides significantly decreased at VCF 8.0, whereas did not decrease up to VCF 6.0 during NF operation. Therefore, VCF 6.0 was recommended for economical process. COD and BOD decreased by more than 98% after NF process, and SS were not detected after UF process. These results indicated sequential filtration process was useful for separation of isoflavones and oligosaccharides from Sunmul and for reducing water contaminants.

응집-여과-중화 공정에 의해 전처리된 아크릴 폐수의 한외여과와 역삼투 모듈 조합 공정에의 적용 (Application in Ultrafiltration and Reverse Osmosis Module Set with Acrylic Wastewater Pretreated by Coagulation-Filtration-Neutralization Process)

  • 이광현;강병철;이종백
    • 멤브레인
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    • 제18권1호
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    • pp.1-6
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    • 2008
  • 아크릴 폐수를 응집-여과-중화의 전처리 공정에 적용하여 막오염 인자를 최소화 한 후 UF/RO 공정에 적용하였다. 막의 형태 및 종류에 따라 한외여과 및 역삼투 모듈을 조합을 이루어 전처리 수를 온도 및 압력변화에 따라 적용하여 분리 특성을 고찰하였다. 투과 플럭스는 모듈 set 1의 UF모듈보다 모듈 set 4의 UF모듈의 투과량이 약 $2{\sim}3$배 더 많이 배출됨을 확인하였다. 최종적인 투과량은 관형모듈과 조합을 이룬 모듈 set 2와 모듈 set 3이 좋은 결과를 나타내었다. 모든 UF 모듈에서 TDS, T-N 및 COD의 제거 효율은 온도 및 압력변화에 영향을 받지 않고 제거 효율 또한 낮음을 알 수 있었다. RO모듈에서 TDS, T-N 및 COD가 우수한 제거 효율을 보였다. 아크릴 폐수의 최종적인 수질결과는 공장폐수의 배출 허용기준을 만족하였고, 막모듈 조합은 폐수의 재활용 가능성을 확인할 수 있었다.

응집-UF 전처리 공정이 압력지연삼투 공정에 미치는 영향 (Effects of coagulation-UF pretreatment on pressure retarded osmosis membrane process)

  • 고길현;김수현;김정선;강임석
    • 상하수도학회지
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    • 제35권4호
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    • pp.285-292
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    • 2021
  • Osmotic power is to produce electric power by using the chemical potential of two flows with the difference of salinity. Water permeates through a semipermeable membrane from a low concentration feed solution to a high concentration draw solution due to osmotic pressure. In a pressure retarded osmosis (PRO) process, river water and wastewater are commonly used as low salinity feed solution, whereas seawater and brine from the SWRO plant are employed as draw solution. During the PRO process using wastewater effluent as feed solution, PRO membrane fouling is usually caused by the convective or diffusive transport of PRO which is the most critical step of PRO membrane in order to prevent membrane fouling. The main objective of this study is to assess the PRO membrane fouling reduction by pretreatment to remove organic matter using coagulation-UF membrane process. The experimental results obtained from the pretreatment test showed that the optimum ferric chloride and PAC dosage for removal of organic matter applied for the coagulation and adsorption process was 50 mg/L as FeCl3 (optimum pH 5.5). Coagulation-UF pretreatment process was higher removal efficiency of organic matter, as also resulting in the substantial improvement of water flux of PRO membrane.

Effects of Reaction pH and Hardener Type on Reactivity, Properties, and Performance of Urea-Formaldehyde (UF) Resin

  • Park, Byung-Dae;Kim, Yoon Soo;So, Won Tek;Lim, Kie Pyo
    • Journal of the Korean Wood Science and Technology
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    • 제30권3호
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    • pp.1-11
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    • 2002
  • This study was conducted to investigate the effects of reaction pH conditions and hardener types on the reactivity, chemical structure and adhesion performance of UF resins. Three different reaction pH conditions, such as traditional alkaline-acid (7.5 → 4.5), weak acid (4.5), and strong acid (1.0), were used to synthesize UF resins which were cured by adding three different hardeners (ammonium chloride, ammonium citrate, and zinc nitrate) to measure adhesion strength. Fourier transform infrared (FT-IR) and carbon-13 nuclear magnetic resonance (13C-NMR) spectroscopies were employed to study chemical structure of the resin prepared under three different reaction pH conditions. Adhesion strength of the resins cured with three different hardeners was determined with lap shear specimens in tension. The gel time of UF resins decreased with an increasing in the amount of both ammonium chloride and ammonium citrate added in the resins. However, the gel time increased for zinc nitrate. Both FT-IR and 13C-NMR spectroscopies showed that the strong reaction pH condition produce uronic structures in UF resin, while both alkaline-acid and weak acid conditions produce quite similar chemical species in the resins. The maximum adhesion strength was occurred with the resin prepared under strong acid pH condition. However, this study indicated that the weak acid reaction condition provide a balance between increasing resin reactivity and improving adhesion strength of UF resin. The measurement of formaldehyde emission from the panels bonded with the UF resins prepared is planned for future work.

막분리(NF, UF)를 이용한 자연유기물(NOM) 제거에 관한 연구(II) - NF, UF 운전특성과 HAA생성능 제거 -

  • 송양석;박용훈;조영관;조재원;박돈희
    • 한국생물공학회:학술대회논문집
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    • 한국생물공학회 2003년도 생물공학의 동향(XII)
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    • pp.334-338
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    • 2003
  • 막분리 공정을 모형시설에 도입 후 약 2년간에 걸쳐 막의 구성을 달리하여 운영하였으며, 원수 및 처리수의 수질특성을 조사하였다. 원수의 수질특성은 친수성 물질이 53%, 소수성 물질 28% 나머지는 반친수성물질로 구성된 것으로 조사되었으며, UF 및 NF 처리수의 분자량 분포를 조사한 결과 원수와 달리 큰 분자량을 갖는 부분이 제거된 것을 볼 수 있었다. UF와 NF의 막분리 공정운전 결과를 종합해 본 결과, UF막인 GH(2500Da)와 GM(8000Da) 경우 GM이 생산량 및 운전특성에서 GH에 비해 우수한 결과를 보여 주었으며, NF막인 HL$(150{\sim}300Da)$과 GM의 비교 운전한 결과 NF막인 HL의 유기물 제거 효과가 우수한 것을 보여 주고 있다. 그러나 UF막인 GM의 경우 MWCO가 8000Da로 NF막인 HL에 비해 큼에도 불구하고 유기물 제거 면에서 상당히 우수한 유기물 제거 효과를 보여 주었으며, 소독부산물의 생성능 평가에서도 50%이상의 양호한 제거 효과를 보여 주었다.

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Energy-efficient charging of sensors for UAV-aided wireless sensor network

  • Rahman, Shakila;Akter, Shathee;Yoon, Seokhoon
    • International Journal of Internet, Broadcasting and Communication
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    • 제14권4호
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    • pp.80-87
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    • 2022
  • Lack of sufficient battery capacity is one of the most important challenges impeding the development of wireless sensor networks (WSNs). Recent innovations in the areas of wireless energy transfer and rechargeable batteries have made it possible to advance WSNs. Therefore, in this article, we propose an energy-efficient charging of sensors in a WSN scenario. First, we have formulated the problem as an integer linear programming (ILP) problem. Then a utility function-based greedy algorithm named UGreedy/UF1 is proposed for solving the problem. Finally, the performance of UGreedy/UF1 is analyzed along with other baseline algorithms: UGreedy/UF2, 2-opt TSP, and Greedy TSP. The simulation results show that UGreedy/UF1 performs better than others both in terms of the deadline missing ratio of sensors and the total energy consumption of UAVs.

베마이트를 이용한 UF 세라믹 분리막의 제조 (Fabrication of Boehmite-based UF Ceramic Membrane)

  • 위인희;신동욱;한규성;김진호;조우석;황광택
    • 한국세라믹학회지
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    • 제51권4호
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    • pp.337-343
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    • 2014
  • A single layer ultrafiltration(UF) ceramic membrane was prepared using boehmite sol. Boehmite was synthesized using a typical sol-gel process with optimization of the viscosity, pH, molar ratio of aluminum isopropoxide(AIP) and $HNO_3$. Boehmite sol was coated on a microfiltration(MF) support using the dip-coating method. MF support was dipped into the boehmite sol with a withdrawal speed of 5 mm/s and was maintained for 10 s in the boehmite sol, resulting in a uniform UF membrane layer of $10{\mu}m$ thickness. The porosity of the obtained membrane was measured and found to be 41.2%; the pore size was found to range from 80~100 nm, corresponding to the pore size of the UF membrane. The flux of the obtained membrane was initially 540 $L/m^2h$ and approximately 85% of the initial flux was recovered using a periodic back-flushing process.

견직물에 대한 요소수지가공에 관한 연구 (Studies on Finshing of Silk Fabric with Urea Formaldehyde Resin.)

  • 유영철
    • 한국잠사곤충학회지
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    • 제27권2호
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    • pp.47-53
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    • 1985
  • 요소-formaldehyde 수지를 여러 가지 조건에서 견직물에 처리하여 다음과 같은 결과를 얻었다. 1. 수명수지의 생성 조건은 요소 1mol에 대하여 formaline을 2mod 이상 사용하여 pH 4∼5로 수지욕을 만들어야 한다. 2. 수지농도가 증가하는데 비례적으로 수지부착율도 증가한다. 상대적으로 수분율을 감소하는 경향을 보였다. 3. wet pick 70%, 80%, 90%, 100% 중에서 70%일 경우가 수지잔존율이 가장 높았다. 4. curing 조건에 따른 수지의 부착율은 온도가 높을수록 탈락율은 감소하며 부착율은 증가된다. 5. 촉매의 양은 (NH4)2SO4 경우는 수지에 대하여 2.5%, HCI 경우는 1%, tataric acid 경우는 10%가 적당하였고 나머지 NaHCO3, Zn(NO3)2·6H2O인 경우는 분석이 곤란하였다. 6. 촉매의 종류에 따른 부착율은 산성 혹은 (NH4)2SO4와 같은 잠복성 촉매가 뛰어난 효과를 나타냈다. 7. 촉매에 따른 세탁견뢰성은 산성 촉매일수록 뛰어난 효과를 나타냈다.

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Influence of Initial Molar Ratios on the Performance of Low Molar Ratio Urea-Formaldehyde Resin Adhesives

  • LUBIS, Muhammad Adly Rahandi;PARK, Byung-Dae
    • Journal of the Korean Wood Science and Technology
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    • 제48권2호
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    • pp.136-153
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    • 2020
  • In this paper, the influence of initial formaldehyde/urea (F/U) molar ratios on the performance of low molar ratio (1.0) urea-formaldehyde (UF) resin adhesives has been investigated. Two initial F/U molar ratios, i.e., the first and second initial molar ratios were used for the alkaline addition reaction. Three levels of the first initial F/U molar ratios (2.0, 3.0, and 4.0) and two levels of the second initial molar ratios (2.0 and 1.7) were employed to prepare a total of six UF resins with an identical final molar ratio (1.0). The basis properties, functional groups, molecular weight, crystallinity, and thermal curing properties of the UF resins were characterized in detail. Higher levels (3.0 and 4.0) of the first initial F/U molar ratio provided the UF resins with better properties (non-volatile solids content, viscosity, gelation time, pH, and specific gravity) than those of the resins prepared with the conventional level F/U molar ratio of 2.0. Statistical analysis suggested that combining the first and second initial molar ratio of 4.0 with 1.7 would result in UF resins with greater adhesion strength and lower formaldehyde emission than those of the resins prepared with other molar ratios. The results showed that higher levels of the first initial molar ratio resulted in a more branched structure, as indicated by GPC, FTIR, DSC, XRD, and greater adhesion strength than those of the other UF resins with an identical final molar ratio of 1.0.

폐식용유를 이용한 소형 디젤기관의 성능 (Performances of the Used Frying Oil on a Small Diesel Engine)

  • 김성태;정형길;김영복
    • Journal of Biosystems Engineering
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    • 제26권3호
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    • pp.209-220
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    • 2001
  • This study was carried out to investigate the usability of the used frying oil, which was extracted from soybean, as one of the alternative fuel of a small diesel engine. For the experiment, NO. 2 diesel oil [D], used frying oil [UF], and their volumetric blends were applied and analysis of the properties and compositions of the experimental fuels were conducted. A four cycle diesel engine with single cylinder, water cooling system, maximum output 8.1 ㎾/2,200 rpm was selected and a direct injection chamber and a precombustion chamber were attached alternately. The results obtained were as follows: 1. Engine power (BHP) were increased from 4.13~4.27㎾ to 9.08~9.15㎾ for diesel oil, from 4.05~4.19㎾ to 8.44~8.92㎾ for UF, and from 4.01~4.48㎾ to 8.69~9.16㎾ for blend fuel, as the engine speed increased from 1,000 rpm to 2,200 rpm. The BHP in case of the direct combustion chamber were fluctuated higher than those of the pre-combustion chamber. 2. With the engine speed increased, torque of the engine were increased from 39.50~40.80 N.m to 42.89 N.m, then decreased to 39.44~39.77 N.m for diesel oil, and increased from 38.73~40.04 N.m to 40.12~40.82 N.m then decreased as 36.53~38.76 N.m for UF. Torque of the blend fuels were increased from 38.75~41.76 N.m to 40.47~42.89 N.m then decreased to 37.73~39.78 N.m. There is no significant difference of torque between the type of combustion chambers. 3. The specific fuel consumption of the UF was increased about 20 percent depending on the engine speed variations. And in case of direct injection chamber, about 12 percent lower fuel consumption was observed than that of precombustion chamber. 4. NOx emission of the UF was higher than that of diesel oil at above 1,800rpm of the engine speed. In case of the direct injection chamber, NOx emission was revealed higher about 59 percent than that of the precombustion chamber, depending on the range of the engine speeds. 5. Smoke emission was decreased in case of UF compared with diesel oil on direct injection chamber. When using precombustion chamber smoke emission was a little higher than that of the direct injection chamber were showed at the engine speed range. 6. At all the engine speed range, exhaust gas temperatures were decreased 2~3$^{\circ}C$ for UF used engine compared with those of the diesel oil. The exhaust gas temperature of the direct injection chamber was higher than that of the precombustion chamber by 72$^{\circ}C$. 7. Unburnt materials remained in the cylinder in case of the pre-combustion chamber was smaller and softer than that of the direct combustion chamber. 8. The feasibility of the blend fuel B-1 and B-2 were verified as a direct combustion chamber was attached to the diesel engine, with respect to the power performance of the engine.

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