• Title/Summary/Keyword: U2

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High Temperature Oxidation Behavior of Nd-doped $UO_2$ (네오듐 고용 이산화우라늄의 고온 산화거동)

  • Lee, Jae-Won;Kang, Sang-Jun;Kim, Young-Hwan;Cho, Kwang-Hun;Park, Guen-IL;Lee, Jung-Won
    • Applied Chemistry for Engineering
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    • v.24 no.3
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    • pp.227-230
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    • 2013
  • The phase change of $(U_{1-x}Nd_x)_3O_8$ powder produced by oxidation of Nd-doped $UO_2$ pellet at $500^{\circ}C$ was investigated by high temperature oxidation heat treatment at $900{\sim}1500^{\circ}C$ under an air atmosphere. The XRD analysis results showed that the formation of $(U_{1-y}Nd_y)O_{2+z}$ phase and $U_3O_8$ phase from metastable $(U,Nd)_3O_8$ phase initiated at a temperature of $1000^{\circ}C$. The relative integrated intensity of $(U_{1-y}Nd_y)O_{2+z}$ phase to $U_3O_8$ phase increased with increasing of the oxidation temperature from 1100 to $1500^{\circ}C$. And also, it was found from the SEM observation that the particle size of $(U_{1-y}Nd_y)O_{2+z}$ phase increased with increasing of the oxidation temperature. However, electrone probe X-ray microanalyzer (EPMA) analysis results showed that Nd contents in $(U_{1-y}Nd_y)O_{2+z}$ phase decreased with increasing of the oxidation temperature. This behavior on the ground of XRD, SEM, and EPMA analysis data could be interpreted in terms of the transportation of U ions from $U_3O_8$ phase into $(U_{1-y}Nd_y)O_{2+z}$ phase through the interface of two phases during high temperature oxidation.

Effect of Salicylic and Picolinic Acids Acids on the Adsorption of U(VI) onto Oxides (산화물 표면의 U(VI) 흡착에 미치는 살리실산과 피콜린산의 영향)

  • Park, Kyoung-Kyun;Jung, Euo-Chang;Cho, Hye-Ryun;Song, Kyu-Seok
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.7 no.4
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    • pp.219-227
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    • 2009
  • The effect of organic acids on the adsorption of U(VI) onto oxide surfaces ($TiO_2)$(anatase), $SiO_2$(amorphous) and $Al_2O_3$(amorphous)) has been investigated. Two different organic acids, salicylic and picolinic acids, were used. Changes of adsorption ratio of U(VI), which depend on the existence of organic acids in a sample, were measured as a function of pH. Quantities of adsorbed organic acids, which depend on the existence of U(VI) in a sample, were also measured as a function of pH. It is confirmed that the soluble complex formation of U(VI) with organic acids can deteriorate the adsorption of U(VI) onto $TiO_2$ surface. It is noteworthy that salicylic acid does not affect the adsorption of U(VI) onto $SiO_2$ surface, however, picolinic acid enhances the adsorption of U(VI) onto $SiO_2$ surface. The latter effect can be understood by considering the formation of a ternary surface complex on $SiO_2$ surface, which was confirmed by the co-adsorption of picolinic acid with U(VI) and the change in a fluorescence spectra of U(VI) on surface, In the case of $Al_2O_3$, organic acids themselves were largely adsorbed onto a surface without deteriorating the adsorption of U(VI). This would support the possibility of a ternary surface complex formation on the $Al_2O_3$ surface, and an additional spectroscopic study is required.

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The High Temperature Oxidation Behavior of l0wt%$Gd_2 O_3$- Doped $UO_2$

  • J.H. Yang;K.W. Kang;Kim, K.S.;K.W. Song;Kim, J.H.
    • Nuclear Engineering and Technology
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    • v.33 no.3
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    • pp.307-314
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    • 2001
  • The changes of weight gain, structure, morphology and uranium oxidation states in l0wt% G $d_2$ $O_3$-doped U $O_2$ during the oxidation below 475$^{\circ}C$ and heat treatment at 130$0^{\circ}C$ in air were investigated using TGA, XRD, SEM, EPMA and XPS. The room temperature ( $U_{0.86}$G $d_{0.14}$) $O_2$Cubic Phase Converted to highly distorted ( $U_{0.86}$G $d_{0.14}$)$_3$ $O_{8}$ -type sing1e Phase by oxidation at 475 $^{\circ}C$ in air. This oxidized phase was reduced by annealing at 130$0^{\circ}C$ in air. The room temperature XRD pattern of the 130$0^{\circ}C$ annealed powder revealed that ( $U_{0.86}$G $d_{0.14}$)$_3$ $O_{8}$ -type single phase was separated into Gd-depleted $U_3$ $O_{8}$ and Gd-enriched ( $U_{0.7}$G $d_{0.3}$) $O_2$$_{+x}$ type cubic phase. The reduction and phase separation by the high temperature annealing of kinetically metastable and highly deformed ( $U_{0.86}$G $d_{0.14}$)$_3$ $O_{8}$ -type phase are interpreted in terms of cation size difference between G $d^3$$^{+}$ and U according to the oxidation state of U.U.U.U.U.te of U.U.U.U.U.

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Research on the Relative Importance and the Priority for the Functions of the U-City Service Aid Organization (U-City 서비스 지원기관 기능의 상대적 중요도와 우선순위 연구)

  • Yi, Mi Sook;Shin, Dong Bin;Lee, Jae Yong
    • Spatial Information Research
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    • v.21 no.2
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    • pp.35-43
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    • 2013
  • The aim of this research is to analyze the priority to functions of the U-city Service Aid Organization(USAO), which is to support invigorating U-City industry. This research analyzes the relative importance and the priority about the functional area and components of UASO based on AHP. This research also performs a sensitivity analysis. The research result shows that relative importance of functional area is like following orders: 1) distribution of U-City service-related information, 2) quality certification of U-City-related products and services, 3) R&D of U-City technology, 4) standardization of U-City, 5) U-City human resource development. The relative importance order of functional components is 1) establishment of U-City information distribution organization, 2) construction and management of U-City information distribution network, 3) supporting U-City information distribution and price policy, 4) providing U-City information list for distribution, 5) preparation and application of quality certification standard of U-City products and services, 6) research on legal system of U-City items, targets, and procedures for quality certification, 7) research, analysis, and provision of U-City information distribution situation, 8) level examination of constructed infrastructures and services in U-City, 9) U-City core technology development and localization of technology, 10) standardization of collected U-City information, service classification, distribution system. This research result can be applied directly to design functions of USAO. The result also can be used for duty management, human resource planning, or resource allocation.

Flexural Behavior of Segmental U-Girder and Composite U-Girder Using Ultra High Performance Concrete (초고강도 섬유보강 콘크리트를 사용한 분절형 U거더 및 합성 U거더의 휨거동)

  • Lee, Seung-Jae;Makhbal, Tsas-Orgilmaa;Kim, Sung-Tae;Han, Sang-Mook
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.5 no.3
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    • pp.290-297
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    • 2017
  • The flexural behavior tests of UHPC segmental U-girder and composite U-girder which has 160MPa compressive strength and 15.4m length were carried out. The test variables are volume fraction of steel fibers and slab over the U-girder. Each U-girder has longitudinal re-bars in web and lower flange. PS tendons which has 2 of 15.2mm diameter in upper flange and PS tendons which has 7 of 15.2mm diameter in lower flange were arranged and prestressed at onetime in U-girder connection stage. Enough strong prestressing force which applied to U-girder due to ultra high performance concrete strength can withstand the self weight and dead load in U-girder stage. By comparison with the brittle behavior of U-girder, composite U-girder showed the stable and ductile behavior. After the construction of slab over U-girder, flexural load capacity of composite U-girder can bear the design load in final construction stage with only one time prestressing operation which already carried out in U-girder stage. This simple prestressing method due to the ultra high strength concrete have the advantage in construction step and cost. The shear key which has narrow space has the strong composite connection between ultra high strength concrete U-girder and high strength concrete slab didn't show any slip and opening right before failure load.

A Study on the Sorption Behavior of U(VI) ion by Arsenazo I-XAD-2 Chelating Resin (Arsenazo I-XAD-2 킬레이트수지를 이용한 U(VI) 이온의 분리 및 농축에 관한 연구)

  • Lee, Chang-Hun;Lee, Si-Eun;Lim, Jae-Hee;Eom, Tae-Yoon;Kim, In-Whan;Kang, Chang-Hee;Lee, Won
    • Analytical Science and Technology
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    • v.6 no.5
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    • pp.489-499
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    • 1993
  • Some sorption behaviors of U(VI) ion on Arsenazo I-XAD-2 chelating resin were investigated. This chelating resin was synthesized by the diazonium coupling of Amberlite XAD-2 resin with Arsenzo I chelating reagent and characterized by elementary analysis method and IR spectrometry. The optimum conditions for the sorption of U(VI) ion were examined with respect to pH, U(VI) ion concentration and shaking time. Total sorption capacity of this chelating resin on U(VI) ion was 0.39mmol U(VI)/g resin in the pH range of 4.0~4.5. This chelating resin was showed increased sorption capacity on the increased pH value. It was confirmed that sorption mechanism of U(VI) ion on the Arsenazo I-XAD-2 chelating resin was competition reacting between U(VI) ion and $H^+$ ion. Breakthrough volume and overall capacity of U(VI) ion measured by column were was 600 ml and 0.38 mmol U(VI)/g resin, respectively. The desorption of U(VI) ion was showed recovery of 90~96% using 3M $HNO_3$ and 3M $Na_2CO_3$ as a desorption solution. The separation and concentration of U(VI) ion from natural water and sea water was performed successfully by Arsenazo I-XAD-2 chelating resin.

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A Study on the Establishment of U-City Data Management (U-City정보의 생산.수집.가공.활용 및 유통 등 정보관리방안 수립 연구)

  • Ahn, Jong-Wook;Shin, Dong-Bin
    • Journal of Korean Society for Geospatial Information Science
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    • v.17 no.2
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    • pp.27-35
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    • 2009
  • U-City law was enacted U-City construction to support efficiently. But U-City planning system is not set. And detailed instructions are not also available. In particular, U-City data is not available and specific plans and instructions. Therefore, in this research, "U-City Law" by the state and local governments need to establish in the U-City Comprehensive Plan and the U-City master plan to be included in U-City data management was presented matters. U-City comprehensive plan provides the direction of the U-City master plan. Detailed action task are (1) U-City data management standards for the establishment of cooperation and sharing (2) Establishment of U-City data processing and activation (3) U-City data distribution system infrastructure (4) Establishment of data quality and price. U-City master plan is based on the U-City comprehensive plan. And U-City master plan for the data managements are (1) U-City data on the production plan (2) U-City data on the collection plan (3) U-City data on the processing plan (4) U-City data on the activation plan (5) U-City data on the distribution plan.

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A NOTE ON LIE IDEALS OF PRIME RINGS

  • Shuliang, Huang
    • Communications of the Korean Mathematical Society
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    • v.25 no.3
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    • pp.327-333
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    • 2010
  • Let R be a 2-torsion free prime ring, U a nonzero Lie ideal of R such that $u^2\;{\in}\;U$ for all $u\;{\in}\;U$. In the present paper, it is proved that if d is a nonzero derivation and [[d(u), u], u] = 0 for all $u\;{\in}\;U$, then $U\;{\subseteq}\;Z(R)$. Moreover, suppose that $d_1$, $d_2$, $d_3$ are nonzero derivations of R such that $d_3(y)d_1(x)\;=\;d_2(x)d_3(y)$ for all x, $y\;{\in}\;U$, then $U\;{\subseteq}\;Z(R)$. Finally, some examples are given to demonstrate that the restrictions imposed on the hypothesis of the above results are not superfluous.