• Analytical Science and Technology
• /
• v.6 no.1
• /
• pp.83-92
• /
• 1993

The electrochemical behaviors of lanthanide ion(La and Nd) and lanthanide complexes with 2, 2, 6, 6-tetramethyl-3, 5-heptanedione(THD), sym-hydroxydibenzo-16-crown-5(HD16C5) and sym-dibenzo-16-crown-5-oxyacetic acid(D16C5A) ligands in acton solution have been investigated by the use of cyclic voltammetry and direct current polarography. The peak potential and peak current, their dependency on the concentration, temperature, the reversibility of the eleotrode reactions are described. The reduction of the lanthanide ions and complexes in 0.05 M TEAP proceeded one-electron step in first step and one two-electron step in second step. These reduction step was irreversible and the reduction current was diffusion controlled. Macrovcyclic crown ethers, sym-hydroxydibenzo-16-crown-5(HD16C5) and sym-dibenzo-16-crown-5-oxyacetic acid(D16C5A), were prepared from 1, 5-bis-(2-hydroxyphenoxy)-3-oxapentane with epichlorohydrin. The voltammetric behaviors of Ln(III)-HD16C5 and Ln-D16C5A complexes in aceton solution have been investigated by the voltammetric method. The composition and stability constants of lanthanide complexes were determined.

• Journal of Korean Society for Quality Management
• /
• v.45 no.2
• /
• pp.191-207
• /
• 2017

Purpose: To develop an interactive version of the conventional process capability-based approach, called 'Interactive Process Capability-Based Approach (IPCA)' in multi-response surface optimization to obtain a satisfactory compromise which incorporates a decision maker(DM)'s preference information precisely. Methods: The proposed IPCA consists of 4 steps. Step 1 is to obtain the estimated process capability indices and initialize the parameters. Step 2 is to maximize the overall process capability index. Step 3 is to evaluate the optimization results. If all the responses are satisfactory, the procedure stops with the most preferred compromise solution. Otherwise, it moves to Step 4. Step 4 is to adjust the preference parameters. The adjustment can be made in two modes: relaxation and tightening. The relaxation is to make the importance of one of the satisfactory responses lower, which is implemented by decreasing its weight. The tightening is to make the importance of one of the unsatisfactory responses higher, which is implemented by increasing its weight. Then, the procedure goes back to Step 2. If there is no response to be adjusted, it stops with the unsatisfactory compromise solution. Results: The proposed IPCA was illustrated through a multi-response surface problem, colloidal gas aphrons problem. The illustration shows that it can generate a satisfactory compromise through an interactive procedure which enables the DM to provide his or her preference information conveniently. Conclusion: The proposed IPCA has two major advantages. One is to obtain a satisfactory compromise which is faithful to the DM preference structure. The other is to make the DM's participation in the interactive procedure easier by using the process capability index in judging satisfaction/unsatisfaction. The process capability index is very familiar with quality practitioners as well as indicates the process performance levels numerically.

• Structural Engineering and Mechanics
• /
• v.48 no.6
• /
• pp.849-878
• /
• 2013

This paper consists of two parts, which broadly examines solution techniques abilities for the structures with geometrical nonlinear behavior. In part I of the article, formulations of several well-known approaches will be presented. These solution strategies include different groups, such as: residual load minimization, normal plane, updated normal plane, cylindrical arc length, work control, residual displacement minimization, generalized displacement control, modified normal flow, and three-parameter ellipsoidal, hyperbolic, and polynomial schemes. For better understanding and easier application of the solution techniques, a consistent mathematical notation is employed in all formulations for correction and predictor steps. Moreover, other features of these approaches and their algorithms will be investigated. Common methods of determining the amount and sign of load factor increment in the predictor step and choosing the correct root in predictor and corrector step will be reviewed. The way that these features are determined is very important for tracing of the structural equilibrium path. In the second part of article, robustness and efficiency of the solution schemes will be comprehensively evaluated by performing numerical analyses.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2010.02a
• /
• pp.323-323
• /
• 2010

Saw damage of crystalline silicon wafer is unavoidable factor. Usually, alkali treatment for removing the damage has been carried out as the saw damage removal (SDR) process for priming the alkali texture. It usually takes lots of time and energy to remove the sawed damages for solar grade crystalline silicon wafers We implemented two different mixed acidic solution treatments to obtain the improved surface structure of silicon wafer without much sacrifice of the silicon wafer thickness. At the first step, the silicon wafer was dipped into the mixed acidic solution of $HF:HNO_3$=1:2 ration for polished surface and at the second step, it was dipped into the diluted mixed acidic solution of $HF:HNO_3:H_2O$=7:3:10 ratio for porous structure. This double treatment to the silicon wafer brought lower reflectance (25% to 6%) and longer carrier lifetime ($0.15\;{\mu}s$ to $0.39\;{\mu}s$) comparing to the bare poly-crystalline silicon wafer. With optimizing the concentration ratio and the dilution ratio, we can not only effectively substitute the time consuming process of SDR to some extent but also skip plasma enhanced chemical vapor deposition (PECVD) process. Moreover, to conduct alkali texture for pyramidal structure on silicon wafer surface, we can use only nitric acid rich solution of the mixed acidic solution treatment instead of implementing SDR.

• The Journal of the Acoustical Society of Korea
• /
• v.15 no.2
• /
• pp.72-78
• /
• 1996

This thesis deals with a method to solve a two-and-one-half-dimensional ($2\frac12$ D) problem, which means that the ocean environment is two-dimensional whereas the source is fully three-dimensionally propagating, including three-dimensional refraction phenomena and three-dimensional back-scattering, using two-dimensional two-way parabolic equation method combined with Fourier synthesis. Two dimensional two-way parabolic equation method uses Galerkin's method for depth and Crank-Nicolson method and alternating direction for range and provides a solution available to range-dependent problem with wave-field back-scattered from discontinuous interface. Since wavenumber, k, is the function of depth and vertical or horizontal range, we can reduce a dimension of three-dimensional Helmholtz equation by Fourier transforming in the range direction. Thus transformed two-dimensional Helmholtz equation is solved through two-way parabolic equation method. Finally, we can have the $2\frac12$ D solution by inverse Fourier transformation of the spectral solution gained from in the last step. Numerical simulation has been carried out for a canonical ocean environment with stair-step bottom in order to test its accuracy using the present analysis. With this spectral parabolic equation method, we have examined three-dimensional acoustic propagation properties in a specified site in the Korean Straits.

• Journal of the Korean Mathematical Society
• /
• v.50 no.5
• /
• pp.1129-1163
• /
• 2013

Based on finite element discretization, two linearization approaches to the defect-correction method for the steady incompressible Navier-Stokes equations are discussed and investigated. By applying $m$ times of Newton and Picard iterations to solve an artificial viscosity stabilized nonlinear Navier-Stokes problem, respectively, and then correcting the solution by solving a linear problem, two linearized defect-correction algorithms are proposed and analyzed. Error estimates with respect to the mesh size $h$, the kinematic viscosity ${\nu}$, the stability factor ${\alpha}$ and the number of nonlinear iterations $m$ for the discrete solution are derived for the linearized one-step defect-correction algorithms. Efficient stopping criteria for the nonlinear iterations are derived. The influence of the linearizations on the accuracy of the approximate solutions are also investigated. Finally, numerical experiments on a problem with known analytical solution, the lid-driven cavity flow, and the flow over a backward-facing step are performed to verify the theoretical results and demonstrate the effectiveness of the proposed defect-correction algorithms.

• Journal of the Korean Ceramic Society
• /
• v.45 no.4
• /
• pp.191-195
• /
• 2008

Highly ordered silver nanowire with a diameter of 10 nm was arrayed by electroless deposition in a porous anodic aluminum oxide(AAO) membrane. The AAO membrane was fabricated electrochemically in an oxalic acid solution via a two-step anodization process, while growth of the silver nanowire was initiated by using electroless deposition at the long-range-ordered nanochannels of the AAO membrane followed by thermal reduction of a silver nitrate aqueous solution by increasing the temperature up to $350^{\circ}C$ for an hour. An additional electro-chemical procedure was applied after the two-step anodization to control the pore size and channel density of AAO, which enabled us to fabricate highly-ordered silver nanowire on a large scale. Electroless deposition of silver nitrate aqueous solution into the AAO membrane and thermal reduction of silver nanowires was performed by increasing the temperature up to $350^{\circ}C$ for 1 h. The morphologies of silver nanowires arrayed in the AAO membrane were investigated using SEM. The chemical composition and crystalline structure were confirmed by XRD and EDX. The electroless-deposited silver nanowires in AAO revealed a well-crystallized self-ordered array with a width of 10 nm.

• Journal of the Institute of Electronics Engineers of Korea SP
• /
• v.41 no.3
• /
• pp.121-127
• /
• 2004

This paper presents a new vertex selection scheme for shape approximation. In the proposed method, final vertex points are determined by "two-step procedure". In the first step, initial vertices are simply selected on the contour, which constitute a subset of the original contour, using conventional methods such as an iterated refinement method (IRM) or a progressive vertex selection (PVS) method In the second step, a vertex adjustment Process is incorporated to generate final vertices which are no more confined to the contour and optimal in the view of the given distortion measure. For the optimality of the final vertices, the dynamic programming (DP)-based solution for the adjustment of vertices is proposed. There are two main contributions of this work First, we show that DP can be successfully applied to vertex adjustment. Second, by using DP, the global optimality in the vertex selection can be achieved without iterative processes. Experimental results are presented to show the superiority of our method over the traditional methods.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
• /
• 2000.11a
• /
• pp.587-592
• /
• 2000

The optimization method based on an enhanced genetic algorithms is proposed for multimodal function optimization in this paper. This method is consisted of two main steps. The first step is global search step using the genetic algorithm(GA) and function assurance criterion(FAC). The belonging of an population to initial solution group is decided according to the FAC. The second step is to decide the similarity between individuals, and to research the optimum solutions by simplex method in reconstructive search space. Two numerical examples are also presented in this paper to comparing with conventional methods.

• Proceedings of the Computational Structural Engineering Institute Conference
• /
• 2008.04a
• /
• pp.20-25
• /
• 2008

The finite element analysis for porous media is severe job because constituents have different physical peoperties, and element's continuity and stability should be considered. Thus, we propose the new mixed finite element method in order to overcome the problems. In this method, multi time step, remeshing step, and sub iteration step are introduced. The multi time step and remeshing step make it possible to satisfy a stability and an accuracy during sub iteration in which global time is determined. Finally, the proposed method is compared with the ABAQUS(2007) software and exact solution(Schiffman 1967) through two dimensional consolidation model.