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Recent Progress in High-Luminance Quantum Dot Light-Emitting Diodes

  • Rhee, Seunghyun;Kim, Kyunghwan;Roh, Jeongkyun;Kwak, Jeonghun
    • Current Optics and Photonics
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    • v.4 no.3
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    • pp.161-173
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    • 2020
  • Colloidal quantum dots (QDs) have gained tremendous attention as a key material for highly advanced display technologies. The performance of QD light-emitting diodes (QLEDs) has improved significantly over the past two decades, owing to notable progress in both material development and device engineering. The brightness of QLEDs has improved by more than three orders of magnitude from that of early-stage devices, and has attained a value in the range of traditional inorganic LEDs. The emergence of high-luminance (HL) QLEDs has induced fresh demands to incorporate the unique features of QDs into a wide range of display applications, beyond indoor and mobile displays. Therefore it is necessary to assess the present status and prospects of HL-QLEDs, to expand the application domain of QD-based light sources. As part of this study, we review recent advances in HL-QLEDs. In particular, based on reports of brightness exceeding 105 cd/㎡, we have summarized the major approaches toward achieving high brightness in QLEDs, in terms of material development and device engineering. Furthermore, we briefly introduce the recent progress achieved toward QD laser diodes, being the next step in the development of HL-QLEDs. This review provides general guidelines for achieving HL-QLEDs, and reveals the high potential of QDs as a universal material solution that can enable realization of a wide range of display applications.

The development of high-performance PRO module and effects of operating condition on the performance of PRO module (고성능 PRO 모듈 개발 및 운전조건이 모듈 성능에 미치는 영향)

  • Han, Man Jae;Sim, Yeonju;Lee, Jong Hwa
    • Journal of Korean Society of Water and Wastewater
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    • v.31 no.4
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    • pp.303-310
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    • 2017
  • Pressure retarded osmosis(PRO) has attracted much attention as potential technology to reduce the overall energy consumption for reverse osmosis(RO) desalination. The RO/PRO hybrid process is considered as the most logical next step for future desalination. The PRO process aims to harness the osmotic energy difference of two aqueous solutions separated by a semipermeable membrane. By using the concentrated water(RO brine) discharged from existing RO plants, the PRO process can effectively exploit a greater salinity gradient to reduce the energy cost of processing concentrated water. However, in order to use RO brine as the draw solution, PRO membrane must have high water flux and enough mechanical strength to withstand the high operational pressure. This study investigates the development of a thin film composite PRO membrane and spiral wound module for high power density. Also, the influence of membrane backing layer on the overall power density was studied using the characteristic factors of PRO membranes. Finally, the performance test of an 8-inch spiral wound module was carried out under various operating conditions(i.e. hydraulic pressure, flow rate, temperature). As the flow rate and temperature increased under the same hydraulic pressure, the PRO performance increased due to the growth of water permeability coefficient and osmotic pressure. For a high performance PRO system, in order to optimize the operating conditions, it is highly recommended that the flow pressure be minimized while the flow rate is maintained at a high level.

Expression and Purification of Biologically Active Human Bone Morphogenetic Protein-4 in Recombinant Chinese Hamster Ovary Cells

  • Cha, Minyub;Han, Nara;Pi, Jia;Jeong, Yongsu;Baek, Kwanghee;Yoon, Jaeseung
    • Journal of Microbiology and Biotechnology
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    • v.27 no.7
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    • pp.1281-1287
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    • 2017
  • Bone morphogenetic protein-4 (BMP-4) is considered to have therapeutic potential for various diseases, including cancers; however, the high expression of biologically active recombinant human BMP-4 (rhBMP-4) needed for its manufacture for therapeutic purposes has yet to be established. In the current study, we established a recombinant Chinese hamster ovary (rCHO) cell line overexpressing rhBMP-4 as well as a production process using 7.5-l bioreactor (5 L working volume). The expression of the mature rhBMP-4 was significantly enhanced by recombinant furin expression. The combination of a chemically defined medium and a nutrient supplement solution for high expression of rhBMP-4 was selected and used for bioreactor cultures. The 11-day fed-batch cultures of the established rhBMP-4-expressing rCHO cells in the 7.5-L bioreactor produced approximately 32 mg/l of rhBMP-4. The mature rhBMP-4 was purified to homogeneity from the culture supernatant using a two-step chromatographic procedure, resulting in a recovery rate of approximately 55% and a protein purity greater than 95%. The N-terminal amino acid sequences and N-linked glycosylation of the purified rhBMP-4 were confirmed by N-terminal sequencing and de-N-glycosylation analysis, respectively. The mature purified rhBMP-4 has been proved to be functionally active, with an effective dose concentration of $EC_{50}$ of 2.93 ng/ml.

On Numerical Method for Radiation Problem of a 2-D Floating Body (2차원 부유체 강제동요문제의 수치해석에 관하여)

  • Y.S. Shin;K.P. Rhee
    • Journal of the Society of Naval Architects of Korea
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    • v.30 no.2
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    • pp.43-53
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    • 1993
  • There exist two difficulties in the nonlinear wave-body problems. First is the abrupt behavior near the intersection point between the body and the free surface, and second is the far field treatment. In this paper, the far field treatment is considered. The main idea is the Taylor series expansion of free-surface geometry and the application of F.F.T. algorithm. The numerical step is as follows. The velocity potential is expressed by the Green's theorem. and the solution is obtained by iteration method. In the iteration stage, the expressions by the Green's theorem are transformed to the convolution forts with the expansion of free surface by the wave slope. Here F.F.T. is applied, so the computing time can be of O(Nlog N) where N is the number of unknowns. The numerical analysis is carried out and the results are compared with other results in linear floating body problem and nonlinear moving pressure patch problem, and good agreements are obtained. Finally nonlinear floating body radiation problem is carried out with computing time of O(Nlog N).

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Quantitative Analysis of Lysophosphatidic Acid in Human Plasma by Tandem Mass Spectrometry

  • Kim, Ho-Hyun;Yoon, Hye-Ran;Pyo, Dong-Jin
    • Bulletin of the Korean Chemical Society
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    • v.23 no.8
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    • pp.1139-1143
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    • 2002
  • Analysis of lysophosphatidic acids (LPAs) is of clinical importance as they can serve a potential marker for ovarian and other gynecological cancers and obesity. It is critically important to develop a highly sensitive and specific method for the early detection of gynecological cancers to improve the overall outcome of this disease. We have established a novel quantification method of LPAs in human plasma by negative ionization tandem mass spectrometry (MS-MS) using multiple reaction monitoring (MRM) mode without the conventional TLC step. Protein-bound lipids, LPAs in plasma were extracted with methanol : chloroform (2:1) containing LPA C14:0 as an internal standard under acidic condition. Following back extraction with chloroform and water, the centrifuged lower phase was evaporated and reconstituted in methanol. The reconstituted solution was directly injected into electrospray source of MS/MS. For MRM mode, Q1 ions selected were m/z 409, 433, 435, 437 and 457 which corresponds to molecular mass [M-H]- of C16:0, C18:2, C18:1, C18:0 and C20:4 LPA, respectively. Q2 ions selected for MRM were m/z 79, phosphoryl product. Using MS/MS with MRM mode, all the species of LPAs were completely separated from plasma matrix without severe interferences. This method allowed simultaneous detection and quantification of different species of LPAs in a plasma over a linear dynamic range of 0.01-25 ㎛olL-1 . The detection limit of the method was 0.3 pmol/mL, with a correlation coefficient of 0.9983 in most LPAs analyzed. When applied to the plasmas of normal and gynecological cancer patients, this new method differentiated two different groups by way of total LPA level.

Low-Complexity Handheld 3-D Scanner Using a Laser Pointer (단일 레이저 포인터를 이용한 저복잡도 휴대형 3D 스캐너)

  • Lee, Kyungme;Lee, Yeonkyung;Park, Doyoung;Yoo, Hoon
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.64 no.3
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    • pp.458-464
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    • 2015
  • This paper proposes a portable 3-D scanning technique using a laser pointer. 3-D scanning is a process that acquires surface information from an 3-D object. There have been many studies on 3-D scanning. The methods of 3-D scanning are summarized into some methods based on multiple cameras, line lasers, and light pattern recognition. However, those methods has major disadvantages of their high cost and big size for portable appliances such as smartphones and digital cameras. In this paper, a 3-D scanning system using a low-cost and small-sized laser pointer are introduced to solve the problems. To do so, we propose a 3-D localization technique for a laser point. The proposed method consists of two main parts; one is a fast recognition of input images to obtain 2-D information of a point laser and the other is calibration based on the least-squares technique to calculate the 3-D information overall. To verified our method, we carry out experiments. It is proved that the proposed method provides 3-D surface information although the system is constructed by extremely low-cost parts such a chip laser pointer, compared to existing methods. Also, the method can be implemented in small-size; thus, it is enough to use in mobile devices such as smartphones.

Effects of Pressure Ratio on Population Inversion in a DF Chemical Laser with Concurrent Lasing

  • Park, Jun-Sung;Baek, Seung-Wook
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2004.03a
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    • pp.287-293
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    • 2004
  • A numerical simulation is presented for investigating the effects of pressure ratio of $D_2$ injector to supersonic nozzle on the population inversion in the DF chemical laser cavity, while a lasing concurrently takes place. The laser beam is generated between the mirrors in the cavity and it is important to obtain stronger population inversion and more uniform distribution of the excited molecules in the laser cavity in order to produce high power laser beam with good quality. In this study, these phenomena are investigated by means of analyzing the distributions of the DF excited molecules and the F atom used as an oxidant, while simultaneously estimating the maximum small signal and saturated gains and power in the DF chemical laser cavity. For the numerical solution, an 11-species (including DF molecules in various excited states of energies), 32-step chemistry model is adopted for the chemical reaction of the DF chemical laser system. The results are discussed by comparison with two $D_2$injector pressure cases; 192 torr and 388.64 torr. Major results reveal that in the resonator, stronger population inversions occur in the all transitions except DF(1)-DF(0), when the $D_2$injection pressure is lower. But, the higher $D_2$injection pressure provides a favorable condition for DF(1)-DF(0) transition to generate the higher power laser beam. In other words, as the pressure of $D_2$injector increases, the maximum small signal gain in the $V_{1-0}$ transition, which is in charge of generating most of laser power, becomes higher. Therefore, the total laser beam power becomes higher.r.

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The Kinetics of Radical Polymerization of Styrene with Tricaprylymethylammonium Chloride as a Phase-Transfer Catalyst (상이동촉매인 트리카프릴메틸암모니움 클로라이드를 사용한 스티렌 라디칼중합의 동력학적 연구)

  • Park, Sang-Wook;Sohn, In-Joe;Park, Sang-Bo
    • Journal of Adhesion and Interface
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    • v.2 no.2
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    • pp.11-19
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    • 2001
  • The phase-transfer catalyzed radical polymerization of styrene was carried out using tricaprylylmethylammonium chloride as a phase-transfer catalyst in a two-phase system of an aqueous $Na_2S_2O_8$ solution and toluene at $60^{\circ}C$ under nitrogen atmosphere. The initial rate of radical polymerization was expressed as the combined terms of concentrations of quaternary onium cation and peroxydisulfate anion in the aqueous phase rather than the fed concentrations of catalyst and $Na_2S_2O_8$. The observed initial rate of radical polymerization was used to analyze the radical polymerization mechanism with a cycle phase-transfer initiation step in the heterogeneous liquid-liquid system. The viscosity average molecular weight of polystyrene was inversely proportional to concentration of $Na_2S_2O_8$ expressed as $[Q^+]([S_2O{_8}^{2-}]{\alpha}_2)^{1/2}$ derived by the radical polymerization mechanism.

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A Comparison of Methods to Remove the Boron Rich Layer Formed at Boron Doping Process for c-Si Solar Cell Applications (결정질 실리콘 태양전지의 적용을 위해 보론 확산 공정에서 생성되는 Boron Rich Layer 제거 연구)

  • Choi, Ju Yeon;Cho, Young Joon;Chang, Hyo Sik
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.10
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    • pp.665-669
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    • 2015
  • We investigated and compared two methods of in-situ oxidation and chemical etching treatment (CET) to remove the boron rich layer (BRL). The BRL is generally formed during boron doping process. It has to be controlled in order not to degrade carrier lifetime and reduce electrical properties. A boron emitter is formed using $BBr_3$ liquid source at $930^{\circ}C$. After that, in-situ oxidation was followed by injecting oxygen of 1,000 sccm into the furnace during ramp down step and compared with CET using a mixture of acid solution for a short time. Then, we analyzed passivation effect by depositing $Al_2O_3$. The results gave a carrier lifetime of $110.9{\mu}s$, an open-circuit voltage ($V_{oc}$) of 635 mV at in-situ oxidation and a carrier lifetime of $188.5{\mu}s$, an $V_{oc}$ of 650 mV at CET. As a result, CET shows better properties than in-situ oxidation because of removing BRL uniformly.

Synthesis and Shape Control of Goethite Nano Particles (Goethite의 합성 및 형상제어)

  • Choi, Hyun-Bin;Chun, Myoung-Pyo;Chun, Seung-Yeop;Hwang, Jin-Ah
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.29 no.9
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    • pp.552-558
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    • 2016
  • Goethite, ${\alpha}$-FeOOH have various applications such as absorbent, pigment and source for magnetic materials. Goethite particles were synthesized in a two step process, where $Fe(OH)_2$ were synthesized in nitrogen atmosphere using $FeSO_4$ as a raw material in the first process, and after that acicular goethite particles were obtained in an air oxidation process of $Fe(OH)_2$ in highly alkaline aqueous solution. Their phase and microstructure were investigated with XRD and FE-SEM. It was found that the morphology of goethite and the ratio of length-to-width (aspect ratio) of acicular goethite are dependent on the some factors such as R value ($OH^-/Fe^{2+}$), air flow rate and pH conditions. In particular, R value has the strongest influence on the synthesized goethite morphology. It is considered that the optimal value R is 4.5 because X-ray diffraction peaks of goethite have the highest intensity at that value. Morphology of goethite particles was controlled by air flow rates, showing that their size and aspect ratio are getting smaller and decrease, respectively as air flow rate increases. The largest goethite particle obtained is about 1,500 nm in length and 150 nm in diameter.