• Title/Summary/Keyword: Two-layered Structure

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An Extended $H\ddot{u}ckel$ Study of Two Dimensional Layered Compound: FeOCl

  • Kim, Sang Ho;Kim Hojing
    • Bulletin of the Korean Chemical Society
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    • v.14 no.1
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    • pp.132-137
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    • 1993
  • The electronic structure of two dimensional layered compound, FeOCl, is studied with the band model and the cluster model approximation employing Extended-Huckel (EH) method. We examine the effects of intercalation (e.g., localization of transferred electron, conductivity increase). FeOCl has the electronic structure typical for layered compounds as expected. For FeOCl-$Li_{1/2}$ system, the charge transfer from Li to the FeOCl lattice occurs, and electrons are built up almost exclusively on Fe atoms. The partially filled band of FeOCl-$Li_{1/2}$ complex is responsible for the increase in conductivity.

First-Principles Study on the Electronic Structure of Bulk and Single-Layer Boehmite

  • Son, Seungwook;Kim, Dongwook;Na-Phattalung, Sutassana;Ihm, Jisoon
    • Nano
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    • v.13 no.12
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    • pp.1850138.1-1850138.6
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    • 2018
  • Two-dimensional (2D) or layered materials have a great potential for applications in energy storage, catalysis, optoelectronics and gas separation. Fabricating novel 2D or quasi-2D layered materials composed of relatively abundant and inexpensive atomic species is an important issue for practical usage in industry. Here, we suggest the layer-structured AlOOH (Boehmite) as a promising candidate for such applications. Boehmite is a well-known layer-structured material and a single-layer can be exfoliated from the bulk boehmite by breaking the interlayer hydrogen bonding. We study atomic and electronic band structures of both bulk and single-layer boehmite, and also obtain the single-layer exfoliation energy using first-principles calculations.

High-Temperature Oxidation Behavior of Commercial Pure Titanium in Mixed Gases (혼합가스 분위기 중에서 공업용 순 타이타늄의 고온산화 거동)

  • Park, S.H.;Ahn, Y.S.
    • Journal of Power System Engineering
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    • v.11 no.2
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    • pp.44-50
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    • 2007
  • The oxidation behavior of commercial pure titanium is investigated in the temperature range of $727^{\circ}C{\sim}950^{\circ}C$ in mixed gases. The weight change is measured by TGA during oxidation in mixed gases. The oxidation behavior indicated by weight gain or the growth of oxide layer is based on the linear rate law at high temperatures. The structure of the oxide scale formed during oxidation is analysed by optical microscopy, electron probe microanalyzer, scanning electron microscope and x-ray diffraction. Oxide scales have a $TiO_2$ structure, and are constituted with multi-layered or two layered porous external one and a dense internal one. Ti-O solid solution region is formed at the interface of metal and scale layer. The formation of oxide scale is influenced by the oxidation temperature, time, crystal structure and the condition of atmosphere.

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A Two-Layered Fuzzy Logic Controller for Systems with Deadzones

  • Kim, Jong-Hwan;Park, Jong-Hwan;Lee, Seon-Woo
    • Proceedings of the Korean Institute of Intelligent Systems Conference
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    • 1993.06a
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    • pp.826-829
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    • 1993
  • Existing fuzzy control methods do not perform well when applied to systems containing nonlinearities arising from unknown deadzones. We propose a novel two-layered fuzzy logic controller for controlling systems with deadzones. The two-layered control structure consists of a fuzzy logic-based pre-compensator followed by a conventional fuzzy logic controller. Our proposed controller exhibits superior transient and steady-state performance compared to conventional fuzzy controllers. We illustrate the effectiveness of our scheme using computer simulation examples.

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Lateral capacity of piles in layered soil: a simple approach

  • Mandal, Bikash;Roy, Rana;Dutta, Sekhar Chandra
    • Structural Engineering and Mechanics
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    • v.44 no.5
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    • pp.571-584
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    • 2012
  • Appropriate assessment of lateral capacity of pile foundation is known to be a complex problem involving soil-structure interaction. Having reviewed the available methods in brief, relative paucity of simple and rational technique to evaluate lateral capacity of pile in layered soil is identified. In this context, two efficient approaches for the assessment of lateral capacity of short pile embedded in bi-layer cohesive deposit is developed. It is presumed that the allowable lateral capacity of short pile is generally dictated by the permissible lateral displacement within which pile-soil system may be assumed to be elastic. The applicability of the scheme, depicted through illustration, is believed to be of ample help at least for practical purpose.

3-D Axisymmetric Fluid-Structure-Soil Interaction Analysis Using Mixed-Fluid-Element and Infinite-Element (혼합형 유체요소와 무한요소를 이용한 3차원 축대칭 유체-구조물-지반 상호작용해석)

  • 김재민;장수혁;윤정방
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 1999.10a
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    • pp.257-266
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    • 1999
  • This paper presents a method of seismic analysis for a cylindrical liquid storage structure on/in horizontally layered half.space considering the effects of the interior fluid and exterior soil medium in the frequency domain. To capture the essence of fluid-structure-soil interaction effects effectively, a mixed finite element with two-field (u, p) approximation is employed to model the compressive inviscid fluid, while the structure and soil medium are presented by the 3-D axisymmetric finite elements and dynamic infinite elements. The present FE-based method can be applied to the system with complex geometry of fluid region as well as with inhomogeneous near-field soil medium, since it can directly model both the fluid and the soil. For the purpose of verification, dominant peak frequencies in transfer functions for horizontal motions of cylindrical fluid storage tanks with rigid massless foundation on a homogeneous viscoelastic half.space are compared with those by two different added mass approaches for the fluid motion. The comparison indicates that the Present FE-based methodology gives accurate solution for the fluid-structure-soil interaction problem. Finally, as a demonstration of versatility of the present study, a seismic analysis for a real-scale LNG storage tank embedded in layered half.space is carried out, and its member forces along the height of the structure are compared with those by an added mass approach developed by the present writers.

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Analysis and Modelling of Vibration Performance for Multi-layered Corrugated Structure

  • Kim, Jin Nyul;Sim, Jae Min;Park, Min Jung;Kim, Ghi Seok;Kim, Jongsoon;Park, Jong Min
    • Journal of Biosystems Engineering
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    • v.38 no.4
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    • pp.327-334
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    • 2013
  • Purpose: The purpose of this study was to analyze for resonant frequency, vibration transmissibility and damping ratio of multi-layered corrugated structures using a random vibration test. Methods: The random vibration test was performed by the ASTM D4728 specifications using two paperboards (S120, K180) and two types of flutes (A/F, B/F). Damping ratio of the multi-layered corrugated structures was estimated using a theoretical equation derived from the measured resonant frequency and transmissibility. Results: The resonant frequency and vibration transmissibility of the multi-layered corrugated structures of K180 and B-flute were higher than those of S120 and A-flute, respectively; however, the damping ratio of each sample had the opposite tendency. The resonant frequency was inversely proportional to the sample thickness and static stress; vibration transmissibility and damping ratio were not correlated with sample thickness and static stress. In addition, we developed a mathematical model of the resonant frequency with variables of sample thickness and static stress. Conclusions: Results of this study can be useful for environment-friendly and optimal packaging design since vibration has been a key factor in cushioning packaging design.

Design of Modal Transducer in 2D Structure Using Multi-Layered PVDF Films Based on Electrode Pattern Optimization (다층 압전 필름의 전극 패턴 최적화를 통한 2차원 구조물에서의 모달 변환기 구현)

  • 유정규;김지철;김승조
    • Journal of KSNVE
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    • v.8 no.4
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    • pp.632-642
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    • 1998
  • A method based on finite element discretization is developed for optimizing the polarization profile of PVDF film to create the modal transducer for specific modes. Using this concept, one can design the modal transducer in two-dimensional structure having arbitrary geometry and boundary conditions. As a practical means for implementing this polarization profile without repoling the PVDF film the polarization profile is approximated by optimizing electrode patterns, lamination angles, and poling directions of the multi-layered PVDF transducer. This corresponds to the approximation of a continuous function using discrete values. The electrode pattern of each PVDF layer is optimized by deciding the electrode of each finite element to be used or not. Genetic algorithm, suitable for discrete problems, is used as an optimization scheme. For the optimization of each layers lamination angle, the continuous lamination angle is encoded into discrete value using binary 5 bit string. For the experimental demonstration, a modal sensor for first and second modes of cantilevered composite plate is designed using two layers of PVDF films. The actuator is designed based on the criterion of minimizing the system energy in the control modes under a given initial condition. Experimental results show that the signals from residual modes are successfully reduced using the optimized multi-layered PVDF sensor. Using discrete LQG control law, the modal peaks of first and second modes are reduced in the amount of 12 dB and 4 dB, resepctively.

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Shaking table test on soil-structure interaction system (2) : Superstructure with foundation on layered soil (건물-지반 시스템에 관한 진동대실험 (2) : 성층지반위의 구조물)

  • Lee Sung-Kyung;Masato Motosaka;Min Kyung-Won
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 2005.04a
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    • pp.529-537
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    • 2005
  • This paper proposes the shaking table testing method, without any soil specimen only using building model as an experimental part, considering dynamic soil-structure interaction based on the substructure method. The two-layered soil is assumed as a soil model of the entire soil-structure interaction syhstem(SSI) in this paper. Differently from the constant soil stiffness, the frequency-dependent dynamic soil stiffness is approximated for the case of both acceleration and velocity feedback, respectively. The interaction force is observed from measuring the accelerations at superstructure. Using the soil filters corresponding to the approximated dynamic soil stiffness, the shaking table drives the acceleration or velocity, which the needed motion to give the building specimen the SSI effects. Experimental results show the applicability the proposed methodologies to the shaking table test considering dynamic soil-structure interaction.

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Experimenal Study on Unsteady Double-Diffusive Convection in a Rectangle (사각형 용기내의 비정상 이중확산유동에 관한 실험적 연구)

  • 홍남호;김창수;현명택
    • Journal of Ocean Engineering and Technology
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    • v.8 no.1
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    • pp.105-113
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    • 1994
  • Double-diffusive convection induced by simultaneously-imposed lateral temperature and concentration gradients in a rectangular enclosure with aspect retio, 2.0 has been studied experimentally for adiabatic and isothermal horizontal boundary conditions. Visual observations show two distinct flow structures depending on the buoyancy ratio. The unicell flow structure is observed for a lower buoyancy ratio while the layered flow structure appears for a higher buoyancy ratio. There exists an unstable flow regime between two buoyancy ratios.

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