• Title/Summary/Keyword: Tween

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Adhesive Properties of Emulsion PSA Polymerized Using Tween Series Nonionic Surfactants (Tween계 비이온 계면활성제를 이용하여 중합한 에멀션점착제의 접착물성)

  • Lim, Tae Kyun;Lee, Myung Cheon
    • Korean Chemical Engineering Research
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    • v.52 no.3
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    • pp.289-293
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    • 2014
  • In making emulsion type pressure sensitive adhesive (PSA), environmentally friendly Tween series nonionic surfactants were used to find out the possibility of substituting the traditional nonyl-phenyl nonionic surfactant (NP-40) by comparing their adhesive properties. Results exhibited that the PSA used Tween series nonionic surfactants showed much better adhesive properties in peel strength and holding power than that used NP-40.

Combined Effect of Lidocaine Hydrochloride with Some Surfactants ( I ) (유화제(乳化劑)와 Lidocaine.HCl의 병용효과에 관(關)한 연구(硏究)( I ))

  • Kim, Yong-Hyoun;Yeum, Chul-Ho;Choi, Jun-Shik
    • Journal of Pharmaceutical Investigation
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    • v.12 no.2
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    • pp.31-36
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    • 1982
  • The effect of some surfactants, such as tween 40, tween 80, span 80, and triethanolamine, on the absorption of lidocaine was studied using goldfish as a model of absorption kinetics. This model was believed that reciprocal overturn time and death time were the occurrence of biological effect versus drug absorption. The results were as follows; The threshold concentration of lidocaine was significantly reduced by the surfactants. Overturn time and death time of goldfish in the lidocaine solution were reduced by such surfactants as tween 40, tween 80, span 80 and triethanolamine, and more reduced with increasing concentration of surfactants except tween 40 and tween 80. The plots of reciprocal death time versus lidocaine concentration were linear relationship with a positive concentration intercept such as minimum effective concentration (0.2-0.8%). As results it is believed that these surfactants may form complexes with lidocaine or affect the goldfish membrane to make more permeable to lidocaine, which is adsorbed more rapidly.

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Production of Ligninase in Agitated Submerged Cultures of Phanerochaete chrysosporium Diffuse Mycelia (진탕 배양(培養)에 의한 Phanerochaete chrysosporium Diffuse 균사(菌絲)의 Ligninase 생성(生成)에 관한 연구(硏究))

  • Kim, Kyung-Soo;Kim, Young-Ho;Kang, An-Seok;You, Chang-Hyun;Cha, Dong-Yeul;CROAN, SUKI C.
    • The Korean Journal of Mycology
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    • v.21 no.4
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    • pp.310-315
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    • 1993
  • Phanerochaete chrysosporium is a white rot fungus which secrets a family of lignin-degrading enzymes under nutrient limitation. Ligninase was extracellularly produced in agitated submerged cultures of P. chrysosporium, SC 26. Addition of veratryl alcohol(4 mM), and benzyl alcohol(10 mM) with 0.1% Tween 20 to the culture medium stimulated ligninase production. However, ligninase was not detected when both treatments of veratryl alcohol and benzyl alcohol without Tween 20 were added to the medium. Addition of 0.1 % Tween 20 to the culture medium had little effect on ligninase activity. The ligninase activity was maximum on day 5-8 for veratryl alcohol, and benzyl alcohol with 0.1 % Tween 20 additive medium.

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Effects of Tween 80 and Fibrolytic Enzymes on Ruminal Fermentation and Digestibility of Feeds in Holstein Cows

  • Baah, J.;Shelford, J.A.;Hristov, A.N.;McAllister, T.A.;Cheng, K.J.
    • Asian-Australasian Journal of Animal Sciences
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    • v.18 no.6
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    • pp.816-824
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    • 2005
  • The effects of the nonionic surfactant Tween 80 and a mixture of fibrolytic enzymes on total tract digestion, in situ disappearance (ISD) and ruminal fermentation characteristics of orchardgrass hay and barley grain were investigated in a 4${\times}$4 Latin square experiment with 4 non-lactating Holstein cows and 4 diets in 4 periods. Cows were offered a total mixed ration of 50% rolled barley grain and 50% orchardgrass hay treated with either 1) water (control), 2) 0.2% (vol/wt) Tween 80, 3) 0.2% (vol/wt) hydrolytic enzyme, or 4) 0.2% hydrolytic enzyme plus 0.2% Tween 80. Total tract digestibility coefficients of DM, nitrogen, NDF and ADF were not affected (p>0.05) by dietary treatment. Compared to the control, the rate of ISD of DM from orchardgrass hay was faster (p<0.05) in cows receiving diets treated with the enzyme alone or with enzyme plus Tween 80 (0.06/h vs. 0.076 and 0.069/h). The rate of digestion was lower (p<0.05) as compared to control when barley grain was treated with these additives. Ruminal fluid pH and concentrations of total VFA, acetate, isobutyrate and butyrate were not affected (p>0.05) by treatments. Cows that consumed diets treated with enzyme plus Tween 80 had higher (p<0.05) ruminal concentrations of propionate and isovalerate, and lower (p<0.05) acetate:propionate ratios. Compared to the control, microbial protein synthesis tended (p = 0.13) to increase with the addition of enzyme to the diet while nonammonia nitrogen flow to the duodenum increased (p<0.05) with both enzyme and Tween 80 treatments. The study indicated that fibrolytic enzymes alone or in combination with Tween 80 could enhance ISD of orchardgrass hay and ruminal concentrations of propionate, valerate and iso-valerate, but do not affect total tract digestibility.

Ostwald Ripening Stability of Curcumin-Loaded MCT Nanoemulsion: Influence of Various Emulsifiers

  • Kim, Sun-Hyung;Ji, Yeun-Sun;Lee, Eui-Seok;Hong, Soon-Taek
    • Preventive Nutrition and Food Science
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    • v.21 no.3
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    • pp.289-295
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    • 2016
  • Curcumin is a flavonoid found in the rhizome of the turmeric plant (Curcuma longa L.) and has recently attracted interest because it has numerous biological functions and therapeutic properties. In the present study, we attempted to incorporate curcumin into medium-chain triglyceride (MCT) nanoemulsions (0.15 wt% curcumin, 10 wt% MCT oil, and 10 wt% emulsifiers) with various emulsifiers [polyoxyethylene (20) sorbitan monolaurate (Tween-20), sorbitan monooleate (SM), and soy lecithin (SL)]. The physicochemical properties of the nanoemulsions including the Ostwald ripening stability were investigated. The initial droplet size was found to be 89.08 nm for the nanoemulsion with 10 wt% Tween-20 (control), and when Tween-20 was partially replaced with SM and SL, the size decreased: 73.43 nm with 4 wt% SM+6 wt% Tween-20 and 67.68 nm with 4 wt% SL+6 wt% Tween-20 (prepared at 15,000 psi). When the nanoemulsions were stored for 28 days at room temperature, the droplet size increased as the storage time increased. The largest increase was observed for the control nanoemulsion, followed by the 4 wt% SL+6 wt% Tween-20 and 4 wt% SM+6 wt% Tween-20 systems. The Turbiscan dispersion stability results strongly supported the relationship between droplet size and storage time. The time-dependent increase in droplet size was attributed to the Ostwald ripening phenomenon. Thus, the Ostwald ripening stability of curcumin-loaded MCT nanoemulsions with Tween-20 was considerably improved by partially replacing the Tween-20 with SM or SL. In addition, curcumin may have acted as an Ostwald ripening inhibitor.

Surfactant-enhanced Soil Washing using Tween and Tergitol Series Surfactants for Kuwait Soil Heavily Contaminated with Crude Oil

  • Heo, Hyojin;Lee, Minhee
    • Journal of Soil and Groundwater Environment
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    • v.20 no.5
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    • pp.26-33
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    • 2015
  • Batch experiments were performed to investigate the feasibility of a surfactant-enhanced soil washing process for soils heavily contaminated with crude oil in Kuwait. TPH concentration of the contaminated soil was 223,754 mg/kg, sampled from the bottom of a vaporized oil extraction pond in the Burgan reservoir field. Commercialized eight nonionic surfactants (Tween and Tergitol series) were used to measure the aqueous solubility for the crude oil. Among them, two Tergitol surfactants were used to evaluate the TPH removal efficiency of the surfactant-enhanced soil washing for heavily contaminated Kuwait soil. The solubility of the crude oil in surfactant solution was in the order Tergitol 15-S-7 > Tergitol 15-S-9 > Tergitol 15-S-12 > Tween-80 > Tween-20 > Tween-60, which showed that the crude oil solubilities of the Tergitol series were higher than those of the Tween series. The TPH removal efficiencies of 2% and 5% Tergitol 15-S-9 solution were 59% and 65%, respectively. Because the residual TPH concentration in the washed soil was still higher than the clean-up level (10,000 mg/kg), the soil washing process was repeated five times. After the fifth washing, the residual TPH concentration in the soil went down to 7,680 mg/kg and its removal efficiency was 97%.

Studies on the Haemagglutinating and Complement Fixing Activities, and Infectivity of Murray Valley Encephalitis Virus (뇌염(腦炎)바이러스의 적혈구응집력가(赤血球凝集力價)와 보체결합력가(補體結合力價) 및 감염력(感染力)에 관한 연구(硏究))

  • Chung, Young Suk
    • Korean Journal of Veterinary Research
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    • v.12 no.1
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    • pp.77-84
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    • 1972
  • Throughout the studies the following experimental results were obtained and summarized. 1. Treatment of MVE virus with acetone, Tween-ether and Tween-ether-protamine sulphate caused an eight to 16 fold increase in HA activity. 2. Treatment with acetone and Tween-ether resulted in a four fold increase in CF activity. Treatment with Tween-ether-protamine sulphate decreased the activity. 3. The crude virus showed a complete loss of infectivity after treatment with Tween-ether, but three log unit was, decreased with acetone treatment. 4. The HA activity of treated and crude virus was disappeared after heating at $37^{\circ}C$ for 60 minutes but CF activity was increased. 5. Tween-ether or acetone treatment equally applicable to the preparation of haemagglutinin for HI test. 6. Zonal centrifugation of crude virus in a linear ten to 60 percent sucrose gradient showed two peaks of CF activity, and one of high buoy ant density part accompanied by HA activity and infectivity and the other of lower density part. Acetone treatment brought a decrease of the high density CF activity but not affected the second peak of low density found with crude virus, and resulted in increased HA activity and decreased infectivity. The peaks of HA, CF and infectivity after acetone treatment were not clearly separated. Tween-ether treatment caused a loss of the peak of CF activity found in the area of high density with crude virus, but the peak in the area of low density was not affected. This peak of CF activity was separated from noninfectious HA activity. The HA and CF activities were considered to be contributed by different parts of the varion.

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Mixed Micellizations of TTAB with Other Surfactants (DTAB, CTAB, Tween-20, Tween-40, and Tween-80) (TTAB와 다른 계면활성제(DTAB, CTAB, Tween-20, Tween-40 및 Tween-80)와의 혼합미셀화에 대한 연구)

  • Lee, Nam-Min;Lee, Byung-Hwan
    • Journal of the Korean Chemical Society
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    • v.56 no.5
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    • pp.556-562
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    • 2012
  • The critical micelle concentration (CMC) and the counter-ion binding constant (B) for the mixed micellizations of TTAB (tetradecyltrimethylammonium bromide) with other surfactants (DTAB, CTAB, Tween-20, Tween-40, and Tween-80) in aqueous solution of 4-chlorobenzoic acid (0.5 mM) at $25^{\circ}C$ were determined as a function of ${\alpha}_1$ (the overall mole fraction of TTAB) by using the spectrophotometric method and the conductivity method. Various thermodynamic parameters ($X_i$, ${\gamma}_i$, $C_i$, $a_i^M$, ${\beta}$, and ${\Delta}H_{mix}$) were calculated for each mixed surfactant system and compared with the other mixed surfactant systems by means of the equations derived from the nonideal mixed micellar model. The results show that TTAB/DTAB mixed system has a great positive deviation from the ideal mixed micellar model and the other mixed systems have great negative deviations from the ideal mixed model.

Mixed Micellar Properties Dodecyldimethyl(3-sulfopropyl)ammonium Hydroxide with Other Surfactants (Dodecyldimethyl(3-sulfopropyl)ammonium Hydroxide와 다른 계면활성제와의 혼합미셀화에 관한 연구)

  • Lee, Nam-Min;Lee, Byung-Hwan
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.4
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    • pp.602-611
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    • 2014
  • The critical micelle concentration (CMC) of the zwitterionic surfactant of dodecyldimethyl(3-sulfopropyl)ammonium hydroxide(LSB, $CH_3(CH_2)_{11}N^+(CH_3)_2(CH_2)_3SO{_3}^-$) and LSB/Tween-20, LSB/Tween-40, LSB/Tween-80 and LSB/DTAB, LSB/TTAB, LSB/CTAB mixed surfactant systems were determined by using the UV/Vis absorbance method from 284 K to 312 K. And the effects of temperature on the micellization have been measured for the thermodynamic study. The results show that the measured values of gibbs free energy are all negative in the whole measured. The values of enthalpy are positive Tween-20, And negative other surfactants. but the values of entropy are positive in the whole measured temperature region. The results show that all of the thermodynamic parameters are dependent on temperature and alkyl-group's length.

Effect of Tween 20 on the Penetration of Ketoprofen through Excised Rat Skin (트윈 20이 케토프로펜의 흰쥐 피부투과에 미치는 영향)

  • Kim, Jung-Ju;Chi, Sang-Cheol;Shim, Chang-Koo;Kim, Chong-Kook
    • Journal of Pharmaceutical Investigation
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    • v.22 no.2
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    • pp.163-166
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    • 1992
  • The effect of Tween 20 on the penetration of ketoprofen in aqueous vehicles through excised rat skin has been evaluated. The addition of Tween 20, up to 2%, in water containing ketoprofen decreased the penetration of ketoprofen through the skin compared with the reference vehicle without this surfactant. However, the addition of Tween 20 in ketoprofen aqueous vehicle increased diffusion parameter significantly which was compensated with the lowered partition parameter.

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