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http://dx.doi.org/10.12925/jkocs.2014.31.4.602

Mixed Micellar Properties Dodecyldimethyl(3-sulfopropyl)ammonium Hydroxide with Other Surfactants  

Lee, Nam-Min (Department of Applied Chemical Engineering, Korea University of Tech. & Education)
Lee, Byung-Hwan (Department of Applied Chemical Engineering, Korea University of Tech. & Education)
Publication Information
Journal of the Korean Applied Science and Technology / v.31, no.4, 2014 , pp. 602-611 More about this Journal
Abstract
The critical micelle concentration (CMC) of the zwitterionic surfactant of dodecyldimethyl(3-sulfopropyl)ammonium hydroxide(LSB, $CH_3(CH_2)_{11}N^+(CH_3)_2(CH_2)_3SO{_3}^-$) and LSB/Tween-20, LSB/Tween-40, LSB/Tween-80 and LSB/DTAB, LSB/TTAB, LSB/CTAB mixed surfactant systems were determined by using the UV/Vis absorbance method from 284 K to 312 K. And the effects of temperature on the micellization have been measured for the thermodynamic study. The results show that the measured values of gibbs free energy are all negative in the whole measured. The values of enthalpy are positive Tween-20, And negative other surfactants. but the values of entropy are positive in the whole measured temperature region. The results show that all of the thermodynamic parameters are dependent on temperature and alkyl-group's length.
Keywords
zwitterionic surfactant; lauryl sulfobetaine; gibbs free energy; enthalpy; entropy;
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Times Cited By KSCI : 4  (Citation Analysis)
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