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Structural Transition of A-Type Zeolite: Molecular Dynamics Study

  • Song, Mee-Kyung;Chon, Hak-Ze
    • Bulletin of the Korean Chemical Society
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    • v.14 no.2
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    • pp.255-258
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    • 1993
  • Molecular dynamics (MD) calculations were carried out in order to investigate the effect of MD cell size to predict the melting phenomena of A-type zeolite. We studied two model systems: a pseudocell of $(T_2O_4Na)_n$, (L= 12.264 $^{\AA}$, N= 84) and a true-cell of (SiAlO$_4Na)_n$. (L= 24.528 $^{\AA}$, N= 672), where T is Si or Al. The radial and bond angle distribution functions of T(Si, Al)-O-T(Si, Al) and diffusion coefficients of T and O were reported at various temperatures. For the true-cell model, the melting temperature is below 1500 K and probably around 1000 K, which is about 600-700 K lower than the pseudocell model. Although it took more time (about 30 times longer) to obtain the molecular trajectories of the true-cell model than those of the pseudocell model, the true-cell model gave more realistic structural transition for the A-type zeolite, which agrees with experiment.

TPR-TNR plot for confusion matrix

  • Hong, Chong Sun;Oh, Tae Gyu
    • Communications for Statistical Applications and Methods
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    • v.28 no.2
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    • pp.161-169
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    • 2021
  • The two-dimensional confusion matrix used in credit assessment, biostatistics, and many other fields consists of true positive, true negative, false positive, and false negative. Their rates, such as the true positive rate (TPR), true negative rate (TNR), false positive rate, and false negative rate, can be applied to measure its accuracy. In this study, we propose the TPR-TNR plot, a graphical method that can geometrically describe and explain these rates based on the confusion matrix. The proposed TPR-TNR plot consists of two right-angled triangles. We obtain that the TPR and TNR describe the acute angles of right-angled triangles in the plot. These acute angles can be used to determine optimal thresholds corresponding to lots of accuracy measures.

RELIABILITY OF NUMERICAL SOLUTIONS OF THE G-EULER PROCESS

  • YU, DONG WON
    • Journal of the Korean Society for Industrial and Applied Mathematics
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    • v.26 no.1
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    • pp.49-66
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    • 2022
  • The G-Euler process has been proposed to overcome the difficulties of the calculation of the exponential function of the Jacobian. It is an explicit method that uses the exponential function of the scalar skew-symmetric matrix. We define the moving shapes of true solutions and the moving shapes of numerical solutions. It is discussed whether the moving shape of the numerical solution matches the moving shape of the true solution. The match rates of these two kinds of moving shapes are sequentially calculated by the G-Euler process without using the true solution. It is shown that the closer the minimum match rate is to 100%, the more closely the numerical solutions follow the true solutions to the end. The minimum match rate indicates the reliability of the numerical solution calculated by the G-Euler process. The graphs of the Lorenz system in Perko [1] are different from those drawn by the G-Euler process. By the way, there is no basis for claiming that the Perko's graphs are reliable.

True Stress-True Strain Curve Fitting Methodology for Finite Element Analysis (유한요소해석을 위한 재료의 진응력-진변형률 커브 피팅 방법론)

  • Kim, Y.J.;Gu, G.H.;Seo, M.H.;Kim, H.S.
    • Transactions of Materials Processing
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    • v.31 no.4
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    • pp.194-199
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    • 2022
  • In finite element method (FEM) simulations, constitutive models are widely used and developed to represent a wide range of true stress-strain curves using a small number of modeling parameters. Nevertheless, many studies has been conducted to find a suitable constitutive model and optimal modeling parameters to represent experimentally obtained true stress-strain curves. Therefore, in this study, a new constitutive modeling approach using the combined Swift and Voce model is suggested, and confirmed through comparisons of the experimental results with the FEM simulation results.

A Study of the Hinge Axis Point (Hinge Axis Point에 관한 연구)

  • Jung, Kum-Tae
    • The Journal of Korean Academy of Prosthodontics
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    • v.22 no.1
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    • pp.72-78
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    • 1984
  • The notion that the axis of the shaft of the articulator must coincide the patient's mandibular transverse axis tells us the importance of locating the axis precisely. When using kinematic axis to transfer a cast to an articulator, the anatomic asymmetry of the contralateral points will result in certain distortion when the axis transferred to an articulator where the mechanical axis produces symmetry. In this study, after locating the true hinge axis point with Denar hinge axis locator, the discrepancies between true hinge axis point and arbitrary hinge axis point that was 13mm anterior from the posterior margin of center of trangus to the outer canthus of eye were measured. And the discrepancies between left and right true hinge axis point in the superoinferior and anteroposterior directions were measured. For this study, 20 dental students who have no missing teeth and no difficulties of mandibular movement were selected. Upper and lower cast of subjects were mounted on Denar Mark II articulator uisng Denar Slidematic face-bow and centric relation record for the measurement of discrepancies between left and right true hinge axis points. The results obtained as follows. 1. The mean distance from the arbitrary hinge axis point to the true hinge axis point was as follows. Right: horizontal distance; 1.99mm, vertical distance; 2.12mm, linear distance; 3.36 mm. Left: horizontal distance; 1.39mm, vertical distance; 2.06mm, linear distance; 2.09mm. Total: horizontal distance; 1.69mm, vertical distance; 2.09mm linear distance; 3.06 mm. 2. The 87.5% of true hinge axis points were within 5mm of the arbitrary hinge axis point. 3. The mean discrepancies between the right and left hinge axis point were 2.92mm in superoinferior direction and 4.74mm in anteroposterior direction. 4. When transferring the axis to the articulator, anatomic asymmetry between right: and left axis point produces in dislocation of cast on the articulator, and undesirable shift in esthetic tooth position will be resulted.

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Design of 5'' True Color FED Driving System (5'' True Color FED 구동시스템 설계)

  • Shin, Hong-Jae;Kwon, Oh-Kyong;Kwack, Kae-Dal
    • Journal of the Institute of Electronics Engineers of Korea SC
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    • v.38 no.5
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    • pp.70-78
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    • 2001
  • We have developed a novel driving system of 5' true color FED using voltage controlled PWM method which has current control effect. The proposed method has the advantage of voltage controlled pulse width modulation method and current control method. Also, we propose a new circuit model of FED subpixel for circuit simulation of FED driving circuits, considering some parasitic effects, i.e., cross talk, line coupling effect and leakage current to the adjacent cathode lines. Output stage of the data driving circuit is optimized using the proposed circuit model. In video data processing, FED controller uses the parallel processing of R.G.B input data, so duty ratio is maximized and brightness of FED increases. With this results, no noise and high quality performance is achieved in display of 5' true color FED.

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A Study on Analyzing the Live Skyline Cable Logging Mechanics (유동식 가선집재시스템 Live Skyline의 역학분석에 관한 연구)

  • Chung, Joo Sang;Chung, Woo Dam
    • Journal of Korean Society of Forest Science
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    • v.83 no.3
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    • pp.357-364
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    • 1994
  • In this paper, the characteristics of cable logging systems, of which skyline length is adjustable during operation are discussed from a standpoint of system geometry. Among the cable logging systems, the live skyline is the typical one, of which operation is easy to understand. To analyze the cable logging mechanics of the live skyline, computer models were developed. In developing the computer models, the concept of the live skyline operation was classified into 'true live skyline' and 'live skyline with lift'. The former assumes to adjust skyline length continuously to maintain the skyline clearance over ground constant during inhaul ; the latter assumes to shorten the skyline length only to keep the minimum skyline clearance during inhaul. The computer model was used in investigating the mechanical efficiency and the operational characteristics of the live skyline system. First, the payload capability of live skyline was compared with that of standing skyline. Second, the effect of the change in the log-drag geometry on the payload capability of live skyline was investigated. Finally, the payload capability of live skyline with lift was compared with that of true live skyline as an effort to explain the concepts of true live skyline and live skyline with lift.

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