• Title/Summary/Keyword: Tri¬

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Dephosphpoylation of P-Nitrophenyldiphenylphosphinate by Benzimidazole Catalyzed with Ethyl tri-n-octyl Ammonium Bromide(ETABr) (ETABr 용액내에서 P-Nitrophenyldiphenylphosphinate의 탈인산화반응에 미치는 Benzimidazole의 촉매효과)

  • Kim, Jeung-Bea;Kim, Hak-Yoon
    • Journal of Environmental Science International
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    • v.16 no.5
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    • pp.641-647
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    • 2007
  • The phase transfer catalysis(PTC) reagent, ethyl tri-octyl ammonium bromide(ETABr), strongly catalyzes the reaction of p-nitrophenyi diphenyl phosphinate(p-NPDPIN) with benzimidazole(BI) and its anion($BI^{\theta}$). In ETABr solutions, the dephosphorylation reactions exhibit higher first order kinetics with respect to the nucleophile, BI, and ETABr, suggesting that reactions are occuring in small aggregates of the three species including the sub-strate(p-NPDPIN), whereas the reaction of p-NPDPIN with $OH^{\theta}$ is not catalyzed by ETABr. This behavior for the drastic rate-enhancement of the dephosphorylation is referred as 'aggregation complex model' for reaction of hydrophobic organic phosphinates with benzimidazole(BI) in hydrophobic quarternary ammonium salt(ETABr) solutions.

IMPROVED ASTRONOMICAL IMAGE REPRODUCING TECHNIQUES (천체사진건판의 진보된 영상 재현법)

  • Jeon, Yeong-Beom
    • Publications of The Korean Astronomical Society
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    • v.8 no.1
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    • pp.105-117
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    • 1993
  • Astronomical plates have a very large density range (dynamical range). Many exposed astronomical photographic plates do not provide detailed structures for very high densities, and some include hidden images for very low densities. The former can be fixed through 'Unsharp Masking' technique and the latter through 'Image Amplification' technique. Besides, we can find intrinsic colors of celestial bodies through 'Tri Color Composition' technique. Images of several plates which were observed from Sobaek Observatory with 61cm telescope are reproduced by the three kinds of image reproducing techniques. As reproduced image examples, we display an Orion nebula and a waxing crescent moon images through unsharp masking technique and an M81 image through image amplification technique. An Orion nebula and a Dumbbell nebula images are also given as results of tri color composition technique.

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Theoretical Analysis of Digital PLL (디지털 위상 고정 루프의 이론적 해석)

  • 박영철;김재형;차균현
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.17 no.5
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    • pp.460-471
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    • 1992
  • By setting a new model to describe the time-discontinuous operation of PLL loop which used tri-state and sample-hold method, the stability analysis of nonlinear PLL has been performed in z-domain and the state equations for the transient response has been introduced. Until now, the lin-ear analysis by approximation of time-discontinuous to time-continuous operation had not found then stable region of time-discontinuous digital PLL exactly. However, the analysis In z-domain by the new model has been found the unstable region where the time-continuous analysis had have not. 1'herefore the limit of loop coefficient has been computed to design digital PLL optimally.

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SOME FACTORS INFLUENCING TRI-L-ALANINE DISAPPEARANCE AND RUMEN BACTERIAL GROWTH YIELD IN VITRO

  • Ha, J.K.;Kennelly, J.J.;Lee, S.C.
    • Asian-Australasian Journal of Animal Sciences
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    • v.4 no.4
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    • pp.369-375
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    • 1991
  • A series of in vitro incubation studies with washed rumen bacteria were conducted to determine the influence of incubation time and concentrations of peptides, alanine, ammonia nitrogen and carbohydrate on the rate of peptide disappearance and on bacterial growth. Disappearance rate of tri-alanine (ala3) under various conditions was between 30.6 and $58.2mg\;hr^-$ per gram bacterial dry matter. Ala3 was removed from the incubation medium in an almost linear fashion as incubation time and ala3 concentration was increased. Washed rumen bacteria utilized ala3 faster than di-l-alanine (ala2) at all concentrations. Adding 9mM carbohydrate significantly increased ala3 disappearance, but level of ammonia nitrogen had no influence on ala3 disappearance. The presence of alanine in the medium significantly lowered ala3 utilization by rumen bacteria. Bacterial dry matter and nitrogen growth yield were not influenced by alanine and peptides when incubation medium already contained a sufficient level of ammonia nitrogen. Increased ammonia nitrogen in the presence of ala3 did not stimulate bacterial growth. Carbohydrate significantly increased bacterial dry matter and nitrogen growth as expected. Results indicate that the rate of peptide utilization by rumen bacteria may be altered by type and concentration of peptides, and energy supply, and this may be mediated through changes in numbers and type of bacteria.

A Study on the Riser Fatigue Analysis Using a Quarter-modal Spectrum (사봉형 스펙트럼을 이용한 라이저 피로해석 연구)

  • Kim, Sang Woo;Lee, Seung Jae;Choi, Sol Mi
    • Journal of the Society of Naval Architects of Korea
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    • v.53 no.6
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    • pp.514-520
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    • 2016
  • Oil and gas production riser systems need to be designed considering a wide band quarter-modal analysis which contains low-, wave-, VIV(Vortex induced vibration) frequencies. The VIV can be separated into cross-flow(CF) and in-line(IL) components. In this study, the various idealized tri- and quarter-modal spectra are suggested to analyze fatigue damage on the production riser system. In order to evaluate the fatigue damage increment caused by the IL's motion, tri- and quarter-modal spectral fatigue damages are calculated in time domain. And the fatigue damage calculated from two different modal spectra are compared quantitatively. Then the suitability of existent wide band fatigue damage models for quarter modal spectrum was evaluated by comparison of frequency domain calculation and time domain calculation. The result show that although spectral density of IL motion is not remarkable in quantity, the effect on the fatigue damage is significant and existent fatigue damage models are not adequately estimating damage by quarter-modal spectra.

DIMENSIONAL ACCURACY OF EPOXY RESINS AND THEIR COMPATIBILITY WITH IMPRESSION MATERIALS (EPOXY RESIN의 정확도와 인상재와의 친화성에 관한 연구)

  • Chang, Su-Kyoung;Chang, Ik-Tae;Yim, Soon-Ho
    • The Journal of Korean Academy of Prosthodontics
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    • v.37 no.3
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    • pp.383-394
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    • 1999
  • The indirect technique for making cast restoration requires that dies be as accurate and durable as possible. Currently, stone is the most commonly used material for die. However, it has some problems such as the weakness in its strength and low abrasion resistance. Recently, epoxy resin die systems have become available. The purpose of this study was to examine two commercially available resin die systems and evaluate some characteristics for their clinical performance. This study evaluated the dimensional accuracy of epoxy resins and their wettability with impression materials. In this study, the first experiment was about dimensional accuracy of different die materials. The master model was made of stainless steel. 10 models were made of two epoxy resins (Die-epoxy, Tri-epoxy) and a die stone (Fujirock) each. Occlusal diameter (Dimension I), occluso-gingival height (Dimension II), and interabutment distance (Dimension III) were measured in each model. Next, the contact angles of die materials with impression materials were observed. The blocks were made of polyether, hydrophilic additional silicone, polysulfide impression materials. By drop-ping the same amount (0.05ml) of Tri-epoxy, Die-epoxy, and die stone on the blocks, 10 samples of each die material were made. After setting of materials, the contact angles were measured. The results of this study were as follows. 1. The expansion of stone die and the shrinkage of resin dies in occlusal diameter were observed, and stone and Tri-epoxy were expanded and Die-epoxy was shrinked in occluso-gingival height. There was little change among materials in interabutment distance (p<0.05). 2. In comparison with the master model Tri-epoxy had the least variation in measurement of the three die systems examined. Die-epoxy was next, and die stone showed the greatest variation. 3. The compatibility of die stone for polyether, hydrophilic additional silicone, polysulfide decreased in order, wherease epoxy materials had the decreased compatibility for polyether and polysulnde, hydrophilic additional silicone in order. It was not statistically different between polyether and polysulfide (p<0.05). 4. The contact angles of Tri-epoxy, Die-epoxy, die stone were getting bigger in order.

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The Study of KOGAS DME Process in Small and Medium Sized Gas Field Containing $CO_2$ ($CO_2$가 함유된 중소규모 가스전을 위한 KOGAS DME Process 연구)

  • Mo, Yong-Gi;Cho, Won-Jun;Song, Taek-Yong;Baek, Young-Soon
    • Journal of the Korean Institute of Gas
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    • v.14 no.4
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    • pp.51-55
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    • 2010
  • The global activities to reduce the $CO_2$ emission as a greenhouse gas have been various efforts. Under this circumstance, small and medium sized gas field containing $CO_2$ to develop as LNG is not economic feasibility. Particularly, for the separation of $CO_2$ in gas field, separation facilities should be installed to add. This is and increase in plant construction cost and separated $CO_2$ emission into the atmosphere is not the result of greenhouse gas reduction. When the uneconomic gas field apply the KOGAS DME process, the gas field containing $CO_2$ can be increase economic feasibility because of natural gas and $CO_2$ can be use to resource gas. The Tri-reformer produced syngas as H2 and CO in KOGAS DME process and the resource gases are natural gas, steam, oxygen and $CO_2$. The $CO_2$ is used as raw material gases from recover $CO_2$ in DME process. In this study, we investigated range of application of $CO_2$ in gas field.

Novel Polyurethane Binder for Propellant based on Hydroxyl-terminated Copolyether (폴리에테르 공중합체 디올(HTPE)을 사용한 새로운 추진제용 폴리우레탄 바인더)

  • Song Jong-Kwon;Pan Xiao;Lee Bum-Jae;Jeon Jun-Pyo;Hwang Gab-Sung
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2005.11a
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    • pp.417-421
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    • 2005
  • Novel two synthetic technics using cationic ring-opening copolymerization of tetrahydrofuran (THF) and ethylene oxide (EO), or just polymerized EO on Poly-THF, could lead to random hydroxyl-terminated poly(EO-ran-THF) or tri-block PEG-PTHF-PEC, respectively. These reactions were carried out using $BF_3O(C_2H_5)_2$ as catalyst, 1,4-butanediol or PTHF as diol initiator. Copolymer structures were controlled by monomer feed ratio, or initial PTHF and EO monomer added amount. The molecular weight of polymer was merely dependant on the ratio of [monomer]/[diol], but not on catalyst. Well-defined random and block hydroxyl-terminated copolyether was found to be as the prepolymer for the propellant binder from the experiment to polyurethane with them.

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The Sensitivity Comparison of Immunodiagnostic Assays for Diagnosing Dengue Fever

  • Zahoor, Muhammad;Bahadar, Haji;Uddin, Salah;Naz, Sumaira
    • Korean Journal of Clinical Laboratory Science
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    • v.48 no.4
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    • pp.275-279
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    • 2016
  • Dengue fever is a vector borne disease caused by a dengue virus. It is an RNA virus of the family flaviviridae, with different serotypes. Herein, we report our attempt to carry out a sensitivity comparison of immunodiagnostic assays for dengue fever in dengue positive patients. Blood samples from 189 volunteers were collected. To determine the sensitivity of the NS1 test, two different types of tests-immunochromatographic tri-line test and rapid dengue test (RDT)-as well as IgM and IgG capture ELISA were performed. The result of RDT has shown that 59.7% of volunteers were IgM positive and 50.2% were IgG positive. Conversely, the results from capture ELISA shows 79.8% and 59.7% for IgM and IgG, respectively. The sensitivity of the capture ELISA test for IgM and IgG was higher than that of immunochromatographic tri-line rapid test, but the specificity was lower. Therefore, to confirm dengue fever, we recommend performing more detailed, investigative tests since a single test may not be sufficient.

A Study on Korean 4-connected Digit Recognition Using Demi-syllable Context-dependent Models (반음절 문맥종속 모델을 이용한 한국어 4 연숫자음 인식에 관한 연구)

  • 이기영;최성호;이호영;배명진
    • The Journal of the Acoustical Society of Korea
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    • v.22 no.3
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    • pp.175-181
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    • 2003
  • Because a word of Korean digits is a syllable and deeply coarticulatied in connected digits, some recognition models based on demisyllables have been proposed by researchers. However, they could not show an excellent recognition results yet. This paper proposes a recognition model based on extended and context-dependent demisyllables, such as a tri-demisyllable like a tri-phone, for the Korean 4-connected digits recognition. For experiments, we use a toolkit of HTK 3.0 for building this model of continuous HMMs using training Korean connected digits from SiTEC database and for recognizing unknown ones. The results show that the recognition rate is 92% and this model has an ability to improve the recognition performance of Korean connected digits.