• Title/Summary/Keyword: Transport layer

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Effects of Polyamidoamine Dendrimers on the Catalytic Layers of a Membrane Electrode Assembly in Fuel Cells

  • Lee Jin Hwa;Won Jongok;Oh In Hwan;Ha Heung Yong;Cho Eun Ae;Kang Yong Soo
    • Macromolecular Research
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    • v.14 no.1
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    • pp.101-106
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    • 2006
  • The transport of reactant gas, electrons and protons at the three phase interfaces in the catalytic layers of membrane electrode assemblies (MEAs) in proton exchange, membrane fuel cells (PEMFCs) must be optimized to provide efficient transport to and from the electrochemical reactions in the solid polymer electrolyte. The aim of reducing proton transport loss in the catalytic layer by increasing the volume of the conducting medium can be achieved by filling the voids in the layer with small-sized electrolytes, such as dendrimers. Generation 1.5 and 3.5 polyamidoamine (PAMAM) dendrimer electrolytes are well-controlled, nanometer-sized materials with many peripheral ionic exchange, -COOH groups and were used for this purpose in this study. The electrochemically active surface area of the deposited catalyst material was also investigated using cyclic voltammetry, and by analyzing the Pt-H oxidation peak. The performances of the fuel cells with added PAMAM dendrimers were found to be comparable to that of a fuel cell using MEA, although the Pt utilization was reduced by the adsorption of the dendrimers to the catalytic layer.

Structure and Vorticity of the Current Observed Across the Western Channel of the Korea Strait in September of 1987-1989

  • Byun, Sang-Kyung;Kaneko, Arata
    • Ocean and Polar Research
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    • v.21 no.2
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    • pp.99-108
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    • 1999
  • With sectional data obtained in September of 1987, 1988 and 1989 by quadrireciprocal ADCP measurement and CTD cast, the current structure, volume transport and vorticity in the Western Channel of the Korea Strait were studied. The characteristics of Tsushima Current water persisted throughout the summer especially in the homogeneous water of temperature $14-16^{\circ}C$ located at the depth of 50-100m below seasonal termocline. Thickness and velocity of the homogeneous layer are about 10-170m and 20-60cm/s. and the relative vorticity for this layer is shown to be nearly constant and it is smaller than the planetary vorticity. Potential vorticity of $2.70-7.10{\times}10^{-6}m^{-1}s^{-1}$ is found to be dependent mainly on planetary rather than on the relative vorticities. The Tsushima Current water represented by the homogeneous layer R14-16^{\circ}C$ may keep the potential vorticity at the area of strong current in the Strait. The ADCP current structure is similar to geostrophic current and the core of the current with the speed of 30-50cm/s is situated in the middle layer over the deep trough. With large tidal fluctuation the volume transport has mean value of 1.17sv which was about 40% larger than that of geostrophic calculation.

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Hierarchical Location Mobility Management using MobilityManagement Points in IP networks

  • Park, Chul Ho;Oh, Sang Yeob
    • Journal of Korea Multimedia Society
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    • v.25 no.8
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    • pp.1069-1074
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    • 2022
  • IP mobility can be handled in different layers of the protocol. Mobile IP has been proposed to handle the mobility of Internet hosts in the network layer. Recently, a new method based on the SIGMA mobility architecture has been proposed to support mobility management with reduced packet loss and latency. The location management structure is not suitable for frequent mobile handover due to the high mobility of the user with this transport layer solution. In this paper, we propose a location management optimization method in a mobile communication network by applying hierarchical location management using MMPs(Mobility Management Points) for transport layer mobility management. Therefore, we propose an efficient hierarchical mobility management structure even between heterogeneous wireless networks using MMPs for the probability that a mobile terminal can change multiple location areas between two messages and calls. The proposed method shows reduction in location update cost and data retrieval cost using MMPs, and as opposed to mobility appearing in time intervals with the minimum cost required to reach 90% of the stabilized cost, the mobility location update search, location It was found that the message processing cost per area was reduced.

Optimization of radiation shields made of Fe and Pb for the spent nuclear fuel transport casks

  • V.G. Rudychev;N.A. Azarenkov;I.O. Girka;Y.V. Rudychev
    • Nuclear Engineering and Technology
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    • v.55 no.2
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    • pp.690-695
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    • 2023
  • Recommendations are given to improve the efficiency of radiation protection of transport casks for SNF transportation. The attenuation of ${\gamma}$-quanta of long-lived isotopes 134Cs, 137mBa(137Cs), 154Eu and 60Co by optimizing the thicknesses and arrangement of layers of Fe and Pb radiation shields of transport casks is studied. The fixed radiation shielding mass (fixed mass thickness) is chosen as the main optimization criterion. The effect of the placement order of Fe and Pb layers in a combined two-layer radiation shield with an equivalent thickness of 30 cm is studied in detail. It is shown that with the same mass thicknesses of the Fe and Pb layers, the placement of Fe in the first layer, and Pb - in the second one provides more than twofold attenuation of ${\gamma}$-quanta compared to the reverse placement: Pb - in the first layer, Fe - in the second. The increase in the efficiency of attenuation of ${\gamma}$-quanta for TC with combined shielding of Fe and Pb is shown to be achieved by designing the first layer of radiation shielding around the canister with SNF from Fe of the maximum possible thickness.

Enhanced Performance of the OLED with Plasma Treated ITO and Plasma Polymerized Methyl Methacrylate Buffer Layer (ITO 플라즈마 표면처리와 ppMMA 버퍼층으로 제작한 OLED의 발광특성)

  • Lim Jae-Sung;Shin Paik-Kvun
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.55 no.1
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    • pp.30-33
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    • 2006
  • Transparent indium tin oxide (ITO) anode surface was modified using $O_3$ Plasma and organic ultrathin buffer layers were deposited on the ITO surface using 13.56 MHz RF plasma polymerization technique. The EL efficiency, operating voltage and lifetime of the organic light-emitting device (OLED) were investigated in order to study the effect of the plasma surface treatment and role of plasma polymerized organic ultrathin buffer layer. Poly methylmethacrylate (PMMA) layers were plasma polymerized on the ITO anode as buffer layer between anode and hole transport layer (HTL). The plasma polymerization of the organic ultrathin layer were carried out at a homemade capacitive-coupled RF plasma equipment. N,N'-diphenyl-N,N'(3- methylphenyl)-1,1'-diphenyl-4,4'-diamine (TPD) as HTL, Tris(8-hydroxyquinolinato) Aluminum $(Alq_3)$ as both emitting layer (EML)/electron transport layer (ETL), and aluminum layer as cathode were deposited using thermal evaporation technique. Effects of the plasma surface treatment of ITO and plasma polymerized buffer layers on the OLED performance were discussed.

Analytical polarization curve of DMFC anode

  • Kulikovsky, A.A.
    • Advances in Energy Research
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    • v.1 no.1
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    • pp.35-52
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    • 2013
  • A model for DMFC anode performance is developed. The model takes into account potential--independent methanol adsorption on the catalyst surface, finite rate of proton transport through the anode catalyst layer (ACL), and a potential loss due to methanol transport in the anode backing layer. An approximate analytical half--cell polarization curve is derived and equations for the anode limiting current density are obtained. The polarization curve is fitted to the curves measured by Nordlund and Lindbergh and parameters resulted from the fitting are discussed.

Low voltage driving red phosphorescent organic light-emitting devices

  • Kim, Tae-Yong;Suh, Won-Gyu;Moon, Dae-Gyu
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.461-464
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    • 2008
  • We have developed low voltage driving red phosphorescent organic light-emitting devices using a new electron transport layer. $Ir(piq)_3$ and CBP were used as a phosphorescent dopant and an emission host, respectively. The device exhibits a luminance of $1000\;cd/m^2$ at a voltage of 2.8 V. This high luminance at low voltage results from a high electron conduction behavior of the new electron transport layer.

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(An HTTP-Based Application Layer Security Protocol for Wireless Internet Services) (무선 인터넷 서비스를 위한 HTTP 기반의 응용 계층 보안 프로토콜)

  • 이동근;김기조;임경식
    • Journal of KIISE:Information Networking
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    • v.30 no.3
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    • pp.377-386
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    • 2003
  • In this paper, we present an application layer protocol to support secure wireless Internet services, called Application Layer Security(ALS). The drawbacks of the two traditional approaches to secure wireless applications motivated the development of ALS. One is that in the conventional application-specific security protocol such as Secure HyperText Transfer Protocol(S-HTTP), security mechanism is included in the application itself. This gives a disadvantage that the security services are available only to that particular application. The other is that a separate protocol layer is inserted between the application and transport layers, as in the Secure Sockets Layer(SSL)/Transport Layer Security(TLS). In this case, all channel data are encrypted regardless of the specific application's requirements, resulting in much waste of network resources. To overcome these problems, ALS is proposed to be implemented on top of HTTP so that it is independent of the various transport layer protocols, and provides a common security interface with security applications so that it greatly improves the portability of security applications. In addition, since ALS takes advantages of well-known TLS mechanism, it eliminates the danger of malicious attack and provides applications with various security services such as authentication, confidentiality integrity and digital signature, and partial encryption. We conclude this paper with an example of applying ALS to the solution of end-to-end security in a present commercial wireless protocol stack, Wireless Application Protocol.

Charge-Carrier Transport Properties and Fluorescence Behaviors Depending on Charge Transport Complex of Organic Photoconductor Containing Liquid Crystal (액정을 함유하는 유기 광도점체의 전하 수송착체에 의한 Charge-Carrier수송 특성과 형광거동)

  • Lee, Bong; Jung, Sung-Young;Moon, Doo-Dyung
    • Polymer(Korea)
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    • v.25 no.5
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    • pp.719-727
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    • 2001
  • Recently it was found that the charge carrier transport properties are significantly enhanced due to effective intermolecular $\pi$-orbital overlapping and low disorder of hopping sites caused by self-organization of liquid crystal molecules. In this study, the xerographic properties of a double-layer photoconductor doped with nematic liquid crystal, 4-pentyl-4'-cyanoterphenyl (5CT), as a charge-carrier transport material to enhance the charge-tarrier mobility were investigated. From the results of measured surface voltage properties for the photoconductor doped with various concentrations of liquid crystal, 5CT, the initial voltage was found to increase with the concentration of 5CT and the dark decay decreased with the concentration of 5CT. The highest sensitivity was obtained at a specific concentration, 40wt% 5CT. The fluorescence behavior of the carrier transport layer (CTL) was also investigated. It was found that the charge-carrier transport properties of the organic photoconductor depend on the charge-carrier transport properties of the complex. The TNF : 5CT (40 wt%) and OXD : 5CT (40 wt%)samples showed the highest sensitivity because the greatest charge transport complex was termed between the charge-carrier transport materials in these samples.

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An End-to-End Mobility Support Mechanism based on mSCTP (mSCTP를 이용한 종단간 이동성 지원 방안)

  • 장문정;이미정;고석주
    • Journal of KIISE:Information Networking
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    • v.31 no.4
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    • pp.393-404
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    • 2004
  • Recently, mSCTP (Mobile SCTP) has been proposed as a transport layer approach for supporting mobility. mSCTP is based on the ‘multi-homing’ feature of Stream Control Transmission Protocol(SCTP), and utilize the functions to dynamically add or delete IP addresses of end points to or from the existing connectionin order to support mobility. In this paper, we propose a mechanism to determine when to add or delete an W address, utilizing the link layer radio signal strength information in order to enhance the performance of mSCTP We also propose a mechanism for a mobile node to initiate the change of data delivery path based on link layer radio signal strength information. In addition, if it takes long time to acquire new data path, we propose an approach for reducing handover latency. The simulation results show that the performance of proposed transport layer mobility support mechanism is competitive compared to the traditional network layer mobility supporting approach. Especially, when the moving speed of mobile node is fast, it shows better performance than the traditional network layer approaches.